Antimony mercaplde heat stabilizer for polyvinyl chlorideis synthesized from antimony trioxide and mercaptocarboxylic acid esters, HS(CH2).COoi-C8H17 (n=1～2) at 100～115 C In the presence of 0. 5%～1 % an organic aci...Antimony mercaplde heat stabilizer for polyvinyl chlorideis synthesized from antimony trioxide and mercaptocarboxylic acid esters, HS(CH2).COoi-C8H17 (n=1～2) at 100～115 C In the presence of 0. 5%～1 % an organic acid catalyst. Some physicochemicalconstants of the compounds, such as density and refractive index, aredetermined. The complexes are hydrolabll in aqueous solutions andthe bond of Sb-S is weaker than that of Sb-o. The forming bondproperty of antimony tris (mercaptoacid ester ) has been elucidatedby measurement of infrared spectra in comparison with mercaptocarboxylic acid esters. The polyvinyl chloride resins containing antimony mercaptide heat stabilizers, do not darken at elevated temperatures and exhibit a high degree of stability. It is proposed that mercaptocarboxylic acid ester freeradicals can esterify PVC microradicals at carbon atoms with upaired electrons.展开更多
文摘Antimony mercaplde heat stabilizer for polyvinyl chlorideis synthesized from antimony trioxide and mercaptocarboxylic acid esters, HS(CH2).COoi-C8H17 (n=1～2) at 100～115 C In the presence of 0. 5%～1 % an organic acid catalyst. Some physicochemicalconstants of the compounds, such as density and refractive index, aredetermined. The complexes are hydrolabll in aqueous solutions andthe bond of Sb-S is weaker than that of Sb-o. The forming bondproperty of antimony tris (mercaptoacid ester ) has been elucidatedby measurement of infrared spectra in comparison with mercaptocarboxylic acid esters. The polyvinyl chloride resins containing antimony mercaptide heat stabilizers, do not darken at elevated temperatures and exhibit a high degree of stability. It is proposed that mercaptocarboxylic acid ester freeradicals can esterify PVC microradicals at carbon atoms with upaired electrons.
