The energy storage mechanism of azobenzene is based on the transformation of molecular cis and trans isomerization,while NBD/QC,DHA/VHF,and fulvalene dimetal complexes realize the energy storage function by changing t...The energy storage mechanism of azobenzene is based on the transformation of molecular cis and trans isomerization,while NBD/QC,DHA/VHF,and fulvalene dimetal complexes realize the energy storage function by changing the molecular structure.Acting as“molecular batteries,”they can exhibit excellent charging and discharging behavior by converting between trans and cis isomers or changing molecular structure upon absorption of ultraviolet light.Key properties determining the performance of STFs are stored energy,energy density,half-life,and solar energy conversion efficiency.This review is aiming to provide a comprehensive and authoritative overview on the recent advancements of azobenzene molecular photoswitch system in STFs fields,including derivatives and carbon nano-templates,which is emphasized for its attractive performance.Although the energy storage performance of Azo-STFs has already reached the level of commercial lithium batteries,the cycling capability and controllable release of energy still need to be further explored.For this,some potential solutions to the cycle performance are proposed,and the methods of azobenzene controllable energy release are summarized.Moreover,energy stored by STFs can be released in the form of mechanical energy,which in turn can also promote the release of thermal energy from STFs,implying that there could be a relationship between mechanical and thermal energy in Azo-STFs,providing a potential direction for further research on Azo-STFs.展开更多
An innovative heterojunction is fabricated between two sides of a freestanding thin film of HCl-doped polyaniline （PANI） derivative containing azobenzene side-chain, which is synthesized through an N-alkyl-substitut...An innovative heterojunction is fabricated between two sides of a freestanding thin film of HCl-doped polyaniline （PANI） derivative containing azobenzene side-chain, which is synthesized through an N-alkyl-substituted reaction. of the film, the side with being irradiated by UV light during preparation is represented as ＇A side＇; the other side without being irradiated is represented as ＇N side＇. The electrical properties of the heterojunction are measured and the rectifying effect is observed in the current voltage characteristic curves with the values of rectifying ratio （30 being 20 at ±0.06 V at T = 77 K and 4 at ±0.02 V at T = 300 K separately.展开更多
The orientation switching of a single azobenzene molecule on Au(111)surface excited by tunneling electrons and/or photons has been demonstrated in recent experiments.Here we investigate the rotation behavior of this m...The orientation switching of a single azobenzene molecule on Au(111)surface excited by tunneling electrons and/or photons has been demonstrated in recent experiments.Here we investigate the rotation behavior of this molecular rotor by first-principles density functional theory(DFT)calculation.The anchor phenyl ring prefers adsorption on top of the fcc hollow site,simulated by a benzene molecule on close packed atomic surface.The adsorption energy for an azobenzene molecule on Au(111)surface is calculated to be about 1.76 eV.The rotational energy profile has been mapped with one of the phenyl rings pivots around the fcc hollow site,illustrating a potential barrier about 50 meV.The results are consistent with experimental observations and valuable for exploring a broad spectrum of molecules on this noble metal surface.展开更多
The nonlinear optical properties of an azobenzene polymer azol2-MO were investigated by a Z-scan technique. The polymer was synthesized by assembling the liquid-crystalline polymer azol2 with methyl orange. The nonlin...The nonlinear optical properties of an azobenzene polymer azol2-MO were investigated by a Z-scan technique. The polymer was synthesized by assembling the liquid-crystalline polymer azol2 with methyl orange. The nonlinear refrac- tive index （1.39×10^-15 cm2/W） and the nonlinear absorption coefficient （0.11 cm/GW） of azol2-MO were determined with 532-nm picosecond laser pulses at the irradiance of 92.40 GW/cm2. When compared to the nonlinear properties of azol2 and methyl orange, azol2-MO possesses the advantages of its two constituents and shows larger nonlinear optical properties.展开更多
A series of azobenzene liquid crystals with one or two terminal acrylate groups were synthesized and their polymers were fabricated.The azobenzene liquid crystals and their polymers achieved the photoisomerization fro...A series of azobenzene liquid crystals with one or two terminal acrylate groups were synthesized and their polymers were fabricated.The azobenzene liquid crystals and their polymers achieved the photoisomerization from the liquid crystalline trans-isomer to the isotropic cis-isomer with UV irradiation.Then,the cis to trans isomerization induced by an electric field was studied,the time required for electro-isomerization was measured,the texture change and absorption variation from cis to trans form induced by the electric field were observed clearly,and the time required for electro-isomerization was much shorter than that for thermal relaxation.The influence of the polar group（fluorine）,terminal acrylate group,and flexible alkyl chain on the time of electro-isomerization was studied.The results show that the compounds with polar fluorine group require shorter time for electro-isomerization and the polymerization of terminal acrylate group delays the electro-isomerization.展开更多
基金financially supported by the State Key Program of National Natural Science Foundation of China (No. 51633007 and 52130303)the National Natural Science Foundation of China (Nos. 51803151, 51973152, 51973151 and 51773147)
文摘The energy storage mechanism of azobenzene is based on the transformation of molecular cis and trans isomerization,while NBD/QC,DHA/VHF,and fulvalene dimetal complexes realize the energy storage function by changing the molecular structure.Acting as“molecular batteries,”they can exhibit excellent charging and discharging behavior by converting between trans and cis isomers or changing molecular structure upon absorption of ultraviolet light.Key properties determining the performance of STFs are stored energy,energy density,half-life,and solar energy conversion efficiency.This review is aiming to provide a comprehensive and authoritative overview on the recent advancements of azobenzene molecular photoswitch system in STFs fields,including derivatives and carbon nano-templates,which is emphasized for its attractive performance.Although the energy storage performance of Azo-STFs has already reached the level of commercial lithium batteries,the cycling capability and controllable release of energy still need to be further explored.For this,some potential solutions to the cycle performance are proposed,and the methods of azobenzene controllable energy release are summarized.Moreover,energy stored by STFs can be released in the form of mechanical energy,which in turn can also promote the release of thermal energy from STFs,implying that there could be a relationship between mechanical and thermal energy in Azo-STFs,providing a potential direction for further research on Azo-STFs.
基金Project supported by the National Natural Science Foundation of China (Grant No 10604038)the Program for New Century Excellent Talents in University,China (Grant No NCET-07-0472)
文摘An innovative heterojunction is fabricated between two sides of a freestanding thin film of HCl-doped polyaniline （PANI） derivative containing azobenzene side-chain, which is synthesized through an N-alkyl-substituted reaction. of the film, the side with being irradiated by UV light during preparation is represented as ＇A side＇; the other side without being irradiated is represented as ＇N side＇. The electrical properties of the heterojunction are measured and the rectifying effect is observed in the current voltage characteristic curves with the values of rectifying ratio （30 being 20 at ±0.06 V at T = 77 K and 4 at ±0.02 V at T = 300 K separately.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21961142021,11774395,91753136,and 11727902)the Beijing Natural Science Foundation,China(Grant No.4181003)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant Nos.XDB30201000 and XDB28000000).
文摘The orientation switching of a single azobenzene molecule on Au(111)surface excited by tunneling electrons and/or photons has been demonstrated in recent experiments.Here we investigate the rotation behavior of this molecular rotor by first-principles density functional theory(DFT)calculation.The anchor phenyl ring prefers adsorption on top of the fcc hollow site,simulated by a benzene molecule on close packed atomic surface.The adsorption energy for an azobenzene molecule on Au(111)surface is calculated to be about 1.76 eV.The rotational energy profile has been mapped with one of the phenyl rings pivots around the fcc hollow site,illustrating a potential barrier about 50 meV.The results are consistent with experimental observations and valuable for exploring a broad spectrum of molecules on this noble metal surface.
基金Project supported by the National Natural Science Foundation of China (Grant No.11174203)
文摘The nonlinear optical properties of an azobenzene polymer azol2-MO were investigated by a Z-scan technique. The polymer was synthesized by assembling the liquid-crystalline polymer azol2 with methyl orange. The nonlinear refrac- tive index （1.39×10^-15 cm2/W） and the nonlinear absorption coefficient （0.11 cm/GW） of azol2-MO were determined with 532-nm picosecond laser pulses at the irradiance of 92.40 GW/cm2. When compared to the nonlinear properties of azol2 and methyl orange, azol2-MO possesses the advantages of its two constituents and shows larger nonlinear optical properties.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61435008 and 61575063)
文摘A series of azobenzene liquid crystals with one or two terminal acrylate groups were synthesized and their polymers were fabricated.The azobenzene liquid crystals and their polymers achieved the photoisomerization from the liquid crystalline trans-isomer to the isotropic cis-isomer with UV irradiation.Then,the cis to trans isomerization induced by an electric field was studied,the time required for electro-isomerization was measured,the texture change and absorption variation from cis to trans form induced by the electric field were observed clearly,and the time required for electro-isomerization was much shorter than that for thermal relaxation.The influence of the polar group（fluorine）,terminal acrylate group,and flexible alkyl chain on the time of electro-isomerization was studied.The results show that the compounds with polar fluorine group require shorter time for electro-isomerization and the polymerization of terminal acrylate group delays the electro-isomerization.
