Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, con...Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescence properties of the Eu(III) and Tb(III) complexes were also studied.展开更多
Two series of solid complexes of rare earth nitrates and picrates with the "back-to-back" terpyridine, 6′,6″-bis(2-pyridyl)-2,2′:4′,4″:2″,2′″-quaterpyridine (L) have been synthesized. These complexes...Two series of solid complexes of rare earth nitrates and picrates with the "back-to-back" terpyridine, 6′,6″-bis(2-pyridyl)-2,2′:4′,4″:2″,2′″-quaterpyridine (L) have been synthesized. These complexes have been characterized by elemental analysis, conductivity measurements, thermal analysis and IR spectroscopy. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied.展开更多
文摘Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescence properties of the Eu(III) and Tb(III) complexes were also studied.
文摘Two series of solid complexes of rare earth nitrates and picrates with the "back-to-back" terpyridine, 6′,6″-bis(2-pyridyl)-2,2′:4′,4″:2″,2′″-quaterpyridine (L) have been synthesized. These complexes have been characterized by elemental analysis, conductivity measurements, thermal analysis and IR spectroscopy. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied.
