Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employe...Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employed to fabricate a multi-layer PENG based on a cellulose/polyvinylidene fluoride(PVDF)blend film matrix,incorporating multi-phase BCZT(0.1BaZr_(0.2)Ti_(0.8)O_(3)-0.9Ba_(0.7)Ca_(0.3)TiO_(3))ceramic fillers.Structural characterization via SEM and TEM revealed that an intricate hydrogen-bond network facilitated the uniform dispersion of ceramic fillers within the composite film’s sub-layers.In order to study the effect of filler distribution on piezoelectric performance,the single-and double-layer composite films with varying BCZT configurations were produced and evaluated.The results demonstrated that double-layer PENGs exhibit significantly enhanced electrical output compared to their single-layer counterparts,with the D-L_(3)H_(7) configuration achieving an open circuit voltage(V_(OC))of 23.13 V and a short circuit current(I_(SC))of 8.32μA.This enhancement is attributed to increased inter-layer interfaces,which effectively suppressed charge injection and migration,leading to improved charge density.Additionally,the presence of sharp tipped hexagonal tetragonal phase nanoparticles induced an electric field enhancement effect,further optimizing performance.展开更多
Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2...Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.展开更多
Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or ...Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or attitude instability,seriously compromising mission reliability.To address this engineering challenge,this paper proposes a multi-point low-impact locking/release mechanism based on the mobility model and energy conversion strategy.Through establishing a DOF constraint framework system,this paper systematically analyzes the energy transfer and conversion characteristics during the wing separation process,reveals the generation mechanism of impact loads,and conducts research on low-impact design based on energy conversion strategy.Building on this foundation,a single-point locking/release mechanism employing parallel trapezoidal key shaft structure was designed,which increases frictional contact time and reduces the energy release rate,thereby achieving low-impact characteristics.The mechanism's performance was validated through physical prototype development and systematic functional testing(including unlocking force,synchronization,and impact tests).Experimental results demonstrate:(1)Under 14 kN preload condition,the maximum unlocking force was only 92.54 N,showing a linear relationship with preload that satisfies the"strong-connection/weak-unlock"design requirement;(2)Wing separation was completed within 46 ms,with synchronization time difference among three separation mechanisms stably controlled within 12-14 ms,proving rapid and reliable operation;(3)The unlocking impact acceleration ranged between 26 and 73 g,below the 100 g design limit,confirming the effectiveness of the energy conversion strategy.The proposed low-impact locking/release mechanism design method based on energy conversion strategy resolves the traditional challenges of high impact and synchronization deficiencies.The synergistic optimization mechanism of"structural load reduction and performance improvement"provides a highly reliable technical solution for wing separable mechanisms while offering novel design insights for wing connection/separation systems engineering.展开更多
The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this...The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.展开更多
In recent years,the booming development of the e-commerce platform economy has brought new momentum to economic growth.As a crucial commercial tool for businesses operating on online platforms,the return strategy has ...In recent years,the booming development of the e-commerce platform economy has brought new momentum to economic growth.As a crucial commercial tool for businesses operating on online platforms,the return strategy has been widely of concern in industry and academia.On the one hand,return strategies can stimulate consumer demand and increase sales.On the other hand,the production process typically generates significant carbon dioxide emissions.Currently,governments are paying increasing attention to carbon emissions issues,and cap-and-trade regulation is one of the most widely adopted carbon emission policies by governments.This paper utilizes game theory models to investigate the issue of returns for competing enterprises with energy consumption differences under the backdrop of cap-and-trade regulation.The study results indicate the following:First,controlling the cap can effectively control carbon emissions.Second,when the return cost and the difference in carbon consumption between the two manufacturers are low,it is optimal for both parties not to provide return service due to restrictions from cap-and-trade regulation and competitive pressures.Additionally,low-energy-consumption manufacturers have an advantage in competition.Furthermore,this paper explores the changes in parameters such as the profits and production quantities of competing enterprises with variations in the cap.Consequently,it offers favorable suggestions for the government’s concerns during the implementation of carbon emission policies and provides practical guidance for manufacturers’return decisions.展开更多
In this paper,we study the optimal investment problem of an insurer whose surplus process follows the diffusion approximation of the classical Cramer-Lundberg model.Investment in the foreign markets is allowed,and the...In this paper,we study the optimal investment problem of an insurer whose surplus process follows the diffusion approximation of the classical Cramer-Lundberg model.Investment in the foreign markets is allowed,and therefore,the foreign exchange rate model is incorporated.Under the allowing of selling and borrowing,the problem of maximizing the expected exponential utility of terminal wealth is studied.By solving the corresponding Hamilton-Jacobi-Bellman equations,the optimal investment strategies and value functions are obtained.Finally,numerical analysis is presented.展开更多
Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field c...Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.展开更多
When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution...When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.展开更多
In the realm of missile defense systems,the self-sufficient maneuver capacity of missile swarms is pivotal for their survival.Through the analysis of the missile dynamics model,a time-efficient cooperative attack stra...In the realm of missile defense systems,the self-sufficient maneuver capacity of missile swarms is pivotal for their survival.Through the analysis of the missile dynamics model,a time-efficient cooperative attack strategy for missile swarm is proposed.Based on the distribution of the attackers and defenders,the collision avoidance against the defenders is considered during the attack process.By analyzing the geometric relationship between the relative velocity vector and relative position vector of the attackers and defenders,the collision avoidance constrains of attacking swarm are redefined.The key point is on adjusting the relative velocity vectors to fall outside the collision cone.This work facilitates high-precision attack toward the target while keeping safe missing distance between other attackers during collision avoidance process.By leveraging an innovative repulsion artificial function,a time-efficient cooperative attack strategy for missile swarm is obtained.Through rigorous simulation,the effectiveness of this cooperative attack strategy is substantiated.Furthermore,by employing Monte Carlo simulation,the success rate of the cooperative attack strategy is assessesed and the optimal configuration for the missile swarm is deduced.展开更多
As a crucial process in the coordinated strikes of unmanned aerial vehicles(UAVs), weapon-target assignment is vital for optimizing the allocation of available weapons and effectively exploiting the capabilities of UA...As a crucial process in the coordinated strikes of unmanned aerial vehicles(UAVs), weapon-target assignment is vital for optimizing the allocation of available weapons and effectively exploiting the capabilities of UAVs. Existing weapon-target assignment methods primarily focus on macro cluster constraints while neglecting individual strategy updates. This paper proposes a novel weapon-target assignment method for UAVs based on the multi-strategy threshold public goods game(PGG). By analyzing the concept mapping between weapon-target assignment for UAVs and multi-strategy threshold PGG, a weapon-target assignment model for UAVs based on the multi-strategy threshold PGG is established, which is adaptively complemented by the diverse cooperation-defection strategy library and the utility function based on the threshold mechanism. Additionally, a multi-chain Markov is formulated to quantitatively describe the stochastic evolutionary dynamics, whose evolutionary stable distribution is theoretically derived through the development of a strategy update rule based on preference-based aspiration dynamic. Numerical simulation results validate the feasibility and effectiveness of the proposed method, and the impacts of selection intensity, preference degree and threshold on the evolutionary stable distribution are analyzed. Comparative simulations show that the proposed method outperforms GWO, DE, and NSGA-II, achieving 17.18% higher expected utility than NSGA-II and reducing evolutionary stable times by 25% in large-scale scenario.展开更多
Game theory can be applied to the air combat decision-making problem of multiple unmanned combat air vehicles(UCAVs).However,it is difficult to have satisfactory decision-making results completely relying on air comba...Game theory can be applied to the air combat decision-making problem of multiple unmanned combat air vehicles(UCAVs).However,it is difficult to have satisfactory decision-making results completely relying on air combat situation information,because there is a lot of time-sensitive information in a complex air combat environment.In this paper,a constraint strategy game approach is developed to generate intelligent decision-making for multiple UCAVs in complex air combat environment with air combat situation information and time-sensitive information.Initially,a constraint strategy game is employed to model attack-defense decision-making problem in complex air combat environment.Then,an algorithm is proposed for solving the constraint strategy game based on linear programming and linear inequality(CSG-LL).Finally,an example is given to illustrate the effectiveness of the proposed approach.展开更多
Orthogonal variable spreading factor channelization codes are widely used to provide variable data rates for supporting different bandwidth requirements in wideband code division multiple access (WCDMA) systems. A new...Orthogonal variable spreading factor channelization codes are widely used to provide variable data rates for supporting different bandwidth requirements in wideband code division multiple access (WCDMA) systems. A new code match scheme for WCDMA code tree management was proposed. The code match scheme is similar to the existing crowed-first scheme. When choosing a code for a user, the code match scheme only compares the one up layer of the allocated codes, unlike the crowed-first scheme which perhaps compares all up layers. So the operation of code match scheme is simple, and the average time delay is decreased by 5.1%. The simulation results also show that the code match strategy can decrease the average code blocking probability by 8.4%.展开更多
Objective This study was to evaluate the efficacy and safety of a short acting reduced dose fibrinolytic regimen to promote early infarct related artery (IRA) patency for acyute myocardial infarction (AMI) patients re...Objective This study was to evaluate the efficacy and safety of a short acting reduced dose fibrinolytic regimen to promote early infarct related artery (IRA) patency for acyute myocardial infarction (AMI) patients referred for percutaneous coronary intervention (PCI).Methods Following aspirin and heparin, 166 patients were randomized to a 50 mg bolus of recombinant tissue type plasminogen activator(rt PA) or to a same volume sodium chloride injection followed by immediate primary PCI. The end points included patency rates on catheterization laboratory (cath lab) arrival, revascularization results when PCI was performed, complication rates, left ventricular function and restored patency rate following PCI. Results Patency on cath lab arrival was 64% with rt PA (34% TIMI 3,30% TIMI 2), while 31% of placebo (13% TIMI 3, 18% TIMI 2). There was no difference in the restored TIMI 3 rates of IRA between the two groups (85% vs 87%). No difference were observed in stroke or major bleeding. Left ventricular function was similar in both groups (52±9% vs 50±8%), but left ventricular ejection fraction fraction (LVEF) was higher with patent IRA (TIMI 3) on cath lab arrival than that of others (56±12% vs 48±10%).Conclusions Strategy thrombolytic regimens were compatible with subsequent PCI lead to more frequenc early recanalization (before cath lab arrival), which facilitates greater left ventricular function preservation with no augmentation of adverse events.展开更多
Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise...Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise of meeting guidance system requirements, the influence of control moment provided by a motor on the flight stability is analyzed in this paper. Firstly, the effect of the rolling movement on stability is analyzed based on the stability criterion derived using the Hurwitz stability theory. Secondly, the evaluation parameters combining the features of different control periods that could assess the variation of stability features after the motor torque are obtained. These effective formulas are used to indicate that, to reduce the flight instability risks, the stabilized rolling speed of roll speed keeping period should be as small as possible; the variation trend of motor torque during the rolling speed controlling period and the roll angle of the forward body during roll angle switching period are recommended corresponding to the projectile and trajectory characteristics. Moreover,detailed numerical simulations of 155 mm dual-spin projectile are satisfactory agreement with the theoretical results.展开更多
The exchanged hypercube EH(s, t) (where s ≥ 1 and t ≥ 1) is obtained by systematically reducing links from a regular hypercube Q,+t+l. One-step diagnosis of exchanged hypercubes which involves only one testi...The exchanged hypercube EH(s, t) (where s ≥ 1 and t ≥ 1) is obtained by systematically reducing links from a regular hypercube Q,+t+l. One-step diagnosis of exchanged hypercubes which involves only one testing phase during which processors test each other is discussed. The diagnosabilities of exchanged hypercubes are studied by using the pessimistic one-step diagno- sis strategy under two kinds of diagnosis models: the PMC model and the MM model. The main results presented here are the two proofs that the degree of diagnosability of the EH(s, t) under pessimistic one-step tl/tl fault diagnosis strategy is 2s where I ≤ s ≤ t (respectively, 2t, where 1 ≤ t ≤ s) based on the PMC model and that it is also 2s where 1 ≤ s ≤ t (respectively, 2t, where 1 ≤ t ≤ s) based on the MM* model.展开更多
A search strategy based on the maximal information gain principle is presented for the cued search of phased array radars. First, the method for the determination of the cued search region, arrangement of beam positio...A search strategy based on the maximal information gain principle is presented for the cued search of phased array radars. First, the method for the determination of the cued search region, arrangement of beam positions, and the calculation of the prior probability distribution of each beam position is discussed. And then, two search algorithms based on information gain are proposed using Shannon entropy and Kullback-Leibler entropy, respectively. With the proposed strategy, the information gain of each beam position is predicted before the radar detection, and the observation is made in the beam position with the maximal information gain. Compared with the conventional method of sequential search and confirm search, simulation results show that the proposed search strategy can distinctly improve the search performance and save radar time resources with the same given detection probability.展开更多
Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) w...Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) was designed followed the end-effector principle, and an active partial body weight support(PBWS) system was introduced to facilitate successful gait training. For successful establishment of a walking gait on the GTR with PBWS, the motion laws of the GTR were planned to enable the phase distribution relationships of the cycle step, and the center of gravity(COG) trajectory of the human body during gait training on the GTR was measured. A coordinated control strategy was proposed based on the impedance control principle. A robotic prototype was developed as a platform for evaluating the design concepts and control strategies. Preliminary gait training with a healthy subject was implemented by the robotic-assisted gait training system and the experimental results are encouraging.展开更多
In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing ...In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing from the traditional matrix encoding strategy,DMES dynamically chose the size of each message group in a given set of adoptable message sizes.The appearance possibilities of all adoptable sizes were set in accordance with the desired embedding performance(embedding rate or bit-change rate).Accordingly,a searching algorithm that could provide an optimal combination of appearance possibilities was proposed.Furthermore,the roulette wheel algorithm was employed to determine the size of each message group according to the optimal combination of appearance possibilities.The effectiveness of DMES was evaluated in StegVoIP,which is a typical covert communication system based on VoIP.The experimental results demonstrate that DMES can adjust embedding capacity and embedding transparency effectively and flexibly,and achieve the desired embedding performance in any case.For the desired embedding rate,the average errors are not more than 0.000 8,and the standard deviations are not more than 0.002 0;for the desired bit-change rate,the average errors are not more than 0.001 4,and the standard deviations are not more than 0.002 6.展开更多
The optimum control strategy and the saving potential of all variable chiller plant under the conditions of changing building cooling load and cooling water supply temperature were investigated. Based on a simulation ...The optimum control strategy and the saving potential of all variable chiller plant under the conditions of changing building cooling load and cooling water supply temperature were investigated. Based on a simulation model of water source chiller plant established in dynamic transient simulation program (TRNSYS),the four-variable quadratic orthogonal regression experiments were carried out by taking cooling load,cooling water supply temperature,cooling water flow rate and chilled water flow rate as variables,and the fitting formulas expressing the relationships between the total energy consumption of chiller plant with the four selected parameters was obtained. With the SAS statistical software and MATHEMATICA mathematical software,the optimal chilled water flow rate and cooling water flow rate which result in the minimum total energy consumption were determined under continuously varying cooling load and cooling water supply temperature. With regard to a chiller plant serving an office building in Shanghai,the total energy consumptions under different control strategies were computed in terms of the forecasting function of cooling load and water source temperature. The results show that applying the optimal control strategy to the chiller plant can bring a saving of 23.27% in power compared with the corresponding conventional variable speed plant,indicating that the optimal control strategy can improve the energy efficiency of chiller plant.展开更多
基金National Natural Science Foundation of China(52472132)Opening Project of Engineering Research Center of Eco-friendly Polymeric Materials,Ministry of Education(EFP-KF2403)Innovation Service Capability Support Plan of Xianyang(Science and Technology Innovation Talents)。
文摘Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employed to fabricate a multi-layer PENG based on a cellulose/polyvinylidene fluoride(PVDF)blend film matrix,incorporating multi-phase BCZT(0.1BaZr_(0.2)Ti_(0.8)O_(3)-0.9Ba_(0.7)Ca_(0.3)TiO_(3))ceramic fillers.Structural characterization via SEM and TEM revealed that an intricate hydrogen-bond network facilitated the uniform dispersion of ceramic fillers within the composite film’s sub-layers.In order to study the effect of filler distribution on piezoelectric performance,the single-and double-layer composite films with varying BCZT configurations were produced and evaluated.The results demonstrated that double-layer PENGs exhibit significantly enhanced electrical output compared to their single-layer counterparts,with the D-L_(3)H_(7) configuration achieving an open circuit voltage(V_(OC))of 23.13 V and a short circuit current(I_(SC))of 8.32μA.This enhancement is attributed to increased inter-layer interfaces,which effectively suppressed charge injection and migration,leading to improved charge density.Additionally,the presence of sharp tipped hexagonal tetragonal phase nanoparticles induced an electric field enhancement effect,further optimizing performance.
文摘Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.
文摘Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or attitude instability,seriously compromising mission reliability.To address this engineering challenge,this paper proposes a multi-point low-impact locking/release mechanism based on the mobility model and energy conversion strategy.Through establishing a DOF constraint framework system,this paper systematically analyzes the energy transfer and conversion characteristics during the wing separation process,reveals the generation mechanism of impact loads,and conducts research on low-impact design based on energy conversion strategy.Building on this foundation,a single-point locking/release mechanism employing parallel trapezoidal key shaft structure was designed,which increases frictional contact time and reduces the energy release rate,thereby achieving low-impact characteristics.The mechanism's performance was validated through physical prototype development and systematic functional testing(including unlocking force,synchronization,and impact tests).Experimental results demonstrate:(1)Under 14 kN preload condition,the maximum unlocking force was only 92.54 N,showing a linear relationship with preload that satisfies the"strong-connection/weak-unlock"design requirement;(2)Wing separation was completed within 46 ms,with synchronization time difference among three separation mechanisms stably controlled within 12-14 ms,proving rapid and reliable operation;(3)The unlocking impact acceleration ranged between 26 and 73 g,below the 100 g design limit,confirming the effectiveness of the energy conversion strategy.The proposed low-impact locking/release mechanism design method based on energy conversion strategy resolves the traditional challenges of high impact and synchronization deficiencies.The synergistic optimization mechanism of"structural load reduction and performance improvement"provides a highly reliable technical solution for wing separable mechanisms while offering novel design insights for wing connection/separation systems engineering.
基金supported by Southern Marine Science and Guangdong Laboratory(Zhuhai)(Grant No.SML2023SP229)。
文摘The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.
基金supported by Anhui Philosophy and Social Science Foundation(AHSKY2021D147)。
文摘In recent years,the booming development of the e-commerce platform economy has brought new momentum to economic growth.As a crucial commercial tool for businesses operating on online platforms,the return strategy has been widely of concern in industry and academia.On the one hand,return strategies can stimulate consumer demand and increase sales.On the other hand,the production process typically generates significant carbon dioxide emissions.Currently,governments are paying increasing attention to carbon emissions issues,and cap-and-trade regulation is one of the most widely adopted carbon emission policies by governments.This paper utilizes game theory models to investigate the issue of returns for competing enterprises with energy consumption differences under the backdrop of cap-and-trade regulation.The study results indicate the following:First,controlling the cap can effectively control carbon emissions.Second,when the return cost and the difference in carbon consumption between the two manufacturers are low,it is optimal for both parties not to provide return service due to restrictions from cap-and-trade regulation and competitive pressures.Additionally,low-energy-consumption manufacturers have an advantage in competition.Furthermore,this paper explores the changes in parameters such as the profits and production quantities of competing enterprises with variations in the cap.Consequently,it offers favorable suggestions for the government’s concerns during the implementation of carbon emission policies and provides practical guidance for manufacturers’return decisions.
基金supported by the National Natural Science Foundation of China(Grant No.12301603).
文摘In this paper,we study the optimal investment problem of an insurer whose surplus process follows the diffusion approximation of the classical Cramer-Lundberg model.Investment in the foreign markets is allowed,and therefore,the foreign exchange rate model is incorporated.Under the allowing of selling and borrowing,the problem of maximizing the expected exponential utility of terminal wealth is studied.By solving the corresponding Hamilton-Jacobi-Bellman equations,the optimal investment strategies and value functions are obtained.Finally,numerical analysis is presented.
基金supported by the National Natural Science Foundation of China(52164028,52274297)the Start-up Research Foundation of Hainan University(KYQD(ZR)20008,KYQD(ZR)21125,KYQD(ZR)23169))+1 种基金Collaborative Innovation Center of Marine Science and Technology of Hainan University(XTCX2022HYC14)Innovative Research Project for Postgraduate Students in Hainan Province(Qhyb2024-95).
文摘Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.
基金supported by the National Natural Science Foundation of China(72471240).
文摘When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.
基金supported by the Intelligent Aerospace System Leading Innovation Team Program of Zhejiang(2022R01003).
文摘In the realm of missile defense systems,the self-sufficient maneuver capacity of missile swarms is pivotal for their survival.Through the analysis of the missile dynamics model,a time-efficient cooperative attack strategy for missile swarm is proposed.Based on the distribution of the attackers and defenders,the collision avoidance against the defenders is considered during the attack process.By analyzing the geometric relationship between the relative velocity vector and relative position vector of the attackers and defenders,the collision avoidance constrains of attacking swarm are redefined.The key point is on adjusting the relative velocity vectors to fall outside the collision cone.This work facilitates high-precision attack toward the target while keeping safe missing distance between other attackers during collision avoidance process.By leveraging an innovative repulsion artificial function,a time-efficient cooperative attack strategy for missile swarm is obtained.Through rigorous simulation,the effectiveness of this cooperative attack strategy is substantiated.Furthermore,by employing Monte Carlo simulation,the success rate of the cooperative attack strategy is assessesed and the optimal configuration for the missile swarm is deduced.
基金supported by the National Natural Science Foundation of China (No. 62073267)。
文摘As a crucial process in the coordinated strikes of unmanned aerial vehicles(UAVs), weapon-target assignment is vital for optimizing the allocation of available weapons and effectively exploiting the capabilities of UAVs. Existing weapon-target assignment methods primarily focus on macro cluster constraints while neglecting individual strategy updates. This paper proposes a novel weapon-target assignment method for UAVs based on the multi-strategy threshold public goods game(PGG). By analyzing the concept mapping between weapon-target assignment for UAVs and multi-strategy threshold PGG, a weapon-target assignment model for UAVs based on the multi-strategy threshold PGG is established, which is adaptively complemented by the diverse cooperation-defection strategy library and the utility function based on the threshold mechanism. Additionally, a multi-chain Markov is formulated to quantitatively describe the stochastic evolutionary dynamics, whose evolutionary stable distribution is theoretically derived through the development of a strategy update rule based on preference-based aspiration dynamic. Numerical simulation results validate the feasibility and effectiveness of the proposed method, and the impacts of selection intensity, preference degree and threshold on the evolutionary stable distribution are analyzed. Comparative simulations show that the proposed method outperforms GWO, DE, and NSGA-II, achieving 17.18% higher expected utility than NSGA-II and reducing evolutionary stable times by 25% in large-scale scenario.
基金supported by Major Projects for Science and Technology Innovation 2030(Grant No.2018AA0100800)Equipment Pre-research Foundation of Laboratory(Grant No.61425040104)in part by Jiangsu Province“333”project under Grant BRA2019051.
文摘Game theory can be applied to the air combat decision-making problem of multiple unmanned combat air vehicles(UCAVs).However,it is difficult to have satisfactory decision-making results completely relying on air combat situation information,because there is a lot of time-sensitive information in a complex air combat environment.In this paper,a constraint strategy game approach is developed to generate intelligent decision-making for multiple UCAVs in complex air combat environment with air combat situation information and time-sensitive information.Initially,a constraint strategy game is employed to model attack-defense decision-making problem in complex air combat environment.Then,an algorithm is proposed for solving the constraint strategy game based on linear programming and linear inequality(CSG-LL).Finally,an example is given to illustrate the effectiveness of the proposed approach.
基金Project(60202005) supported by the National Natural Science Foundation of China
文摘Orthogonal variable spreading factor channelization codes are widely used to provide variable data rates for supporting different bandwidth requirements in wideband code division multiple access (WCDMA) systems. A new code match scheme for WCDMA code tree management was proposed. The code match scheme is similar to the existing crowed-first scheme. When choosing a code for a user, the code match scheme only compares the one up layer of the allocated codes, unlike the crowed-first scheme which perhaps compares all up layers. So the operation of code match scheme is simple, and the average time delay is decreased by 5.1%. The simulation results also show that the code match strategy can decrease the average code blocking probability by 8.4%.
文摘Objective This study was to evaluate the efficacy and safety of a short acting reduced dose fibrinolytic regimen to promote early infarct related artery (IRA) patency for acyute myocardial infarction (AMI) patients referred for percutaneous coronary intervention (PCI).Methods Following aspirin and heparin, 166 patients were randomized to a 50 mg bolus of recombinant tissue type plasminogen activator(rt PA) or to a same volume sodium chloride injection followed by immediate primary PCI. The end points included patency rates on catheterization laboratory (cath lab) arrival, revascularization results when PCI was performed, complication rates, left ventricular function and restored patency rate following PCI. Results Patency on cath lab arrival was 64% with rt PA (34% TIMI 3,30% TIMI 2), while 31% of placebo (13% TIMI 3, 18% TIMI 2). There was no difference in the restored TIMI 3 rates of IRA between the two groups (85% vs 87%). No difference were observed in stroke or major bleeding. Left ventricular function was similar in both groups (52±9% vs 50±8%), but left ventricular ejection fraction fraction (LVEF) was higher with patent IRA (TIMI 3) on cath lab arrival than that of others (56±12% vs 48±10%).Conclusions Strategy thrombolytic regimens were compatible with subsequent PCI lead to more frequenc early recanalization (before cath lab arrival), which facilitates greater left ventricular function preservation with no augmentation of adverse events.
文摘Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise of meeting guidance system requirements, the influence of control moment provided by a motor on the flight stability is analyzed in this paper. Firstly, the effect of the rolling movement on stability is analyzed based on the stability criterion derived using the Hurwitz stability theory. Secondly, the evaluation parameters combining the features of different control periods that could assess the variation of stability features after the motor torque are obtained. These effective formulas are used to indicate that, to reduce the flight instability risks, the stabilized rolling speed of roll speed keeping period should be as small as possible; the variation trend of motor torque during the rolling speed controlling period and the roll angle of the forward body during roll angle switching period are recommended corresponding to the projectile and trajectory characteristics. Moreover,detailed numerical simulations of 155 mm dual-spin projectile are satisfactory agreement with the theoretical results.
基金supported by the National Natural Science Fundation of China(61363002)
文摘The exchanged hypercube EH(s, t) (where s ≥ 1 and t ≥ 1) is obtained by systematically reducing links from a regular hypercube Q,+t+l. One-step diagnosis of exchanged hypercubes which involves only one testing phase during which processors test each other is discussed. The diagnosabilities of exchanged hypercubes are studied by using the pessimistic one-step diagno- sis strategy under two kinds of diagnosis models: the PMC model and the MM model. The main results presented here are the two proofs that the degree of diagnosability of the EH(s, t) under pessimistic one-step tl/tl fault diagnosis strategy is 2s where I ≤ s ≤ t (respectively, 2t, where 1 ≤ t ≤ s) based on the PMC model and that it is also 2s where 1 ≤ s ≤ t (respectively, 2t, where 1 ≤ t ≤ s) based on the MM* model.
基金the High Technology Research and Development Programme of China (2003AA134030)
文摘A search strategy based on the maximal information gain principle is presented for the cued search of phased array radars. First, the method for the determination of the cued search region, arrangement of beam positions, and the calculation of the prior probability distribution of each beam position is discussed. And then, two search algorithms based on information gain are proposed using Shannon entropy and Kullback-Leibler entropy, respectively. With the proposed strategy, the information gain of each beam position is predicted before the radar detection, and the observation is made in the beam position with the maximal information gain. Compared with the conventional method of sequential search and confirm search, simulation results show that the proposed search strategy can distinctly improve the search performance and save radar time resources with the same given detection probability.
基金Project(61175128) supported by the National Natural Science Foundation of ChinaProject(2008AA040203) supported by the National High Technology Research and Development Program of China
文摘Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) was designed followed the end-effector principle, and an active partial body weight support(PBWS) system was introduced to facilitate successful gait training. For successful establishment of a walking gait on the GTR with PBWS, the motion laws of the GTR were planned to enable the phase distribution relationships of the cycle step, and the center of gravity(COG) trajectory of the human body during gait training on the GTR was measured. A coordinated control strategy was proposed based on the impedance control principle. A robotic prototype was developed as a platform for evaluating the design concepts and control strategies. Preliminary gait training with a healthy subject was implemented by the robotic-assisted gait training system and the experimental results are encouraging.
基金Project(2009AA01A402) supported by the National High-Tech Research and Development Program of ChinaProject(NCET-06-0650) supported by Program for New Century Excellent Talents in University Project(IRT-0725) supported by Program for Changjiang Scholars and Innovative Research Team in Chinese University
文摘In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing from the traditional matrix encoding strategy,DMES dynamically chose the size of each message group in a given set of adoptable message sizes.The appearance possibilities of all adoptable sizes were set in accordance with the desired embedding performance(embedding rate or bit-change rate).Accordingly,a searching algorithm that could provide an optimal combination of appearance possibilities was proposed.Furthermore,the roulette wheel algorithm was employed to determine the size of each message group according to the optimal combination of appearance possibilities.The effectiveness of DMES was evaluated in StegVoIP,which is a typical covert communication system based on VoIP.The experimental results demonstrate that DMES can adjust embedding capacity and embedding transparency effectively and flexibly,and achieve the desired embedding performance in any case.For the desired embedding rate,the average errors are not more than 0.000 8,and the standard deviations are not more than 0.002 0;for the desired bit-change rate,the average errors are not more than 0.001 4,and the standard deviations are not more than 0.002 6.
基金Project(G-0805-10156) supported by US Energy Foundation
文摘The optimum control strategy and the saving potential of all variable chiller plant under the conditions of changing building cooling load and cooling water supply temperature were investigated. Based on a simulation model of water source chiller plant established in dynamic transient simulation program (TRNSYS),the four-variable quadratic orthogonal regression experiments were carried out by taking cooling load,cooling water supply temperature,cooling water flow rate and chilled water flow rate as variables,and the fitting formulas expressing the relationships between the total energy consumption of chiller plant with the four selected parameters was obtained. With the SAS statistical software and MATHEMATICA mathematical software,the optimal chilled water flow rate and cooling water flow rate which result in the minimum total energy consumption were determined under continuously varying cooling load and cooling water supply temperature. With regard to a chiller plant serving an office building in Shanghai,the total energy consumptions under different control strategies were computed in terms of the forecasting function of cooling load and water source temperature. The results show that applying the optimal control strategy to the chiller plant can bring a saving of 23.27% in power compared with the corresponding conventional variable speed plant,indicating that the optimal control strategy can improve the energy efficiency of chiller plant.