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二氧化锰电极现场透射X射线吸收谱研究
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作者 汪夏燕 李朋恺 +1 位作者 夏定国 刘涛 《湘潭大学自然科学学报》 CAS CSCD 1999年第4期64-67,共4页
运用现场透射X射线吸收谱法对可充碱锰电池的二氧化锰电极在放电过程中的结构变化进行了研究.结果表明放电过程中二氧化锰中的锰发生了结构重排,[MnO6]八面体的角边共享的程度发生了变化.随放电深度的增大,锰的第一近邻的配位数减小,Mn... 运用现场透射X射线吸收谱法对可充碱锰电池的二氧化锰电极在放电过程中的结构变化进行了研究.结果表明放电过程中二氧化锰中的锰发生了结构重排,[MnO6]八面体的角边共享的程度发生了变化.随放电深度的增大,锰的第一近邻的配位数减小,Mn- O键键长增大. 展开更多
关键词 x射线吸收谱法 可充碱锰电池 二氧化锰 电极
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Prediction of XRF analyzers error for elements on-line assaying using Kalman Filter 被引量:3
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作者 Nakhaei F Sam A +1 位作者 Mosavi MR Nakhaei A 《International Journal of Mining Science and Technology》 SCIE EI 2012年第4期595-601,共7页
Determination of chemical elements assay plays an important role in mineral processing operations.This factor is used to control process accuracy,recovery calculation and plant profitability.The new assaying methods i... Determination of chemical elements assay plays an important role in mineral processing operations.This factor is used to control process accuracy,recovery calculation and plant profitability.The new assaying methods including chemical methods,X-ray fluorescence and atomic absorption spectrometry are advanced and accurate.However,in some applications,such as on-line assaying process,high accuracy is required.In this paper,an algorithm based on Kalman Filter is presented to predict on-line XRF errors.This research has been carried out on the basis of based the industrial real data collection for evaluating the performance of the presented algorithm.The measurements and analysis for this study were conducted at the Sarcheshmeh Copper Concentrator Plant located in Iran.The quality of the obtained results was very satisfied;so that the RMS errors of prediction obtained for Cu and Mo grade assaying errors in rougher feed were less than 0.039 and 0.002 and in final flotation concentration less than 0.58 and 0.074,respectively.The results indicate that the mentioned method is quite accurate to reduce the on-line XRF errors measurement. 展开更多
关键词 PredictionAccuracyx-ray fluorescence Kalman FilterAssayingError
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