The electromagnetically induced grating effect in thermal and cold atoms has been studied theoretically. Studies have shown that, by adjusting the parameters, the first-order diffraction efficiency of the probe beam i...The electromagnetically induced grating effect in thermal and cold atoms has been studied theoretically. Studies have shown that, by adjusting the parameters, the first-order diffraction efficiency of the probe beam in the cold atomic system and the thermal atomic system is 34% and 31%, respectively, which is very close to the ideal diffraction efficiency of the sinusoidal grating. However, it is more difficult to prepare the cold atomic system than to prepare the thermal atomic system in the practical application, so the study of the electromagnetically induced grating effect in the thermal atomic system may be helpful for practical applications.展开更多
We theoretically investigate the Doppler effect on optical bistability in an N-type active Raman gain atomic system inside an optical ring cavity. It is shown that the Doppler effect can greatly enhance the dispersion...We theoretically investigate the Doppler effect on optical bistability in an N-type active Raman gain atomic system inside an optical ring cavity. It is shown that the Doppler effect can greatly enhance the dispersion and thus create the bistable behaviour or greatly increase the bistable region, which has been known as the positive Doppler effect on optical bistability. In addition, we find that a positive Doppler effect can change optical bistability from the hybrid dispersion-gain type to a dispersive type.展开更多
This paper investigates the breaking point between fast- and slow-light in a degenerate two-level atomic system, where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the...This paper investigates the breaking point between fast- and slow-light in a degenerate two-level atomic system, where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the strength of the pumping field. An equivalent incoherent pumping rate is introduced in this simplified theoretical model which exploits the dependence of this feature. The experimental observation is presented as evidence of the breaking point where the injected power is about 0.08 mW.展开更多
We have investigated the two-dimensional （2D） atom localization via probe absorption in a coherently driven four-level atomic system by means of a radio-frequency field driving a hyperfine transition. It is found th...We have investigated the two-dimensional （2D） atom localization via probe absorption in a coherently driven four-level atomic system by means of a radio-frequency field driving a hyperfine transition. It is found that the detecting probability and precision of 2D atom localization can be significantly improved via adjusting the system parameters. As a result, our scheme may be helpful in laser cooling or the atom nano-lithography via atom localization.展开更多
We theoretically investigate the phenomena of electromagnetically induced grating in an M-type five-level atomic system. It is found that a weak field can be effectively diffracted into high-order directions using a s...We theoretically investigate the phenomena of electromagnetically induced grating in an M-type five-level atomic system. It is found that a weak field can be effectively diffracted into high-order directions using a standing wave coupling field, and different depths of the phase modulation can disperse the diffraction light into different orders. When the phase modulation depth is approximated to the orders of π, 2π and 3π, the first-, second- and third-order diffraction intensity reach the maximum, respectively. Thus we can take advantage of the phase modulation to control the probe light dispersing into the required high orders.展开更多
Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibiliti...Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibilities for quantum optics research,which can be obtained under the localization method.We study the behavior of three-dimensional(3D)Rydberg atom localization in a four-level configuration with the measurement of the spatial optical absorption.The atomic localization precision depends strongly on the detuning and Rabi frequency of the involved laser fields.A 100%probability of finding the Rydberg atom at a specific 3D position is achieved with precision of~0.031λ.This work demonstrates the possibility for achieving the 3D atom localization of the Rydberg atom in the experiment.展开更多
The spontaneous emission decay dynamics of a tripod configuration four-level atom driven by a single laser field is studied. Under different initial conditions, we discuss the effects of quantum interference and detun...The spontaneous emission decay dynamics of a tripod configuration four-level atom driven by a single laser field is studied. Under different initial conditions, we discuss the effects of quantum interference and detuning of external driving field on atomic spontaneous emission properties. For the larger detuning, the interesting phenomena of the spectral line narrowing are found which stem from the contribution of external driving field.展开更多
Transient coherent oscillations in a closed A system under far-off resonant Raman fields were investigated theoreti- cally. It has been found that the coherent superposition of the ground states can be formed due to t...Transient coherent oscillations in a closed A system under far-off resonant Raman fields were investigated theoreti- cally. It has been found that the coherent superposition of the ground states can be formed due to the absorption even for initial maximal mixed ground states. The absorption oscillates with a period depending on the two-photon detuning when the system is initially in a transparent state and the two-photon Raman detuning is suddenly changed. The amplitude of the absorption decays with the decay rate of the ground states, which is different from the case when the lasers are applied resonantly. These transient coherent oscillations can be used to measure the relaxation rate of the ground states.展开更多
We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomi...We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomic system is lower than that in the V-type atomic system which is exactly the same as that in the Λ-type atomic system. In addition, the effect of relative coupling strength on entropic uncertainty is opposite in Markov region and non-Markov region, and the influence of a common environment and independent environments in Markov region and non-Markov region is also opposite. One can reduce the entropic uncertainty by decreasing relative coupling strength or placing the system in two separate environments in the Markov case. In the non-Markov case, the entropic uncertainty can be reduced by increasing the relative coupling strength or by placing the system in a common environment.展开更多
We illustrate our experimental observation of coexisting the controllable spatial splitting and intensity suppression of four-wave mixing （FWM） beam in a V-type three-level atomic system. The peak number and separat...We illustrate our experimental observation of coexisting the controllable spatial splitting and intensity suppression of four-wave mixing （FWM） beam in a V-type three-level atomic system. The peak number and separation distance of the FWM beam are controlled by the intensities and frequencies of the laser beams, as well as atomic density.展开更多
In the present paper, we investigate the behavior of two-dimensional atom localization in a five-level M-scheme atomic system driven by two orthogonal standing-wave fields. We find that the precision and resolution of...In the present paper, we investigate the behavior of two-dimensional atom localization in a five-level M-scheme atomic system driven by two orthogonal standing-wave fields. We find that the precision and resolution of the atom localization depends on the probe field detuning significantly. And because of the effect of the microwave field, an atom can be located at a particular position via adjusting the system parameters.展开更多
For atoms in external electric fields,the hyperpolarizabilities are the coefficients describing the nonlinear interactions contributing to the induced energies at the fourth power of the applied electric fields.Accura...For atoms in external electric fields,the hyperpolarizabilities are the coefficients describing the nonlinear interactions contributing to the induced energies at the fourth power of the applied electric fields.Accurate evaluations of these coefficients for various systems are crucial for improving precision in advanced atom-based optical lattice clocks and for estimating field-induced effects in atoms for quantum information applications.However,there is a notable scarcity of research on atomic hyperpolarizabilities,especially in the relativistic realm.Our work addresses this gap by establishing a novel set of alternative formulas for the hyperpolarizability based on the fourth-order perturbation theory.These formulas offer a more reasonable regrouping of scalar and tensor components compared to previous formulas,thereby enhancing their correctness and applicability.To validate our formulas,we perform the calculations for the ground and low-lying excited pure states of few-electron atoms H,Li,and Be^(+).The highly accurate results obtained for the H atom could serve as benchmarks for further development of other theoretical methods.展开更多
Reasonably constructing an atomic interface is pronouncedly essential for surface-related gas-sensing reaction.Herein,we present an ingen-ious feedback-regulation system by changing the interactional mode between sing...Reasonably constructing an atomic interface is pronouncedly essential for surface-related gas-sensing reaction.Herein,we present an ingen-ious feedback-regulation system by changing the interactional mode between single Pt atoms and adjacent S species for high-efficiency SO_(2)sensing.We found that the single Pt sites on the MoS_(2)surface can induce easier volatiliza-tion of adjacent S species to activate the whole inert S plane.Reversely,the activated S species can provide a feedback role in tailoring the antibonding-orbital electronic occupancy state of Pt atoms,thus creating a combined system involving S vacancy-assisted single Pt sites(Pt-Vs)to synergistically improve the adsorption ability of SO_(2)gas molecules.Further-more,in situ Raman,ex situ X-ray photoelectron spectroscopy testing and density functional theory analysis demonstrate the intact feedback-regulation system can expand the electron transfer path from single Pt sites to whole Pt-MoS_(2)supports in SO_(2)gas atmosphere.Equipped with wireless-sensing modules,the final Pt1-MoS_(2)-def sensors array can further realize real-time monitoring of SO_(2)levels and cloud-data storage for plant growth.Such a fundamental understanding of the intrinsic link between atomic interface and sensing mechanism is thus expected to broaden the rational design of highly effective gas sensors.展开更多
Photocatalytic oxygen reduction for hydrogen peroxide(H_(2)O_(2))synthesis presents a green and costeffective production method.However,achieving highly selective H_(2)O_(2)synthesis remains challenging,necessitating ...Photocatalytic oxygen reduction for hydrogen peroxide(H_(2)O_(2))synthesis presents a green and costeffective production method.However,achieving highly selective H_(2)O_(2)synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative by-products.Herein,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H_(2)O_(2)and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride(CNRb).The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h^(-1)for H_(2)O_(2)generation and photooxidation rate of 3.75 mM h^(-1)for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion(SCC)efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical formation.This is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product formation.This study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H_(2)O_(2)coupled with biomass valorization.展开更多
Atomically precise metal nanoclusters are an emerging type of nanomaterial which has diverse interfacial metal-ligand coordination motifs that can significantly affect their physicochemical properties and functionalit...Atomically precise metal nanoclusters are an emerging type of nanomaterial which has diverse interfacial metal-ligand coordination motifs that can significantly affect their physicochemical properties and functionalities.Among that,Cu nanoclusters have been gaining continuous increasing research attentions,thanks to the low cost,diversified structures,and superior catalytic performance for various reactions.In this review,we first summarize the recent progress regarding the synthetic methods of atomically precise Cu nanoclusters and the coordination modes between Cu and several typical ligands and then discuss the catalytic applications of these Cu nanoclusters with some explicit examples to explain the atomical-level structure-performance relationship.Finally,the current challenges and future research perspectives with some critical thoughts are elaborated.We hope this review can not only provide a whole picture of the current advances regarding the synthesis and catalytic applications of atomically precise Cu nanoclusters,but also points out some future research visions in this rapidly booming field.展开更多
This paper investigates the entropy squeezing of a moving two-level atom interacting with the two-mode entangled coherent field via two-photon transition by using an entropic uncertainty relation and the degree of ent...This paper investigates the entropy squeezing of a moving two-level atom interacting with the two-mode entangled coherent field via two-photon transition by using an entropic uncertainty relation and the degree of entanglement between the two-mode fields by using quantum relative entropy.The results obtained from numerical calculation indicate that the squeezed period,the duration of entropy squeezing and the maximal squeezing can be controlled by appropriately choosing the intensity of the light field,the atomic motion and the field-mode structure.The atomic motion leads to the periodic recovery of the initial maximal degree of entanglement between the two-mode fields.Moreover,there exists a corresponding relation between the time evolution properties of the atomic entropy squeezing and those of the entanglement between the two-mode fields.展开更多
Using modularized components, we have built a miniaturized optical system for 87Rb atomic fountain clock that is fitted on an 80 cm × 60 cm optical breadboard. Compared with the conventional optical setup on the ...Using modularized components, we have built a miniaturized optical system for 87Rb atomic fountain clock that is fitted on an 80 cm × 60 cm optical breadboard. Compared with the conventional optical setup on the table, our system is more compact, more robust and miniaturized. Taking advantage of this system, laser beams are transmitted through eight optical fibre patch cords from the optical breadboard to an ultra high vacuum system. This optical setup has operated for five months in our fountain system and required no alignment.展开更多
Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utiliz...Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered.展开更多
In recent years,low-dimensional transition metal chalcogenide(TMC)materials have garnered growing research attention due to their superior electronic,optical,and catalytic properties compared to their bulk counterpart...In recent years,low-dimensional transition metal chalcogenide(TMC)materials have garnered growing research attention due to their superior electronic,optical,and catalytic properties compared to their bulk counterparts.The controllable synthesis and manipulation of these materials are crucial for tailoring their properties and unlocking their full potential in various applications.In this context,the atomic substitution method has emerged as a favorable approach.It involves the replacement of specific atoms within TMC structures with other elements and possesses the capability to regulate the compositions finely,crystal structures,and inherent properties of the resulting materials.In this review,we present a comprehensive overview on various strategies of atomic substitution employed in the synthesis of zero-dimensional,one-dimensional and two-dimensional TMC materials.The effects of substituting elements,substitution ratios,and substitution positions on the structures and morphologies of resulting material are discussed.The enhanced electrocatalytic performance and photovoltaic properties of the obtained materials are also provided,emphasizing the role of atomic substitution in achieving these advancements.Finally,challenges and future prospects in the field of atomic substitution for fabricating low-dimensional TMC materials are summarized.展开更多
The development of redox bifunctional electrocatalysts with high performance,low cost,and long lifetimes is essential for achieving clean energy goals.This study proposed an atom capture strategy for anchoring dual si...The development of redox bifunctional electrocatalysts with high performance,low cost,and long lifetimes is essential for achieving clean energy goals.This study proposed an atom capture strategy for anchoring dual single atoms(DSAs)in a zinc-zeolitic imidazolate framework(Zn-ZIF),followed by calcination under an N_(2) atmosphere to synthesize ruthenium-platinum DSAs supported on a nitrogendoped carbon substrate(RuPt DSAs-NC).Theoretical calculations showed that the degree of Ru 5dxz-~*O 2p_x orbital hybridization was high when^(*)O was adsorbed at the Ru site,indicating enhanced covalent hybridization of metal sites and oxygen ligands,which benefited the adsorption of intermediate species.The presence of the RuPtN_6 active center optimized the absorption-desorption behavior of intermediates,improving the electrocatalytic performance of the oxygen reduction reaction(ORR)and the oxygen evolution reaction(DER),RuPt DSAs-NC exhibited a 0.87 V high half-wave potential and a 268 mV low overpotential at 10 mA cm^(-2)in an alkaline environment.Furthermore,rechargeable zinc-air batteries(ZABs)achieved a peak power density of 171 MW cm^(-2).The RuPt DSAs-NC demonstrated long-term cycling for up to 500 h with superior round-trip efficiency.This study provided an effective structural design strategy to construct DSAs active sites for enhanced electrocata lytic performance.展开更多
基金supported by the National Natural Science Foundation of China(Grants Nos.11004126 and 61275212)the Natural Science Foundation of Shanxi Province,China(Grant No.2011021003-1)
文摘The electromagnetically induced grating effect in thermal and cold atoms has been studied theoretically. Studies have shown that, by adjusting the parameters, the first-order diffraction efficiency of the probe beam in the cold atomic system and the thermal atomic system is 34% and 31%, respectively, which is very close to the ideal diffraction efficiency of the sinusoidal grating. However, it is more difficult to prepare the cold atomic system than to prepare the thermal atomic system in the practical application, so the study of the electromagnetically induced grating effect in the thermal atomic system may be helpful for practical applications.
基金Project supported by the National Natural Science Foundation of China (Grant No. 60978013)the Shanghai Rising Star Project,China (Grant No. 11QA1407400)
文摘We theoretically investigate the Doppler effect on optical bistability in an N-type active Raman gain atomic system inside an optical ring cavity. It is shown that the Doppler effect can greatly enhance the dispersion and thus create the bistable behaviour or greatly increase the bistable region, which has been known as the positive Doppler effect on optical bistability. In addition, we find that a positive Doppler effect can change optical bistability from the hybrid dispersion-gain type to a dispersive type.
基金Project supported by the Key Program of the National Natural Science Foundation of China (Grant No.60837004)the Key Project of Jiangxi Electric Power Company (Grant Nos.200950801 and 200950802)
文摘This paper investigates the breaking point between fast- and slow-light in a degenerate two-level atomic system, where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the strength of the pumping field. An equivalent incoherent pumping rate is introduced in this simplified theoretical model which exploits the dependence of this feature. The experimental observation is presented as evidence of the breaking point where the injected power is about 0.08 mW.
基金the National Natural Science Foundation of China(Grant No.11205001)the National Basic Research Program of China(Grant No.2010CB234607)the Postdoctoral Science Foundation of Anhui University,China
文摘We have investigated the two-dimensional （2D） atom localization via probe absorption in a coherently driven four-level atomic system by means of a radio-frequency field driving a hyperfine transition. It is found that the detecting probability and precision of 2D atom localization can be significantly improved via adjusting the system parameters. As a result, our scheme may be helpful in laser cooling or the atom nano-lithography via atom localization.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11274112 and 11474092the Key Project of Shanghai Municipal Education Commission under Grant No 14ZZ056+1 种基金the Shanghai Natural Science Fund Project under Grant No14ZR1410300the Key Research Project of Henan Province Education Department under Grant No 13A140818
文摘We theoretically investigate the phenomena of electromagnetically induced grating in an M-type five-level atomic system. It is found that a weak field can be effectively diffracted into high-order directions using a standing wave coupling field, and different depths of the phase modulation can disperse the diffraction light into different orders. When the phase modulation depth is approximated to the orders of π, 2π and 3π, the first-, second- and third-order diffraction intensity reach the maximum, respectively. Thus we can take advantage of the phase modulation to control the probe light dispersing into the required high orders.
基金the National R&D Program of China(Grant No.2017YFA0304203)the National Natural Science Foundation of China(Grant Nos.61875112,61705122,62075121,and 91736209)+1 种基金the Program for Sanjin Scholars of Shanxi Province,the Key Research and Development Program of Shanxi Province for International Cooperation(Grant No.201803D421034)Shanxi Scholarship Council of China(Grant Nos.2020-073),and 1331KSC.
文摘Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibilities for quantum optics research,which can be obtained under the localization method.We study the behavior of three-dimensional(3D)Rydberg atom localization in a four-level configuration with the measurement of the spatial optical absorption.The atomic localization precision depends strongly on the detuning and Rabi frequency of the involved laser fields.A 100%probability of finding the Rydberg atom at a specific 3D position is achieved with precision of~0.031λ.This work demonstrates the possibility for achieving the 3D atom localization of the Rydberg atom in the experiment.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10904025,10674037 and 50836002)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20092302120024)+3 种基金the China Postdoctoral Science Foundation (Grant No. 20090451007)the Development Program for Outstanding Young Teachers in Harbin Institute of Technology,China (Grant No. HITQNJS. 2009. 030.)the National Basic Research Program of China (Grant No. 2007CB307001)the Program of Excellent Team in Harbin Institute of Technology China
文摘The spontaneous emission decay dynamics of a tripod configuration four-level atom driven by a single laser field is studied. Under different initial conditions, we discuss the effects of quantum interference and detuning of external driving field on atomic spontaneous emission properties. For the larger detuning, the interesting phenomena of the spectral line narrowing are found which stem from the contribution of external driving field.
基金Project supported by the Knowledge Innovation Program of the Chinese Academy of Sciences and the National Basic Research Program of China
文摘Transient coherent oscillations in a closed A system under far-off resonant Raman fields were investigated theoreti- cally. It has been found that the coherent superposition of the ground states can be formed due to the absorption even for initial maximal mixed ground states. The absorption oscillates with a period depending on the two-photon detuning when the system is initially in a transparent state and the two-photon Raman detuning is suddenly changed. The amplitude of the absorption decays with the decay rate of the ground states, which is different from the case when the lasers are applied resonantly. These transient coherent oscillations can be used to measure the relaxation rate of the ground states.
基金Project supported by the National Natural Science Foundation of China(Grant No.11374096).
文摘We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomic system is lower than that in the V-type atomic system which is exactly the same as that in the Λ-type atomic system. In addition, the effect of relative coupling strength on entropic uncertainty is opposite in Markov region and non-Markov region, and the influence of a common environment and independent environments in Markov region and non-Markov region is also opposite. One can reduce the entropic uncertainty by decreasing relative coupling strength or placing the system in two separate environments in the Markov case. In the non-Markov case, the entropic uncertainty can be reduced by increasing the relative coupling strength or by placing the system in a common environment.
基金Supported by the National Natural Science Foundation of China under Grant No 10974151, the New Century Excellent Talent Project （NCET） of the Ministry of Education of China under Grant No 08-0431, the Cross-Disciplinary Project of Xi＇an Jiaotong University under Grant No 2009xjtujc08.
文摘We illustrate our experimental observation of coexisting the controllable spatial splitting and intensity suppression of four-wave mixing （FWM） beam in a V-type three-level atomic system. The peak number and separation distance of the FWM beam are controlled by the intensities and frequencies of the laser beams, as well as atomic density.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60768001 and 10464002)
文摘In the present paper, we investigate the behavior of two-dimensional atom localization in a five-level M-scheme atomic system driven by two orthogonal standing-wave fields. We find that the precision and resolution of the atom localization depends on the probe field detuning significantly. And because of the effect of the microwave field, an atom can be located at a particular position via adjusting the system parameters.
基金supported by the National Natural Science Foundation of China(Grant Nos.12174402 and 12393821)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB0920100 and XDB0920101)+2 种基金the Nature Science Foundation of Hubei Province(Grant Nos.2019CFA058 and 2022CFA013)supported by the Natural Sciences and Engineering Research Council of Canada(NSERC)supported in part by NSF grant PHY-2116679.All the calculations are finished on the APM-Theoretical Computing Cluster(APMTCC)。
文摘For atoms in external electric fields,the hyperpolarizabilities are the coefficients describing the nonlinear interactions contributing to the induced energies at the fourth power of the applied electric fields.Accurate evaluations of these coefficients for various systems are crucial for improving precision in advanced atom-based optical lattice clocks and for estimating field-induced effects in atoms for quantum information applications.However,there is a notable scarcity of research on atomic hyperpolarizabilities,especially in the relativistic realm.Our work addresses this gap by establishing a novel set of alternative formulas for the hyperpolarizability based on the fourth-order perturbation theory.These formulas offer a more reasonable regrouping of scalar and tensor components compared to previous formulas,thereby enhancing their correctness and applicability.To validate our formulas,we perform the calculations for the ground and low-lying excited pure states of few-electron atoms H,Li,and Be^(+).The highly accurate results obtained for the H atom could serve as benchmarks for further development of other theoretical methods.
基金This work was supported by the National Natural Science Foundation of China(62271299)Shanghai Sailing Program(22YF1413400).Shanghai Engineering Research Center for We thank the Integrated Circuits and Advanced Display Materials.
文摘Reasonably constructing an atomic interface is pronouncedly essential for surface-related gas-sensing reaction.Herein,we present an ingen-ious feedback-regulation system by changing the interactional mode between single Pt atoms and adjacent S species for high-efficiency SO_(2)sensing.We found that the single Pt sites on the MoS_(2)surface can induce easier volatiliza-tion of adjacent S species to activate the whole inert S plane.Reversely,the activated S species can provide a feedback role in tailoring the antibonding-orbital electronic occupancy state of Pt atoms,thus creating a combined system involving S vacancy-assisted single Pt sites(Pt-Vs)to synergistically improve the adsorption ability of SO_(2)gas molecules.Further-more,in situ Raman,ex situ X-ray photoelectron spectroscopy testing and density functional theory analysis demonstrate the intact feedback-regulation system can expand the electron transfer path from single Pt sites to whole Pt-MoS_(2)supports in SO_(2)gas atmosphere.Equipped with wireless-sensing modules,the final Pt1-MoS_(2)-def sensors array can further realize real-time monitoring of SO_(2)levels and cloud-data storage for plant growth.Such a fundamental understanding of the intrinsic link between atomic interface and sensing mechanism is thus expected to broaden the rational design of highly effective gas sensors.
基金National Natural Science Foundation of China(22309032,22109120,and 62104170)Guangdong Basic and Applied Basic Research Foundation(2022A1515011737)+2 种基金Science and Technology Program of Guangzhou(2023A04J1395)GDAS’Project of Science and Technology Development(2021GDASYL-20210102010)Zhejiang Provincial Natural Science Foundation of China(LY23F040001)。
文摘Photocatalytic oxygen reduction for hydrogen peroxide(H_(2)O_(2))synthesis presents a green and costeffective production method.However,achieving highly selective H_(2)O_(2)synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative by-products.Herein,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H_(2)O_(2)and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride(CNRb).The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h^(-1)for H_(2)O_(2)generation and photooxidation rate of 3.75 mM h^(-1)for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion(SCC)efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical formation.This is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product formation.This study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H_(2)O_(2)coupled with biomass valorization.
基金supported by the open funds of Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, Chinathe funding from Guangdong Natural Science Funds (No. 2023A0505050107)。
文摘Atomically precise metal nanoclusters are an emerging type of nanomaterial which has diverse interfacial metal-ligand coordination motifs that can significantly affect their physicochemical properties and functionalities.Among that,Cu nanoclusters have been gaining continuous increasing research attentions,thanks to the low cost,diversified structures,and superior catalytic performance for various reactions.In this review,we first summarize the recent progress regarding the synthetic methods of atomically precise Cu nanoclusters and the coordination modes between Cu and several typical ligands and then discuss the catalytic applications of these Cu nanoclusters with some explicit examples to explain the atomical-level structure-performance relationship.Finally,the current challenges and future research perspectives with some critical thoughts are elaborated.We hope this review can not only provide a whole picture of the current advances regarding the synthesis and catalytic applications of atomically precise Cu nanoclusters,but also points out some future research visions in this rapidly booming field.
基金Project supported by the Scientific and Technological Program Foundation of Dezhou,Shandong Province of China (Grant No20080153)the Scientific Research Fund of Dezhou University of China (Grant No 07024)
文摘This paper investigates the entropy squeezing of a moving two-level atom interacting with the two-mode entangled coherent field via two-photon transition by using an entropic uncertainty relation and the degree of entanglement between the two-mode fields by using quantum relative entropy.The results obtained from numerical calculation indicate that the squeezed period,the duration of entropy squeezing and the maximal squeezing can be controlled by appropriately choosing the intensity of the light field,the atomic motion and the field-mode structure.The atomic motion leads to the periodic recovery of the initial maximal degree of entanglement between the two-mode fields.Moreover,there exists a corresponding relation between the time evolution properties of the atomic entropy squeezing and those of the entanglement between the two-mode fields.
文摘Using modularized components, we have built a miniaturized optical system for 87Rb atomic fountain clock that is fitted on an 80 cm × 60 cm optical breadboard. Compared with the conventional optical setup on the table, our system is more compact, more robust and miniaturized. Taking advantage of this system, laser beams are transmitted through eight optical fibre patch cords from the optical breadboard to an ultra high vacuum system. This optical setup has operated for five months in our fountain system and required no alignment.
基金supported by the National Natural Science Foundation of China(22234005,21974070)the Natural Science Foundation of Jiangsu Province(BK20222015)。
文摘Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered.
基金supported by the Teli Fellowship from Beijing Institute of Technology,the National Natural Science Foundation of China(Nos.52303366,22173109).
文摘In recent years,low-dimensional transition metal chalcogenide(TMC)materials have garnered growing research attention due to their superior electronic,optical,and catalytic properties compared to their bulk counterparts.The controllable synthesis and manipulation of these materials are crucial for tailoring their properties and unlocking their full potential in various applications.In this context,the atomic substitution method has emerged as a favorable approach.It involves the replacement of specific atoms within TMC structures with other elements and possesses the capability to regulate the compositions finely,crystal structures,and inherent properties of the resulting materials.In this review,we present a comprehensive overview on various strategies of atomic substitution employed in the synthesis of zero-dimensional,one-dimensional and two-dimensional TMC materials.The effects of substituting elements,substitution ratios,and substitution positions on the structures and morphologies of resulting material are discussed.The enhanced electrocatalytic performance and photovoltaic properties of the obtained materials are also provided,emphasizing the role of atomic substitution in achieving these advancements.Finally,challenges and future prospects in the field of atomic substitution for fabricating low-dimensional TMC materials are summarized.
基金supported by the National Natural Science Foundation of China (No.22309023,22179014)the project of Natural Science Foundation of Chongqing (Grant No.CSTB2022NSCQMSX0270)+3 种基金the China Postdoctoral Science Foundation (No.2022M720593)the youth project of science and technology research program of Chongqing Municipal Education Commission of China (Grant No.KJQN202201127)the Scientific Research Foundation of Chongqing University of Technology (2022ZDZ011,2022PYZ026)the special funding for research projects of Chongqing Human Resources and Social Security Bureau (Grant No.2022CQBSHTB1023)。
文摘The development of redox bifunctional electrocatalysts with high performance,low cost,and long lifetimes is essential for achieving clean energy goals.This study proposed an atom capture strategy for anchoring dual single atoms(DSAs)in a zinc-zeolitic imidazolate framework(Zn-ZIF),followed by calcination under an N_(2) atmosphere to synthesize ruthenium-platinum DSAs supported on a nitrogendoped carbon substrate(RuPt DSAs-NC).Theoretical calculations showed that the degree of Ru 5dxz-~*O 2p_x orbital hybridization was high when^(*)O was adsorbed at the Ru site,indicating enhanced covalent hybridization of metal sites and oxygen ligands,which benefited the adsorption of intermediate species.The presence of the RuPtN_6 active center optimized the absorption-desorption behavior of intermediates,improving the electrocatalytic performance of the oxygen reduction reaction(ORR)and the oxygen evolution reaction(DER),RuPt DSAs-NC exhibited a 0.87 V high half-wave potential and a 268 mV low overpotential at 10 mA cm^(-2)in an alkaline environment.Furthermore,rechargeable zinc-air batteries(ZABs)achieved a peak power density of 171 MW cm^(-2).The RuPt DSAs-NC demonstrated long-term cycling for up to 500 h with superior round-trip efficiency.This study provided an effective structural design strategy to construct DSAs active sites for enhanced electrocata lytic performance.
