In order to get rid of the dependence on high-precision centrifuges in accelerometer nonlinear coefficients calibration,this paper proposes a system-level calibration method for field condition.Firstly,a 42-dimension ...In order to get rid of the dependence on high-precision centrifuges in accelerometer nonlinear coefficients calibration,this paper proposes a system-level calibration method for field condition.Firstly,a 42-dimension Kalman filter is constructed to reduce impact brought by turntable.Then,a biaxial rotation path is designed based on the accelerometer output model,including orthogonal 22 positions and tilt 12 positions,which enhances gravity excitation on nonlinear coefficients of accelerometer.Finally,sampling is carried out for calibration and further experiments.The results of static inertial navigation experiments lasting 4000 s show that compared with the traditional method,the proposed method reduces the position error by about 390 m.展开更多
Aiming at the demand for optimization of hydrodynamic coefficients in submarine's motion equations,an adaptive weight immune genetic algorithm was proposed to optimize hydrodynamic coefficients in motion equations...Aiming at the demand for optimization of hydrodynamic coefficients in submarine's motion equations,an adaptive weight immune genetic algorithm was proposed to optimize hydrodynamic coefficients in motion equations.Some hydrodynamic coefficients of high sensitivity to control and maneuver were chosen as the optimization objects in the algorithm.By using adaptive weight method to determine the weight and target function,the multi-objective optimization could be translated into single-objective optimization.For a certain kind of submarine,three typical maneuvers were chosen to be the objects of study:overshoot maneuver in horizontal plane,overshoot maneuver in vertical plane and turning circle maneuver in horizontal plane.From the results of computer simulations using primal hydrodynamic coefficient and optimized hydrodynamic coefficient,the efficiency of proposed method is proved.展开更多
According to the concept of virtual bending force,a rational explanation for SHOHET's model was presented. Considering the deformation characters of the work rolls in four-high mill,the deformation model of the wo...According to the concept of virtual bending force,a rational explanation for SHOHET's model was presented. Considering the deformation characters of the work rolls in four-high mill,the deformation model of the work roll was regarded as a cantilever beam and new influence coefficients were deduced.The effect of the bending force was taken into account independently. Therefore,the contribution to work roll deflection caused by rolling load,rolling pressure between rolls and bending force can be got from the new formulas.To validate the accuracy of the formulas,the results obtained from the new formulas were compared with those from SHOHET's formulas.It is found that they highly coincide,which illustrates that the formulas are reliable.展开更多
To avoid or reduce the influence of unpredictable motion mode on data association, a new computing method of weighted coefficients of measurements for PDAF is presented in which it is assumed that the current turn rat...To avoid or reduce the influence of unpredictable motion mode on data association, a new computing method of weighted coefficients of measurements for PDAF is presented in which it is assumed that the current turn rate of a maneuvering target changes within a limited range and its turn may be in arbitrary direction during data association. Thus, the predicted center for computing the weighted coefficients is a curved surface in 3-D space, which differs from the predicted center for setting up a validation gate, namely, a point in 3-D space. The distance between a measurement and the curved surface is used to compute its weighted coefficient. To reduce the computational complexity of weighted coefficients, the formulas for computing the maneuvering direction angle and turn rate corresponding to a measurement are presented. Simulation results show the proposed method reduces the percentage of lost tracks and improves the state estimation accuracy in tracking a maneuvering target using PDAF in the presence of clutter.展开更多
The central trinomial coefficient T_(n)denotes the coefficient of x^(n)in the expansion of(1+x+x^(2))^(n).We prove a congruence related to the sums of the central trinomial coefficient and the central binomial coeffic...The central trinomial coefficient T_(n)denotes the coefficient of x^(n)in the expansion of(1+x+x^(2))^(n).We prove a congruence related to the sums of the central trinomial coefficient and the central binomial coefficient,which was conjectured by Z.-W.Sun.展开更多
The Fringe Projection Profilometry(FPP)system with a single exposure time or a single projection intensity is limited by the dynamic range of the camera,which can lead to overexposure and underexposure of the image,re...The Fringe Projection Profilometry(FPP)system with a single exposure time or a single projection intensity is limited by the dynamic range of the camera,which can lead to overexposure and underexposure of the image,resulting in point cloud loss or reduced accuracy.To address this issue,unlike the pixel modulation method of projectors,we utilize the characteristics of color projectors where the intensity of the three-channel LED can be controlled independently.We propose a method for separating the projector's three-channel light intensity,combined with a color camera,to achieve single exposure and multi-intensity image acquisition.Further,the crosstalk coefficient is applied to predict the three-channel reflectance of the measured object.By integrating clustering and channel mapping,we establish a pixel-level mapping model between the projector's three-channel current and the camera's three-channel image intensity,which realizes the optimal projection current prediction and the high dynamic range(HDR)image acquisition.The proposed method allows for high-precision three-dimensional(3D)data acquisition of HDR scenes with a single exposure.The effectiveness of this method has been validated through experiments with standard planes and standard steps,showing a significant reduction in mean absolute error(44.6%)compared to existing singleexposure HDR methods.Additionally,the number of images required for acquisition is significantly reduced(by 70.8%)compared to multi-exposure fusion methods.This proposed method has great potential in various FPP-related fields.展开更多
Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical cha...Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.展开更多
In this paper,a feature selection method for determining input parameters in antenna modeling is proposed.In antenna modeling,the input feature of artificial neural network(ANN)is geometric parameters.The selection cr...In this paper,a feature selection method for determining input parameters in antenna modeling is proposed.In antenna modeling,the input feature of artificial neural network(ANN)is geometric parameters.The selection criteria contain correlation and sensitivity between the geometric parameter and the electromagnetic(EM)response.Maximal information coefficient(MIC),an exploratory data mining tool,is introduced to evaluate both linear and nonlinear correlations.The EM response range is utilized to evaluate the sensitivity.The wide response range corresponding to varying values of a parameter implies the parameter is highly sensitive and the narrow response range suggests the parameter is insensitive.Only the parameter which is highly correlative and sensitive is selected as the input of ANN,and the sampling space of the model is highly reduced.The modeling of a wideband and circularly polarized antenna is studied as an example to verify the effectiveness of the proposed method.The number of input parameters decreases from8 to 4.The testing errors of|S_(11)|and axis ratio are reduced by8.74%and 8.95%,respectively,compared with the ANN with no feature selection.展开更多
The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electro...The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electrolyte,Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3),utilizing cyclic voltammetry and square wave voltammetry techniques.The results show that Fe(Ⅲ)reduction occurs in two steps:Fe(Ⅲ)+e^(−)→Fe(Ⅱ),Fe(Ⅱ)+2e^(−)→Fe,and that the redox process of Fe(Ⅲ)/Fe(Ⅱ)at the tungsten electrode is an irreversible reaction controlled by diffusion.The diffusion coefficients of Fe(Ⅲ)in the molten Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3)in the temperature range of 1248–1278 K are between 1.86×10^(−6)cm^(2)/s and 1.58×10^(−4)cm^(2)/s.The diffusion activation energy of Fe(Ⅲ)in the molten salt is 1825.41 kJ/mol.As confirmed by XRD analysis,potentiostatic electrolysis at−0.857 V(vs.O_(2)/O_(complex)^(2-))for 6 h produces metallic iron on the cathode.展开更多
Water-coupled charge blasting is a promising technique to efficiently break rock masses.In this study,numerical models of double boreholes with water-coupled charge are established using LS-DYNA and are calibrated by ...Water-coupled charge blasting is a promising technique to efficiently break rock masses.In this study,numerical models of double boreholes with water-coupled charge are established using LS-DYNA and are calibrated by the tests of rock masses subjected to explosion loads to examine its performance.The crack levels of rock mass induced by water-coupled charge blasting and air-coupled charge blasting are first compared.It is found that water-coupled charge blasting is more appropriate to fracture deep rock mass than air-coupled charge blasting.In addition,the effects of rock properties,water-coupled charge coefficients,and borehole connection angles on the performance of water-coupled charge blasting are investigated.The results show that rock properties and water-coupled charge coefficients can greatly influence the crack and fragmentation levels of rock mass induced by water-coupled charge blasting under uniform and non-uniform in-situ stresses.However,changing borehole-connection angles can only affect crack and fragmentation levels of rock mass under non-uniform in-situ stresses but barely affect those under uniform in-situ stresses.A formula is finally proposed by considering the above-mentioned factors to provide the design suggestion of water-coupled charge blasting to fracture rock mass with different in-situ stresses.展开更多
Dilatancy is a fundamental volumetric growth behavior observed during loading and serves as a key index to comprehending the intricate nonlinear behavior and constitutive equation structure of rock.This study focuses ...Dilatancy is a fundamental volumetric growth behavior observed during loading and serves as a key index to comprehending the intricate nonlinear behavior and constitutive equation structure of rock.This study focuses on Jinping marble obtained from the Jinping Underground Laboratory in China at a depth of 2400 m.Various uniaxial and triaxial tests at different strain rates,along with constant confining pressure tests and reduced confining pressure tests under different confining pressures were conducted to analyze the mechanical response and dilatancy characteristics of the marble under four stress paths.Subsequently,a new empirical dilatancy coefficient is proposed based on the energy dissipation method.The results show that brittle failure characteristics of marble under uniaxial compression are more obvious with the strain rate increasing,and plastic failure characteristics of marble under triaxial compression are gradually strengthened.Furthermore,compared to the constant confining pressure,the volume expansion is relatively lower under unloading condition.The energy dissipation is closely linked to the process of dilatancy,with a rapid increase of dissipated energy coinciding with the beginning of dilatancy.A new empirical dilatancy coefficient is defined according to the change trend of energy dissipation rate curve,of which change trend is consistent with the actual dilatancy response in marble under different stress paths.The existing empirical and theoretical dilatancy models are analyzed,which shows that the empirical dilatancy coefficient based on the energy background is more universal.展开更多
Ammonium dinitramide(ADN)is a new type of green energetic oxidizer with excellent energy density and low pollution combustion characteristics.However,the strong hygroscopicity has a significant impact on its practical...Ammonium dinitramide(ADN)is a new type of green energetic oxidizer with excellent energy density and low pollution combustion characteristics.However,the strong hygroscopicity has a significant impact on its practical application.To assist in the research on moisture-proof modification of ADN materials,an innovative hygroscopic modeling approach was proposed to evaluate the hygroscopicity of ADN at various temperatures and humidities.By investigating the diffusion coefficient of water molecules in molecular dynamics processes,a visual insight into the hygroscopic process of ADN was gained.Furthermore,analyzing the non-covalent interactions between ADN and water molecules,the hygroscopicity of ADN could be evaluated qualitatively and quantitatively.The energy analysis revealed that electrostatic forces play a dominant role in the process of water adsorption by ADN,whereas van der Waals forces impede it.As a whole,the simulation results show that ADN presents the following hygroscopic law:At temperatures ranging from 273 K to 373 K and relative humidity(RH)from 10%to 100%,the hygroscopicity of ADN generally shows an increasing trend with the rise in temperature and humidity based on the results of three simulations.According to the non-hygroscopic point(298 K,52%RH)of ADN obtained by experiment in the literature,a non-hygroscopic range of temperature and humidity for ADN can be depicted when the simulation results in relative hygroscopicity is less than or equal to 17%.This study can provide effective strategies for screening anti-hygroscopic modified materials of ADN.展开更多
Underground energy and resource development,deep underground energy storage and other projects involve the global stability of multiple interconnected cavern groups under internal and external dynamic disturbances.An ...Underground energy and resource development,deep underground energy storage and other projects involve the global stability of multiple interconnected cavern groups under internal and external dynamic disturbances.An evaluation method of the global stability coefficient of underground caverns based on static overload and dynamic overload was proposed.Firstly,the global failure criterion for caverns was defined based on its band connection of plastic-strain between multi-caverns.Then,overloading calculation of the boundary geostress and seismic intensity on the caverns model was carried out,and the critical unstable state of multi-caverns can be identified,if the plastic-strain band appeared between caverns during these overloading processes.Thus,the global stability coefficient for the multi-caverns under static loading and earthquake was obtained based on the corresponding overloading coefficient.Practical analysis for the Yingliangbao(YLB)hydraulic caverns indicated that this method can not only effectively obtain the global stability coefficient of caverns under static and dynamic earthquake conditions,but also identify the caverns’high-risk zone of local instability through localized plastic strain of surrounding rock.This study can provide some reference for the layout design and seismic optimization of underground cavern group.展开更多
Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics...Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics within NC-based propellants was reported,and its effect on the evolution of mechanical properties was not interpreted yet.This study is conducted to gain a comprehensive understanding of hot-air drying for NC-based propellants and clarify the effect of temperature on solvent transport behavior and further the change of mechanical properties during drying.The drying kinetic curves show the drying time required is decreased but the steady solvent content is increased and the drying rate is obviously increased with the increase of hot-air temperatures,indicating hot-air temperatures have a significant effect on drying kinetics.A modified drying model was established,and results show it is more appropriate to describe solvent transport behavior within NC-based propellants.Moreover,two linear equations were established to exhibit the relationship between solvent content and its effect on the change of tensile properties,and the decrease of residual solvent content causes an obvious increase of tensile strength and tensile modulus of propellant products,indicating its mechanical properties can be partly improved by adjustment of residual solvent content.The outcomes can be used to clarify solvent transport mechanisms and optimize drying process parameters of double-based gun propellants.展开更多
In this paper,we introduce the censored composite conditional quantile coefficient(cC-CQC)to rank the relative importance of each predictor in high-dimensional censored regression.The cCCQC takes advantage of all usef...In this paper,we introduce the censored composite conditional quantile coefficient(cC-CQC)to rank the relative importance of each predictor in high-dimensional censored regression.The cCCQC takes advantage of all useful information across quantiles and can detect nonlinear effects including interactions and heterogeneity,effectively.Furthermore,the proposed screening method based on cCCQC is robust to the existence of outliers and enjoys the sure screening property.Simulation results demonstrate that the proposed method performs competitively on survival datasets of high-dimensional predictors,particularly when the variables are highly correlated.展开更多
Most earth-dam failures are mainly due to seepage,and an accurate assessment of the permeability coefficient provides an indication to avoid a disaster.Parametric uncertainties are encountered in the seepage analysis,...Most earth-dam failures are mainly due to seepage,and an accurate assessment of the permeability coefficient provides an indication to avoid a disaster.Parametric uncertainties are encountered in the seepage analysis,and may be reduced by an inverse procedure that calibrates the simulation results to observations on the real system being simulated.This work proposes an adaptive Bayesian inversion method solved using artificial neural network(ANN)based Markov Chain Monte Carlo simulation.The optimized surrogate model achieves a coefficient of determination at 0.98 by ANN with 247 samples,whereby the computational workload can be greatly reduced.It is also significant to balance the accuracy and efficiency of the ANN model by adaptively updating the sample database.The enrichment samples are obtained from the posterior distribution after iteration,which allows a more accurate and rapid manner to the target posterior.The method was then applied to the hydraulic analysis of an earth dam.After calibrating the global permeability coefficient of the earth dam with the pore water pressure at the downstream unsaturated location,it was validated by the pore water pressure monitoring values at the upstream saturated location.In addition,the uncertainty in the permeability coefficient was reduced,from 0.5 to 0.05.It is shown that the provision of adequate prior information is valuable for improving the efficiency of the Bayesian inversion.展开更多
基金supported by the National Natural Science Foundation of China(42276199).
文摘In order to get rid of the dependence on high-precision centrifuges in accelerometer nonlinear coefficients calibration,this paper proposes a system-level calibration method for field condition.Firstly,a 42-dimension Kalman filter is constructed to reduce impact brought by turntable.Then,a biaxial rotation path is designed based on the accelerometer output model,including orthogonal 22 positions and tilt 12 positions,which enhances gravity excitation on nonlinear coefficients of accelerometer.Finally,sampling is carried out for calibration and further experiments.The results of static inertial navigation experiments lasting 4000 s show that compared with the traditional method,the proposed method reduces the position error by about 390 m.
文摘Aiming at the demand for optimization of hydrodynamic coefficients in submarine's motion equations,an adaptive weight immune genetic algorithm was proposed to optimize hydrodynamic coefficients in motion equations.Some hydrodynamic coefficients of high sensitivity to control and maneuver were chosen as the optimization objects in the algorithm.By using adaptive weight method to determine the weight and target function,the multi-objective optimization could be translated into single-objective optimization.For a certain kind of submarine,three typical maneuvers were chosen to be the objects of study:overshoot maneuver in horizontal plane,overshoot maneuver in vertical plane and turning circle maneuver in horizontal plane.From the results of computer simulations using primal hydrodynamic coefficient and optimized hydrodynamic coefficient,the efficiency of proposed method is proved.
基金Project(20050216007) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘According to the concept of virtual bending force,a rational explanation for SHOHET's model was presented. Considering the deformation characters of the work rolls in four-high mill,the deformation model of the work roll was regarded as a cantilever beam and new influence coefficients were deduced.The effect of the bending force was taken into account independently. Therefore,the contribution to work roll deflection caused by rolling load,rolling pressure between rolls and bending force can be got from the new formulas.To validate the accuracy of the formulas,the results obtained from the new formulas were compared with those from SHOHET's formulas.It is found that they highly coincide,which illustrates that the formulas are reliable.
文摘To avoid or reduce the influence of unpredictable motion mode on data association, a new computing method of weighted coefficients of measurements for PDAF is presented in which it is assumed that the current turn rate of a maneuvering target changes within a limited range and its turn may be in arbitrary direction during data association. Thus, the predicted center for computing the weighted coefficients is a curved surface in 3-D space, which differs from the predicted center for setting up a validation gate, namely, a point in 3-D space. The distance between a measurement and the curved surface is used to compute its weighted coefficient. To reduce the computational complexity of weighted coefficients, the formulas for computing the maneuvering direction angle and turn rate corresponding to a measurement are presented. Simulation results show the proposed method reduces the percentage of lost tracks and improves the state estimation accuracy in tracking a maneuvering target using PDAF in the presence of clutter.
基金National Natural Science Foundation of China(11971222,12071208)Jiangsu Qinglan ProjectProject of Guangzhou Huashang College(2022HSDS27)。
文摘The central trinomial coefficient T_(n)denotes the coefficient of x^(n)in the expansion of(1+x+x^(2))^(n).We prove a congruence related to the sums of the central trinomial coefficient and the central binomial coefficient,which was conjectured by Z.-W.Sun.
文摘The Fringe Projection Profilometry(FPP)system with a single exposure time or a single projection intensity is limited by the dynamic range of the camera,which can lead to overexposure and underexposure of the image,resulting in point cloud loss or reduced accuracy.To address this issue,unlike the pixel modulation method of projectors,we utilize the characteristics of color projectors where the intensity of the three-channel LED can be controlled independently.We propose a method for separating the projector's three-channel light intensity,combined with a color camera,to achieve single exposure and multi-intensity image acquisition.Further,the crosstalk coefficient is applied to predict the three-channel reflectance of the measured object.By integrating clustering and channel mapping,we establish a pixel-level mapping model between the projector's three-channel current and the camera's three-channel image intensity,which realizes the optimal projection current prediction and the high dynamic range(HDR)image acquisition.The proposed method allows for high-precision three-dimensional(3D)data acquisition of HDR scenes with a single exposure.The effectiveness of this method has been validated through experiments with standard planes and standard steps,showing a significant reduction in mean absolute error(44.6%)compared to existing singleexposure HDR methods.Additionally,the number of images required for acquisition is significantly reduced(by 70.8%)compared to multi-exposure fusion methods.This proposed method has great potential in various FPP-related fields.
文摘Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.
基金National Natural Science Foundation of China(62161048)Sichuan Science and Technology Program(2022NSFSC0547,2022ZYD0109)。
文摘In this paper,a feature selection method for determining input parameters in antenna modeling is proposed.In antenna modeling,the input feature of artificial neural network(ANN)is geometric parameters.The selection criteria contain correlation and sensitivity between the geometric parameter and the electromagnetic(EM)response.Maximal information coefficient(MIC),an exploratory data mining tool,is introduced to evaluate both linear and nonlinear correlations.The EM response range is utilized to evaluate the sensitivity.The wide response range corresponding to varying values of a parameter implies the parameter is highly sensitive and the narrow response range suggests the parameter is insensitive.Only the parameter which is highly correlative and sensitive is selected as the input of ANN,and the sampling space of the model is highly reduced.The modeling of a wideband and circularly polarized antenna is studied as an example to verify the effectiveness of the proposed method.The number of input parameters decreases from8 to 4.The testing errors of|S_(11)|and axis ratio are reduced by8.74%and 8.95%,respectively,compared with the ANN with no feature selection.
基金Project(52074084)supported by the National Natural Science Foundation of China。
文摘The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electrolyte,Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3),utilizing cyclic voltammetry and square wave voltammetry techniques.The results show that Fe(Ⅲ)reduction occurs in two steps:Fe(Ⅲ)+e^(−)→Fe(Ⅱ),Fe(Ⅱ)+2e^(−)→Fe,and that the redox process of Fe(Ⅲ)/Fe(Ⅱ)at the tungsten electrode is an irreversible reaction controlled by diffusion.The diffusion coefficients of Fe(Ⅲ)in the molten Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3)in the temperature range of 1248–1278 K are between 1.86×10^(−6)cm^(2)/s and 1.58×10^(−4)cm^(2)/s.The diffusion activation energy of Fe(Ⅲ)in the molten salt is 1825.41 kJ/mol.As confirmed by XRD analysis,potentiostatic electrolysis at−0.857 V(vs.O_(2)/O_(complex)^(2-))for 6 h produces metallic iron on the cathode.
基金Projects(52334003,52104111,52274249)supported by the National Natural Science Foundation of ChinaProject(2022YFC2903901)supported by the National Key R&D Project of ChinaProject(2024JJ4064)supported by the Natural Science Foundation of Hunan Province,China。
文摘Water-coupled charge blasting is a promising technique to efficiently break rock masses.In this study,numerical models of double boreholes with water-coupled charge are established using LS-DYNA and are calibrated by the tests of rock masses subjected to explosion loads to examine its performance.The crack levels of rock mass induced by water-coupled charge blasting and air-coupled charge blasting are first compared.It is found that water-coupled charge blasting is more appropriate to fracture deep rock mass than air-coupled charge blasting.In addition,the effects of rock properties,water-coupled charge coefficients,and borehole connection angles on the performance of water-coupled charge blasting are investigated.The results show that rock properties and water-coupled charge coefficients can greatly influence the crack and fragmentation levels of rock mass induced by water-coupled charge blasting under uniform and non-uniform in-situ stresses.However,changing borehole-connection angles can only affect crack and fragmentation levels of rock mass under non-uniform in-situ stresses but barely affect those under uniform in-situ stresses.A formula is finally proposed by considering the above-mentioned factors to provide the design suggestion of water-coupled charge blasting to fracture rock mass with different in-situ stresses.
基金Project(2022NSFSC0279)supported by the General Project of Sichuan Natural Science Foundation,ChinaProject(Z17113)supported by the Key Scientific Research Fund of Xihua University,ChinaProject(SR21A04)supported by the Research Center for Social Development and Social Risk Control of Sichuan Province,Key Research Base of Philosophy and Social Sciences,Sichuan University,China。
文摘Dilatancy is a fundamental volumetric growth behavior observed during loading and serves as a key index to comprehending the intricate nonlinear behavior and constitutive equation structure of rock.This study focuses on Jinping marble obtained from the Jinping Underground Laboratory in China at a depth of 2400 m.Various uniaxial and triaxial tests at different strain rates,along with constant confining pressure tests and reduced confining pressure tests under different confining pressures were conducted to analyze the mechanical response and dilatancy characteristics of the marble under four stress paths.Subsequently,a new empirical dilatancy coefficient is proposed based on the energy dissipation method.The results show that brittle failure characteristics of marble under uniaxial compression are more obvious with the strain rate increasing,and plastic failure characteristics of marble under triaxial compression are gradually strengthened.Furthermore,compared to the constant confining pressure,the volume expansion is relatively lower under unloading condition.The energy dissipation is closely linked to the process of dilatancy,with a rapid increase of dissipated energy coinciding with the beginning of dilatancy.A new empirical dilatancy coefficient is defined according to the change trend of energy dissipation rate curve,of which change trend is consistent with the actual dilatancy response in marble under different stress paths.The existing empirical and theoretical dilatancy models are analyzed,which shows that the empirical dilatancy coefficient based on the energy background is more universal.
基金supported by the National Natural Science Foundation of China(Grant Nos.22375098,21805139 and 12102194)the Joint Funds of the National Natural Science Foundation of China(Grant No.U2141202)Young Elite Scientists Sponsorship Program by CAST(Grant No.2021QNRC001).
文摘Ammonium dinitramide(ADN)is a new type of green energetic oxidizer with excellent energy density and low pollution combustion characteristics.However,the strong hygroscopicity has a significant impact on its practical application.To assist in the research on moisture-proof modification of ADN materials,an innovative hygroscopic modeling approach was proposed to evaluate the hygroscopicity of ADN at various temperatures and humidities.By investigating the diffusion coefficient of water molecules in molecular dynamics processes,a visual insight into the hygroscopic process of ADN was gained.Furthermore,analyzing the non-covalent interactions between ADN and water molecules,the hygroscopicity of ADN could be evaluated qualitatively and quantitatively.The energy analysis revealed that electrostatic forces play a dominant role in the process of water adsorption by ADN,whereas van der Waals forces impede it.As a whole,the simulation results show that ADN presents the following hygroscopic law:At temperatures ranging from 273 K to 373 K and relative humidity(RH)from 10%to 100%,the hygroscopicity of ADN generally shows an increasing trend with the rise in temperature and humidity based on the results of three simulations.According to the non-hygroscopic point(298 K,52%RH)of ADN obtained by experiment in the literature,a non-hygroscopic range of temperature and humidity for ADN can be depicted when the simulation results in relative hygroscopicity is less than or equal to 17%.This study can provide effective strategies for screening anti-hygroscopic modified materials of ADN.
基金Project(2023YFC2907204)supported by the National Key Research and Development Program of ChinaProject(52325905)supported by the National Natural Science Foundation of ChinaProject(DJ-HXGG-2023-16)supported by the Key Technology Research Projects of Power China。
文摘Underground energy and resource development,deep underground energy storage and other projects involve the global stability of multiple interconnected cavern groups under internal and external dynamic disturbances.An evaluation method of the global stability coefficient of underground caverns based on static overload and dynamic overload was proposed.Firstly,the global failure criterion for caverns was defined based on its band connection of plastic-strain between multi-caverns.Then,overloading calculation of the boundary geostress and seismic intensity on the caverns model was carried out,and the critical unstable state of multi-caverns can be identified,if the plastic-strain band appeared between caverns during these overloading processes.Thus,the global stability coefficient for the multi-caverns under static loading and earthquake was obtained based on the corresponding overloading coefficient.Practical analysis for the Yingliangbao(YLB)hydraulic caverns indicated that this method can not only effectively obtain the global stability coefficient of caverns under static and dynamic earthquake conditions,but also identify the caverns’high-risk zone of local instability through localized plastic strain of surrounding rock.This study can provide some reference for the layout design and seismic optimization of underground cavern group.
基金the National Natural Science Foundation of China(Grant No.22075146).
文摘Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics within NC-based propellants was reported,and its effect on the evolution of mechanical properties was not interpreted yet.This study is conducted to gain a comprehensive understanding of hot-air drying for NC-based propellants and clarify the effect of temperature on solvent transport behavior and further the change of mechanical properties during drying.The drying kinetic curves show the drying time required is decreased but the steady solvent content is increased and the drying rate is obviously increased with the increase of hot-air temperatures,indicating hot-air temperatures have a significant effect on drying kinetics.A modified drying model was established,and results show it is more appropriate to describe solvent transport behavior within NC-based propellants.Moreover,two linear equations were established to exhibit the relationship between solvent content and its effect on the change of tensile properties,and the decrease of residual solvent content causes an obvious increase of tensile strength and tensile modulus of propellant products,indicating its mechanical properties can be partly improved by adjustment of residual solvent content.The outcomes can be used to clarify solvent transport mechanisms and optimize drying process parameters of double-based gun propellants.
基金Outstanding Youth Foundation of Hunan Provincial Department of Education(Grant No.22B0911)。
文摘In this paper,we introduce the censored composite conditional quantile coefficient(cC-CQC)to rank the relative importance of each predictor in high-dimensional censored regression.The cCCQC takes advantage of all useful information across quantiles and can detect nonlinear effects including interactions and heterogeneity,effectively.Furthermore,the proposed screening method based on cCCQC is robust to the existence of outliers and enjoys the sure screening property.Simulation results demonstrate that the proposed method performs competitively on survival datasets of high-dimensional predictors,particularly when the variables are highly correlated.
基金Project(202006430012)supported by the China Scholarship Council。
文摘Most earth-dam failures are mainly due to seepage,and an accurate assessment of the permeability coefficient provides an indication to avoid a disaster.Parametric uncertainties are encountered in the seepage analysis,and may be reduced by an inverse procedure that calibrates the simulation results to observations on the real system being simulated.This work proposes an adaptive Bayesian inversion method solved using artificial neural network(ANN)based Markov Chain Monte Carlo simulation.The optimized surrogate model achieves a coefficient of determination at 0.98 by ANN with 247 samples,whereby the computational workload can be greatly reduced.It is also significant to balance the accuracy and efficiency of the ANN model by adaptively updating the sample database.The enrichment samples are obtained from the posterior distribution after iteration,which allows a more accurate and rapid manner to the target posterior.The method was then applied to the hydraulic analysis of an earth dam.After calibrating the global permeability coefficient of the earth dam with the pore water pressure at the downstream unsaturated location,it was validated by the pore water pressure monitoring values at the upstream saturated location.In addition,the uncertainty in the permeability coefficient was reduced,from 0.5 to 0.05.It is shown that the provision of adequate prior information is valuable for improving the efficiency of the Bayesian inversion.
