Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an excep...Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.展开更多
Achieving the spin-exchange relaxation-free(SERF)state in atomic comagnetometers(ACMs)necessitates a stable and weak magnetic environment.This paper presents the design of a miniaturized permalloy magnetic shielding s...Achieving the spin-exchange relaxation-free(SERF)state in atomic comagnetometers(ACMs)necessitates a stable and weak magnetic environment.This paper presents the design of a miniaturized permalloy magnetic shielding spherical shell(MSSS)with minimal apertures,tailored to meet these requirements.By employing a combination of analytical solutions and finite element analysis(FEA),we achieved superior magnetic shielding while maintaining a compact form factor.The analytical solution for the shielding factor indicated that a four-layer permalloy sphere shell with optimized air gaps was necessary.A numerical analysis model of the MSSS was developed and validated using COMSOL software,confirming the suitability of the air gaps.The size,shape,and orientation of the openings in the perforated sphere shell were meticulously designed and optimized to minimize residual magnetism.The optimal structure was fabricated,resulting in triaxial shielding factors of 47619,52631,and 21739,meeting the anticipated requirements.A comparison of simulation results with experimental tests demonstrated the efficacy of the design methodology.This study has significant implications for ultrasensitive magnetic field detection devices requiring weak magnetic field environments,such as atomic gyroscopes,magnetometers,atomic interferometers,and atomic clocks.展开更多
In order to improve the energy output consistency of 3, 3’-diamino-4, 4’-azoxyfurazan(DAAF) in the new insensitive booster and the safety and efficiency in the preparation process, a continuous preparation system of...In order to improve the energy output consistency of 3, 3’-diamino-4, 4’-azoxyfurazan(DAAF) in the new insensitive booster and the safety and efficiency in the preparation process, a continuous preparation system of DAAF from synthesis to spherical coating was designed and established in this paper, which combined ultrasonic micromixing reaction with microdroplet globular template. In the rapid micromixing stage, the microfluidic mixing technology with ultrasonic was used to synergistically strengthen the uniform and rapid mass transfer mixing reaction between raw materials to ensure the uniformity of DAAF particle nucleation-growth, and to prepare high-quality DAAF crystals with uniform structure and morphology and concentrated particle size distribution. In the microdroplet globular template stage, the microfluidic droplet technology was used to form a droplet globular template with uniform size under the shear action of the continuous phase of the dispersed phase solution containing DAAF particles and binder. The size of the droplet template was controlled by adjusting the flow rate ratio between the continuous phase and the dispersed phase. In the droplet globular template, with the diffusion of the solvent in the dispersed phase droplets, the binder precipitates to coat the DAAF into a ball, forming a DAAF microsphere with high sphericity, narrow particle size distribution and good monodispersity. The problem of discontinuity and DAAF particle suspension in the process was solved, and the coating theory under this process was studied. DAAF was coated with different binder formulations of fluororubber(F2604), nitrocellulose(NC) and NC/glycidyl azide polymer(GAP), and the process verification and evaluation of the system were carried out. The balling effects of large, medium and small droplet templates under different binder formulations were studied. The scanning electron microscope(SEM) results show that the three droplet templates under the three binder formulations exhibit good balling effect and narrow particle size distribution. The DAAF microspheres were characterized by powder X-ray diffraction(XRD), differential scanning calorimetry(DSC), thermo-gravimetric(TG) and sensitivity analyzer. The results showed that the crystal structure of DAAF did not change during the process, and the prepared DAAF microspheres had lower decomposition temperature and lower mechanical sensitivity than raw DAAF. The results of detonation parameters show that the coating of DAAF by using the above three binder formulations will not greatly reduce the energy output of DAAF, and has comparable detonation performance to raw DAAF. This study proves an efficient and safe continuous system from synthesis to spherical coating modification of explosives, which provides a new way for the continuous, safe and efficient preparation of spherical explosives.展开更多
To achieve the controllable release of energy of nitrocellulose-based propellants,this paper combines the cellulose-based nanocomposites aqueous coating(Surelease®-NC)with fluidized bed coating equipment to succe...To achieve the controllable release of energy of nitrocellulose-based propellants,this paper combines the cellulose-based nanocomposites aqueous coating(Surelease®-NC)with fluidized bed coating equipment to successfully prepare the coated spherical propellant for the first time.The effects of fluidized bed coating temperature,air velocity,flow speed and atomization pressure on the adhesion rate,coating integrity and coating uniformity of the coated spherical propellant were investigated,and the preparation of coated spherical propellant with homogeneous size and structural integrity was achieved for the first time.The microscopic morphology,chemical structure,water vapor adsorption behavior,combustion performance,and ageing resistance property of the coated spherical propellant were systematically investigated by,Fourier transforms infrared spectroscopy(FTIR),Micro confocal raman spectrometer,field scanning electron microscopy(SEM),dynamic vapor adsorption techniques,and closed bomb test,confirming the surface core-shell structure and the tightly bonded interfacial structure of coated spherical propellant.Meanwhile,the coated spherical propellant has good hygroscopic,excellent progressive burning and long storage stability.展开更多
In order to improve the processing precision and shorten the hob manufacturing cycle of the face gear,a precision generating hobbing method for face gear with the assembly spherical hob is proposed.Firstly,the evoluti...In order to improve the processing precision and shorten the hob manufacturing cycle of the face gear,a precision generating hobbing method for face gear with the assembly spherical hob is proposed.Firstly,the evolution of the cylindrical gear to spherical hob basic worm is analyzed,then the spherical hob basic worm is designed,thus the basic worm and spiral angle equation of spherical hob are obtained.Secondly,based on the design method of the existing hob,the development method of the assembly spherical hob is analyzed,the cutter tooth and the cutter substrate of the assembly hob are designed,and the whole assembly is finished.Thirdly,based on the need of face gear hobbing,a numerical control machine for gear hobbing is developed,and the equation of the face gear is obtained.Fourth,for reducing the face gear processing errors induced by equivalent installation errors,the error analysis model is established and the impacts of each error on the gear tooth surface are analyzed.Finally,the assembly spherical hob is manufactured and the gear hobbing test is completed.According to the measurement results,the processing parameters of face gear hobbing are modified,and the deviation of tooth surface is significantly reduced.展开更多
Because of various error factors,the detecting errors in the real-time experimental data of the wear depth affect the accuracy of the detecting data.The self-made spherical plain bearing tester was studied,and its tes...Because of various error factors,the detecting errors in the real-time experimental data of the wear depth affect the accuracy of the detecting data.The self-made spherical plain bearing tester was studied,and its testing principle of the wear depth of the spherical plain bearing was introduced.Meanwhile,the error factors affecting the wear-depth detecting precision were analyzed.Then,the comprehensive error model of the wear-depth detecting system of the spherical plain bearing was built by the multi-body system theory(MBS).In addition,the thermal deformation of the wear-depth detecting system caused by varying the environmental temperature was detected.Finally,according to the above experimental parameters,the thermal errors of the related parts of the comprehensive error model were calculated by FEM.The results show that the difference between the simulation value and the experimental value is less than 0.005 mm,and the two values are close.The correctness of the comprehensive error model is verified under the thermal error experimental conditions.展开更多
The collision and wear caused by inevitable clearance in kinematic pair have an effect on the dynamic characteristics of the mechanism.Therefore,we established the dynamic model of a 3RSR(R is the revolute joint and S...The collision and wear caused by inevitable clearance in kinematic pair have an effect on the dynamic characteristics of the mechanism.Therefore,we established the dynamic model of a 3RSR(R is the revolute joint and S is the spherical joint)parallel mechanism with spherical joint clearance based on the modified Flores contact force model and the modified Coulomb friction model using Newton-Euler method.The standard quaternion was introduced in the constraint equation,and the four-order Runge-Kutta method was adopted to solve the 3RSR dynamic model.The simulation results were compared and analyzed with the numerical results.The geometrical parameters of the worn ball socket were solved based on the Archard wear model,and the geometrical reconstruction of the worn surface was carried out.The geometric reconstruction parameters were substituted into the dynamic model,which was to analyze the dynamic response of the 3RSR parallel mechanism with wear and spherical joint clearance.The simulation results show that the irregular wear occurs in the spherical joint with clearance under the presence of the impact and friction force.The long-term wear will increase the fluctuation of the contact force,thereby decreasing the movement stability of the mechanism.展开更多
High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,tempe...High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,temperature field induced by this kind of transducer in multi-layer media will be simulated through solving Pennes equation with finite difference method,and the influence of initial sound pressure,absorption coefficient,and thickness of different layers of biological tissue as well as thermal conductivity parameter on sound focus and temperature distribution will be analyzed,respectively.The results show that the temperature in focus area increases faster while the initial sound pressure and thermal conductivity increase.The absorption coefficient is smaller,the ultrasound intensity in the focus area is bigger,and the size of the focus area is increasing.When the thicknesses of different layers of tissue change,the focus position changes slightly,but the sound intensity of the focus area will change obviously.The temperature in focus area will rise quickly before reaching a threshold,and then the temperature will keep in the threshold range.展开更多
The performance of the chemical fuel determines the altitude,range and longevity of spacecraft in air and space exploration.Promising alternatives(e.g.,hypergolic ionic liquids or high-energy composites)with high-ener...The performance of the chemical fuel determines the altitude,range and longevity of spacecraft in air and space exploration.Promising alternatives(e.g.,hypergolic ionic liquids or high-energy composites)with high-energy density,heat of formation and fast initial rate are considered as potential chemical fuels.As the high-energy density material,hexanitrohexaazaisowurtzitane(CL-20)often serves as secondary explosive with poor self-propagating combustion behaviors.Herein,90%loading CL-20 microspheres with uniform particle sizes are precisely prepared by microfluid method,which exhibit unique hierarchical structure.The morphology,thermal behaviors,as well as combustion performance were further investigated.The results demonstrated that as-prepared spherical particles exhibit prominent thermal compatibility,and the enhanced self-sustaining combustion performance.This work provides an efficient method achieving the uniform high-energy density particles with excellent self-sustaining combustion performance.展开更多
The microscopic characteristics of skeletal particles in rock and soil media have important effects on macroscopic mechanical properties.A mathematical procedure called spherical harmonic function analysis was here de...The microscopic characteristics of skeletal particles in rock and soil media have important effects on macroscopic mechanical properties.A mathematical procedure called spherical harmonic function analysis was here developed to characterize micromorphology of particles and determine the meso effects in a discrete manner.This method has strong mathematical properties with respect to orthogonality and rotating invariance.It was used here to characterize and reconstruct particle micromorphology in three-dimensional space.The applicability and accuracy of the method were assessed through comparison of basic geometric properties such as volume and surface area.The results show that the micromorphological characteristics of reproduced particles become more and more readily distinguishable as the reproduced order number of spherical harmonic function increases,and the error can be brought below 5%when the order number reaches 10.This level of precision is sharp enough to distinguish the characteristics of real particles.Reconstructed particles of the same size but different reconstructed orders were used to form cylindrical samples,and the stress-strain curves of these samples filled with different-order particles which have their mutual morphological features were compared using PFC3D.Results show that the higher the spherical harmonic order of reconstructed particles,the lower the initial compression modulus and the larger the strain at peak intensity.However,peak strength shows only a random relationship to spherical harmonic order.Microstructure reconstruction was here shown to be an efficient means of numerically simulating of multi-scale rock and soil media and studying the mechanical properties of soil samples.展开更多
Focusing on obstacle avoidance in three-dimensional space for unmanned aerial vehicle(UAV), the direct obstacle avoidance method in dynamic space based on three-dimensional velocity obstacle spherical cap is proposed,...Focusing on obstacle avoidance in three-dimensional space for unmanned aerial vehicle(UAV), the direct obstacle avoidance method in dynamic space based on three-dimensional velocity obstacle spherical cap is proposed, which quantifies the influence of threatening obstacles through velocity obstacle spherical cap parameters. In addition, the obstacle avoidance schemes of any point on the critical curve during the multi-obstacles avoidance are given. Through prediction, the insertion point for the obstacle avoidance can be obtained and the flight path can be replanned. Taking the Pythagorean Hodograph(PH) curve trajectory re-planning as an example, the three-dimensional direct obstacle avoidance method in dynamic space is tested. Simulation results show that the proposed method can realize the online obstacle avoidance trajectory re-planning, which increases the flexibility of obstacle avoidance greatly.展开更多
A novel spherical tremella-like Sb2O3 was prepared by using metal-organic frameworks(MOFs)method under a mild liquid-phase reaction condition,and was further employed as an anode material for lithium-ion batteries(LIB...A novel spherical tremella-like Sb2O3 was prepared by using metal-organic frameworks(MOFs)method under a mild liquid-phase reaction condition,and was further employed as an anode material for lithium-ion batteries(LIBs).The effect of reaction temperature and time on morphologies of Sb2O3 was studied.The results from SEM and TEM demonstrate that the tremella-like Sb2O3 architecture are composed of numerous nanosheets with high specific surface area.When the tremella-like Sb2O3 was used as LIBs anode,the discharge and charge capacities can achieve 724 and 446 mA·h/g in the first cycle,respectively.Moreover,the electrode retains an impressive high capacity of 275 mA·h/g even after 50 cycles at 20 mA/g,indicating that the material is extremely promising for application in LIBs.展开更多
The microstructures and growth process characteristics precipitation-crystallization method were investigated by SEM, TEM of spherical Ni（OH）2 particles synthesized by the aqueous and XRD, and their growth mechanism...The microstructures and growth process characteristics precipitation-crystallization method were investigated by SEM, TEM of spherical Ni（OH）2 particles synthesized by the aqueous and XRD, and their growth mechanism was discussed. With the reaction beginning and continuing, amorphous Ni（OH）2 nano-crystallites grow up to spherical micron-particles with radially arranged crystallites. The nucleation, crystallization and re-crystallization led by Ostwald ripening simultaneously take place through the whole growth processes. With the course from reversible aggregation to irreversible agglomeration, the Ni（OH）2 particles tend to grow according to the template growth model： the growth on the crystallite templates stretching in the radius directions is free and quick, while the growth rate for crystallites in other directions is confined due to lower monomers concentration and tends to dissolve So it is only the radially arranged crystallites that predominate in the particle and lead to characteristic microstructures.展开更多
In order to predict accurately the characteristics of supersonic flow in new type externally pressurized spherical air bearings under large bearing clearance and high air supply pressure, which could decrease their lo...In order to predict accurately the characteristics of supersonic flow in new type externally pressurized spherical air bearings under large bearing clearance and high air supply pressure, which could decrease their load carrying capacity and stability, a CFD-based analysis was introduced to solve the three-dimensional turbulent complete compressible air flow governing equations. The realizable κ-ε model was used as a turbulent closure illustrate that the interaction exists between shock waves The supersonic flow field near air inlets was analyzed. The flow structures and boundary layer, and the flow separation is formed at the lower comer and the lower wall around the point of a maximum velocity. The numerical results show that the conversion from supersonic flow to subsonic flow in spherical air bearing occurs through a shock region （pseudo-shock）, and the viscous boundary layer results in the flow separation and reverse flow near the shock. The calculation results basically agree with the corresponding experimental data.展开更多
Spherical Ni（OH）2 particles were prepared by an aqueous solution precipitation route. The structure of spherical Ni（OH）2 was investigated by scanning electron microscopy and transmission electron microscopy and co...Spherical Ni（OH）2 particles were prepared by an aqueous solution precipitation route. The structure of spherical Ni（OH）2 was investigated by scanning electron microscopy and transmission electron microscopy and compared with that of traditional Ni（OH）2. The results show that the spherical nickel hydroxide consists of （Ni（OH）2） spheres with a reticulate structure of platelet-like, which is almost arranged radially and the crystalline grains intervene and connect with each other to form a three-dimensional net. The spherical Ni（OH）2 particle is full of pores, crannies between cleave planes. It is supposed that this structure is beneficial to the structural stability for the spherical particles during the charge/discharge processes and can improve the cycle life of the electrode; the pores and the crannies in spherical particles can shorten the proton diffusion distance and speed its velocity, which may result in that the local polarization is lowered. The electrochemical performances of the spherical Ni（OH）2 are improved by enhancing the conducting properties of the crystalline lattice due to its quick proton diffusion.展开更多
In order to promote the tolerance and controllability of the multi-degree-of-freedom(M-DOF) ultrasonic motor, a novel two-degree-of-freedom(2-DOF) spherical ultrasonic motor using three traveling-wave type annular sta...In order to promote the tolerance and controllability of the multi-degree-of-freedom(M-DOF) ultrasonic motor, a novel two-degree-of-freedom(2-DOF) spherical ultrasonic motor using three traveling-wave type annular stators was put forward. Firstly,the structure and working principle of this motor were introduced, especially a spiral spring as the preload applied component was designed for adaptive adjustment. Then, the friction drive model of 2-DOF spherical motor was built up from spatial geometric relation between three annular stators and the spherical rotor which was used to analyze the mechanical characteristics of the motor.The optimal control strategy for minimum norm solution of three stators' angular velocity was proposed, using Moore-Penrose generalized inverse matrix. Finally, a 2-DOF prototype was fabricated and tested, which ran stably and controllably. The maximum no-load velocity and stall torque are 92 r/min and 90 m N·m, respectively. The 2-DOF spherical ultrasonic motor has compact structure, easy assembly, good performance and stable operation.展开更多
Spherical cobalt carbonate with high tap density, good crystallization and uniform particle size was prepared by controlled chemical crystal method using cobalt chloride and ammonium bicarbonate as cobalt source and p...Spherical cobalt carbonate with high tap density, good crystallization and uniform particle size was prepared by controlled chemical crystal method using cobalt chloride and ammonium bicarbonate as cobalt source and precipitator. The effects of pH value and reaction time on crystallization and physical properties of cobalt carbonate were studied. The results show that the key factors influencing the preparation process of spherical cobalt carbonate with high tap density and good crystallization are how to control pH value (7.25±0.05) and keep some reaction time (about 10 h). Co4O3 was prepared by sintering spherical morphology CoCO3 samples at varied temperatures. The results show that as the decomposition temperature increases, the as-obtained Co4O3 products with porous structure transform into polyhedral structure with glazed surface, and simultaneously the cobalt content and tap density increase. However, the specific surface area shows a trend of decrease.展开更多
文摘Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.
基金supported by Hefei National Laboratory,Innovation Program for Quantum Science and Technology(Grant Nos.2021ZD0300500 and 2021ZD0300503).
文摘Achieving the spin-exchange relaxation-free(SERF)state in atomic comagnetometers(ACMs)necessitates a stable and weak magnetic environment.This paper presents the design of a miniaturized permalloy magnetic shielding spherical shell(MSSS)with minimal apertures,tailored to meet these requirements.By employing a combination of analytical solutions and finite element analysis(FEA),we achieved superior magnetic shielding while maintaining a compact form factor.The analytical solution for the shielding factor indicated that a four-layer permalloy sphere shell with optimized air gaps was necessary.A numerical analysis model of the MSSS was developed and validated using COMSOL software,confirming the suitability of the air gaps.The size,shape,and orientation of the openings in the perforated sphere shell were meticulously designed and optimized to minimize residual magnetism.The optimal structure was fabricated,resulting in triaxial shielding factors of 47619,52631,and 21739,meeting the anticipated requirements.A comparison of simulation results with experimental tests demonstrated the efficacy of the design methodology.This study has significant implications for ultrasensitive magnetic field detection devices requiring weak magnetic field environments,such as atomic gyroscopes,magnetometers,atomic interferometers,and atomic clocks.
基金National Natural Science Foundation of China(Grant No.22005275)to provide fund for conducting experiments.
文摘In order to improve the energy output consistency of 3, 3’-diamino-4, 4’-azoxyfurazan(DAAF) in the new insensitive booster and the safety and efficiency in the preparation process, a continuous preparation system of DAAF from synthesis to spherical coating was designed and established in this paper, which combined ultrasonic micromixing reaction with microdroplet globular template. In the rapid micromixing stage, the microfluidic mixing technology with ultrasonic was used to synergistically strengthen the uniform and rapid mass transfer mixing reaction between raw materials to ensure the uniformity of DAAF particle nucleation-growth, and to prepare high-quality DAAF crystals with uniform structure and morphology and concentrated particle size distribution. In the microdroplet globular template stage, the microfluidic droplet technology was used to form a droplet globular template with uniform size under the shear action of the continuous phase of the dispersed phase solution containing DAAF particles and binder. The size of the droplet template was controlled by adjusting the flow rate ratio between the continuous phase and the dispersed phase. In the droplet globular template, with the diffusion of the solvent in the dispersed phase droplets, the binder precipitates to coat the DAAF into a ball, forming a DAAF microsphere with high sphericity, narrow particle size distribution and good monodispersity. The problem of discontinuity and DAAF particle suspension in the process was solved, and the coating theory under this process was studied. DAAF was coated with different binder formulations of fluororubber(F2604), nitrocellulose(NC) and NC/glycidyl azide polymer(GAP), and the process verification and evaluation of the system were carried out. The balling effects of large, medium and small droplet templates under different binder formulations were studied. The scanning electron microscope(SEM) results show that the three droplet templates under the three binder formulations exhibit good balling effect and narrow particle size distribution. The DAAF microspheres were characterized by powder X-ray diffraction(XRD), differential scanning calorimetry(DSC), thermo-gravimetric(TG) and sensitivity analyzer. The results showed that the crystal structure of DAAF did not change during the process, and the prepared DAAF microspheres had lower decomposition temperature and lower mechanical sensitivity than raw DAAF. The results of detonation parameters show that the coating of DAAF by using the above three binder formulations will not greatly reduce the energy output of DAAF, and has comparable detonation performance to raw DAAF. This study proves an efficient and safe continuous system from synthesis to spherical coating modification of explosives, which provides a new way for the continuous, safe and efficient preparation of spherical explosives.
基金supported by the National Natural Science Foundation of China (Grant No.22005143)Young Elite Scientists Sponsorship Program by CAST (Grant No.2022QNRC001)。
文摘To achieve the controllable release of energy of nitrocellulose-based propellants,this paper combines the cellulose-based nanocomposites aqueous coating(Surelease®-NC)with fluidized bed coating equipment to successfully prepare the coated spherical propellant for the first time.The effects of fluidized bed coating temperature,air velocity,flow speed and atomization pressure on the adhesion rate,coating integrity and coating uniformity of the coated spherical propellant were investigated,and the preparation of coated spherical propellant with homogeneous size and structural integrity was achieved for the first time.The microscopic morphology,chemical structure,water vapor adsorption behavior,combustion performance,and ageing resistance property of the coated spherical propellant were systematically investigated by,Fourier transforms infrared spectroscopy(FTIR),Micro confocal raman spectrometer,field scanning electron microscopy(SEM),dynamic vapor adsorption techniques,and closed bomb test,confirming the surface core-shell structure and the tightly bonded interfacial structure of coated spherical propellant.Meanwhile,the coated spherical propellant has good hygroscopic,excellent progressive burning and long storage stability.
基金Project(9140xx8020212xx)supported by the Advanced Research Foundation,ChinaProject(GZ2018KF003)supported by the State Key Laboratory of Smart Manufacturing for Special Vehicles and Transmission System,China
文摘In order to improve the processing precision and shorten the hob manufacturing cycle of the face gear,a precision generating hobbing method for face gear with the assembly spherical hob is proposed.Firstly,the evolution of the cylindrical gear to spherical hob basic worm is analyzed,then the spherical hob basic worm is designed,thus the basic worm and spiral angle equation of spherical hob are obtained.Secondly,based on the design method of the existing hob,the development method of the assembly spherical hob is analyzed,the cutter tooth and the cutter substrate of the assembly hob are designed,and the whole assembly is finished.Thirdly,based on the need of face gear hobbing,a numerical control machine for gear hobbing is developed,and the equation of the face gear is obtained.Fourth,for reducing the face gear processing errors induced by equivalent installation errors,the error analysis model is established and the impacts of each error on the gear tooth surface are analyzed.Finally,the assembly spherical hob is manufactured and the gear hobbing test is completed.According to the measurement results,the processing parameters of face gear hobbing are modified,and the deviation of tooth surface is significantly reduced.
基金Project(2014E00468R)supported by Technological Innovation Fund of Aviation Industry Corporation of China
文摘Because of various error factors,the detecting errors in the real-time experimental data of the wear depth affect the accuracy of the detecting data.The self-made spherical plain bearing tester was studied,and its testing principle of the wear depth of the spherical plain bearing was introduced.Meanwhile,the error factors affecting the wear-depth detecting precision were analyzed.Then,the comprehensive error model of the wear-depth detecting system of the spherical plain bearing was built by the multi-body system theory(MBS).In addition,the thermal deformation of the wear-depth detecting system caused by varying the environmental temperature was detected.Finally,according to the above experimental parameters,the thermal errors of the related parts of the comprehensive error model were calculated by FEM.The results show that the difference between the simulation value and the experimental value is less than 0.005 mm,and the two values are close.The correctness of the comprehensive error model is verified under the thermal error experimental conditions.
基金Project(2018YFB1307900)supported by the National Key R&D Program of ChinaProject(51775473)supported by the National Natural Science Foundation of China+3 种基金Projects(E2018203140,E2019203109)supported by the Natural Science Foundation of Hebei Province,ChinaProject(ZD2019020)supported by the Key Research Project in Higher Education Institutions of Hebei Province,ChinaProject(2017KSYS009)supported by the Key Laboratory of Robotics and Intelligent Equipment of Guangdong Regular Institutions of Higher Education,ChinaProject(KCYCXPT2017006)supported by the Innovation Center of Robotics and Intelligent Equipment of Dongguan University of Technology,China。
文摘The collision and wear caused by inevitable clearance in kinematic pair have an effect on the dynamic characteristics of the mechanism.Therefore,we established the dynamic model of a 3RSR(R is the revolute joint and S is the spherical joint)parallel mechanism with spherical joint clearance based on the modified Flores contact force model and the modified Coulomb friction model using Newton-Euler method.The standard quaternion was introduced in the constraint equation,and the four-order Runge-Kutta method was adopted to solve the 3RSR dynamic model.The simulation results were compared and analyzed with the numerical results.The geometrical parameters of the worn ball socket were solved based on the Archard wear model,and the geometrical reconstruction of the worn surface was carried out.The geometric reconstruction parameters were substituted into the dynamic model,which was to analyze the dynamic response of the 3RSR parallel mechanism with wear and spherical joint clearance.The simulation results show that the irregular wear occurs in the spherical joint with clearance under the presence of the impact and friction force.The long-term wear will increase the fluctuation of the contact force,thereby decreasing the movement stability of the mechanism.
基金Project(11174077)supported by the National Natural Science Foundation of ChinaProject(11JJ3079)supported by the Hunan Provincial Natural Science Foundation of ChinaProjects(12C0237,11C0844)supported by the Science Research Program of Education Department of Hunan Province,China
文摘High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,temperature field induced by this kind of transducer in multi-layer media will be simulated through solving Pennes equation with finite difference method,and the influence of initial sound pressure,absorption coefficient,and thickness of different layers of biological tissue as well as thermal conductivity parameter on sound focus and temperature distribution will be analyzed,respectively.The results show that the temperature in focus area increases faster while the initial sound pressure and thermal conductivity increase.The absorption coefficient is smaller,the ultrasound intensity in the focus area is bigger,and the size of the focus area is increasing.When the thicknesses of different layers of tissue change,the focus position changes slightly,but the sound intensity of the focus area will change obviously.The temperature in focus area will rise quickly before reaching a threshold,and then the temperature will keep in the threshold range.
基金supported by the Project of State Key Laboratory of Environment-friendly Energy Materials,Southwest University of Science and Technology(No.20fksy18)。
文摘The performance of the chemical fuel determines the altitude,range and longevity of spacecraft in air and space exploration.Promising alternatives(e.g.,hypergolic ionic liquids or high-energy composites)with high-energy density,heat of formation and fast initial rate are considered as potential chemical fuels.As the high-energy density material,hexanitrohexaazaisowurtzitane(CL-20)often serves as secondary explosive with poor self-propagating combustion behaviors.Herein,90%loading CL-20 microspheres with uniform particle sizes are precisely prepared by microfluid method,which exhibit unique hierarchical structure.The morphology,thermal behaviors,as well as combustion performance were further investigated.The results demonstrated that as-prepared spherical particles exhibit prominent thermal compatibility,and the enhanced self-sustaining combustion performance.This work provides an efficient method achieving the uniform high-energy density particles with excellent self-sustaining combustion performance.
基金Project(2015CB057903)supported by the National Basic Research Program of ChinaProjects(51679071,51309089)supported by the National Natural Science Foundation of China+2 种基金Project(BK20130846)supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(2013BAB06B00)supported by the National Key Technology R&D Program,ChinaProject(2015B06014)supported by the Fundamental Research Funds for the Central Universities,China
文摘The microscopic characteristics of skeletal particles in rock and soil media have important effects on macroscopic mechanical properties.A mathematical procedure called spherical harmonic function analysis was here developed to characterize micromorphology of particles and determine the meso effects in a discrete manner.This method has strong mathematical properties with respect to orthogonality and rotating invariance.It was used here to characterize and reconstruct particle micromorphology in three-dimensional space.The applicability and accuracy of the method were assessed through comparison of basic geometric properties such as volume and surface area.The results show that the micromorphological characteristics of reproduced particles become more and more readily distinguishable as the reproduced order number of spherical harmonic function increases,and the error can be brought below 5%when the order number reaches 10.This level of precision is sharp enough to distinguish the characteristics of real particles.Reconstructed particles of the same size but different reconstructed orders were used to form cylindrical samples,and the stress-strain curves of these samples filled with different-order particles which have their mutual morphological features were compared using PFC3D.Results show that the higher the spherical harmonic order of reconstructed particles,the lower the initial compression modulus and the larger the strain at peak intensity.However,peak strength shows only a random relationship to spherical harmonic order.Microstructure reconstruction was here shown to be an efficient means of numerically simulating of multi-scale rock and soil media and studying the mechanical properties of soil samples.
基金supported by the Aeronautical Science Foundation of China(20135584010)
文摘Focusing on obstacle avoidance in three-dimensional space for unmanned aerial vehicle(UAV), the direct obstacle avoidance method in dynamic space based on three-dimensional velocity obstacle spherical cap is proposed, which quantifies the influence of threatening obstacles through velocity obstacle spherical cap parameters. In addition, the obstacle avoidance schemes of any point on the critical curve during the multi-obstacles avoidance are given. Through prediction, the insertion point for the obstacle avoidance can be obtained and the flight path can be replanned. Taking the Pythagorean Hodograph(PH) curve trajectory re-planning as an example, the three-dimensional direct obstacle avoidance method in dynamic space is tested. Simulation results show that the proposed method can realize the online obstacle avoidance trajectory re-planning, which increases the flexibility of obstacle avoidance greatly.
基金Project(51674114)supported by the National Natural Science Foundation of ChinaProject(2019JJ40069)supported by the Natural Science Foundation of Hunan Province,ChinaProject(16K025)supported by the Key Laboratory of the Education Department of Hunan Province,China
文摘A novel spherical tremella-like Sb2O3 was prepared by using metal-organic frameworks(MOFs)method under a mild liquid-phase reaction condition,and was further employed as an anode material for lithium-ion batteries(LIBs).The effect of reaction temperature and time on morphologies of Sb2O3 was studied.The results from SEM and TEM demonstrate that the tremella-like Sb2O3 architecture are composed of numerous nanosheets with high specific surface area.When the tremella-like Sb2O3 was used as LIBs anode,the discharge and charge capacities can achieve 724 and 446 mA·h/g in the first cycle,respectively.Moreover,the electrode retains an impressive high capacity of 275 mA·h/g even after 50 cycles at 20 mA/g,indicating that the material is extremely promising for application in LIBs.
基金Project(50134020) supported by the National Natural Science Foundation of ChinaProject supported by Postdoctoral Fund of Central South University
文摘The microstructures and growth process characteristics precipitation-crystallization method were investigated by SEM, TEM of spherical Ni（OH）2 particles synthesized by the aqueous and XRD, and their growth mechanism was discussed. With the reaction beginning and continuing, amorphous Ni（OH）2 nano-crystallites grow up to spherical micron-particles with radially arranged crystallites. The nucleation, crystallization and re-crystallization led by Ostwald ripening simultaneously take place through the whole growth processes. With the course from reversible aggregation to irreversible agglomeration, the Ni（OH）2 particles tend to grow according to the template growth model： the growth on the crystallite templates stretching in the radius directions is free and quick, while the growth rate for crystallites in other directions is confined due to lower monomers concentration and tends to dissolve So it is only the radially arranged crystallites that predominate in the particle and lead to characteristic microstructures.
基金Project(2002AA742049) supported by the National High Technology Research and Development Program of China
文摘In order to predict accurately the characteristics of supersonic flow in new type externally pressurized spherical air bearings under large bearing clearance and high air supply pressure, which could decrease their load carrying capacity and stability, a CFD-based analysis was introduced to solve the three-dimensional turbulent complete compressible air flow governing equations. The realizable κ-ε model was used as a turbulent closure illustrate that the interaction exists between shock waves The supersonic flow field near air inlets was analyzed. The flow structures and boundary layer, and the flow separation is formed at the lower comer and the lower wall around the point of a maximum velocity. The numerical results show that the conversion from supersonic flow to subsonic flow in spherical air bearing occurs through a shock region （pseudo-shock）, and the viscous boundary layer results in the flow separation and reverse flow near the shock. The calculation results basically agree with the corresponding experimental data.
基金Project(50134020) supported by the National Natural Science Foundation of China
文摘Spherical Ni（OH）2 particles were prepared by an aqueous solution precipitation route. The structure of spherical Ni（OH）2 was investigated by scanning electron microscopy and transmission electron microscopy and compared with that of traditional Ni（OH）2. The results show that the spherical nickel hydroxide consists of （Ni（OH）2） spheres with a reticulate structure of platelet-like, which is almost arranged radially and the crystalline grains intervene and connect with each other to form a three-dimensional net. The spherical Ni（OH）2 particle is full of pores, crannies between cleave planes. It is supposed that this structure is beneficial to the structural stability for the spherical particles during the charge/discharge processes and can improve the cycle life of the electrode; the pores and the crannies in spherical particles can shorten the proton diffusion distance and speed its velocity, which may result in that the local polarization is lowered. The electrochemical performances of the spherical Ni（OH）2 are improved by enhancing the conducting properties of the crystalline lattice due to its quick proton diffusion.
基金Project(51107111)supported by the National Natural Science Foundation of China
文摘In order to promote the tolerance and controllability of the multi-degree-of-freedom(M-DOF) ultrasonic motor, a novel two-degree-of-freedom(2-DOF) spherical ultrasonic motor using three traveling-wave type annular stators was put forward. Firstly,the structure and working principle of this motor were introduced, especially a spiral spring as the preload applied component was designed for adaptive adjustment. Then, the friction drive model of 2-DOF spherical motor was built up from spatial geometric relation between three annular stators and the spherical rotor which was used to analyze the mechanical characteristics of the motor.The optimal control strategy for minimum norm solution of three stators' angular velocity was proposed, using Moore-Penrose generalized inverse matrix. Finally, a 2-DOF prototype was fabricated and tested, which ran stably and controllably. The maximum no-load velocity and stall torque are 92 r/min and 90 m N·m, respectively. The 2-DOF spherical ultrasonic motor has compact structure, easy assembly, good performance and stable operation.
文摘Spherical cobalt carbonate with high tap density, good crystallization and uniform particle size was prepared by controlled chemical crystal method using cobalt chloride and ammonium bicarbonate as cobalt source and precipitator. The effects of pH value and reaction time on crystallization and physical properties of cobalt carbonate were studied. The results show that the key factors influencing the preparation process of spherical cobalt carbonate with high tap density and good crystallization are how to control pH value (7.25±0.05) and keep some reaction time (about 10 h). Co4O3 was prepared by sintering spherical morphology CoCO3 samples at varied temperatures. The results show that as the decomposition temperature increases, the as-obtained Co4O3 products with porous structure transform into polyhedral structure with glazed surface, and simultaneously the cobalt content and tap density increase. However, the specific surface area shows a trend of decrease.
