This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and sil...This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and silicon-based delay compositions,using thermodynamic software.A multiphase flowthermal-solid coupling model was established,and the combustion process of the pyrotechnic charges within a closed bomb was simulated.The pyrotechnic shock generated by combustion was predicted.The combustion pressures and pyrotechnic shocks were measured.The simulation results demonstrated good agreement with experimental results.Additionally,the mechanism of shock generation by the combustion of pyrotechnic charges in the closed bomb was analyzed.The effects of the combustion characteristics of the pyrotechnic charges on the resulting pyrotechnic shocks were systematically investigated.Notably,the shock response spectrum of the gas-generating pyrotechnic charges is greater than that of the micro gas compositions at most frequencies,particularly in the mid-field pyrotechnic shocks(3-10 kHz).Furthermore,the pyrotechnic shocks increase approximately linearly with the impulse of the gas-generating pyrotechnic charges.展开更多
Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical cha...Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.展开更多
The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experim...The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.展开更多
To explore the design criteria for composite charges and reveal the intrinsic relationship between the detonation wave propagation in composite charges and the overall energy distribution of shock waves,this study ana...To explore the design criteria for composite charges and reveal the intrinsic relationship between the detonation wave propagation in composite charges and the overall energy distribution of shock waves,this study analyzes the propagation and interaction processes of detonation waves in composite charges with different structural dimensions and explosive combinations. It also investigates the spatial distribution characteristics of the resulting shock wave loads. Based on dimensional analysis theory, a theoretical analysis of the shock wave overpressure distribution in free air fields is conducted. Utilizing the derived dimensionless function relationships, the hydrocode AUTODYN is employed to investigate the effects of charge structure parameters and explosive combinations on the internal overdriven detonation phenomena and the distribution of shock wave loads. It is found that the overdriven detonation phenomenon in the inner layer of composite charges increases the strength of the axial detonation wave,thereby enhancing the intensity of the primary end wave formed upon refraction into the air, which affects the distribution characteristics of the shock wave overpressure. Research has shown that increasing the thickness ratio and detonation velocity ratio of composite charges is beneficial for exacerbating the phenomenon of overdriven detonation, improving the primary end wave intensity and axial overpressure. This gain effect gradually weakens with the propagation of shock waves. When overdriven detonation occurs inside the composite charge, the detonation pressure first increases and then decreases. The Mach reflection pressure of the composite charge with a larger aspect ratio is attenuated to a greater extent. In addition, as the aspect ratio of the composite charge increases, the shock wave energy gradually flows from the axial direction to the radial direction. Therefore, as the aspect ratio of the composite charge increases, the primary end wave intensity and axial overpressure gradually decrease.展开更多
To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based sim...To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based simulation(NNS)method with higher accuracy and better efficiency was proposed.The NNS method consisted of three main steps.First,the parameters of blast loads,including the peak pressures and impulses of cylindrical charges with different aspect ratios(L/D)at different stand-off distances and incident angles were obtained by two-dimensional numerical simulations.Subsequently,incident shape factors of cylindrical charges with arbitrary aspect ratios were predicted by a neural network.Finally,reflected shape factors were derived and implemented into the subroutine of the ABAQUS code to modify the CONWEP model,including modifications of impulse and overpressure.The reliability of the proposed NNS method was verified by related experimental results.Remarkable accuracy improvement was acquired by the proposed NNS method compared with the unmodified CONWEP model.Moreover,huge efficiency superiority was obtained by the proposed NNS method compared with the CEL method.The proposed NNS method showed good accuracy when the scaled distance was greater than 0.2 m/kg^(1/3).It should be noted that there is no need to generate a new dataset again since the blast loads satisfy the similarity law,and the proposed NNS method can be directly used to simulate the blast loads generated by different cylindrical charges.The proposed NNS method with high efficiency and accuracy can be used as an effective method to analyze the dynamic response of structures under blast loads,and it has significant application prospects in designing protective structures.展开更多
A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small sphe...A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small spherical explosive charge generated in rock, is used to further study the triggering time of strain gauges installed in radial direction at same distances but different positions surrounding a cylindrical explosive charge in rock. The duration of the first compression phase and peak value of strain wave, and furthermore, their differences are analyzed and some explanations are given. Besides that, the gauge orientation in which the maximum peak value occurs is also discussed. At last, the effect of velocity of detonation(V.O.D.) of a cylindrical explosive charge on the strain waves generated in the surrounding rock is taken as key research and the pattern of peak amplitude of a strain wave varies with the V.O.D. is likely to have been found.展开更多
In current guidelines, the free air blast loads(overpressure and impulse) are determined by spherical charges, although most of ordnance devices are more nearly cylindrical than spherical in geometry. This may result ...In current guidelines, the free air blast loads(overpressure and impulse) are determined by spherical charges, although most of ordnance devices are more nearly cylindrical than spherical in geometry. This may result in a great underestimation of blast loads in the near field and lead to an unsafe design.However, there is still a lack of systematic quantitative analysis of the blast loads generated from cylindrical charges. In this study, a numerical model is developed by using the hydrocode AUTODYN to investigate the influences of aspect ratio and orientation on the free air blast loads generated from center-initiated cylindrical charges. This is done by examining the pressure contours, the peak overpressures and impulses for various aspect ratios ranged from 1 to 8 and arbitrary orientation monitored along every azimuth angle with an interval of 5°. To characterize the distribution patterns of blast loads,three regions, i.e., the axial region, the vertex region and the radial region are identified, and the propagation of blast waves in each region is analyzed in detail. The complexity of blast loads of cylindrical charges is found to result from the bridge wave and its interaction with primary waves. Several empirical formulas are presented based on curve-fitting the numerical data, including the orientation where the maximum peak overpressure emerges, the critical scaled distance beyond which the charge shape effect could be neglected and blast loads with varied aspect ratio in arbitrary orientation, all of which are useful for blast-resistant design.展开更多
The photoconversion of CO_(2) to carbon-containing fuels,splitting water into H_(2),selective organic synthesis,reduction of N_(2) to NH3,and hazardous organic contaminant degradation represent feasible schemes for so...The photoconversion of CO_(2) to carbon-containing fuels,splitting water into H_(2),selective organic synthesis,reduction of N_(2) to NH3,and hazardous organic contaminant degradation represent feasible schemes for solving environmental and energy issues.In 1972,TiO_(2) was applied for decomposing water into H_(2) and O_(2) via photocatalysis.Owing to its the low visible-light utilization,fast charge recombination,and high energy barrier for water oxidation,overall photocatalytic water-splitting efficiency is extremely low.Because H_(2) is more economically valuable than O_(2),sacrificial agent-assisted photocatalytic H_(2) evolution has been extensively investigated.Because the sacrificial agent can quickly consume photoexcited holes and effectively reduce the water oxidation energy barrier,photocatalytic H_(2) evolution efficiency can be increased by 3-4 orders of magnitude compared to photocatalytic water splitting.However,the overuse of sacrificial agents contributes to wasted photoexcited holes and expensive processes,while presenting potential environmental issues.Recently,overall charge utilization and improved redox efficiency have been achieved by coupling photocatalytic reduction with oxidation reactions.Moreover,overall charge utilization can boost charge separation and increase photocatalyst durability.However,the photocatalytic mechanism of the overall redox reactions remains unclear,owing to the complex reaction processes and design difficulties.Herein,the basic principles of photocatalysis are discussed from the perspective of light harvesting,photoexcited charge separation,thermodynamics,and redox reaction kinetics.Photocatalytic redox reactions,including overall water photodecomposition,photocatalytic H_(2) evolution coupled with organic oxidation,photocatalytic CO_(2) reduction coupled with organic oxidation,photocatalytic H_(2)O_(2) production coupled with organic oxidation,photocatalytic N_(2) reduction coupled with N_(2) oxidation,and photocatalytic organic reduction coupled with organic oxidation,can be systematically classified according to the coupling of photocatalytic oxidation reactions with photocatalytic reduction reactions.Subsequently,the design of photocatalytic redox reactions is considered in terms of the modulation of photocatalyst materials,reaction conditions,and diversity of reactants and products.In addition,the vital role of density functional theory(DFT)calculations for unveiling photoexcited charge transfer,rate-determining steps,and redox reaction barriers are discussed in the context of the work function,electron density difference,Bader charge,and variation in the intermediate adsorption free energy profiles.The activity and mechanism of various photocatalytic redox reactions were elaborately analyzed through in situ characterizations and DFT calculations using representative cases.Finally,the overall photocatalytic redox reactions were summarized with a focus on the construction of an S-scheme heterojunction photocatalyst,reasonable loading of cocatalysts,photocatalyst morphology regulation,novel photocatalyst development,reasonable selection of the oxidation half-reaction and reduction half-reaction for coupling,and combined in situ characterization and DFT calculations.This work provides a reference for promising design strategies and insight into the mechanism of overall photocatalytic redox reactions.展开更多
The bore-center annular shaped charge(BCASC)is a new type of shaped charge which can generate a larger-diameter hole in steel targets than classical shaped charges.In this paper,the influence of three liner materials,...The bore-center annular shaped charge(BCASC)is a new type of shaped charge which can generate a larger-diameter hole in steel targets than classical shaped charges.In this paper,the influence of three liner materials,i.e.molybdenum,nickel and copper,on BCASC formation and penetrating into steel targets was investigated by experiment and numerical simulation.The simulation results were well consistent with the experimental results.This study showed that,at 0.50D standoff distance,the axial velocity of the molybdenum projectile was lower than that of the nickel and copper projectiles.The nickel and copper projectiles had almost the same head velocity.The absolute values of the radial velocity of the molybdenum projectile head was lower than that of the nickel and copper projectiles.However,at 0.75D standoff distance,the absolute values of the radial velocity of the molybdenum projectile head became much greater than that of the nickel and copper projectile heads.The projectile formed by BCASC with the molybdenum liner had the highest penetration depth of 61.5 mm,which was 10.0%and 21.3%higher than that generated by the copper and nickel projectiles.展开更多
A layered charge composed of the JH-2 explosive enveloped by a thick-walled cylindrical casing(active aluminum/rubber and inert lithium fluoride/rubber composites) was designed and explosion experiments were conducted...A layered charge composed of the JH-2 explosive enveloped by a thick-walled cylindrical casing(active aluminum/rubber and inert lithium fluoride/rubber composites) was designed and explosion experiments were conducted in a 1.3 m3tank and a 113 m3bunker.The blast parameters,including the quasistatic pressure(ΔpQS),special impulse(I),and peak overpressure(Δpmax),and images of the explosion process were recorded,and the influence of the Al content(30% and 50%) and Al particle size(1,10,and 50 μm) on the energy release of aluminum/rubber composites were investigated.The results revealed that the use of an active layer increased the peak overpressure generated by the primary blast wave,as well as the quasistatic pressure and special impulse related to fuel burning within tens of milliseconds after detonation.When the Al content was increased from 30% to 50%,the increases of ΔpQS and I were not obvious,and Δpmaxeven decreased,possibly because of decreased combustion efficiency and greater absorption of the blast wave energy for layers with 50% Al.Compared with the pure JH-2charge,the charge with 1 μm Al particles produced the highest Δpmax,indicating that better transient blast performance was generated by smaller Al particles.However,the charge with 10 μm Al particles showed the largest ΔpQSand I,suggesting that a stronger destructive effect occurred over a longer duration for charges that contained moderate 10 μm Al.展开更多
Testing rocket and space technology objects in ground conditions for resistance to the impact of meteoroids and fragments of space debris can be carried out using shaped charges. To substantiate the design parameters ...Testing rocket and space technology objects in ground conditions for resistance to the impact of meteoroids and fragments of space debris can be carried out using shaped charges. To substantiate the design parameters of shaped charges that ensure the formation of aluminum particles in a wide velocity range(from 2.5 to 16 km/s), numerical modeling of the formation process was carried out within the framework of a two-dimensional axisymmetric problem of continuum mechanics using three different computing codes to increase the reliability of the results. The calculations consider shaped charges with a diameter of 20-100 mm with aluminum liners of various shapes. It is shown that the formation of particles with velocities close to the lower limit of the considered range is ensured by gently sloping segmental liners of degressive thickness. To form higher-velocity particles with velocities over 5 km/s, it is proposed to use combined liners, the jet-forming part of which has the shape of a hemisphere of constant thickness or the shape of a semi-ellipsoid or semi-superellipsoid of rotation of degressive thickness.展开更多
Shaped charge has been widely used for penetrating concrete.However,due to the obvious difference between the propagation of shock waves and explosion products in water and air,the theory governing the formation of sh...Shaped charge has been widely used for penetrating concrete.However,due to the obvious difference between the propagation of shock waves and explosion products in water and air,the theory governing the formation of shaped charge jets in water as well as the underwater penetration effect of concrete need to be studied.In this paper,we introduced a modified forming theory of an underwater hemispherical shaped charge,and investigated the behavior of jet formation and concrete penetration in both air and water experimentally and numerically.The results show that the modified jet forming theory predicts the jet velocity of the hemispherical liner with an error of less than 10%.The underwater jets exhibit at least 3%faster and 11%longer than those in air.Concrete shows different failure modes after penetration in air and water.The depth of penetration deepens at least 18.75%after underwater penetration,accompanied by deeper crater with 65%smaller radius.Moreover,cracks throughout the entire target are formed,whereas cracks exist only near the penetration hole in air.This comprehensive study provides guidance for optimizing the structure of shaped charge and improves the understanding of the permeability effect of concrete in water.展开更多
The cavity characteristics in liquid-filled containers caused by high-velocity impacts represent an important area of research in hydrodynamic ram phenomena.The dynamic expansion of the cavity induces liquid pressure ...The cavity characteristics in liquid-filled containers caused by high-velocity impacts represent an important area of research in hydrodynamic ram phenomena.The dynamic expansion of the cavity induces liquid pressure variations,potentially causing catastrophic damage to the container.Current studies mainly focus on non-deforming projectiles,such as fragments,with limited exploration of shaped charge jets.In this paper,a uniquely experimental system was designed to record cavity profiles in behind-armor liquid-filled containers subjected to shaped charge jet impacts.The impact process was then numerically reproduced using the explicit simulation program ANSYS LS-DYNA with the Structured Arbitrary Lagrangian-Eulerian(S-ALE)solver.The formation mechanism,along with the dimensional and shape evolution of the cavity was investigated.Additionally,the influence of the impact kinetic energy of the jet on the cavity characteristics was analyzed.The findings reveal that the cavity profile exhibits a conical shape,primarily driven by direct jet impact and inertial effects.The expansion rates of both cavity length and maximum radius increase with jet impact kinetic energy.When the impact kinetic energy is reduced to 28.2 kJ or below,the length-to-diameter ratio of the cavity ultimately stabilizes at approximately 7.展开更多
To know about the radiation effects on the super large array 9 k×9 k CCDs used in a space telescope induced by energetic protons,the experiments of the super large array 9 k×9 k charge coupled devices(CCDs)u...To know about the radiation effects on the super large array 9 k×9 k CCDs used in a space telescope induced by energetic protons,the experiments of the super large array 9 k×9 k charge coupled devices(CCDs)used in the space telescope irradiated by 60 MeV and 100 MeV protons are presented.The samples were exposed by 60 MeV and 100 MeV protons at fluences of 5×10^(9)/cm^(2) and 1×10^(10)/cm^(2),respectively.The degradations of the main performance parameters of the super large array CCDs which are paid special attention to the space telescope are investigated.The full well capacity,mean dark current,and the charge transfer inefficiency(CTI)versus proton fluence are presented,which are tested at very low temperature of-85℃.The annealing tests of 168 h were carried out after proton irradiation.The dark images before and after proton irradiation are also presented to compare the image degradation.The degradation mechanisms of the super large array CCDs irradiated by protons are analyzed.The experimental results show that the main performance parameters of the CCDs are degraded after 60 MeV and 100 MeV protons and the degradations induced by 60 MeV protons are larger than that induced by 100 MeV protons.The experimental results of the super large array CCDs irradiated by protons will provide the basic test data support for orbit life assessment of the space telescope.展开更多
Lithium-ion batteries(LIBs)are an electrochemical energy storage technology that has been widely used for portable electrical devices,electric vehicles,and grid storage,etc.To satisfy the demand for user convenience e...Lithium-ion batteries(LIBs)are an electrochemical energy storage technology that has been widely used for portable electrical devices,electric vehicles,and grid storage,etc.To satisfy the demand for user convenience especially for electric vehicles,the development of a fast-charging technology for LIBs has become a critical focus.In commercial LIBs,the slow kinetics of Li+intercalation into the graphite anode from the electrolyte solution is known as the main restriction for fast-charging.We summarize the recent advances in obtaining fast-charging graphite-based anodes,mainly involving modifications of the electrolyte solution and graphite anode.Specifically,strategies for increasing the ionic conductivity and regulating the Li+solvation/desolvation state in the electrolyte solution,as well as optimizing the fabrication and the intrinsic activity of graphite-based anodes are discussed in detail.This review considers practical ways to obtain fast Li+intercalation kinetics into a graphite anode from the electrolyte as well as analysing progress in the commercialization of fast-charging LIBs.展开更多
Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surf...Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surface area,and less active sites limits its solar energy utilization.Hydrothermal method was utilized to synthesize the bimetallic material of Cu_(x)Co_(1-x)in this work.Co was loaded onto the Cu surface due to the electrons generated by the surface plasmon resonance(SPR)effect occurring on the Cu surface.Cu_(x)Co_(1-x)exhibits high photocatalytic conversion of CO_(2)efficiency under irradiation,which mainly because the Co nanoparticles on the surface of Cu can be used as cocatalysts to enhance the photocharge transfer.Cu_(0.6)Co_(0.4)exhibits the comparatively best photocatalytic conversion efficiency of CO_(2)in the first 6 h light irradiation.The yields of CO and CH_(4)reached 35.26 and 2.71μmol/(g·h),respectively.Upon illumination,electrons were produced,with the majority of them moving towards the interface.This movement contributes to the increased lifetime of photogenerated electron-hole pairs,which in turn boosts the photocatalytic efficiency.The findings of this research provide significant insights for creating photocatalysts that are both highly effective and stable in CO_(2)reduction processes.展开更多
High-temperature piezoelectric vibration sensors are the preferred choice for structural health monitoring in harsh environments such as high temperatures and complex vibrations.Bismuth layer-structured CaBi_(4)Ti_(4)...High-temperature piezoelectric vibration sensors are the preferred choice for structural health monitoring in harsh environments such as high temperatures and complex vibrations.Bismuth layer-structured CaBi_(4)Ti_(4)O_(15)(CBT)high-temperature piezoelectric ceramics,with high Curie temperature(TC),are the key components for piezoelectric vibration sensors operating at temperatures exceeding 500℃.However,their low piezoelectric coefficient(d_(33))greatly limits their high-temperature applications.In this work,a novel Bi^(3+)self-doping strategy was employed to enhance the piezoelectric performance of CBT ceramics.The enhancement is attributed to an increase in the number of grain boundaries,providing more sites for space charge accumulation and promoting formation of space charge polarization.Furthermore,given that space charge polarization predominantly occurs at low frequencies,dielectric temperature spectra at different frequencies were used to elucidate the mechanism by which space charge polarization enhances piezoelectric properties of CBT ceramics.Excellent overall performance was achieved for the CBT-based high-temperature piezoelectric ceramics.Among them,TC reached 778℃,d_(33) increased by more than 30%,reaching 20.1 pC/N,and the electrical resistivity improved by one order of magnitude(reaching 6.33×10^(6)Ω·cm at 500℃).These advancements provide a key functional material with excellent performance for practical applications of piezoelectric vibration sensors at 500℃and above.展开更多
The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs b...The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs based on M-EMLs separated by polyethyleneimine ethoxylated(PEIE)layer with different stacking sequences of blue(B),green(G),and red(R)QDs layer were used to intuitively explore the injection,transportation and recombination processes of the charge carriers in QLEDs by using the time-resolved electroluminescence(TrEL)spectra.From the TrEL spectra mea-surements,green and red emissions were obtained first in the QLEDs with the EMLs sequences of G/PEIE/B/PEIE/R and B/PEIE/R/PEIE/G along the direction of light emission,respectively.While the QLEDs adopt EMLs sequences of B/PEIE/G/PEIE/R,the blue,green and red emissions were obtained nearly at the same time.The above phenomenon can be attributed to different charge carrier transmission and radiation recombination process in the EMLs due to different valence band offsets and conduction band offsets between R-,G-and B-QDs by using different sequences of EMLs.White emission with coordi-nates of(0.31,0.31)and correlated color temperature(CCT)of 5916 K was obtained in the QLEDs with the EMLs se-quences of B/PEIE/G/PEIE/R,which can be attributed to the relative uniform emission of B-,G-and R-QDs due to the effec-tive injection and radiation recombination of charge carriers in each of the EMLs.The above results have great significance for further understanding and improving the performance of QLEDs with M-EMLs.展开更多
Optical field manipulation,an emerging frontier in photonics,demonstrates significant potential in biomedical microscopy,quantum state engineering,and micro-nano fabrication.To address the critical limitations of curr...Optical field manipulation,an emerging frontier in photonics,demonstrates significant potential in biomedical microscopy,quantum state engineering,and micro-nano fabrication.To address the critical limitations of current optical modulation technologies in achieving full-parameter precision control,we proposed a novel approach for dynamic azimuthal optical field modulation based on dual-spiral arrays.By designing spatially interleaved spiral structures with different initial radii while maintaining identical periodic parameters,we achieved continuous optical modulation spanning the full 0-2πrange in azimuthal field distribution.Through rigorous numerical simulations,we systematically established a quantitative correlation between the structural parameters and azimuthal optical field patterns,revealing,for the first time,a quasi-linear relationship between the radius difference and the resultant optical distribution.This theoretical framework advances our fundamental understanding of structured optical field manipulation as well as provides a new paradigm for programmable photonic device design,with distinct technical advantages in super-resolution imaging and optical tweezer systems.展开更多
文摘This study calculates the combustion characteristics of various gas-generating and micro gas pyrotechnic charges,including aluminium/potassium perchlorate,boron/potassium nitrate,carbon black/potassium nitrate,and silicon-based delay compositions,using thermodynamic software.A multiphase flowthermal-solid coupling model was established,and the combustion process of the pyrotechnic charges within a closed bomb was simulated.The pyrotechnic shock generated by combustion was predicted.The combustion pressures and pyrotechnic shocks were measured.The simulation results demonstrated good agreement with experimental results.Additionally,the mechanism of shock generation by the combustion of pyrotechnic charges in the closed bomb was analyzed.The effects of the combustion characteristics of the pyrotechnic charges on the resulting pyrotechnic shocks were systematically investigated.Notably,the shock response spectrum of the gas-generating pyrotechnic charges is greater than that of the micro gas compositions at most frequencies,particularly in the mid-field pyrotechnic shocks(3-10 kHz).Furthermore,the pyrotechnic shocks increase approximately linearly with the impulse of the gas-generating pyrotechnic charges.
文摘Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel.
基金financially supported by the Fundamental Research Funds for the Central Universities(Grant No.30923011018)。
文摘The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.
基金funded by the National Natural Science Foundation of China(Grant No. 12302437)Jiangsu Provincial Natural Science Foundation (Grant No.SBK2023045424)。
文摘To explore the design criteria for composite charges and reveal the intrinsic relationship between the detonation wave propagation in composite charges and the overall energy distribution of shock waves,this study analyzes the propagation and interaction processes of detonation waves in composite charges with different structural dimensions and explosive combinations. It also investigates the spatial distribution characteristics of the resulting shock wave loads. Based on dimensional analysis theory, a theoretical analysis of the shock wave overpressure distribution in free air fields is conducted. Utilizing the derived dimensionless function relationships, the hydrocode AUTODYN is employed to investigate the effects of charge structure parameters and explosive combinations on the internal overdriven detonation phenomena and the distribution of shock wave loads. It is found that the overdriven detonation phenomenon in the inner layer of composite charges increases the strength of the axial detonation wave,thereby enhancing the intensity of the primary end wave formed upon refraction into the air, which affects the distribution characteristics of the shock wave overpressure. Research has shown that increasing the thickness ratio and detonation velocity ratio of composite charges is beneficial for exacerbating the phenomenon of overdriven detonation, improving the primary end wave intensity and axial overpressure. This gain effect gradually weakens with the propagation of shock waves. When overdriven detonation occurs inside the composite charge, the detonation pressure first increases and then decreases. The Mach reflection pressure of the composite charge with a larger aspect ratio is attenuated to a greater extent. In addition, as the aspect ratio of the composite charge increases, the shock wave energy gradually flows from the axial direction to the radial direction. Therefore, as the aspect ratio of the composite charge increases, the primary end wave intensity and axial overpressure gradually decrease.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52271317 and 52071149)the Fundamental Research Funds for the Central Universities(HUST:2019kfy XJJS007)。
文摘To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based simulation(NNS)method with higher accuracy and better efficiency was proposed.The NNS method consisted of three main steps.First,the parameters of blast loads,including the peak pressures and impulses of cylindrical charges with different aspect ratios(L/D)at different stand-off distances and incident angles were obtained by two-dimensional numerical simulations.Subsequently,incident shape factors of cylindrical charges with arbitrary aspect ratios were predicted by a neural network.Finally,reflected shape factors were derived and implemented into the subroutine of the ABAQUS code to modify the CONWEP model,including modifications of impulse and overpressure.The reliability of the proposed NNS method was verified by related experimental results.Remarkable accuracy improvement was acquired by the proposed NNS method compared with the unmodified CONWEP model.Moreover,huge efficiency superiority was obtained by the proposed NNS method compared with the CEL method.The proposed NNS method showed good accuracy when the scaled distance was greater than 0.2 m/kg^(1/3).It should be noted that there is no need to generate a new dataset again since the blast loads satisfy the similarity law,and the proposed NNS method can be directly used to simulate the blast loads generated by different cylindrical charges.The proposed NNS method with high efficiency and accuracy can be used as an effective method to analyze the dynamic response of structures under blast loads,and it has significant application prospects in designing protective structures.
基金Projects(51304239,51374243)supported by the National Natural Science Foundation of China
文摘A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small spherical explosive charge generated in rock, is used to further study the triggering time of strain gauges installed in radial direction at same distances but different positions surrounding a cylindrical explosive charge in rock. The duration of the first compression phase and peak value of strain wave, and furthermore, their differences are analyzed and some explanations are given. Besides that, the gauge orientation in which the maximum peak value occurs is also discussed. At last, the effect of velocity of detonation(V.O.D.) of a cylindrical explosive charge on the strain waves generated in the surrounding rock is taken as key research and the pattern of peak amplitude of a strain wave varies with the V.O.D. is likely to have been found.
基金supported by the National Natural Science Foundations of China (51808550, 52078133)the China Postdoctoral Science Foundation (2020M671296)。
文摘In current guidelines, the free air blast loads(overpressure and impulse) are determined by spherical charges, although most of ordnance devices are more nearly cylindrical than spherical in geometry. This may result in a great underestimation of blast loads in the near field and lead to an unsafe design.However, there is still a lack of systematic quantitative analysis of the blast loads generated from cylindrical charges. In this study, a numerical model is developed by using the hydrocode AUTODYN to investigate the influences of aspect ratio and orientation on the free air blast loads generated from center-initiated cylindrical charges. This is done by examining the pressure contours, the peak overpressures and impulses for various aspect ratios ranged from 1 to 8 and arbitrary orientation monitored along every azimuth angle with an interval of 5°. To characterize the distribution patterns of blast loads,three regions, i.e., the axial region, the vertex region and the radial region are identified, and the propagation of blast waves in each region is analyzed in detail. The complexity of blast loads of cylindrical charges is found to result from the bridge wave and its interaction with primary waves. Several empirical formulas are presented based on curve-fitting the numerical data, including the orientation where the maximum peak overpressure emerges, the critical scaled distance beyond which the charge shape effect could be neglected and blast loads with varied aspect ratio in arbitrary orientation, all of which are useful for blast-resistant design.
文摘The photoconversion of CO_(2) to carbon-containing fuels,splitting water into H_(2),selective organic synthesis,reduction of N_(2) to NH3,and hazardous organic contaminant degradation represent feasible schemes for solving environmental and energy issues.In 1972,TiO_(2) was applied for decomposing water into H_(2) and O_(2) via photocatalysis.Owing to its the low visible-light utilization,fast charge recombination,and high energy barrier for water oxidation,overall photocatalytic water-splitting efficiency is extremely low.Because H_(2) is more economically valuable than O_(2),sacrificial agent-assisted photocatalytic H_(2) evolution has been extensively investigated.Because the sacrificial agent can quickly consume photoexcited holes and effectively reduce the water oxidation energy barrier,photocatalytic H_(2) evolution efficiency can be increased by 3-4 orders of magnitude compared to photocatalytic water splitting.However,the overuse of sacrificial agents contributes to wasted photoexcited holes and expensive processes,while presenting potential environmental issues.Recently,overall charge utilization and improved redox efficiency have been achieved by coupling photocatalytic reduction with oxidation reactions.Moreover,overall charge utilization can boost charge separation and increase photocatalyst durability.However,the photocatalytic mechanism of the overall redox reactions remains unclear,owing to the complex reaction processes and design difficulties.Herein,the basic principles of photocatalysis are discussed from the perspective of light harvesting,photoexcited charge separation,thermodynamics,and redox reaction kinetics.Photocatalytic redox reactions,including overall water photodecomposition,photocatalytic H_(2) evolution coupled with organic oxidation,photocatalytic CO_(2) reduction coupled with organic oxidation,photocatalytic H_(2)O_(2) production coupled with organic oxidation,photocatalytic N_(2) reduction coupled with N_(2) oxidation,and photocatalytic organic reduction coupled with organic oxidation,can be systematically classified according to the coupling of photocatalytic oxidation reactions with photocatalytic reduction reactions.Subsequently,the design of photocatalytic redox reactions is considered in terms of the modulation of photocatalyst materials,reaction conditions,and diversity of reactants and products.In addition,the vital role of density functional theory(DFT)calculations for unveiling photoexcited charge transfer,rate-determining steps,and redox reaction barriers are discussed in the context of the work function,electron density difference,Bader charge,and variation in the intermediate adsorption free energy profiles.The activity and mechanism of various photocatalytic redox reactions were elaborately analyzed through in situ characterizations and DFT calculations using representative cases.Finally,the overall photocatalytic redox reactions were summarized with a focus on the construction of an S-scheme heterojunction photocatalyst,reasonable loading of cocatalysts,photocatalyst morphology regulation,novel photocatalyst development,reasonable selection of the oxidation half-reaction and reduction half-reaction for coupling,and combined in situ characterization and DFT calculations.This work provides a reference for promising design strategies and insight into the mechanism of overall photocatalytic redox reactions.
基金supported by the National Natural Science Foundation of China(No.11732003)Beijing Natural Science Foundation(No.8182050)+1 种基金Science Challenge Project(No.TZ2016001)National Key R&D Program of China(No.2017YFC0804700)
文摘The bore-center annular shaped charge(BCASC)is a new type of shaped charge which can generate a larger-diameter hole in steel targets than classical shaped charges.In this paper,the influence of three liner materials,i.e.molybdenum,nickel and copper,on BCASC formation and penetrating into steel targets was investigated by experiment and numerical simulation.The simulation results were well consistent with the experimental results.This study showed that,at 0.50D standoff distance,the axial velocity of the molybdenum projectile was lower than that of the nickel and copper projectiles.The nickel and copper projectiles had almost the same head velocity.The absolute values of the radial velocity of the molybdenum projectile head was lower than that of the nickel and copper projectiles.However,at 0.75D standoff distance,the absolute values of the radial velocity of the molybdenum projectile head became much greater than that of the nickel and copper projectile heads.The projectile formed by BCASC with the molybdenum liner had the highest penetration depth of 61.5 mm,which was 10.0%and 21.3%higher than that generated by the copper and nickel projectiles.
基金funded by the National Natural Science Foundation of China(Grant No.11972018)the Defense Pre-Research Joint Foundation of Chinese Ordnance Industry(Grant No.6141B012858)。
文摘A layered charge composed of the JH-2 explosive enveloped by a thick-walled cylindrical casing(active aluminum/rubber and inert lithium fluoride/rubber composites) was designed and explosion experiments were conducted in a 1.3 m3tank and a 113 m3bunker.The blast parameters,including the quasistatic pressure(ΔpQS),special impulse(I),and peak overpressure(Δpmax),and images of the explosion process were recorded,and the influence of the Al content(30% and 50%) and Al particle size(1,10,and 50 μm) on the energy release of aluminum/rubber composites were investigated.The results revealed that the use of an active layer increased the peak overpressure generated by the primary blast wave,as well as the quasistatic pressure and special impulse related to fuel burning within tens of milliseconds after detonation.When the Al content was increased from 30% to 50%,the increases of ΔpQS and I were not obvious,and Δpmaxeven decreased,possibly because of decreased combustion efficiency and greater absorption of the blast wave energy for layers with 50% Al.Compared with the pure JH-2charge,the charge with 1 μm Al particles produced the highest Δpmax,indicating that better transient blast performance was generated by smaller Al particles.However,the charge with 10 μm Al particles showed the largest ΔpQSand I,suggesting that a stronger destructive effect occurred over a longer duration for charges that contained moderate 10 μm Al.
文摘Testing rocket and space technology objects in ground conditions for resistance to the impact of meteoroids and fragments of space debris can be carried out using shaped charges. To substantiate the design parameters of shaped charges that ensure the formation of aluminum particles in a wide velocity range(from 2.5 to 16 km/s), numerical modeling of the formation process was carried out within the framework of a two-dimensional axisymmetric problem of continuum mechanics using three different computing codes to increase the reliability of the results. The calculations consider shaped charges with a diameter of 20-100 mm with aluminum liners of various shapes. It is shown that the formation of particles with velocities close to the lower limit of the considered range is ensured by gently sloping segmental liners of degressive thickness. To form higher-velocity particles with velocities over 5 km/s, it is proposed to use combined liners, the jet-forming part of which has the shape of a hemisphere of constant thickness or the shape of a semi-ellipsoid or semi-superellipsoid of rotation of degressive thickness.
基金supported by the National Science Foundation of China(Grant Nos.12372361,12102427,12372335 and 12102202)the Fundamental Research Funds for the Central Universities(Grant No.30923010908)Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX23_0520).
文摘Shaped charge has been widely used for penetrating concrete.However,due to the obvious difference between the propagation of shock waves and explosion products in water and air,the theory governing the formation of shaped charge jets in water as well as the underwater penetration effect of concrete need to be studied.In this paper,we introduced a modified forming theory of an underwater hemispherical shaped charge,and investigated the behavior of jet formation and concrete penetration in both air and water experimentally and numerically.The results show that the modified jet forming theory predicts the jet velocity of the hemispherical liner with an error of less than 10%.The underwater jets exhibit at least 3%faster and 11%longer than those in air.Concrete shows different failure modes after penetration in air and water.The depth of penetration deepens at least 18.75%after underwater penetration,accompanied by deeper crater with 65%smaller radius.Moreover,cracks throughout the entire target are formed,whereas cracks exist only near the penetration hole in air.This comprehensive study provides guidance for optimizing the structure of shaped charge and improves the understanding of the permeability effect of concrete in water.
基金financial support from the National Natural Science Foundation of China(Grant No.11572159).
文摘The cavity characteristics in liquid-filled containers caused by high-velocity impacts represent an important area of research in hydrodynamic ram phenomena.The dynamic expansion of the cavity induces liquid pressure variations,potentially causing catastrophic damage to the container.Current studies mainly focus on non-deforming projectiles,such as fragments,with limited exploration of shaped charge jets.In this paper,a uniquely experimental system was designed to record cavity profiles in behind-armor liquid-filled containers subjected to shaped charge jet impacts.The impact process was then numerically reproduced using the explicit simulation program ANSYS LS-DYNA with the Structured Arbitrary Lagrangian-Eulerian(S-ALE)solver.The formation mechanism,along with the dimensional and shape evolution of the cavity was investigated.Additionally,the influence of the impact kinetic energy of the jet on the cavity characteristics was analyzed.The findings reveal that the cavity profile exhibits a conical shape,primarily driven by direct jet impact and inertial effects.The expansion rates of both cavity length and maximum radius increase with jet impact kinetic energy.When the impact kinetic energy is reduced to 28.2 kJ or below,the length-to-diameter ratio of the cavity ultimately stabilizes at approximately 7.
基金The National Science Foundation of China(U2167208,11875223)Natural Science Basic Research Program of Shaanxi(2024JC-JCQN)The Foundation of State Key Laboratory of China(NKLIPR2320)。
文摘To know about the radiation effects on the super large array 9 k×9 k CCDs used in a space telescope induced by energetic protons,the experiments of the super large array 9 k×9 k charge coupled devices(CCDs)used in the space telescope irradiated by 60 MeV and 100 MeV protons are presented.The samples were exposed by 60 MeV and 100 MeV protons at fluences of 5×10^(9)/cm^(2) and 1×10^(10)/cm^(2),respectively.The degradations of the main performance parameters of the super large array CCDs which are paid special attention to the space telescope are investigated.The full well capacity,mean dark current,and the charge transfer inefficiency(CTI)versus proton fluence are presented,which are tested at very low temperature of-85℃.The annealing tests of 168 h were carried out after proton irradiation.The dark images before and after proton irradiation are also presented to compare the image degradation.The degradation mechanisms of the super large array CCDs irradiated by protons are analyzed.The experimental results show that the main performance parameters of the CCDs are degraded after 60 MeV and 100 MeV protons and the degradations induced by 60 MeV protons are larger than that induced by 100 MeV protons.The experimental results of the super large array CCDs irradiated by protons will provide the basic test data support for orbit life assessment of the space telescope.
文摘Lithium-ion batteries(LIBs)are an electrochemical energy storage technology that has been widely used for portable electrical devices,electric vehicles,and grid storage,etc.To satisfy the demand for user convenience especially for electric vehicles,the development of a fast-charging technology for LIBs has become a critical focus.In commercial LIBs,the slow kinetics of Li+intercalation into the graphite anode from the electrolyte solution is known as the main restriction for fast-charging.We summarize the recent advances in obtaining fast-charging graphite-based anodes,mainly involving modifications of the electrolyte solution and graphite anode.Specifically,strategies for increasing the ionic conductivity and regulating the Li+solvation/desolvation state in the electrolyte solution,as well as optimizing the fabrication and the intrinsic activity of graphite-based anodes are discussed in detail.This review considers practical ways to obtain fast Li+intercalation kinetics into a graphite anode from the electrolyte as well as analysing progress in the commercialization of fast-charging LIBs.
基金supported by the Doctoral Research Start-up Project of Yuncheng University(YQ-2023067)Project of Shanxi Natural Science Foundation(202303021211189)+2 种基金Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Provinces(20220036)Shanxi Province Intelligent Optoelectronic Sensing Application Technology Innovation CenterShanxi Province Optoelectronic Information Science and Technology Laboratory,Yuncheng University。
文摘Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surface area,and less active sites limits its solar energy utilization.Hydrothermal method was utilized to synthesize the bimetallic material of Cu_(x)Co_(1-x)in this work.Co was loaded onto the Cu surface due to the electrons generated by the surface plasmon resonance(SPR)effect occurring on the Cu surface.Cu_(x)Co_(1-x)exhibits high photocatalytic conversion of CO_(2)efficiency under irradiation,which mainly because the Co nanoparticles on the surface of Cu can be used as cocatalysts to enhance the photocharge transfer.Cu_(0.6)Co_(0.4)exhibits the comparatively best photocatalytic conversion efficiency of CO_(2)in the first 6 h light irradiation.The yields of CO and CH_(4)reached 35.26 and 2.71μmol/(g·h),respectively.Upon illumination,electrons were produced,with the majority of them moving towards the interface.This movement contributes to the increased lifetime of photogenerated electron-hole pairs,which in turn boosts the photocatalytic efficiency.The findings of this research provide significant insights for creating photocatalysts that are both highly effective and stable in CO_(2)reduction processes.
基金National Natural Science Foundation of China (51932010)。
文摘High-temperature piezoelectric vibration sensors are the preferred choice for structural health monitoring in harsh environments such as high temperatures and complex vibrations.Bismuth layer-structured CaBi_(4)Ti_(4)O_(15)(CBT)high-temperature piezoelectric ceramics,with high Curie temperature(TC),are the key components for piezoelectric vibration sensors operating at temperatures exceeding 500℃.However,their low piezoelectric coefficient(d_(33))greatly limits their high-temperature applications.In this work,a novel Bi^(3+)self-doping strategy was employed to enhance the piezoelectric performance of CBT ceramics.The enhancement is attributed to an increase in the number of grain boundaries,providing more sites for space charge accumulation and promoting formation of space charge polarization.Furthermore,given that space charge polarization predominantly occurs at low frequencies,dielectric temperature spectra at different frequencies were used to elucidate the mechanism by which space charge polarization enhances piezoelectric properties of CBT ceramics.Excellent overall performance was achieved for the CBT-based high-temperature piezoelectric ceramics.Among them,TC reached 778℃,d_(33) increased by more than 30%,reaching 20.1 pC/N,and the electrical resistivity improved by one order of magnitude(reaching 6.33×10^(6)Ω·cm at 500℃).These advancements provide a key functional material with excellent performance for practical applications of piezoelectric vibration sensors at 500℃and above.
文摘The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs based on M-EMLs separated by polyethyleneimine ethoxylated(PEIE)layer with different stacking sequences of blue(B),green(G),and red(R)QDs layer were used to intuitively explore the injection,transportation and recombination processes of the charge carriers in QLEDs by using the time-resolved electroluminescence(TrEL)spectra.From the TrEL spectra mea-surements,green and red emissions were obtained first in the QLEDs with the EMLs sequences of G/PEIE/B/PEIE/R and B/PEIE/R/PEIE/G along the direction of light emission,respectively.While the QLEDs adopt EMLs sequences of B/PEIE/G/PEIE/R,the blue,green and red emissions were obtained nearly at the same time.The above phenomenon can be attributed to different charge carrier transmission and radiation recombination process in the EMLs due to different valence band offsets and conduction band offsets between R-,G-and B-QDs by using different sequences of EMLs.White emission with coordi-nates of(0.31,0.31)and correlated color temperature(CCT)of 5916 K was obtained in the QLEDs with the EMLs se-quences of B/PEIE/G/PEIE/R,which can be attributed to the relative uniform emission of B-,G-and R-QDs due to the effec-tive injection and radiation recombination of charge carriers in each of the EMLs.The above results have great significance for further understanding and improving the performance of QLEDs with M-EMLs.
文摘Optical field manipulation,an emerging frontier in photonics,demonstrates significant potential in biomedical microscopy,quantum state engineering,and micro-nano fabrication.To address the critical limitations of current optical modulation technologies in achieving full-parameter precision control,we proposed a novel approach for dynamic azimuthal optical field modulation based on dual-spiral arrays.By designing spatially interleaved spiral structures with different initial radii while maintaining identical periodic parameters,we achieved continuous optical modulation spanning the full 0-2πrange in azimuthal field distribution.Through rigorous numerical simulations,we systematically established a quantitative correlation between the structural parameters and azimuthal optical field patterns,revealing,for the first time,a quasi-linear relationship between the radius difference and the resultant optical distribution.This theoretical framework advances our fundamental understanding of structured optical field manipulation as well as provides a new paradigm for programmable photonic device design,with distinct technical advantages in super-resolution imaging and optical tweezer systems.
