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基于神经网络的优化算法在EDA中应用研究进展 被引量:1
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作者 赵晨晖 贺珊 +1 位作者 刘先明 郭东辉 《计算机应用研究》 北大核心 2025年第1期1-10,共10页
为了应对芯片设计复杂度的提升,电子设计自动化工具和方法也在不断进步。然而,EDA需要协调达到最佳的功率、性能和面积,通常其不能保证最优的解决方案。EDA工具在电路设计阶段包括逻辑综合、布局布线及验证等均属于多目标、多约束的非... 为了应对芯片设计复杂度的提升,电子设计自动化工具和方法也在不断进步。然而,EDA需要协调达到最佳的功率、性能和面积,通常其不能保证最优的解决方案。EDA工具在电路设计阶段包括逻辑综合、布局布线及验证等均属于多目标、多约束的非线性规划求解过程,且为了更好解决求解中的不确定性和易于出现局域极值等难题,基于神经网络的优化算法已被集成到EDA工具的设计流程中。首先对EDA中的优化问题、多目标优化计算及基于神经网络的优化算法进行了简要概述,继而详细梳理了基于神经网络的优化算法在逻辑综合、布局布线及验证等不同设计阶段中的优化求解方法,并阐述了当前研究所面临的挑战与机遇,希望为集成电路自动化设计及相关领域研究提供参考。 展开更多
关键词 电子设计自动化 非线性规划 多目标优化 神经网络 优化计算
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Marine Predator Algorithm-based Sliding Mode Control of a Novel Motion Simulator for High Column Sloshing Experiments
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作者 DU Zun-feng CHEN Xiang-yu +2 位作者 BAI Hao ZHU Hai-ming HAN Mu-xuan 《船舶力学》 EI CSCD 北大核心 2024年第12期1835-1848,共14页
Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Slidi... Sloshing experiment is crucial to determine the reaction performance of regeneration columns on an offshore floating platform.A novel type of column motion simulating device and a Marine Predator Algorithm-based Sliding Mode Controller(MPA-SMC)are proposed for such sloshing experiments.The simulator consists of a Stewart platform and a steel framework.The Stewart platform is located at the column's center of gravity(CoG)and supported by the steel framework.The platform's hydraulic servo system is controlled by a sliding mode controller with parameters optimized by MPA to improve robustness and precision.A numerical sloshing experiment is conducted using the proposed device and controller.The results show that the novel motion simulator has lower torque during the column sloshes,and the proposed controller performs better than a well-tuned PID controller in terms of target tracking precision and anti-interference capability. 展开更多
关键词 regeneration column sloshing experiment motion simulator Stewart platform sliding mode control marine predator algorithm
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Research on Euclidean Algorithm and Reection on Its Teaching
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作者 ZHANG Shaohua 《应用数学》 北大核心 2025年第1期308-310,共3页
In this paper,we prove that Euclid's algorithm,Bezout's equation and Divi-sion algorithm are equivalent to each other.Our result shows that Euclid has preliminarily established the theory of divisibility and t... In this paper,we prove that Euclid's algorithm,Bezout's equation and Divi-sion algorithm are equivalent to each other.Our result shows that Euclid has preliminarily established the theory of divisibility and the greatest common divisor.We further provided several suggestions for teaching. 展开更多
关键词 Euclid's algorithm Division algorithm Bezout's equation
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An Algorithm for Cloud-based Web Service Combination Optimization Through Plant Growth Simulation
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作者 Li Qiang Qin Huawei +1 位作者 Qiao Bingqin Wu Ruifang 《系统仿真学报》 北大核心 2025年第2期462-473,共12页
In order to improve the efficiency of cloud-based web services,an improved plant growth simulation algorithm scheduling model.This model first used mathematical methods to describe the relationships between cloud-base... In order to improve the efficiency of cloud-based web services,an improved plant growth simulation algorithm scheduling model.This model first used mathematical methods to describe the relationships between cloud-based web services and the constraints of system resources.Then,a light-induced plant growth simulation algorithm was established.The performance of the algorithm was compared through several plant types,and the best plant model was selected as the setting for the system.Experimental results show that when the number of test cloud-based web services reaches 2048,the model being 2.14 times faster than PSO,2.8 times faster than the ant colony algorithm,2.9 times faster than the bee colony algorithm,and a remarkable 8.38 times faster than the genetic algorithm. 展开更多
关键词 cloud-based service scheduling algorithm resource constraint load optimization cloud computing plant growth simulation algorithm
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A Class of Parallel Algorithm for Solving Low-rank Tensor Completion
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作者 LIU Tingyan WEN Ruiping 《应用数学》 北大核心 2025年第4期1134-1144,共11页
In this paper,we established a class of parallel algorithm for solving low-rank tensor completion problem.The main idea is that N singular value decompositions are implemented in N different processors for each slice ... In this paper,we established a class of parallel algorithm for solving low-rank tensor completion problem.The main idea is that N singular value decompositions are implemented in N different processors for each slice matrix under unfold operator,and then the fold operator is used to form the next iteration tensor such that the computing time can be decreased.In theory,we analyze the global convergence of the algorithm.In numerical experiment,the simulation data and real image inpainting are carried out.Experiment results show the parallel algorithm outperform its original algorithm in CPU times under the same precision. 展开更多
关键词 Tensor completion Low-rank CONVERGENCE Parallel algorithm
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Multi-QoS routing algorithm based on reinforcement learning for LEO satellite networks 被引量:1
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作者 ZHANG Yifan DONG Tao +1 位作者 LIU Zhihui JIN Shichao 《Journal of Systems Engineering and Electronics》 2025年第1期37-47,共11页
Low Earth orbit(LEO)satellite networks exhibit distinct characteristics,e.g.,limited resources of individual satellite nodes and dynamic network topology,which have brought many challenges for routing algorithms.To sa... Low Earth orbit(LEO)satellite networks exhibit distinct characteristics,e.g.,limited resources of individual satellite nodes and dynamic network topology,which have brought many challenges for routing algorithms.To satisfy quality of service(QoS)requirements of various users,it is critical to research efficient routing strategies to fully utilize satellite resources.This paper proposes a multi-QoS information optimized routing algorithm based on reinforcement learning for LEO satellite networks,which guarantees high level assurance demand services to be prioritized under limited satellite resources while considering the load balancing performance of the satellite networks for low level assurance demand services to ensure the full and effective utilization of satellite resources.An auxiliary path search algorithm is proposed to accelerate the convergence of satellite routing algorithm.Simulation results show that the generated routing strategy can timely process and fully meet the QoS demands of high assurance services while effectively improving the load balancing performance of the link. 展开更多
关键词 low Earth orbit(LEO)satellite network reinforcement learning multi-quality of service(QoS) routing algorithm
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Temperature control for liquid-cooled fuel cells based on fuzzy logic and variable-gain generalized supertwisting algorithm
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作者 CHEN Lin JIA Zhi-huan +1 位作者 DING Tian-wei GAO Jin-wu 《控制理论与应用》 北大核心 2025年第8期1596-1605,共10页
The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade tempe... The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed. 展开更多
关键词 liquid-cooled fuel cell temperature control generalized supertwisting algorithm fuzzy control equilibrium optimizer
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基于全局-局部信息融合LPV-Net和3D-EDA的心脏半监督分割算法研究
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作者 胡慧称 刘瑞霞 +1 位作者 刘照阳 郭振华 《计算机科学》 北大核心 2025年第S2期435-441,共7页
心脏分割算法提供精准把握心脏结构的信息,辅助医生进行诊断、制定治疗计划以及进行手术前的评估工作,提高临床治疗的效果并减轻并发症。然而,心脏分割在应用中存在诸多问题。手动分割方法不仅耗时费力,并且具有很强的主观意识。全监督... 心脏分割算法提供精准把握心脏结构的信息,辅助医生进行诊断、制定治疗计划以及进行手术前的评估工作,提高临床治疗的效果并减轻并发症。然而,心脏分割在应用中存在诸多问题。手动分割方法不仅耗时费力,并且具有很强的主观意识。全监督的心脏分割方法虽已取得一定成果,但标注数据的依赖性过高。现有的半监督分割方法在处理复杂的心脏结构和病理变化时表现仍不够理想,难以在实际临床环境中稳定应用。为解决这一问题,提出了心脏磁共振成像(MRI)分割方法,结合Linformer and Performer merge V-Net(LPV-Net)和3D Enhanced Discriminator with Attention(3D-EDA)技术,实现了全局-局部信息的有效整合。LPV-Net模块由LinPerBlock和改进的V-Net联袂打造,旨在规范模型训练过程、实现全局与局部信息的有机整合,有效提高分割效果的准确性与鲁棒性。同时引入新鉴别器3D-EDA规范未标记数据,并加入关键模块CARE-Layer,集成自定义注意力模块以增强对特征重要信息的捕捉能力,辅助网络可提高主网络分割指标性能。在左心房数据集上进行综合实验,并将所提方法与MC-Net,V-Net等其他先进的半监督方法进行比较,发现该方法在基准数据集上的表现尤为优异。特别是在使用有限标签数据进行训练时,该方法仍然展示出卓越的性能;当仅使用10%和20%的标记数据进行训练时,该方法的Dice系数分别达到88.50%和90.39%。 展开更多
关键词 半监督分割 全局和局部信息 融合 LPV-Net 3D-eda 左心房 CARELayer
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Research on three-dimensional attack area based on improved backtracking and ALPS-GP algorithms of air-to-air missile
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作者 ZHANG Haodi WANG Yuhui HE Jiale 《Journal of Systems Engineering and Electronics》 2025年第1期292-310,共19页
In the field of calculating the attack area of air-to-air missiles in modern air combat scenarios,the limitations of existing research,including real-time calculation,accuracy efficiency trade-off,and the absence of t... In the field of calculating the attack area of air-to-air missiles in modern air combat scenarios,the limitations of existing research,including real-time calculation,accuracy efficiency trade-off,and the absence of the three-dimensional attack area model,restrict their practical applications.To address these issues,an improved backtracking algorithm is proposed to improve calculation efficiency.A significant reduction in solution time and maintenance of accuracy in the three-dimensional attack area are achieved by using the proposed algorithm.Furthermore,the age-layered population structure genetic programming(ALPS-GP)algorithm is introduced to determine an analytical polynomial model of the three-dimensional attack area,considering real-time requirements.The accuracy of the polynomial model is enhanced through the coefficient correction using an improved gradient descent algorithm.The study reveals a remarkable combination of high accuracy and efficient real-time computation,with a mean error of 91.89 m using the analytical polynomial model of the three-dimensional attack area solved in just 10^(-4)s,thus meeting the requirements of real-time combat scenarios. 展开更多
关键词 air combat three-dimensional attack area improved backtracking algorithm age-layered population structure genetic programming(ALPS-GP) gradient descent algorithm
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Synthesis of thinned linear antenna array using genetic algorithm to lower peak sidelobe level and maintain half-power beamwidth
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作者 STEPANOV Maksim KARASEV Alexey 《Journal of Systems Engineering and Electronics》 2025年第5期1113-1121,共9页
Thinning of antenna arrays has been a popular topic for the last several decades.With increasing computational power,this optimization task acquired a new hue.This paper suggests a genetic algorithm as an instrument f... Thinning of antenna arrays has been a popular topic for the last several decades.With increasing computational power,this optimization task acquired a new hue.This paper suggests a genetic algorithm as an instrument for antenna array thinning.The algorithm with a deliberately chosen fitness function allows synthesizing thinned linear antenna arrays with low peak sidelobe level(SLL)while maintaining the half-power beamwidth(HPBW)of a full linear antenna array.Based on results from existing papers in the field and known approaches to antenna array thinning,a classification of thinning types is introduced.The optimal thinning type for a linear thinned antenna array is determined on the basis of a maximum attainable SLL.The effect of thinning coefficient on main directional pattern characteristics,such as peak SLL and HPBW,is discussed for a number of amplitude distributions. 展开更多
关键词 thinned antenna array genetic algorithm side lobe
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A hybrid genetic algorithm to the program optimization model based on a heterogeneous network
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作者 CHEN Hang DOU Yajie +3 位作者 CHEN Ziyi JIA Qingyang ZHU Chen CHEN Haoxuan 《Journal of Systems Engineering and Electronics》 2025年第4期994-1005,共12页
Project construction and development are an impor-tant part of future army designs.In today’s world,intelligent war-fare and joint operations have become the dominant develop-ments in warfare,so the construction and ... Project construction and development are an impor-tant part of future army designs.In today’s world,intelligent war-fare and joint operations have become the dominant develop-ments in warfare,so the construction and development of the army need top-down,top-level design,and comprehensive plan-ning.The traditional project development model is no longer suf-ficient to meet the army’s complex capability requirements.Projects in various fields need to be developed and coordinated to form a joint force and improve the army’s combat effective-ness.At the same time,when a program consists of large-scale project data,the effectiveness of the traditional,precise mathe-matical planning method is greatly reduced because it is time-consuming,costly,and impractical.To solve above problems,this paper proposes a multi-stage program optimization model based on a heterogeneous network and hybrid genetic algo-rithm and verifies the effectiveness and feasibility of the model and algorithm through an example.The results show that the hybrid algorithm proposed in this paper is better than the exist-ing meta-heuristic algorithm. 展开更多
关键词 program optimization heterogeneous network genetic algorithm portfolio selection.
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Topological optimization of metamaterial absorber based on improved estimation of distribution algorithm
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作者 TAO Shifei LIU Beichen +2 位作者 LIU Sixing WU Fan WANG Hao 《Journal of Systems Engineering and Electronics》 2025年第3期634-641,共8页
An improved estimation of distribution algorithm(IEDA)is proposed in this paper for efficient design of metamaterial absorbers.This algorithm establishes a probability model through the selected dominant groups and sa... An improved estimation of distribution algorithm(IEDA)is proposed in this paper for efficient design of metamaterial absorbers.This algorithm establishes a probability model through the selected dominant groups and samples from the model to obtain the next generation,avoiding the problem of building-blocks destruction caused by crossover and mutation.Neighboring search from artificial bee colony algorithm(ABCA)is introduced to enhance the local optimization ability and improved to raise the speed of convergence.The probability model is modified by boundary correction and loss correction to enhance the robustness of the algorithm.The proposed IEDA is compared with other intelligent algorithms in relevant references.The results show that the proposed IEDA has faster convergence speed and stronger optimization ability,proving the feasibility and effectiveness of the algorithm. 展开更多
关键词 METAMATERIAL topological optimization estimation of distribution algorithm
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Optimization model for performance-based warranty decision of degraded systems based on improved sparrow search algorithm
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作者 DONG Enzhi CHENG Zhonghua +3 位作者 LIU Zichang ZHU Xi WANG Rongcai BAI Yongsheng 《Journal of Systems Engineering and Electronics》 2025年第5期1259-1280,共22页
Performance-based warranties(PBWs)are widely used in industry and manufacturing.Given that PBW can impose financial burdens on manufacturers,rational maintenance decisions are essential for expanding profit margins.Th... Performance-based warranties(PBWs)are widely used in industry and manufacturing.Given that PBW can impose financial burdens on manufacturers,rational maintenance decisions are essential for expanding profit margins.This paper proposes an optimization model for PBW decisions for systems affected by Gamma degradation processes,incorporating periodic inspection.A system performance degradation model is established.Preventive maintenance probability and corrective renewal probability models are developed to calculate expected warranty costs and system availability.A benefits function,which includes incentives,is constructed to optimize the initial and subsequent inspection intervals and preventive maintenance thresholds,thereby maximizing warranty profit.An improved sparrow search algorithm is developed to optimize the model,with a case study on large steam turbine rotor shafts.The results suggest the optimal PBW strategy involves an initial inspection interval of approximately 20 months,with subsequent intervals of about four months,and a preventive maintenance threshold of approximately 37.39 mm wear.When compared to common cost-minimization-based condition maintenance strategies and PBW strategies that do not differentiate between initial and subsequent inspection intervals,the proposed PBW strategy increases the manufacturer’s profit by 1%and 18%,respectively.Sensitivity analyses provide managerial recommendations for PBW implementation.The PBW strategy proposed in this study significantly increases manufacturers’profits by optimizing inspection intervals and preventive maintenance thresholds,and manufacturers should focus on technological improvement in preventive maintenance and cost control to further enhance earnings. 展开更多
关键词 performance-based warranty gamma process periodic inspection intelligent optimization algorithm
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Bayesian-based ant colony optimization algorithm for edge detection
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作者 YU Yongbin ZHONG Yuanjingyang +6 位作者 FENG Xiao WANG Xiangxiang FAVOUR Ekong ZHOU Chen CHENG Man WANG Hao WANG Jingya 《Journal of Systems Engineering and Electronics》 2025年第4期892-902,共11页
Ant colony optimization(ACO)is a random search algorithm based on probability calculation.However,the uninformed search strategy has a slow convergence speed.The Bayesian algorithm uses the historical information of t... Ant colony optimization(ACO)is a random search algorithm based on probability calculation.However,the uninformed search strategy has a slow convergence speed.The Bayesian algorithm uses the historical information of the searched point to determine the next search point during the search process,reducing the uncertainty in the random search process.Due to the ability of the Bayesian algorithm to reduce uncertainty,a Bayesian ACO algorithm is proposed in this paper to increase the convergence speed of the conventional ACO algorithm for image edge detection.In addition,this paper has the following two innovations on the basis of the classical algorithm,one of which is to add random perturbations after completing the pheromone update.The second is the use of adaptive pheromone heuristics.Experimental results illustrate that the proposed Bayesian ACO algorithm has faster convergence and higher precision and recall than the traditional ant colony algorithm,due to the improvement of the pheromone utilization rate.Moreover,Bayesian ACO algorithm outperforms the other comparative methods in edge detection task. 展开更多
关键词 ant colony optimization(ACO) Bayesian algorithm edge detection transfer function.
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An improved genetic algorithm for causal discovery
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作者 MAO Tengjiao BU Xianjin +2 位作者 CAI Chunxiao LU Yue DU Jing 《Journal of Systems Engineering and Electronics》 2025年第3期768-777,共10页
The learning algorithms of causal discovery mainly include score-based methods and genetic algorithms(GA).The score-based algorithms are prone to searching space explosion.Classical GA is slow to converge,and prone to... The learning algorithms of causal discovery mainly include score-based methods and genetic algorithms(GA).The score-based algorithms are prone to searching space explosion.Classical GA is slow to converge,and prone to falling into local optima.To address these issues,an improved GA with domain knowledge(IGADK)is proposed.Firstly,domain knowledge is incorporated into the learning process of causality to construct a new fitness function.Secondly,a dynamical mutation operator is introduced in the algorithm to accelerate the convergence rate.Finally,an experiment is conducted on simulation data,which compares the classical GA with IGADK with domain knowledge of varying accuracy.The IGADK can greatly reduce the number of iterations,populations,and samples required for learning,which illustrates the efficiency and effectiveness of the proposed algorithm. 展开更多
关键词 genetic algorithm(GA) causal discovery convergence rate fitness function mutation operator
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Functional cartography of heterogeneous combat networks using operational chain-based label propagation algorithm
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作者 CHEN Kebin JIANG Xuping +2 位作者 ZENG Guangjun YANG Wenjing ZHENG Xue 《Journal of Systems Engineering and Electronics》 2025年第5期1202-1215,共14页
To extract and display the significant information of combat systems,this paper introduces the methodology of functional cartography into combat networks and proposes an integrated framework named“functional cartogra... To extract and display the significant information of combat systems,this paper introduces the methodology of functional cartography into combat networks and proposes an integrated framework named“functional cartography of heterogeneous combat networks based on the operational chain”(FCBOC).In this framework,a functional module detection algorithm named operational chain-based label propagation algorithm(OCLPA),which considers the cooperation and interactions among combat entities and can thus naturally tackle network heterogeneity,is proposed to identify the functional modules of the network.Then,the nodes and their modules are classified into different roles according to their properties.A case study shows that FCBOC can provide a simplified description of disorderly information of combat networks and enable us to identify their functional and structural network characteristics.The results provide useful information to help commanders make precise and accurate decisions regarding the protection,disintegration or optimization of combat networks.Three algorithms are also compared with OCLPA to show that FCBOC can most effectively find functional modules with practical meaning. 展开更多
关键词 functional cartography heterogeneous combat network functional module label propagation algorithm operational chain
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Multi-platform collaborative MRC-PSO algorithm for anti-ship missile path planning
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作者 LIU Gang GUO Xinyuan +2 位作者 HUANG Dong CHEN Kezhong LI Wu 《Journal of Systems Engineering and Electronics》 2025年第2期494-509,共16页
To solve the problem of multi-platform collaborative use in anti-ship missile (ASM) path planning, this paper pro-posed multi-operator real-time constraints particle swarm opti-mization (MRC-PSO) algorithm. MRC-PSO al... To solve the problem of multi-platform collaborative use in anti-ship missile (ASM) path planning, this paper pro-posed multi-operator real-time constraints particle swarm opti-mization (MRC-PSO) algorithm. MRC-PSO algorithm utilizes a semi-rasterization environment modeling technique and inte-grates the geometric gradient law of ASMs which distinguishes itself from other collaborative path planning algorithms by fully considering the coupling between collaborative paths. Then, MRC-PSO algorithm conducts chunked stepwise recursive evo-lution of particles while incorporating circumvent, coordination, and smoothing operators which facilitates local selection opti-mization of paths, gradually reducing algorithmic space, accele-rating convergence, and enhances path cooperativity. Simula-tion experiments comparing the MRC-PSO algorithm with the PSO algorithm, genetic algorithm and operational area cluster real-time restriction (OACRR)-PSO algorithm, which demon-strate that the MRC-PSO algorithm has a faster convergence speed, and the average number of iterations is reduced by approximately 75%. It also proves that it is equally effective in resolving complex scenarios involving multiple obstacles. More-over it effectively addresses the problem of path crossing and can better satisfy the requirements of multi-platform collabora-tive path planning. The experiments are conducted in three col-laborative operation modes, namely, three-to-two, three-to-three, and four-to-two, and the outcomes demonstrate that the algorithm possesses strong universality. 展开更多
关键词 anti-ship missiles multi-platform collaborative path planning particle swarm optimization(PSO)algorithm
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A tracking algorithm based on adaptive Kalman filter with carrier-to-noise ratio estimation under solar radio bursts interference
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作者 ZHU Xuefen LI Ang +2 位作者 LUO Yimei LIN Mengying TU Gangyi 《Journal of Systems Engineering and Electronics》 2025年第4期880-891,共12页
Solar radio burst(SRB)is one of the main natural interference sources of Global Positioning System(GPS)signals and can reduce the signal-to-noise ratio(SNR),directly affecting the tracking performance of GPS receivers... Solar radio burst(SRB)is one of the main natural interference sources of Global Positioning System(GPS)signals and can reduce the signal-to-noise ratio(SNR),directly affecting the tracking performance of GPS receivers.In this paper,a tracking algorithm based on the adaptive Kalman filter(AKF)with carrier-to-noise ratio estimation is proposed and compared with the conventional second-order phase-locked loop tracking algo-rithms and the improved Sage-Husa adaptive Kalman filter(SHAKF)algorithm.It is discovered that when the SRBs occur,the improved SHAKF and the AKF with carrier-to-noise ratio estimation enable stable tracking to loop signals.The conven-tional second-order phase-locked loop tracking algorithms fail to track the receiver signal.The standard deviation of the carrier phase error of the AKF with carrier-to-noise ratio estimation out-performs 50.51%of the improved SHAKF algorithm,showing less fluctuation and better stability.The proposed algorithm is proven to show more excellent adaptability in the severe envi-ronment caused by the SRB occurrence and has better tracking performance. 展开更多
关键词 solar radio burst(SRB) global positioning system(GPS) adaptive Kalman filter(AKF) tracking algorithm.
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水液相下Eda酮式异构体与超氧化氢自由基反应的DFT理论计算 被引量:3
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作者 潘宇 姜春旭 +4 位作者 王颢霖 杨应 董雷刚 王佐成 李冰 《吉林大学学报(理学版)》 CAS 北大核心 2024年第5期1254-1266,共13页
在M06-2X/SMD/6-311+G(d,p)理论水平下,研究水液相1个大气压、 310.15 K温度下依达拉奉(Eda)酮式异构体与超氧化氢自由基(·HO_(2))的反应机理.结果表明:Eda酮式异构体与·HO_(2)的反应有抽H、加成和单电子转移3个过程;抽H反应... 在M06-2X/SMD/6-311+G(d,p)理论水平下,研究水液相1个大气压、 310.15 K温度下依达拉奉(Eda)酮式异构体与超氧化氢自由基(·HO_(2))的反应机理.结果表明:Eda酮式异构体与·HO_(2)的反应有抽H、加成和单电子转移3个过程;抽H反应主要通过·HO_(2)抽取杂环H和甲基H实现,反应的自由能垒为77.1~78.7 kJ/mol;加成反应可通过·HO_(2)加成不饱和C的过程实现,加成自由能垒为48.2~95.0 kJ/mol;加成到杂环上与甲基相连的C原子的放热反应最具优势,自由能垒为48.2 kJ/mol;单电子转移的自由能垒为141.1 kJ/mol,该过程不能实现.可见,水液相下Eda酮式异构体可通过抽H和加成反应消除·HO_(2). 展开更多
关键词 依达拉奉酮式异构体 超氧化氢自由基 密度泛函理论 过渡态 Marcus理论 电子转移 自由能垒
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基于EDA统计图量化的桥梁动态监测数据质量评估
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作者 殷鹏程 谭曼丽莎 +1 位作者 曹阳梅 单德山 《重庆交通大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第5期9-16,共8页
探索性数据分析统计图在桥梁健康监测动态数据质量评估中已有广泛应用。为了减少人工观察统计图的主观性,通过近似度量方法实现统计图的量化分析,得到多个指标对监测数据进行快速质量评估。在运营环境激励作用下,桥梁结构动力响应具有... 探索性数据分析统计图在桥梁健康监测动态数据质量评估中已有广泛应用。为了减少人工观察统计图的主观性,通过近似度量方法实现统计图的量化分析,得到多个指标对监测数据进行快速质量评估。在运营环境激励作用下,桥梁结构动力响应具有短时线性平稳性,近似服从正态分布。以某大跨斜拉桥振动数据为研究对象,首先,绘制样本数据直方图和Q-Q图,通过观察数据分布特征预先判断数据质量,确定优、良和差3个等级。然后,分别通过KL散度和余弦相似度2种近似度量方法对样本数据直方图和Q-Q图进行量化,得到数据服从正态分布程度的指标;通过箱线图检测样本数据全局异常点,得到正常数据占比;统计分析得到量化值和先验质量等级的对应关系,确定以直方图KL散度和余弦相似度为主、以箱线图正常数据占比为辅的数据质量评估标准。最后,取部分数据为验证集,进一步验证所提方法各个指标的合理性,并给出该方法在实际工程上的应用结果。 展开更多
关键词 桥梁工程 桥梁结构健康监测 数据质量评估 探索性数据分析 KL散度 余弦相似度 箱线图
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