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Controllable synthesis of CuAlO_(2) via solid-phase method and its catalytic performance for methanol steam reforming to hydrogen 被引量:3
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作者 QING Shaojun SUN Xun +3 位作者 LI Xinglong WANG Lei WU Zhiwei WANG Jianguo 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第11期1641-1651,共11页
This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investi... This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance. 展开更多
关键词 CuAlO_(2) solid-phase method methanol steam reforming sustained release catalysis calcination temperature
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Constructing graphite-CeO_(2)interfaces to enhance the photothermal activity for solar-driven dry reforming of methane
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作者 LI Ruitao GONG Kun +3 位作者 DAI Yuanyuan NIU Qiang LIN Tiejun ZHONG Liangshu 《燃料化学学报(中英文)》 北大核心 2025年第8期1137-1147,共11页
CeO_(2) based semiconductor are widely used in solar-driven photothermal catalytic dry reforming of methane(DRM)reaction,but still suffer from low activity and low light utilization efficiency.This study developed gra... CeO_(2) based semiconductor are widely used in solar-driven photothermal catalytic dry reforming of methane(DRM)reaction,but still suffer from low activity and low light utilization efficiency.This study developed graphite-CeO_(2) interfaces to enhance solar-driven photothermal catalytic DRM.Compared with carbon nanotubes-modified CeO_(2)(CeO_(2)-CNT),graphite-modified CeO_(2)(CeO_(2)-GRA)constructed graphite-CeO_(2) interfaces with distortion in CeO_(2),leading to the formation abundant oxygen vacancies.These graphite-CeO_(2) interfaces with oxygen vacancies enhanced optical absorption and promoted the generation and separation of photogenerated carriers.The high endothermic capacity of graphite elevated the catalyst surface temperature from 592.1−691.3℃,boosting light-to-thermal conversion.The synergy between photogenerated carriers and localized heat enabled Ni/CeO_(2)-GRA to achieve a CO production rate of 9985.6 mmol/(g·h)(vs 7192.4 mmol/(g·h)for Ni/CeO_(2))and a light-to-fuel efficiency of 21.8%(vs 13.8%for Ni/CeO_(2)).This work provides insights for designing graphite-semiconductor interfaces to advance photothermal catalytic efficiency. 展开更多
关键词 dry reforming of methane photothermal catalysis CeO_(2) GRAPHITE INTERFACES
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Research progress on metal-support interactions over Ni-based catalysts for CH_(4)-CO_(2)reforming reaction
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作者 SUN Kai JIANG Jianfei +4 位作者 LIU Zixuan GENG Shiqi LIU Zhenmin YANG Jiaqian LI Shasha 《燃料化学学报(中英文)》 北大核心 2025年第4期434-451,共18页
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni... With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies. 展开更多
关键词 CO_(2)utilization CH_(4)-CO_(2)reforming Ni-based catalysts metal-support interactions supports
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Reforming Financial Regulatory System in China after the Stock Market Turbulence:Problems and the Responses
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作者 Chen Zhenyun 《学术界》 CSSCI 北大核心 2016年第10期285-289,共5页
In an age when modern financial companies have become more and more complex,and if not adequately supervised,they can cause lethal harm to the stability of one's financial system.In post-financial crisis era,major... In an age when modern financial companies have become more and more complex,and if not adequately supervised,they can cause lethal harm to the stability of one's financial system.In post-financial crisis era,major developed economies have apparently reinforced the function of the central bank in a country's financial regulatory system.Over the past several years,China has witnessed the huge changes in the financial sector but the financial regulatory framework remains the same as before.The Chinese stock market crash that began on June 12 2015 has urged the domestic regulators to restructure its financial regulatory system.The issue that which modal China should follow has perplexed Chinese policymakers.The governor of People's Bank of China,Zhou Xiaochuan,clearly responded to the problem concerning the current financial regulatory system,and indicated that Chinese regulators and policymakers had still studied the regulatory approach China would adopt during the press of People's Congress of 2016.This paper reviews the development of China's banking regulatory system points out the deficiencies in its original system and analyzes the recent trends of financial regulatory reform in UK to learn the international experience for further reform regarding financial regulatory system in China. 展开更多
关键词 金融规章制度 金融规章制度的改革 大英国协 中国
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Responses of wind-induced internal pressure in a two-compartment building with a dominant opening and background porosity Part 1:Theoretical formulation and experimental verification 被引量:6
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作者 余先锋 全涌 顾明 《Journal of Central South University》 SCIE EI CAS 2012年第10期2940-2948,共9页
The equations governing wind-induced internal pressure responses for a two-compartment building with a dominant opening and background porosity were derived.The unsteady form of the Bernoulli equation,the law of mass ... The equations governing wind-induced internal pressure responses for a two-compartment building with a dominant opening and background porosity were derived.The unsteady form of the Bernoulli equation,the law of mass conservation,and adiabatic equation were used for the derivation.The precision of the governing equations was verified by a wind tunnel test on a rigid model of a low-rise building.The results show that the governing equations can effectively analyze the wind-induced internal pressure responses.The internal pressure responses in both compartments are suppressed due to the additional damping provided by background porosity.The responses of internal pressure in both compartments,especially in the compartment without an external opening,decrease with increased lumped leakage area. 展开更多
关键词 dominant opening internal pressure background porosity additional damping wind tuunel test
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Influencing factors analysis of hard limestone reformation and strength weakening under acidic effect
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作者 HOU Ming-xiao HUANG Bing-xiang +2 位作者 ZHAO Xing-long JIAO Xue-jie ZHENG Chen-yang 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2446-2466,共21页
Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way t... Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines. 展开更多
关键词 hard roof acidic effect structural reformation strength weakening influencing factors
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A Decision Support System for Economic Development and Price Reform
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作者 Hu Lequn, Yang Shetang and Zhang WenzhongInstitute of System Science, Academia Sinica, Beijing, 100080Zhu JunNational Information Center of China, Beijing, 100072 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 1993年第1期65-73,共9页
In this paper, we present a real decision support system applied to China's macroeconomic management. The structure, design and functions of the system are discussed, and the problems occurring in designing and ma... In this paper, we present a real decision support system applied to China's macroeconomic management. The structure, design and functions of the system are discussed, and the problems occurring in designing and making the system are also studied. A case study for China's petroleum price reform is given at the end of the paper. 展开更多
关键词 Decision support system System analysis Interactive method Macroeconomic management Price reform.
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Chinese Rural Comprehensive Reform:Theoretical Innovation,Key Contradictions and Countermeasures
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作者 Zhou Li 《Journal of Northeast Agricultural University(English Edition)》 CAS 2016年第3期79-89,共11页
As a systematic project, Chinese rural comprehensive reform (hereinafter referred to as "the reform") involved multiple dimensions such as rural governance, economy, culture, society and ecology, which laid a soli... As a systematic project, Chinese rural comprehensive reform (hereinafter referred to as "the reform") involved multiple dimensions such as rural governance, economy, culture, society and ecology, which laid a solid foundation for the overall reform in China. Western rural development theory had been proved to be insufficient to support Chinese rural reform. Therefore, theoretical innovation became urgent in the fields of rural governance, government functions, public finance and rural-urban integration etc. In recent years, Chinese rural comprehensive reform had been adjusting itself to the requirements of the "new normal". And during the process of agricultural modernization, the bottlenecks included the contradictory relationships between reform, development and overall stability, agricultural simplification and industrial diversification, economic development and environmental protection, rapid development of urban areas and slow progress of rural areas, grassroots governance and democratic supervision etc. Proper countermeasures would help to settle the above contradictions. 展开更多
关键词 rural comprehensive reform theoretical innovation contradictory relationship
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Chinese Comprehensive Rural Reform: Institutional Vicissitude, Theoretic Framework and Content Structure
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作者 Zhou Li 《Journal of Northeast Agricultural University(English Edition)》 CAS 2015年第3期79-90,共12页
The social and economic development level of rural areas, the productivity of agriculture and the life quality of farmers were always the greatest concerns of Chinese Central Government. Therefore, the research relate... The social and economic development level of rural areas, the productivity of agriculture and the life quality of farmers were always the greatest concerns of Chinese Central Government. Therefore, the research related to rural areas, agriculture and farmers had remained as the prominent parts for a long period and would continue to be prominent in the future to build China into a moderately prosperous nation in an all-round way. Chinese rural area had constantly experienced three significant system reforms since 1978, namely the reform of rural management system, the rural tax and fee reform and the rural comprehensive reform. This paper attempted to analyze the theoretic framework and the content structure of the comprehensive rural reform since it was the higher stage of rural institutional vicissitude, which had changed the governance and operation system and thus promoted the great changes to fundamental social and economic system in rural areas. The theoretic framework of comprehensive rural reform covered three aspects in its content, namely the rural governance theory, the government function theory and the public finance theory. The comprehensive rural reform was a complicated system engineering with multiple dimensions and targets mainly including rural political restructuring, rural economic restructuring and rural public products allocation restructuring. The reform had focused on enhancing the vitality of agricultural and rural development, breaking through the urban and rural binary system, and further reducing the disparity between cities and countrysides, so as to realize the urban-rural integration. It was necessary to clarify and understand the key mechanism and intrinsic logic of the rural comprehensive reform, which was helpful to establish the foundation constituted by scientific methodology to implement the reform and evaluation criterion to judge the reform performance. 展开更多
关键词 comprehensive rural reform institutional vicissitude theoretic framework content structure
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Future China-Africa research collaboration in geoscience:Challenges and opportunities
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作者 Michael H.STEPHENSON Hassina MOURI +5 位作者 Gbenga OKUNLOLA CHENG Li WANG Meng ZHAO Yu GU Liping WANG Chengshan 《地学前缘》 北大核心 2025年第1期459-465,共7页
At the 19th G20 Summit in Brazil in November 2024,China promoted the development of sustainable solutions to climate change,biodiversity loss,and environmental pollution.This continued the theme of the 2016 G20 Hangzh... At the 19th G20 Summit in Brazil in November 2024,China promoted the development of sustainable solutions to climate change,biodiversity loss,and environmental pollution.This continued the theme of the 2016 G20 Hangzhou Summit,at which China placed development at the center of the G20’s macroeconomic policy coordination for the first time,adopting the G20 Action Plan on the United Nations 2030 Agenda for Sustainable Development and the G20 Initiative on Supporting Industrialization in Africa and Least Developed Countries.In Brazil,China announced actions on advancing modernization in Africa over the next three years with a Chinese commitment of RMB360 billion yuan in financial support.In this article,we examine the potential role of geoscience research and practice in development,particularly in the sustainable use of natural resources,the prevention of climate change impacts,as well as mitigation of geo-hazards and their health implications,indicating the areas where China’s geoscience for Africa is strong and where it requires more effort.We find that although China is the world’s leading publisher of scientific papers,its contribution to geoscience in Africa(the globe’s fastest-growing economic area),as shown by bibliometric research,appears to be rather small and inconsistent with the research priorities of Africa.Amongst the priorities for geoscience research in Africa,which are not addressed substantially by the research conducted so far,are sustainable mineral and hydrocarbon development,hydrology and hydrogeology,climate change and resilience,natural hazards,medical geology,agrominerals,and geoscience education and training.A particular opportunity for African nations is the presence of critical minerals-minerals needed for the energy transition and for batteries for electric cars in particular.Africa is well-endowed with many of these critical materials,such as rare earth elements and platinum group metals.Several research groups stress the need for the agency on the part of African institutions to map out these valuable resources,understand their value and the economics and sustainability of their extraction,encourage local business,attract investment,and scrutinize proposals from potential international investors to get the best deals.A strong point of existing China-led geoscience development includes the Deep-time Digital Earth(DDE)program online computing platform and its artificial intelligence tool GeoGPT,which is being developed in partnership with Zhejiang Laboratory.These are being developed with strong China funding support for free and wide global access,with a particular focus on Africa.These advanced tools will help to place the agency of development squarely in the hands of African scientists and institutions.In summary,the following are recommended:(1)a more coordinated and strategic approach to China-led geoscience research in Africa;(2)an Africa-centered,geoscience funding initiative that concentrates on relevant topics to the continent such as critical minerals exploration and other geological resources,materials and processes and their health implications on the populations and ecosystems in general,as well as climate change and climate change resilience;and(3)continued support for China-led international initiatives that seek to increase the agency and capacity of Africa geoscience researchers,for example the Deep-time Digital Earth platform. 展开更多
关键词 open science sustainable development digital empowerment China-Africa geo-collaboration Deep-Time Digital Earth
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2025年第9期I0017-I0017,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE agricultural products open access journal agricultural products processing STORAGE technology engineering
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2025年第11期I0017-I0017,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE agricultural products open access journal agricultural products processing STORAGE technology engineering
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2025年第10期I0017-I0017,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE agricultural products open access journal agricultural products processing STORAGE technology engineering
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产甘油假丝酵母(Candida glycerinogenes)利用未脱毒纤维素水解液开放式发酵产甘油
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作者 赵晓红 宗红 +1 位作者 陆信曜 诸葛斌 《食品与发酵工业》 北大核心 2025年第5期70-77,共8页
未脱毒水解液中的醛类、酚类等物质抑制菌株的生长发酵。产甘油假丝酵母(Candida glycerinogenes)具有多重抗逆性能,过表达相关抗性基因构建重组菌株并进行筛选。相比于对照菌株,过表达CgGCN4的重组菌株在含有3.0 g/L糠醛、2.0 g/L香草... 未脱毒水解液中的醛类、酚类等物质抑制菌株的生长发酵。产甘油假丝酵母(Candida glycerinogenes)具有多重抗逆性能,过表达相关抗性基因构建重组菌株并进行筛选。相比于对照菌株,过表达CgGCN4的重组菌株在含有3.0 g/L糠醛、2.0 g/L香草醛、3.5 g/L乙酸的高糖培养基中生物量分别提高25.2%、14.6%、5.2%;葡萄糖消耗速率分别提高9.9%、5.5%、13.1%;在3.0 g/L糠醛的胁迫下甘油产量提高23.4%。在糠醛、香草醛或乙酸的胁迫下,重组菌株胞内活性氧水平的提高程度分别降低35.2%、28.0%、15.3%,与碘化丙啶的结合水平均有不同程度的降低,表明重组菌株可通过降低胞内活性氧的积累、保持细胞膜的完整性来保持菌株优良的生长与发酵性能。将抗性重组菌株应用于未脱毒甘蔗渣水解液开放式发酵生产甘油,可使耗糖速率提高20.0%;生物量提高12.3%;甘油产量提高21.7%。该研究为未脱毒纤维素水解液的应用提供了新思路及遗传资源。 展开更多
关键词 产甘油假丝酵母 未脱毒水解液 GCN4 甘油 糠醛 香草醛 乙酸 开放式发酵
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Call for Papers from Agricultural Products Processing and Storage
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《食品科学》 北大核心 2025年第20期I0022-I0022,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE agricultural products open access journal agricultural products processing STORAGE technology engineering
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水动力清创系统结合抗生素涂层髓内针对Gustilo-AndersonⅡ型开放性骨折的治疗效果
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作者 黎锦英 陈华媛 +5 位作者 李嘉欣 何诗锶 林丽莎 严斌 韦武 李少川 《动物医学进展》 北大核心 2025年第8期133-139,共7页
为探究水动力清创系统结合抗生素涂层髓内针植入对开放性骨折的治疗与抗感染效果,选用SD大鼠制备Gustilo-AndersonⅡ型开放性骨折感染模型,并对模型大鼠清创后组织细菌减少率、清创所需时间、清创前后核心体温变化及28 d内的存活情况和... 为探究水动力清创系统结合抗生素涂层髓内针植入对开放性骨折的治疗与抗感染效果,选用SD大鼠制备Gustilo-AndersonⅡ型开放性骨折感染模型,并对模型大鼠清创后组织细菌减少率、清创所需时间、清创前后核心体温变化及28 d内的存活情况和影像学、病理组织学、血液学检查结果进行统计与观察。试验结果显示,水动力清创系统相比传统冷器械清创可显著降低模型大鼠骨组织与肌肉组织活菌量,可显著缩短清创时间,减少核心体温丢失;结合抗生素涂层髓内针植入,可提高模型大鼠生存率,改善骨折愈合情况。 展开更多
关键词 开放性骨折 水动力清创系统 抗生素涂层 聚多巴胺
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On the Relationship of the Opening Strategy and the Imbalance of the Internal and External Trade in China
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作者 Pan Liang 《学术界》 CSSCI 北大核心 2015年第3期262-266,共5页
The imbalance of the internal and external trade of China has long been a problem; the external imbalance embodies itself as the long- term surplus of the international balance of payment caused by twin surpluses,and ... The imbalance of the internal and external trade of China has long been a problem; the external imbalance embodies itself as the long- term surplus of the international balance of payment caused by twin surpluses,and the internal imbalance is characterized by high investment,low consumption,high saving rate and the periodic inflation. This paper attempts to analyze the role of the opening strategy in the problem of the imbalance. Under the influence of the internal economic,political and social environment,the export- oriented,opening strategy of introduction of foreign capital and stabilization of exchange rate is established,which may increase the risk of inflation. 展开更多
关键词 失衡 中国 贸易 通货膨胀 平衡问题 社会环境 引进外资 不平衡
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The Participation of Social Organizations and the Reform of the People's Assessor System
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作者 Sun Jian Xu Yun 《学术界》 CSSCI 北大核心 2014年第1期301-306,共6页
In the process of transition from the rural China to modern society,the people's assessor system mainly reflects the citizens' individual participation.However,organized judicial participation has not been pai... In the process of transition from the rural China to modern society,the people's assessor system mainly reflects the citizens' individual participation.However,organized judicial participation has not been paid enough attention in either institutional design or in the actual operation.Judicial participation of social organizations has important significance not only in highlighting the value of people's assessor system,but also in getting out of the "presenting without substantive hearing"predicament in practice.Therefore,the people's court shall guide the orderly participation of social organizations in justice,and make social organizations play a more important role in people's assessor system. 展开更多
关键词 社会组织 改革 社会转型 中国农村 评估系统 人民法院 司法 听证会
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STUDY ON THE ADJOINT METHOD IN DATA ASSIMILATION AND THE RELATED PROBLEMS 被引量:8
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作者 吕咸青 吴自库 +1 位作者 谷艺 田纪伟 《应用数学和力学》 EI CSCD 北大核心 2004年第6期581-590,共10页
It is not reasonable that one can only use the adjoint of model in data assimilation. The simulated numerical experiment shows that for the tidal model, the result of the adjoint of equation is almost the same as that... It is not reasonable that one can only use the adjoint of model in data assimilation. The simulated numerical experiment shows that for the tidal model, the result of the adjoint of equation is almost the same as that of the adjoint of model: the averaged absolute difference of the amplitude between observations and simulation is less than 5.0 cm and that of the phase-lag is less than 5.0°. The results are both in good agreement with the observed M2 tide in the Bohai Sea and the Yellow Sea. For comparison, the traditional methods also have been used to simulate M2 tide in the Bohai Sea and the Yellow Sea. The initial guess values of the boundary conditions are given first, and then are adjusted to acquire the simulated results that are as close as possible to the observations. As the boundary conditions contain 72 values, which should be adjusted and how to adjust them can only be partially solved by adjusting them many times. The satisfied results are hard to acquire even gigantic efforts are done. Here, the automation of the treatment of the open boundary conditions is realized. The method is unique and superior to the traditional methods. It is emphasized that if the adjoint of equation is used, tedious and complicated mathematical deduction can be avoided. Therefore the adjoint of equation should attract much attention. 展开更多
关键词 数据同化 变分分析 伴随方法 潮汐 开边界条件
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Reaction parameters influence on the catalytic performance of copper-silica aerogel in the methanol steam reforming 被引量:1
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作者 Taher Yousefi Amiri Jafarsadegh Moghaddas 《燃料化学学报》 EI CAS CSCD 北大核心 2016年第1期84-90,共7页
Steam reforming of methanol was carried out on the copper-silica aerogel catalyst.The effects of reaction temperature,feed rate,water to methanol molar ratio and carrier gas flowrate on the H_2 production rate and CO ... Steam reforming of methanol was carried out on the copper-silica aerogel catalyst.The effects of reaction temperature,feed rate,water to methanol molar ratio and carrier gas flowrate on the H_2 production rate and CO selectivity were investigated.M ethanol conversion was increased considerably in the range of about 240-300,after which it increased at a slightly lower rate.The used feed flowrate,steam to methanol molar ratio and carrier gas flowwere 1.2-9.0 m L/h,1.2-5.0 and 20-80 m L/min,respectively.Reducing the feed flowrate increased the H_2 production rate.It was found that an increase in the water to methanol ratio and decreasing the carrier gas flowrate slightly increases the H2production rate.Increasing the water to methanol ratio causes the lowest temperature in which CO formation was observed to rise,so that for the ratio of 5.0 no CO formation was detected in temperatures lower than 375℃.In all conditions,by approaching the complete conversion,increasing the main product concentration,increasing the temperature and contact time,and decreasing the steam to methanol ratio,the CO selectivity was increased.These results suggested that CO was formed as a secondary product through reverse water-gas shift reaction and did not participate in the methanol steam reforming reaction mechanism. 展开更多
关键词 copper-silica AEROGEL activity CO SELECTIVITY reaction parameters METHANOL steam reformING
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