The existing theories for closed loop identification with the linear feedback controller are very mature.To apply the existed theories directly in the control field,we propose a new idea about replacing the original u...The existing theories for closed loop identification with the linear feedback controller are very mature.To apply the existed theories directly in the control field,we propose a new idea about replacing the original unknown and nonlinear feedback controller with one approximated linear controller,while guaranteeing the equivalent property for the obtained closed loop system.Based on some statistical correlation functions,one condition is derived to show the equivalent property between the approximated linear controller and the original nonlinear controller.The detailed explicit form,corresponding to the approximated linear controller,is also constructed.Furthermore,to give a complete analysis for closed loop identification,the cost function is rewritten as one extended expression,being convenient to understand.Then spectral estimation is introduced to identify the unknown plant in the closed loop system.Finally,the proposed theories are verified by one simulation example.展开更多
Chain length of closed circle DNA is equal. The same closed circle DNA＇s position corresponds to different recognition sequence, and the same recognition sequence corresponds to different foreign DNA segment, so clos...Chain length of closed circle DNA is equal. The same closed circle DNA＇s position corresponds to different recognition sequence, and the same recognition sequence corresponds to different foreign DNA segment, so closed circle DNA computing model is generalized. For change positive-weighted Hamilton circuit problem, closed circle DNA algorithm is put forward. First, three groups of DNA encoding are encoded for all arcs, and deck groups are designed for all vertices. All possible solutions are composed. Then, the feasible solutions are filtered out by using group detect experiment, and the optimization solutions are obtained by using group insert experiment and electrophoresis experiment. Finally, all optimization solutions are found by using detect experiment. Complexity of algorithm is concluded and validity of DNA algorithm is explained by an example. Three dominances of the closed circle DNA algorithm are analyzed, and characteristics and dominances of group delete experiment are discussed.展开更多
A high-precision shape detecting system of cold rolling strip is developed to meet industrial application, which mainly consists of the shape detecting roller, the collecting ring, the digital signal processing （DSP...A high-precision shape detecting system of cold rolling strip is developed to meet industrial application, which mainly consists of the shape detecting roller, the collecting ring, the digital signal processing （DSP） shape signal processing board and the shape control model. Based on the shape detecting principle, the shape detecting roller is designed with a new integral structure for improving the precision of shape detecting and avoiding scratching strip surface. Based on the DSP technology, the DSP shape signal processing circuit board is designed and embedded in the shape detecting system for the reliability and stability of shape signal processing. The shape detecting system was successfully used in Angang 1 250 mm HC 6-high reversible cold rolling mill. The precision of shape detecting is 0.2 I and the shape deviation is controlled within 6 1 after the close loop shape control is input.展开更多
With a focus on an industrial multivariable system, two subsystems including the flow and the level outputs are analysed and controlled, which have applicability in both real and academic environments. In such a case,...With a focus on an industrial multivariable system, two subsystems including the flow and the level outputs are analysed and controlled, which have applicability in both real and academic environments. In such a case, at first, each subsystem is distinctively represented by its model, since the outcomes point out that the chosen models have the same behavior as corresponding ones. Then, the industrial multivariable system and its presentation are achieved in line with the integration of these subsystems, since the interaction between them can not actually be ignored. To analyze the interaction presented, the Gershgorin bands need to be acquired, where the results are used to modify the system parameters to appropriate values. Subsequently, in the view of modeling results, the control concept in two different techniques including sequential loop closing control(SLCC) scheme and diagonal dominance control(DDC) schemes is proposed to implement on the system through the Profibus network, as long as the OPC(OLE for process control) server is utilized to communicate between the control schemes presented and the multivariable system. The real test scenarios are carried out and the corresponding outcomes in their present forms are acquired. In the same way, the proposed control schemes results are compared with each other, where the real consequences verify the validity of them in the field of the presented industrial multivariable system control.展开更多
Ruptures at the bottom of cartridges are a common cause of failure of ammunitions,which directly threatens the safety of weapons and shooters.Based on plastic tube theory,this study analyses the radial and axial defor...Ruptures at the bottom of cartridges are a common cause of failure of ammunitions,which directly threatens the safety of weapons and shooters.Based on plastic tube theory,this study analyses the radial and axial deformation of a cartridge,considering the radial constraint of the closed end at the bottom of the cartridge.Owing to the influence of the closed end,the bottom of a cartridge does not establish complete contact with the chamber.Owing to strain concentration in the non-contact area,this area is more amenable to the occurrence of cartridge rupture.This theory predicts the location of the fracture more accurately than the traditional theory.The maximum axial deformation of a cartridge comprises bending and friction deformation.The maximum strain at the bottom of the cartridge increased by 135%owing to the introduction of bending strain caused by the closed end.The strain distribution of a cartridge was measured using digital image correlation technology,and the measured result was consistent with the predicted results of the bending deformation theory and rupture case.The effects of wall thickness,radial clearance,friction coefficient,and axial clearance on the axial deformation of the cylinder were studied.Increasing the wall thickness and reducing radial clearance were found to reduce bending deformation;furthermore,lubrication and reduction in axial clearance reduce frictional deformation,which in turn reduce cartridge rupture.展开更多
Using ethanol or acetone as the working fluid, visualization of oscillations in steady state was observed visually by high-speed cameras, and temperature oscillating and heat transfer characteristics of closed-loop pl...Using ethanol or acetone as the working fluid, visualization of oscillations in steady state was observed visually by high-speed cameras, and temperature oscillating and heat transfer characteristics of closed-loop plate oscillating heat pipe with parallel channels(POHP-PC) were experimentally investigated by varying liquid filled ratios(50%, 70%, 85%), section scales(1 mm×1 mm and 1 mm×1.5 mm), inclination angles, working fluids and heating inputs. It was found that during operating there was mixed flow consisting of plug flow and annular flow in channels of oscillating heat pipe at steady-state. There was an equilibrium position for working fluid of condenser during oscillating, and periodic oscillations occurred up and down in the vicinity of equilibrium position. With heat input increasing, equilibrium position rose slowly as a result of vapor pressure of evaporation.Evaporation temperature oscillating amplitude possessed a trend of small-large-small and frequency trend was of small-large during steady-state. It may be generally concluded that temperature, whether evaporator or condenser, fluctuated sharply or rose continuously when oscillating heat pipe coming to dry burning state. Simultaneously, it was found that temperature difference of cooling water possibly dropped with heat input rising during dry burning state. Thermal resistance of No. 2 with acetone was lower than that of No. 1 during experiments, but No. 2 achieving heat transfer limit was earlier than No. 1. However, with ethanol, thermal resistance of No. 1 and No. 2 were similar with the heating input less than 110-120 W and filling ratios of 50% and 70%. And with filling ratio of 85%, heating transfer performance of No. 2 was better compared to No. 1 during all the experiments.展开更多
The closed loop control model was built up for compensating the springback and enhancing the work piece precision.A coupled closed loop algorithm and a finite element method were developed to simulate and correct the ...The closed loop control model was built up for compensating the springback and enhancing the work piece precision.A coupled closed loop algorithm and a finite element method were developed to simulate and correct the springback of incremental sheet forming.A three-dimensional finite element model was established for simulation of springback in incremental sheet forming process.The closed loop algorithm of trajectory profile for the incremental sheet forming based on the wavelet transform combined with fast Fourier transform was constructed.The profile of processing tool path of shallow dishing with spherical surface was designed on the basis of the profile correction algorithm.The result shows that the algorithm can predict an ideal profile of processing track,and the springback error of incremental sheet forming is eliminated effectively.It has good convergence efficiency,and can improve the workpiece dimensional accuracy greatly.展开更多
The problem of robust stabilization for nonlinear systems with partially known uncertainties is considered in this paper. The required information about uncertainties in the system is merely that the uncertainties are...The problem of robust stabilization for nonlinear systems with partially known uncertainties is considered in this paper. The required information about uncertainties in the system is merely that the uncertainties are bounded, but the upper bounds are incompletely known. This paper can be viewed as an extension of the work in reference [1]. To compensate the uncertainties, an adaptive robust controller based on Lyapunov method is proposed and the design algorithm is also suggested. Compared with some previous controllers which can only ensure ultimate uniform boundedness of the systems, the controller given in the paper can make sure that the obtained closed-loop system is asymptotically stable in the large. Simulations show that the method presented is available and effective.展开更多
This paper presents the results of a comparative investigation into the effects of the ignition method on the ballistic properties of a single-base gun propellant,as determined via closed vessel tests.Conventional gun...This paper presents the results of a comparative investigation into the effects of the ignition method on the ballistic properties of a single-base gun propellant,as determined via closed vessel tests.Conventional gunpowder ignition and plasma jet ignition methods were used,and differences in the ignition time were analysed.The influence of the ignition method on the dynamic vivacity is discussed.It is shown that this influence is significant in the first phase of the combustion process,and with respect to the low values of the loading density.In the second phase of the combustion process,and for large values of the loading density,the dynamic vivacity plots for the two ignition methods converge.Regarding the burning law,close values of the exponent were obtained for the two ignition methods.The dynamic vivacity plots determined for plasma ignition reveal stronger dependence on the loading density than those determined for gunpowder ignition.The conclusion is that plasma ignition is not a solution to the problems inherent to the process of determining the ballistic properties of propellants,which results in deviation of the burning process from the geometric burning law.展开更多
This paper focuses on the H∞ controller design for linear systems with time-varying delays and norm-bounded parameter perturbations in the system state and control/disturbance. On the existence of delayed/undelayed f...This paper focuses on the H∞ controller design for linear systems with time-varying delays and norm-bounded parameter perturbations in the system state and control/disturbance. On the existence of delayed/undelayed full state feedback controllers, we present a sufficient condition and give a design method in the form of Riccati equation. The controller can not only stabilize the time-delay system, but also make the H∞ norm of the closed-loop system be less than a given bound. This result practically generalizes the related results in current literature.展开更多
The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a ...The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a way to regulate the closed pore structure and improve the rate capability of HC by the addition of graphene oxide using an emulsification process.In a non-emulsion system,graphene oxide not only shortens ion diffusion paths by inducing the formation of flakelike HC but also significantly improves the rate performance by serving as conductive bridges within the carbon matrix.The prepared graphene/phenolic resin carbon composite has reversible capacities of 362,340,319,274,119,86,69 and 48 mAh g^(−1)at current densities of 0.02,0.05,0.1,0.2,0.5,1,2 and 5 A g^(−1),respectively.When emulsification is introduced,the graphene oxide acts as a nano-confinement template,guiding the cross-linking of phenolic resin to form uniformly sized closed pores.This composite electrode material has the highest plateau capacity of 268 mAh g^(−1)at 20 mA g^(−1).展开更多
The advantages of sodium-ion batteries(SIBs)for large-scale energy storage are well known.Among possible anode materials,hard carbon(HC)stands out as the most viable commercial option because of its superior performan...The advantages of sodium-ion batteries(SIBs)for large-scale energy storage are well known.Among possible anode materials,hard carbon(HC)stands out as the most viable commercial option because of its superior performance.However,there is still disagreement regarding the sodium storage mechanism in the low-voltage plateau region of HC anodes,and the structure-performance relationship between its complex multiscale micro/nanostructure and electrochemical behavior remains unclear.This paper summarizes current research progress and the major problems in understanding HC’s microstructure and sodium storage mechanism,and the relationship between them.Findings about a universal sodium storage mechanism in HC,including predictions about micropore-capacity relationships,and the opportunities and challenges for using HC anodes in commercial SIBs are presented.展开更多
Biomass-derived hard carbons,usually prepared by pyrolysis,are widely considered the most promising anode materials for sodium-ion bat-teries(SIBs)due to their high capacity,low poten-tial,sustainability,cost-effectiv...Biomass-derived hard carbons,usually prepared by pyrolysis,are widely considered the most promising anode materials for sodium-ion bat-teries(SIBs)due to their high capacity,low poten-tial,sustainability,cost-effectiveness,and environ-mental friendliness.The pyrolysis method affects the microstructure of the material,and ultimately its so-dium storage performance.Our previous work has shown that pyrolysis in a sealed graphite vessel im-proved the sodium storage performance of the car-bon,however the changes in its microstructure and the way this influences the sodium storage are still unclear.A series of hard carbon materials derived from corncobs(CCG-T,where T is the pyrolysis temperature)were pyrolyzed in a sealed graphite vessel at different temperatures.As the pyrolysis temperature increased from 1000 to 1400℃ small carbon domains gradually transformed into long and curved domains.At the same time,a greater number of large open pores with uniform apertures,as well as more closed pores,were formed.With the further increase of pyrolysis temperature to 1600℃,the long and curved domains became longer and straighter,and some closed pores gradually became open.CCG-1400,with abundant closed pores,had a superior SIB performance,with an initial reversible ca-pacity of 320.73 mAh g^(-1) at a current density of 30 mA g^(-1),an initial Coulomb efficiency(ICE)of 84.34%,and a capacity re-tention of 96.70%after 100 cycles.This study provides a method for the precise regulation of the microcrystalline and pore structures of hard carbon materials.展开更多
This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This researc...This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This research examines the flow of a three-layered viscous fluid,considering the combined influence of heat and solutal buoyancy driven Rayleigh-Bénard convection,as well as thermal and solutal Marangoni convection.The homotopy perturbation method is used to examine and simulate complex fluid flow and transport phenomena,providing important understanding of the fundamental physics and assisting in the optimization of various battery configurations.The inquiry examines the primary elements that influence Marangoni convection and its impact on battery performance,providing insights on possible enhancements in energy storage devices.The findings indicate that the velocity profiles shown graphically exhibit a prominent core zone characterized by the maximum speed,which progressively decreases as it approaches the walls of the channel.This study enhances our comprehension of fluid dynamics and the transmission of heat and mass in intricate systems,which has substantial ramifications for the advancement of sustainable energy solutions.展开更多
This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and sil...This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and silicon-based delay compositions,using thermodynamic software.A multiphase flowthermal-solid coupling model was established,and the combustion process of the pyrotechnic charges within a closed bomb was simulated.The pyrotechnic shock generated by combustion was predicted.The combustion pressures and pyrotechnic shocks were measured.The simulation results demonstrated good agreement with experimental results.Additionally,the mechanism of shock generation by the combustion of pyrotechnic charges in the closed bomb was analyzed.The effects of the combustion characteristics of the pyrotechnic charges on the resulting pyrotechnic shocks were systematically investigated.Notably,the shock response spectrum of the gas-generating pyrotechnic charges is greater than that of the micro gas compositions at most frequencies,particularly in the mid-field pyrotechnic shocks(3-10 kHz).Furthermore,the pyrotechnic shocks increase approximately linearly with the impulse of the gas-generating pyrotechnic charges.展开更多
文摘The existing theories for closed loop identification with the linear feedback controller are very mature.To apply the existed theories directly in the control field,we propose a new idea about replacing the original unknown and nonlinear feedback controller with one approximated linear controller,while guaranteeing the equivalent property for the obtained closed loop system.Based on some statistical correlation functions,one condition is derived to show the equivalent property between the approximated linear controller and the original nonlinear controller.The detailed explicit form,corresponding to the approximated linear controller,is also constructed.Furthermore,to give a complete analysis for closed loop identification,the cost function is rewritten as one extended expression,being convenient to understand.Then spectral estimation is introduced to identify the unknown plant in the closed loop system.Finally,the proposed theories are verified by one simulation example.
基金supported by the National Natural Science Foundation of China(60574041)the Natural ScienceFoundation of Hubei Province(2007ABA407).
文摘Chain length of closed circle DNA is equal. The same closed circle DNA＇s position corresponds to different recognition sequence, and the same recognition sequence corresponds to different foreign DNA segment, so closed circle DNA computing model is generalized. For change positive-weighted Hamilton circuit problem, closed circle DNA algorithm is put forward. First, three groups of DNA encoding are encoded for all arcs, and deck groups are designed for all vertices. All possible solutions are composed. Then, the feasible solutions are filtered out by using group detect experiment, and the optimization solutions are obtained by using group insert experiment and electrophoresis experiment. Finally, all optimization solutions are found by using detect experiment. Complexity of algorithm is concluded and validity of DNA algorithm is explained by an example. Three dominances of the closed circle DNA algorithm are analyzed, and characteristics and dominances of group delete experiment are discussed.
基金Foundation item: Project(2009AA04Z143) supported by the National High Technology Research and Development Program of ChinaProject (E2011203004) supported by Natural Science Foundation of Hebei Province, ChinaProjects(2011BAF15B03, 2011BAF15B02) supported by the National Science Plan of China
文摘A high-precision shape detecting system of cold rolling strip is developed to meet industrial application, which mainly consists of the shape detecting roller, the collecting ring, the digital signal processing （DSP） shape signal processing board and the shape control model. Based on the shape detecting principle, the shape detecting roller is designed with a new integral structure for improving the precision of shape detecting and avoiding scratching strip surface. Based on the DSP technology, the DSP shape signal processing circuit board is designed and embedded in the shape detecting system for the reliability and stability of shape signal processing. The shape detecting system was successfully used in Angang 1 250 mm HC 6-high reversible cold rolling mill. The precision of shape detecting is 0.2 I and the shape deviation is controlled within 6 1 after the close loop shape control is input.
文摘With a focus on an industrial multivariable system, two subsystems including the flow and the level outputs are analysed and controlled, which have applicability in both real and academic environments. In such a case, at first, each subsystem is distinctively represented by its model, since the outcomes point out that the chosen models have the same behavior as corresponding ones. Then, the industrial multivariable system and its presentation are achieved in line with the integration of these subsystems, since the interaction between them can not actually be ignored. To analyze the interaction presented, the Gershgorin bands need to be acquired, where the results are used to modify the system parameters to appropriate values. Subsequently, in the view of modeling results, the control concept in two different techniques including sequential loop closing control(SLCC) scheme and diagonal dominance control(DDC) schemes is proposed to implement on the system through the Profibus network, as long as the OPC(OLE for process control) server is utilized to communicate between the control schemes presented and the multivariable system. The real test scenarios are carried out and the corresponding outcomes in their present forms are acquired. In the same way, the proposed control schemes results are compared with each other, where the real consequences verify the validity of them in the field of the presented industrial multivariable system control.
基金The authors are grateful for the reviewers’instructive suggestions and careful proofreading.This work was supported by the Equipment Development Department of the Central Military Commission of China(grant nos.301090702)the Foundation of National Laboratory(grant nos.61426060102162606005 and JCKYS2019209C001).
文摘Ruptures at the bottom of cartridges are a common cause of failure of ammunitions,which directly threatens the safety of weapons and shooters.Based on plastic tube theory,this study analyses the radial and axial deformation of a cartridge,considering the radial constraint of the closed end at the bottom of the cartridge.Owing to the influence of the closed end,the bottom of a cartridge does not establish complete contact with the chamber.Owing to strain concentration in the non-contact area,this area is more amenable to the occurrence of cartridge rupture.This theory predicts the location of the fracture more accurately than the traditional theory.The maximum axial deformation of a cartridge comprises bending and friction deformation.The maximum strain at the bottom of the cartridge increased by 135%owing to the introduction of bending strain caused by the closed end.The strain distribution of a cartridge was measured using digital image correlation technology,and the measured result was consistent with the predicted results of the bending deformation theory and rupture case.The effects of wall thickness,radial clearance,friction coefficient,and axial clearance on the axial deformation of the cylinder were studied.Increasing the wall thickness and reducing radial clearance were found to reduce bending deformation;furthermore,lubrication and reduction in axial clearance reduce frictional deformation,which in turn reduce cartridge rupture.
基金Project(51306198)supported by the National Natural Science Foundation of ChinaProject(NR2013K07)supported by Beijing Key Lab of Heating,Gas Supply,Ventilating and Air Conditioning Engineering,China+1 种基金Project(331614013)supported by Beijing University of Civil Engineering and Architecture,ChinaProject(00921915023)supported by Organization Department of Beijing,China
文摘Using ethanol or acetone as the working fluid, visualization of oscillations in steady state was observed visually by high-speed cameras, and temperature oscillating and heat transfer characteristics of closed-loop plate oscillating heat pipe with parallel channels(POHP-PC) were experimentally investigated by varying liquid filled ratios(50%, 70%, 85%), section scales(1 mm×1 mm and 1 mm×1.5 mm), inclination angles, working fluids and heating inputs. It was found that during operating there was mixed flow consisting of plug flow and annular flow in channels of oscillating heat pipe at steady-state. There was an equilibrium position for working fluid of condenser during oscillating, and periodic oscillations occurred up and down in the vicinity of equilibrium position. With heat input increasing, equilibrium position rose slowly as a result of vapor pressure of evaporation.Evaporation temperature oscillating amplitude possessed a trend of small-large-small and frequency trend was of small-large during steady-state. It may be generally concluded that temperature, whether evaporator or condenser, fluctuated sharply or rose continuously when oscillating heat pipe coming to dry burning state. Simultaneously, it was found that temperature difference of cooling water possibly dropped with heat input rising during dry burning state. Thermal resistance of No. 2 with acetone was lower than that of No. 1 during experiments, but No. 2 achieving heat transfer limit was earlier than No. 1. However, with ethanol, thermal resistance of No. 1 and No. 2 were similar with the heating input less than 110-120 W and filling ratios of 50% and 70%. And with filling ratio of 85%, heating transfer performance of No. 2 was better compared to No. 1 during all the experiments.
基金Project(50175034) supported by the National Natural Science Foundation of China
文摘The closed loop control model was built up for compensating the springback and enhancing the work piece precision.A coupled closed loop algorithm and a finite element method were developed to simulate and correct the springback of incremental sheet forming.A three-dimensional finite element model was established for simulation of springback in incremental sheet forming process.The closed loop algorithm of trajectory profile for the incremental sheet forming based on the wavelet transform combined with fast Fourier transform was constructed.The profile of processing tool path of shallow dishing with spherical surface was designed on the basis of the profile correction algorithm.The result shows that the algorithm can predict an ideal profile of processing track,and the springback error of incremental sheet forming is eliminated effectively.It has good convergence efficiency,and can improve the workpiece dimensional accuracy greatly.
文摘The problem of robust stabilization for nonlinear systems with partially known uncertainties is considered in this paper. The required information about uncertainties in the system is merely that the uncertainties are bounded, but the upper bounds are incompletely known. This paper can be viewed as an extension of the work in reference [1]. To compensate the uncertainties, an adaptive robust controller based on Lyapunov method is proposed and the design algorithm is also suggested. Compared with some previous controllers which can only ensure ultimate uniform boundedness of the systems, the controller given in the paper can make sure that the obtained closed-loop system is asymptotically stable in the large. Simulations show that the method presented is available and effective.
基金supported by the National Research Centre,Poland [grant number DOB-BIO8/05/01/2016]the Ministry of Defence of Poland [grant number GBMON/13-988/2018/WAT]
文摘This paper presents the results of a comparative investigation into the effects of the ignition method on the ballistic properties of a single-base gun propellant,as determined via closed vessel tests.Conventional gunpowder ignition and plasma jet ignition methods were used,and differences in the ignition time were analysed.The influence of the ignition method on the dynamic vivacity is discussed.It is shown that this influence is significant in the first phase of the combustion process,and with respect to the low values of the loading density.In the second phase of the combustion process,and for large values of the loading density,the dynamic vivacity plots for the two ignition methods converge.Regarding the burning law,close values of the exponent were obtained for the two ignition methods.The dynamic vivacity plots determined for plasma ignition reveal stronger dependence on the loading density than those determined for gunpowder ignition.The conclusion is that plasma ignition is not a solution to the problems inherent to the process of determining the ballistic properties of propellants,which results in deviation of the burning process from the geometric burning law.
基金This project was supported by the National Natural Science Foundation of China (No. 69974022).
文摘This paper focuses on the H∞ controller design for linear systems with time-varying delays and norm-bounded parameter perturbations in the system state and control/disturbance. On the existence of delayed/undelayed full state feedback controllers, we present a sufficient condition and give a design method in the form of Riccati equation. The controller can not only stabilize the time-delay system, but also make the H∞ norm of the closed-loop system be less than a given bound. This result practically generalizes the related results in current literature.
文摘The demand for high-energy-density sodium-ion batteries has driven research to increase the hard carbon(HC)plateau capacity(<0.1 V),but the plateau capacity-rate capability trade-off limits performance.We report a way to regulate the closed pore structure and improve the rate capability of HC by the addition of graphene oxide using an emulsification process.In a non-emulsion system,graphene oxide not only shortens ion diffusion paths by inducing the formation of flakelike HC but also significantly improves the rate performance by serving as conductive bridges within the carbon matrix.The prepared graphene/phenolic resin carbon composite has reversible capacities of 362,340,319,274,119,86,69 and 48 mAh g^(−1)at current densities of 0.02,0.05,0.1,0.2,0.5,1,2 and 5 A g^(−1),respectively.When emulsification is introduced,the graphene oxide acts as a nano-confinement template,guiding the cross-linking of phenolic resin to form uniformly sized closed pores.This composite electrode material has the highest plateau capacity of 268 mAh g^(−1)at 20 mA g^(−1).
文摘The advantages of sodium-ion batteries(SIBs)for large-scale energy storage are well known.Among possible anode materials,hard carbon(HC)stands out as the most viable commercial option because of its superior performance.However,there is still disagreement regarding the sodium storage mechanism in the low-voltage plateau region of HC anodes,and the structure-performance relationship between its complex multiscale micro/nanostructure and electrochemical behavior remains unclear.This paper summarizes current research progress and the major problems in understanding HC’s microstructure and sodium storage mechanism,and the relationship between them.Findings about a universal sodium storage mechanism in HC,including predictions about micropore-capacity relationships,and the opportunities and challenges for using HC anodes in commercial SIBs are presented.
文摘Biomass-derived hard carbons,usually prepared by pyrolysis,are widely considered the most promising anode materials for sodium-ion bat-teries(SIBs)due to their high capacity,low poten-tial,sustainability,cost-effectiveness,and environ-mental friendliness.The pyrolysis method affects the microstructure of the material,and ultimately its so-dium storage performance.Our previous work has shown that pyrolysis in a sealed graphite vessel im-proved the sodium storage performance of the car-bon,however the changes in its microstructure and the way this influences the sodium storage are still unclear.A series of hard carbon materials derived from corncobs(CCG-T,where T is the pyrolysis temperature)were pyrolyzed in a sealed graphite vessel at different temperatures.As the pyrolysis temperature increased from 1000 to 1400℃ small carbon domains gradually transformed into long and curved domains.At the same time,a greater number of large open pores with uniform apertures,as well as more closed pores,were formed.With the further increase of pyrolysis temperature to 1600℃,the long and curved domains became longer and straighter,and some closed pores gradually became open.CCG-1400,with abundant closed pores,had a superior SIB performance,with an initial reversible ca-pacity of 320.73 mAh g^(-1) at a current density of 30 mA g^(-1),an initial Coulomb efficiency(ICE)of 84.34%,and a capacity re-tention of 96.70%after 100 cycles.This study provides a method for the precise regulation of the microcrystalline and pore structures of hard carbon materials.
基金Project(52276068)supported by the National Natural Science Foundation of China。
文摘This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This research examines the flow of a three-layered viscous fluid,considering the combined influence of heat and solutal buoyancy driven Rayleigh-Bénard convection,as well as thermal and solutal Marangoni convection.The homotopy perturbation method is used to examine and simulate complex fluid flow and transport phenomena,providing important understanding of the fundamental physics and assisting in the optimization of various battery configurations.The inquiry examines the primary elements that influence Marangoni convection and its impact on battery performance,providing insights on possible enhancements in energy storage devices.The findings indicate that the velocity profiles shown graphically exhibit a prominent core zone characterized by the maximum speed,which progressively decreases as it approaches the walls of the channel.This study enhances our comprehension of fluid dynamics and the transmission of heat and mass in intricate systems,which has substantial ramifications for the advancement of sustainable energy solutions.
文摘This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and silicon-based delay compositions,using thermodynamic software.A multiphase flowthermal-solid coupling model was established,and the combustion process of the pyrotechnic charges within a closed bomb was simulated.The pyrotechnic shock generated by combustion was predicted.The combustion pressures and pyrotechnic shocks were measured.The simulation results demonstrated good agreement with experimental results.Additionally,the mechanism of shock generation by the combustion of pyrotechnic charges in the closed bomb was analyzed.The effects of the combustion characteristics of the pyrotechnic charges on the resulting pyrotechnic shocks were systematically investigated.Notably,the shock response spectrum of the gas-generating pyrotechnic charges is greater than that of the micro gas compositions at most frequencies,particularly in the mid-field pyrotechnic shocks(3-10 kHz).Furthermore,the pyrotechnic shocks increase approximately linearly with the impulse of the gas-generating pyrotechnic charges.
