期刊文献+
共找到12,186篇文章
< 1 2 250 >
每页显示 20 50 100
Integrated analysis of plasma rotation effect on HL-3 hybrid scenario
1
作者 薛淼 郑国尧 +5 位作者 薛雷 李佳鲜 王硕 杜海龙 朱毅仁 周月 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期329-336,共8页
The hybrid scenario,which has good confinement and moderate MHD instabilities,is a proposed operation scenario for international thermonuclear experimental reactor(ITER).In this work,the effect of plasma rotation on t... The hybrid scenario,which has good confinement and moderate MHD instabilities,is a proposed operation scenario for international thermonuclear experimental reactor(ITER).In this work,the effect of plasma rotation on the HL-3 hybrid scenario is analyzed with the integrated modeling framework OMFIT.The results show that toroidal rotation has no obvious effect on confinement with a high line averaged density of n_(bar)~(7)×10^(19)m^(-3).In this case,the ion temperature only changes from 4.7 keV to 4.4 keV with the rotation decreasing from 10^(5) rad/s to 10^(3) rad/s,which means that the turbulent heat transport is not dominant.While in the scenarios characterized by lower densities,such as n_(bar)~4×10^(19)m^(-3),turbulent transport becomes dominant in determining heat transport.The ion temperature rises from 3.8 keV to 6.1 keV in the core as the rotation velocity increases from 10^(3) rad/s to 10^(5) rad/s.Despite the ion temperature rising,the rotation velocity does not obviously affect electron temperature or density.Additionally,it is noteworthy that the variation in rotation velocity does not significantly affect the global confinement of plasma in scenarios with low density or with high density. 展开更多
关键词 HL-3 hybrid scenario toroidal rotation integrated modeling
在线阅读 下载PDF
Investigation on the roles of equilibrium toroidal rotation during edge-localized mode mitigated by resonant magnetic perturbations
2
作者 董良康 陈少永 +3 位作者 牟茂淋 罗杨 秦晨晨 唐昌建 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第1期16-33,共18页
The effects of equilibrium toroidal rotation during edge-localized mode(ELM)mitigated by resonant magnetic perturbation(RMP)are studied with the experimental equilibria of the EAST tokamak based on the four-field mode... The effects of equilibrium toroidal rotation during edge-localized mode(ELM)mitigated by resonant magnetic perturbation(RMP)are studied with the experimental equilibria of the EAST tokamak based on the four-field model in the BOUT++code.As the two main parameters to determine the toroidal rotation profiles,the rotation shear and magnitudes were separately scanned to investigate their roles in the impact of RMPs on peeling-ballooning(P-B)modes.On one hand,the results show that strong toroidal rotation shear is favorable for the enhancement of the self-generated E×B shearing rate<ω_(E×B)>with RMPs,leading to significant ELM mitigation with RMP in the stronger toroidal rotation shear region.On the other hand,toroidal rotation magnitudes may affect ELM mitigation by changing the penetration of the RMPs,more precisely the resonant components.RMPs can lead to a reduction in the pedestal energy loss by enhancing the multimode coupling in the turbulence transport phase.The shielding effects on RMPs increase with the toroidal rotation magnitude,leading to the enhancement of the multimode coupling with RMPs to be significantly weakened.Hence,the reduction in pedestal energy loss by RMPs decreased with the rotation magnitude.In brief,the results show that toroidal rotation plays a dual role in ELM mitigation with RMP by changing the shielding effects of plasma by rotation magnitude and affecting<ω_(E×B)>by rotation shear.In the high toroidal rotation region,toroidal rotation shear is usually strong and hence plays a dominant role in the influence of RMP on P-B modes,whereas in the low rotation region,toroidal rotation shear is weak and has negligible impact on P-B modes,and the rotation magnitude plays a dominant role in the influence of RMPs on the P-B modes by changing the field penetration.Therefore,the dual role of toroidal rotation leads to stronger ELM mitigation with RMP,which may be achieved both in the low toroidal rotation region and the relatively high rotation region that has strong rotational shear. 展开更多
关键词 edge-localized mode peeling–ballooning modes resonant magnetic perturbation toroidal rotation plasma response TOKAMAK
在线阅读 下载PDF
Spectral matching based remote sensing identification of two main crop rotation patterns in a large irrigation district
3
作者 DUAN Yuanyuan CHEN Xiuhua +3 位作者 LIU Jun YE Mao LU Wenjing LIU Hongjie 《中国水利水电科学研究院学报(中英文)》 北大核心 2024年第6期640-650,共11页
The rapid identification of planting patterns for major crops in a large irrigated district has vital importance for irrigation management,water fee collection,and crop yield estimation.In this study,the OTSU algorith... The rapid identification of planting patterns for major crops in a large irrigated district has vital importance for irrigation management,water fee collection,and crop yield estimation.In this study,the OTSU algorithm and Mean-Shift algorithm were employed to automatically determine threshold values for mapping two main rotated crop patterns at the pixel scale.A time series analysis was conducted to extract the spatial distribution of rice-wheat and wheat-maize rotations in the Chuanhang irrigation district from 2016 to 2020.The results demonstrate that both threshold segmentation algorithms are reliable in extracting the spatial distribution of the crops,with an overall accuracy exceeding 80%.Additionally,both Kappa coefficients surpass 0.7,indicating better performance by OTSU method.Over the period from 2016 to 2020,the area occupied by rice-wheat rotation cropping ranged from 12500 to 14400 hm 2;whereas wheat-maize rotation cropping exhibited smaller and more variable areas ranging from 19730 to 34070 hm 2.These findings highlight how remote sensing-based approaches can provide reliable support for rapidly and accurately identifying the spatial distribution of main crop rotation patterns within a large irrigation district. 展开更多
关键词 Chuanhang irrigation district rotate crop pattern spectral matching OTSU algorithm Mean-Shift algorithm
在线阅读 下载PDF
A New SLM Scheme Based on Constellation Rotation for PAPR Reduction
4
作者 Xie Yinghai Li Xianhuai Zhao Haibo 《China Communications》 SCIE CSCD 2024年第11期267-277,共11页
A new selected mapping(SLM)scheme based on constellation rotation is proposed to reduce the peak-to-average power ratio(PAPR)of orthogonal frequency division multiplexing(OFDM)signals.Its core idea is to generate abun... A new selected mapping(SLM)scheme based on constellation rotation is proposed to reduce the peak-to-average power ratio(PAPR)of orthogonal frequency division multiplexing(OFDM)signals.Its core idea is to generate abundant candidate signals by rotating different sub-signals of the original frequency signal with different angles.This new signal generation method can simplify the calculation process of candidate time signals into the linear addition of some intermediate signals,which are generated by the inverse fast Fourier transform(IFFT)operation of the original frequency signal.This feature can effectively reduce the computational complexity of candidate signal generation process.And compared to the traditional SLM scheme,the number of complex multiplication and complex addition of new scheme can separately be decreased by about 99.99% and 91.7% with some specific parameters.Moreover,with the help of the constellation detection mechanism at the receiver,there is no need to carry any side information at the transmitter.The simulation results show that,with the same channel transmission performance,the PAPR reduction performance of new scheme can approach or even exceed the upper bound of the traditional SLM scheme,which uses all the vectors in Hadamard matrix as the phase sequences. 展开更多
关键词 constellation rotation low computational complexity new selected mapping scheme peak-toaverage power ratio without side information transmission
在线阅读 下载PDF
AN IMPROVED ROTATION VECTOR ATTITUDE ALGORITHM FOR LASER STRAP-DOWN INERTIAL NAVIGATION SYSTEM 被引量:6
5
作者 林雪原 刘建业 刘红 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2003年第1期47-52,共6页
The laser gyro is most su it able for building the strap down inertial navigation system (SINS), and its acc uracy of attitude algorithm can enormously affect that of the laser SINS. This p aper develops three improv... The laser gyro is most su it able for building the strap down inertial navigation system (SINS), and its acc uracy of attitude algorithm can enormously affect that of the laser SINS. This p aper develops three improved algorithmal expressions for strap down attitude ut ilizing the angular increment output by the laser gyro from the last two and cur rent updating periods according to the number of gyro samples, and analyses the algorithm error in the classical coning motion. Compared with the conventional algorithms, simulational results show that this improved algorithm has higher precision. A new way to improve the rotation vector algorithms is provided. 展开更多
关键词 laser gyro strap down attitude algo rithm coning motion rotation vector error analysis QUATERNION
在线阅读 下载PDF
Effect of Nonlinear Geometric Behavior on Random Response of Rotational Shell
6
作者 高世桥 Niemann H J 《Journal of Beijing Institute of Technology》 EI CAS 2001年第1期23-28,共6页
Aimed at the large deformation problem of industry cooling tower shell, the mathematical model for the random response of rotational shell under the external random excitation is established by statistic perturbation ... Aimed at the large deformation problem of industry cooling tower shell, the mathematical model for the random response of rotational shell under the external random excitation is established by statistic perturbation method. The effect of nonlinear geometric behavior on the response of rotational shell is analyzed. 展开更多
关键词 nonlinear behavior random response rotational shell cooling tower
在线阅读 下载PDF
Nonlinear Stochastic Response of Rotational Shell Under the Action of Stationary Strong Wind Loads
7
作者 高世桥 Niemann H J 《Journal of Beijing Institute of Technology》 EI CAS 2001年第1期29-33,共5页
Based on the theoretical analysis of nonlinear random response of structure, for the engineering practical problem, that is, the large deformation of industry cooling tower shell structure under the action of strong w... Based on the theoretical analysis of nonlinear random response of structure, for the engineering practical problem, that is, the large deformation of industry cooling tower shell structure under the action of strong wind loads, the statistic perturbation method is also used to analyze some statistic characteristics of the nonlinear random response of rotational shell with geometric nonlinearity and stationary strong wind load considered. Through computation, some average values of nornal displacements and the nonlinear effect factor of the cooling tower shell are given. 展开更多
关键词 nonlinear behavior random response rotational shell cooling tower
在线阅读 下载PDF
Stochastic Responses of a Shell of Rotational Symmetry Haing Physically Nonlinear Behavior
8
作者 高世桥 《Journal of Beijing Institute of Technology》 EI CAS 1994年第1期25+19-25,共8页
Concrete is considered as an elastic body when subjected to compressive stress butas a brittle body when subjected to tensile stress. That is, after the elastic extremum it cannotcontinue to bear the stress. Based on ... Concrete is considered as an elastic body when subjected to compressive stress butas a brittle body when subjected to tensile stress. That is, after the elastic extremum it cannotcontinue to bear the stress. Based on this.'cracked' physical model, for stochastic extemalwind loads, nonlinear stochastic constitutive equations have been established. To solve equations of nonlinear stochastic vibration, an iterative statistic linearization method (ISLM) hasbeen developedb. Some statistic characteristics were foundd out. 展开更多
关键词 NON-LINEAR stochastic processes/rotational shell
在线阅读 下载PDF
Method of Improving the Navigation Accuracy of SINS by Continuous Rotation 被引量:22
9
作者 杨勇 缪玲娟 沈军 《Journal of Beijing Institute of Technology》 EI CAS 2005年第1期45-49,共5页
A method of improving the navigation accuracy of strapdown inertial navigation system (SINS) is studied. The particular technique discussed involves the continuous rotation of gyros and accelerometers cluster about th... A method of improving the navigation accuracy of strapdown inertial navigation system (SINS) is studied. The particular technique discussed involves the continuous rotation of gyros and accelerometers cluster about the vertical axis of the vehicle. Then the errors of these sensors will have periodic variation corresponding to components along the body frame. Under this condition, the modulated sensor errors produce reduced system errors. Theoretical analysis based on a new coordinate system defined as sensing frame and test results are presented, and they indicate the method attenuates the navigation errors brought by the gyros' random constant drift and the accelerometer's bias and their white noise compared to the conventional method. 展开更多
关键词 strapdown inertial navigation system (SINS) rotation navigation error
在线阅读 下载PDF
Method of ballistic control and projectile rotation in a novel railgun 被引量:5
10
作者 Bo Tang Ying-tao Xu +3 位作者 Gang Wan Jiang Yue Yong Jin Hai-yuan Li 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2018年第5期628-634,共7页
In order to realize the ballistic control of the railgun and the flight stability of the projectile, a new type of railgun is designed, which can control the muzzle velocity and rotation rate. The method of the muzzle... In order to realize the ballistic control of the railgun and the flight stability of the projectile, a new type of railgun is designed, which can control the muzzle velocity and rotation rate. The method of the muzzle velocity and overload control is to adjust the voltage or other parameters of pulse power supply. It would be easy to change velocity accurately in large wide. Another widespread concern problem is launching the spinning stability projectile by railgun. This paper designed a new structure of additional rails to generate an unsymmetrical magnetic field to produce rotational torque in armature. The structure is simple and can control the rotation rate by linear changing the barrel parameters. The calculation formulas of interior ballistic are derived by Biot-Safar law. The important parameter is the deflection angle of the additional rails relative to the symmetry plane of main rail. The larger the angle, the greater the rotation torque generated in the armature. To maintain the flight stability of the projectile, the barrel structural parameters should be proportional to the projectile structural parameters. When changing the muzzle velocity, the rotation rate will also be the equal proportion change. So that the gyro stability is the same. The experiment proves that the railgun designed in this paper can launch the projectile to rotate. And the rotational projectile may not cause the transition or much arcs. This method expands the application of the railgun. 展开更多
关键词 BALLISTIC CONTROL RAILGUN rotation Spin-stabilized PROJECTILE
在线阅读 下载PDF
Rotational motions of optically trapped microscopic particles by a vortex femtosecond laser 被引量:4
11
作者 冉玲苓 郭忠义 曲士良 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第10期279-282,共4页
The rotational motions of the optically trapped microscopic particles by the vortex femtosecond laser beam are investigated in this paper.Black particles can be trapped and rotated by a vortex femtosecond laser beam v... The rotational motions of the optically trapped microscopic particles by the vortex femtosecond laser beam are investigated in this paper.Black particles can be trapped and rotated by a vortex femtosecond laser beam very effectively because the vortex beam carries orbital angular momentum due to the helical wave-front structure in assoication with the central phase singularity.Trapped black particles rotate in the vortex beam due to the absorption of the angular momentum transferred from the vortex beam.The rotating directions of the trapped particles can be modulated by reversing the topological charge of the optical vortex in the vortex femtosecond beam.And the rotating speeds of the trapped microscopic particles greatly depend on the topological charges of the vortex tweezer and the used pulse energies. 展开更多
关键词 vortex femtosecond laser rotation PARTICLES
在线阅读 下载PDF
Modulation of magnetic and electrical properties of bilayer graphene quantum dots using rotational stacking faults 被引量:2
12
作者 Hong-Ping Yang Wen-Juan Yuan +1 位作者 Jun Luo Jing Zhu 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第7期504-510,共7页
Bilayer graphene quantum dots with rotational stacking faults(RSFs) having different rotational angles were studied.Using the first-principles calculation, we determined that these stacking faults could quantitatively... Bilayer graphene quantum dots with rotational stacking faults(RSFs) having different rotational angles were studied.Using the first-principles calculation, we determined that these stacking faults could quantitatively modulate the magnetism and the distribution of spin and energy levels in the electronic structures of the dots.In addition, by examining the spatial distribution of unpaired spins and Bader charge analysis, we found that the main source of magnetic moment originated from the edge atoms of the quantum dots.Our research results can potentially provide a new path for producing all-carbon nanodevices with different electrical and magnetic properties. 展开更多
关键词 BILAYER graphene quantum DOTS rotationAL STACKING FAULTS FIRST-PRINCIPLES calculation
在线阅读 下载PDF
Continuous Dynamic Rotation Measurements Using a Compact Cold Atom Gyroscope 被引量:12
13
作者 姚战伟 鲁思滨 +4 位作者 李润兵 王锴 曹雷 王谨 詹明生 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第8期41-44,共4页
We present an experimental demonstration of the rotation measurement using a compact cold atom gyroscope. Atom interference fringes are observed in the stationary frame and the rotating frame, respectively. The phase ... We present an experimental demonstration of the rotation measurement using a compact cold atom gyroscope. Atom interference fringes are observed in the stationary frame and the rotating frame, respectively. The phase shift and contrast of the interference fringe are experimentally investigated. The results show that the contrast of the interference fringe is well held when the platform is rotated, and the phase shift of the interference fringe is linearly proportional to the rotation rate of the platform. The long-term stability, which is evaluated by the overlapped Allan deviation, is 8.5 × 10^-6 rad/s over the integrating time of 1000s. 展开更多
关键词 of on as is in Continuous Dynamic rotation Measurements Using a Compact Cold Atom Gyroscope
在线阅读 下载PDF
Rotational symmetry of classical orbits, arbitrary quantization of angular momentum and the role of the gauge field in two-dimensional space 被引量:2
14
作者 辛俊丽 梁九卿 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第4期67-73,共7页
We study quantum classical correspondence in terms of the coherent wave functions of a charged particle in two-dimensional central-scalar potentials as well as the gauge field of a magnetic flux in the sense that the ... We study quantum classical correspondence in terms of the coherent wave functions of a charged particle in two-dimensional central-scalar potentials as well as the gauge field of a magnetic flux in the sense that the probability clouds of wave functions are well localized on classical orbits. For both closed and open classical orbits, the non-integer angular-momentum quantization with the level space of angular momentum being greater or less than h is determined uniquely by the same rotational symmetry of classical orbits and probability clouds of coherent wave functions, which is not necessarily 27r-periodic. The gauge potential of a magnetic flux impenetrable to the particle cannot change the quantization rule but is able to shift the spectrum of canonical angular momentum by a flux-dependent value, which results in a common topological phase for all wave functions in the given model. The well-known quantum mechanical anyon model becomes a special case of the arbitrary quantization, where the classical orbits are 2π-periodic. 展开更多
关键词 quantum-classical correspondence ANYON rotational symmetry arbitrary quantization of angular momentum
在线阅读 下载PDF
The rotational anisotropies in the ferromagnetism/antiferromagnetism 1/ antiferromagnetism 2 exchange bias structures 被引量:2
15
作者 胡经国 Stamps R L 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第7期1595-1601,共7页
The rotational anisotropies in the exchange bias structures of ferromagnetism/antiferromagnetism 1/antiferro- magnetism 2 are studied in this paper. Based on the model, in which the antiferromagnetism is treated with ... The rotational anisotropies in the exchange bias structures of ferromagnetism/antiferromagnetism 1/antiferro- magnetism 2 are studied in this paper. Based on the model, in which the antiferromagnetism is treated with an Ising mean field theory and the rotational anisotropy is assumed to be related to the field created by the moment induced on the antiferromagnetic layer next to the ferromagnetic layer, we can explain why in experiments for ferromag- netism (FM)/antiferromagntism 1 (AFM1)/antiferromagnetism 2 (AFM2) systems the thickness-dependent rotational anisotropy value is non-monotonic, i.e. it reaches a minimum for this system at a specific thickness of the first anti- ferromagnetic layer and exhibits oscillatory behaviour. In addition, we find that the temperature-dependent rotational anisotropy value is in good agreement with the experimental result. 展开更多
关键词 FM/AFM1/AFM2 trilayer rotational anisotropy exchange coupling
在线阅读 下载PDF
Bifurcation and chaos analysis of a nonlinear electromechanical coupling relative rotation system 被引量:1
16
作者 刘爽 赵双双 +1 位作者 孙宝平 张文明 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第9期271-277,共7页
Hopf bifurcation and chaos of a nonlinear electromechanical coupling relative rotation system are studied in this paper. Considering the energy in air-gap field of AC motor, the dynamical equation of nonlinear electro... Hopf bifurcation and chaos of a nonlinear electromechanical coupling relative rotation system are studied in this paper. Considering the energy in air-gap field of AC motor, the dynamical equation of nonlinear electromechanical coupling relative rotation system is deduced by using the dissipation Lagrange equation. Choosing the electromagnetic stiffness as a bifurcation parameter, the necessary and sufficient conditions of Hopf bifurcation are given, and the bifurcation characteristics are studied. The mechanism and conditions of system parameters for chaotic motions are investigated rigorously based on the Silnikov method, and the homoclinic orbit is found by using the undetermined coefficient method. Therefore, Smale horseshoe chaos occurs when electromagnetic stiffness changes. Numerical simulations are also given, which confirm the analytical results. 展开更多
关键词 relative rotation electromechanical coupling Hopf bifurcation CHAOS
在线阅读 下载PDF
Hopf bifurcation control for a coupled nonlinear relative rotation system with time-delay feedbacks 被引量:1
17
作者 刘爽 李雪 +1 位作者 谈书贤 李海滨 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期299-305,共7页
This paper investigates the Hopf bifurcations resulting from time delay in a coupled relative-rotation system with time- delay feedbacks. Firstly, considering external excitation, the dynamical equation of relative ro... This paper investigates the Hopf bifurcations resulting from time delay in a coupled relative-rotation system with time- delay feedbacks. Firstly, considering external excitation, the dynamical equation of relative rotation nonlinear dynamical system with primary resonance and 1:1 internal resonance under time-delay feedbacks is deduced. Secondly, the averaging equation is obtained by the multiple scales method. The periodic solution in a closed form is presented by a perturbation approach. At last, numerical simulations confirm that time-delay theoretical analyses have influence on the Hopf bifurcation point and the stability of periodic solution. 展开更多
关键词 relative rotation coupled nonlinear system BIFURCATION time delay
在线阅读 下载PDF
The effect of the rotational excitation of NO on the stereodynamics for the reaction C(~3P)+NO(X^2Π)→CN(X^2Σ^+)+O(~3P) 被引量:1
18
作者 马建军 邹勇 刘厚通 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第6期338-343,共6页
The stereodynamic properties of the reaction C (^3P) + NO (X2^П) →CN (X^2∑^+) + O (^3P) in different rotational states of reactant NO are studied theoretically by using the quasiclassical trajectory met... The stereodynamic properties of the reaction C (^3P) + NO (X2^П) →CN (X^2∑^+) + O (^3P) in different rotational states of reactant NO are studied theoretically by using the quasiclassical trajectory method on ^2A″ and ^2A′ potential energy surfaces (PESs) at a collision energy of 0.06 eV. The vector properties in different rotational states on the two surfaces are discussed in detail. The results indicate that the rotational excitation of NO has considerable influence on the stereodynamic property of the reaction occurring on the two surfaces. At the same time, the calculated polarization-dependent differential cross sections (PDDCSs) in different initial rotational states manifest that products are strongly polarized at three scattering angles. 展开更多
关键词 quasiclassical trajectory vector correlation rotational excitation
在线阅读 下载PDF
Chaos and chaotic control in a relative rotation nonlinear dynamical system under parametric excitation 被引量:1
19
作者 时培明 韩东颖 刘彬 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第9期112-117,共6页
This paper studies the chaotic behaviours of a relative rotation nonlinear dynamical system under parametric excitation and its control. The dynamical equation of relative rotation nonlinear dynamical system under par... This paper studies the chaotic behaviours of a relative rotation nonlinear dynamical system under parametric excitation and its control. The dynamical equation of relative rotation nonlinear dynamical system under parametric excitation is deduced by using the dissipation Lagrange equation. The. criterion of existence of chaos under parametric excitation is given by using the Melnikov theory. The chaotic behaviours are detected by numerical simulations including bifurcation diagrams, Poincare map and maximal Lyapunov exponent. Furthermore, it implements chaotic control using nomfeedback method. It obtains the parameter condition of chaotic control by the Melnikov theory. Numerical simulation results show the consistence with the theoretical analysis. The chaotic motions can be controlled to periodmotions by adding an excitation term. 展开更多
关键词 relative rotation nonlinear dynamical system parametric excitation chaotic control
在线阅读 下载PDF
Effects of the vibrational and rotational excitation of reagent on the stereodynamics of the reaction S (3P) + H2→ SH + H 被引量:1
20
作者 单广玲 王美山 +1 位作者 杨传路 李艳青 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第6期580-586,共7页
Quasiclassical trajectory (QCT) calculations are first carried out to study the stereodynamics of the S (3p) + H2 → SH + H reaction based on the ab initio 13Atr potential energy surface (PES) (Lii etal. 2012... Quasiclassical trajectory (QCT) calculations are first carried out to study the stereodynamics of the S (3p) + H2 → SH + H reaction based on the ab initio 13Atr potential energy surface (PES) (Lii etal. 2012 J. Chem. Phys. 136 094308). The QCT-calculated reaction probabilities and cross sections for the S + H2 (v = 0, j = 0) reaction are in good agreement with the previous quantum mechanics (QM) results. The vector properties including the alignment, orientation, and polarization- dependent differential cross sections (PDDCSs) of the product SH are presented at a collision energy of 1.8 eV. The effects of the vibrational and rotational excitations of reagent on the stereodynamics are also investigated and discussed in the present work. The calculated QCT results indicate that the vibrational and rotational excitations of reagent play an important role in determining the stereodynamic properties of the title reaction. 展开更多
关键词 STEREODYNAMICS QCT method vector correlation vibrational and rotational excitation
在线阅读 下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部