Microbial fuel cells have already been used as biosensors to monitor assimilable organic carbon(AOC).However,their signal production from AOC is known to be completely suppressed by dissoved oxygen(DO).In this study,t...Microbial fuel cells have already been used as biosensors to monitor assimilable organic carbon(AOC).However,their signal production from AOC is known to be completely suppressed by dissoved oxygen(DO).In this study,two identical microbial electrolysis cell(MEC)based biosensors were inoculated with marine sediment and operated at two different anodic potentials,namely-300 mV and+250 mV relative to Ag/AgCl.The MEC biosensor operated under positive anodic potential conditions had electrochemically active microbial communities on the anode,including members of the Shewanellaceae,Pseudoalteromonadaceae,and Clostridiaceae families.However,the strictly anaerobic members of the Desulfuromonadaceae,Desulfobulbaceae and Desulfobacteraceae families were found only in the negative anodic potential MEC biosensor.The positive anodic potential MEC biosensor showed several other advantages as well,such as faster start-up,significantly higher maximum current production,fivefold improvement in the AOC detection limit,and tolerance of low dissolved oxygen,compared to those obtained from the negative anodic potential MEC biosensor.The developed positive anodic potential MEC biosensor can thus be used as a real-time and inexpensive detector of AOC concentrations in high saline and low DO seawater.展开更多
利用第二次全国土壤调查土壤质地数据（SNSS）和中国区域陆地覆盖资料（CLCV）将陆面过程模式CLM3.5（Community Land Model version 3.5）中基于联合国粮食农业组织发展的土壤质地数据（FAO）和MODIS卫星反演的陆地覆盖数据（MODIS）...利用第二次全国土壤调查土壤质地数据（SNSS）和中国区域陆地覆盖资料（CLCV）将陆面过程模式CLM3.5（Community Land Model version 3.5）中基于联合国粮食农业组织发展的土壤质地数据（FAO）和MODIS卫星反演的陆地覆盖数据（MODIS）进行了替换,使用中国气象局陆面数据同化系统（CMA Land Data Assimilation System,CLDAS）大气强迫场资料,分别驱动基于同时改进土壤质地和陆地覆盖数据的CLM3.5（CLM-new）、基于只改进陆地覆盖数据的CLM3.5（CLM-clcv）、基于只改进土壤质地数据的CLM3.5（CLM-snss）和基于原始下垫面数据的CLM3.5（CLM-ctl）,对内蒙古地区2011~2013年土壤湿度的时空变化进行模拟试验,研究下垫面改进对CLM3.5模拟土壤湿度的影响。将四组模拟结果与46个土壤水分站点观测数据进行对比分析,结果表明：相对于控制试验,CLM-clcv、CLM-snss和CLM-new都能不同程度地改进土壤湿度模拟,其中CLM-clcv主要在呼伦贝尔改进明显,CLM-snss则在除呼伦贝尔以外的大部地区改进显著,CLM-ctl模拟的土壤湿度在各层上均系统性偏大,而CLM-new模拟土壤湿度最好地反映出内蒙古地区观测的土壤湿度的时空变化特征,显著改善了土壤湿度的模拟,体现在与观测值有着更高的相关系数和更小的平均偏差与均方根误差。展开更多
研究I的结果表明:线性平衡方程(LBE)在热带地区不适用,而进一步改进方向是削弱LBE在该区域的约束程度。本文以此为基础,在GRAPES(global/regional assimilation and prediction system)全球变分同化系统中引入动力与统计混合平衡约束方...研究I的结果表明:线性平衡方程(LBE)在热带地区不适用,而进一步改进方向是削弱LBE在该区域的约束程度。本文以此为基础,在GRAPES(global/regional assimilation and prediction system)全球变分同化系统中引入动力与统计混合平衡约束方案。新方案在逐层求解LBE的基础上增加垂直方向的线性回归,回归系数随纬度和高度变化。针对背景误差协方差的分析表明,新方案可以更好的保证独立分析变量间预报误差不相关的基本要求,并大幅度减小热带地区平衡气压预报误差方差的量值和占总方差的比例。单点试验结果表明,与LBE方案相比,新方案对中、高纬影响很小,但在热带地区成功实现了风、压场分析的解耦,两者分析更为独立。并且,虽未考虑具体波动模态,但新方案给出的风、压场协相关结构与研究I的理论分析结果相近。一个月的同化循环与预报结果表明,引入新方案后,赤道外地区的同化预报效果为中性偏正,而热带地区风场的同化预报效果显著提高,LBE方案中平流层低层的风场同化预报异常被基本消除。展开更多
在WRFDA-3DVar(Weather Research and Forecasting model’s 3-dimensional variational data assimilation)的框架下,添加了新的探测器AMSR2(Advanced Microwave Scanning Radiometer 2)微波辐射率资料的同化模块,实现了AMSR2辐射率资...在WRFDA-3DVar(Weather Research and Forecasting model’s 3-dimensional variational data assimilation)的框架下,添加了新的探测器AMSR2(Advanced Microwave Scanning Radiometer 2)微波辐射率资料的同化模块,实现了AMSR2辐射率资料在中小尺度同化系统中的有效使用。台风"山神"(Son-Tinh)直接同化AMSR2资料的个例试验结果表明,AMSR2资料可以很好的探测出台风的形态,并且与没有同化该资料的控制试验相比,同化AMSR2辐射率资料可以有效提高模式分析场的质量,进一步提高了台风中心气压,最大风速和台风路径的预报。展开更多
本研究在WACCM+DART(Whole Atmosphere Community Climate Model,Data Assimilation Research TestBed)临近空间资料同化预报系统中加入SABER(Sounding of the Atmosphere using Broadband Emission Radiometry)和MLS(Microwave Limb So...本研究在WACCM+DART(Whole Atmosphere Community Climate Model,Data Assimilation Research TestBed)临近空间资料同化预报系统中加入SABER(Sounding of the Atmosphere using Broadband Emission Radiometry)和MLS(Microwave Limb Sounder)臭氧观测同化接口,并以2016年2月一次平流层爆发性增温(SSW)过程为模拟个例进行了SABER和MLS臭氧观测同化试验,得出以下结论:同化SABER和MLS臭氧体积浓度观测得出的WACCM+DART臭氧分析场能够较真实反映SSW期间北极上空平流层臭氧廓线随时间的演变特征,且与ERA5(Fifth Generation of ECMWF Reanalyses)再分析资料描述的臭氧变化特征具有很好的一致性;基于SABER和MLS臭氧观测的WACCM臭氧6 h预报检验表明同化臭氧观测对臭氧分析和预报误差的改善效果主要体现在南半球高纬平流层和北半球中高纬平流层中上层—中间层底部;基于ERA5再分析资料的WACCM+DART分析场检验表明同化SABER和MLS臭氧体积浓度资料可在提高北半球高纬地区上平流层—中间层底部臭氧场分析质量的同时减小该地区上平流层—中间层底部温度场和中间层底部纬向风场的分析误差;基于MLS臭氧资料的臭氧中期预报检验表明相对控制试验同化SABER和MLS臭氧体积浓度资料能更好改善0~5 d下平流层和中间层底部臭氧的预报效果。展开更多
卫星资料凭着卫星遥感的全球性、连续性和高频次观测等优势,成为一种重要的非常规资料源,但卫星观测仍然存在各种各样的观测误差,其中包含由于观测偶然性所造成的统计学上的随机误差及仪器本身和辐射传输模式等造成的系统性偏差,这些误...卫星资料凭着卫星遥感的全球性、连续性和高频次观测等优势,成为一种重要的非常规资料源,但卫星观测仍然存在各种各样的观测误差,其中包含由于观测偶然性所造成的统计学上的随机误差及仪器本身和辐射传输模式等造成的系统性偏差,这些误差在很大程度上影响了卫星资料的质量。文中提出了一种能有效订正卫星观测资料系统性偏差的梯度信息同化算法,该方法用一个梯度算子进行模式变量与观测变量的梯度变换,从而达到订正系统性偏差的目的。本文利用WRF(Weather Research Forecast)模式及其同化模式WRFDA(WRF Data Assimilation system),以及AIRS(Atmospheric Infrared Sounder)资料,对台风"圆规"进行了实际的数值模拟和同化试验,数值结果表明,梯度信息同化方法能明显改善台风路径的模拟,在处理可信度较低的资料时仍然适用。另外,通过同化诊断分析,发现卫星资料的系统性偏差对于台风数值模拟有较大影响,而文中提出的梯度信息同化方法能较好的解决此类问题。展开更多
Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwa...Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwangshan,Dawangshan,Gushan and Niangniangshan Formations from early to late.All these volcanic rocks are rich in alkali,and show the similar patterns in rare earth element(REE) distribution.However,some differences can be found in the trace elements and REE patterns.The study of petrology and REE geochemical characteristics shows that these rocks are derived from the underplating of the lithospheric mantle and are contaminated by crustal materials,undergo AFC process during the magmatic evolution.展开更多
Based on the detailed geological investigation and record of galleries and drill holes, a new idea has been advanced that granodiorite is earlier than quartz monzodiorite porphyry. Both of them are products of two dif...Based on the detailed geological investigation and record of galleries and drill holes, a new idea has been advanced that granodiorite is earlier than quartz monzodiorite porphyry. Both of them are products of two different magmatic intrusive activities. The analysis results of trace elements show that the Sr content is beyond any other crustal rock and the Th content is beyond that of Ta. The whole-rock analysis indicates that rockbody is rich in CaO and poor in K2O. In the composition of Pb istope of rockbody, the ratio of 207 Pb to 204Pb is less than 15. 60. All these show that the magma mainly comes from the upper mantle. Ti,Zr,Cr,Nb trace elements and the relation between the Gardini index(τ) and the Rittmann index(σ) indicate that the rockbodies are formed in the orogenic belt and island arc tectonic setting. The summation (2REE) and the characteristic value(m( La)/m( Yb)) of the rare earth elements show that the original rock is alkalic basalt. The analysis of the characteristic values of REE and the quantitative modeling calculation indicate that the rock-forming process is dominated by mixed crystallization. According to the analysis on the rock-forming order, magmatic source, tectonic setting and rock-forming process, combined with the achievements of regional rock-controlling structures and division of sublayer of crust, it is believed that Fenghuangshan rock body derives from the deep-seated alkalic basalt magma. The rock-forming process has undertaken sialic and calcareous assimilation and contamination of two different degrees. The rock-forming model belongs to the typical assimilation and fractional cryatalization mechanism.展开更多
基金Zhenjiang City Key R&D Plan Modern Agriculture Project(No.SH2021017)Zhenjiang“Jinshan Talents”Project 2021Jiangsu Province“Six Talent Peak”Program(No.XCL-111)。
文摘Microbial fuel cells have already been used as biosensors to monitor assimilable organic carbon(AOC).However,their signal production from AOC is known to be completely suppressed by dissoved oxygen(DO).In this study,two identical microbial electrolysis cell(MEC)based biosensors were inoculated with marine sediment and operated at two different anodic potentials,namely-300 mV and+250 mV relative to Ag/AgCl.The MEC biosensor operated under positive anodic potential conditions had electrochemically active microbial communities on the anode,including members of the Shewanellaceae,Pseudoalteromonadaceae,and Clostridiaceae families.However,the strictly anaerobic members of the Desulfuromonadaceae,Desulfobulbaceae and Desulfobacteraceae families were found only in the negative anodic potential MEC biosensor.The positive anodic potential MEC biosensor showed several other advantages as well,such as faster start-up,significantly higher maximum current production,fivefold improvement in the AOC detection limit,and tolerance of low dissolved oxygen,compared to those obtained from the negative anodic potential MEC biosensor.The developed positive anodic potential MEC biosensor can thus be used as a real-time and inexpensive detector of AOC concentrations in high saline and low DO seawater.
文摘利用第二次全国土壤调查土壤质地数据（SNSS）和中国区域陆地覆盖资料（CLCV）将陆面过程模式CLM3.5（Community Land Model version 3.5）中基于联合国粮食农业组织发展的土壤质地数据（FAO）和MODIS卫星反演的陆地覆盖数据（MODIS）进行了替换,使用中国气象局陆面数据同化系统（CMA Land Data Assimilation System,CLDAS）大气强迫场资料,分别驱动基于同时改进土壤质地和陆地覆盖数据的CLM3.5（CLM-new）、基于只改进陆地覆盖数据的CLM3.5（CLM-clcv）、基于只改进土壤质地数据的CLM3.5（CLM-snss）和基于原始下垫面数据的CLM3.5（CLM-ctl）,对内蒙古地区2011~2013年土壤湿度的时空变化进行模拟试验,研究下垫面改进对CLM3.5模拟土壤湿度的影响。将四组模拟结果与46个土壤水分站点观测数据进行对比分析,结果表明：相对于控制试验,CLM-clcv、CLM-snss和CLM-new都能不同程度地改进土壤湿度模拟,其中CLM-clcv主要在呼伦贝尔改进明显,CLM-snss则在除呼伦贝尔以外的大部地区改进显著,CLM-ctl模拟的土壤湿度在各层上均系统性偏大,而CLM-new模拟土壤湿度最好地反映出内蒙古地区观测的土壤湿度的时空变化特征,显著改善了土壤湿度的模拟,体现在与观测值有着更高的相关系数和更小的平均偏差与均方根误差。
文摘研究I的结果表明:线性平衡方程(LBE)在热带地区不适用,而进一步改进方向是削弱LBE在该区域的约束程度。本文以此为基础,在GRAPES(global/regional assimilation and prediction system)全球变分同化系统中引入动力与统计混合平衡约束方案。新方案在逐层求解LBE的基础上增加垂直方向的线性回归,回归系数随纬度和高度变化。针对背景误差协方差的分析表明,新方案可以更好的保证独立分析变量间预报误差不相关的基本要求,并大幅度减小热带地区平衡气压预报误差方差的量值和占总方差的比例。单点试验结果表明,与LBE方案相比,新方案对中、高纬影响很小,但在热带地区成功实现了风、压场分析的解耦,两者分析更为独立。并且,虽未考虑具体波动模态,但新方案给出的风、压场协相关结构与研究I的理论分析结果相近。一个月的同化循环与预报结果表明,引入新方案后,赤道外地区的同化预报效果为中性偏正,而热带地区风场的同化预报效果显著提高,LBE方案中平流层低层的风场同化预报异常被基本消除。
文摘在WRFDA-3DVar(Weather Research and Forecasting model’s 3-dimensional variational data assimilation)的框架下,添加了新的探测器AMSR2(Advanced Microwave Scanning Radiometer 2)微波辐射率资料的同化模块,实现了AMSR2辐射率资料在中小尺度同化系统中的有效使用。台风"山神"(Son-Tinh)直接同化AMSR2资料的个例试验结果表明,AMSR2资料可以很好的探测出台风的形态,并且与没有同化该资料的控制试验相比,同化AMSR2辐射率资料可以有效提高模式分析场的质量,进一步提高了台风中心气压,最大风速和台风路径的预报。
文摘本研究在WACCM+DART(Whole Atmosphere Community Climate Model,Data Assimilation Research TestBed)临近空间资料同化预报系统中加入SABER(Sounding of the Atmosphere using Broadband Emission Radiometry)和MLS(Microwave Limb Sounder)臭氧观测同化接口,并以2016年2月一次平流层爆发性增温(SSW)过程为模拟个例进行了SABER和MLS臭氧观测同化试验,得出以下结论:同化SABER和MLS臭氧体积浓度观测得出的WACCM+DART臭氧分析场能够较真实反映SSW期间北极上空平流层臭氧廓线随时间的演变特征,且与ERA5(Fifth Generation of ECMWF Reanalyses)再分析资料描述的臭氧变化特征具有很好的一致性;基于SABER和MLS臭氧观测的WACCM臭氧6 h预报检验表明同化臭氧观测对臭氧分析和预报误差的改善效果主要体现在南半球高纬平流层和北半球中高纬平流层中上层—中间层底部;基于ERA5再分析资料的WACCM+DART分析场检验表明同化SABER和MLS臭氧体积浓度资料可在提高北半球高纬地区上平流层—中间层底部臭氧场分析质量的同时减小该地区上平流层—中间层底部温度场和中间层底部纬向风场的分析误差;基于MLS臭氧资料的臭氧中期预报检验表明相对控制试验同化SABER和MLS臭氧体积浓度资料能更好改善0~5 d下平流层和中间层底部臭氧的预报效果。
文摘卫星资料凭着卫星遥感的全球性、连续性和高频次观测等优势,成为一种重要的非常规资料源,但卫星观测仍然存在各种各样的观测误差,其中包含由于观测偶然性所造成的统计学上的随机误差及仪器本身和辐射传输模式等造成的系统性偏差,这些误差在很大程度上影响了卫星资料的质量。文中提出了一种能有效订正卫星观测资料系统性偏差的梯度信息同化算法,该方法用一个梯度算子进行模式变量与观测变量的梯度变换,从而达到订正系统性偏差的目的。本文利用WRF(Weather Research Forecast)模式及其同化模式WRFDA(WRF Data Assimilation system),以及AIRS(Atmospheric Infrared Sounder)资料,对台风"圆规"进行了实际的数值模拟和同化试验,数值结果表明,梯度信息同化方法能明显改善台风路径的模拟,在处理可信度较低的资料时仍然适用。另外,通过同化诊断分析,发现卫星资料的系统性偏差对于台风数值模拟有较大影响,而文中提出的梯度信息同化方法能较好的解决此类问题。
基金Project(2011BAB04D01) supported by the National Science and Technology Support Program of China
文摘Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwangshan,Dawangshan,Gushan and Niangniangshan Formations from early to late.All these volcanic rocks are rich in alkali,and show the similar patterns in rare earth element(REE) distribution.However,some differences can be found in the trace elements and REE patterns.The study of petrology and REE geochemical characteristics shows that these rocks are derived from the underplating of the lithospheric mantle and are contaminated by crustal materials,undergo AFC process during the magmatic evolution.
基金the National "973" Project (No. G1999043206) the National Scientific Project for Tackcling Key Problems(No. 2001BA609A-06-02).
文摘Based on the detailed geological investigation and record of galleries and drill holes, a new idea has been advanced that granodiorite is earlier than quartz monzodiorite porphyry. Both of them are products of two different magmatic intrusive activities. The analysis results of trace elements show that the Sr content is beyond any other crustal rock and the Th content is beyond that of Ta. The whole-rock analysis indicates that rockbody is rich in CaO and poor in K2O. In the composition of Pb istope of rockbody, the ratio of 207 Pb to 204Pb is less than 15. 60. All these show that the magma mainly comes from the upper mantle. Ti,Zr,Cr,Nb trace elements and the relation between the Gardini index(τ) and the Rittmann index(σ) indicate that the rockbodies are formed in the orogenic belt and island arc tectonic setting. The summation (2REE) and the characteristic value(m( La)/m( Yb)) of the rare earth elements show that the original rock is alkalic basalt. The analysis of the characteristic values of REE and the quantitative modeling calculation indicate that the rock-forming process is dominated by mixed crystallization. According to the analysis on the rock-forming order, magmatic source, tectonic setting and rock-forming process, combined with the achievements of regional rock-controlling structures and division of sublayer of crust, it is believed that Fenghuangshan rock body derives from the deep-seated alkalic basalt magma. The rock-forming process has undertaken sialic and calcareous assimilation and contamination of two different degrees. The rock-forming model belongs to the typical assimilation and fractional cryatalization mechanism.
