In the field of deep space exploration,the rapid development of terahertz spectrometer has put forward higher requirements to the back-end chirp transform spectrometer(CTS)system.In order to simultaneously meet the me...In the field of deep space exploration,the rapid development of terahertz spectrometer has put forward higher requirements to the back-end chirp transform spectrometer(CTS)system.In order to simultaneously meet the measurement requirements of wide bandwidth and high accuracy spectral lines,we built a CTS system with an analysis bandwidth of 1 GHz and a frequency resolution of 100 kHz around the surface acoustic wave(SAW)chirp filter with a bandwidth of 1 GHz.In this paper,the relationship between the CTS nonlinear phase error shift model and the basic measurement parameters is studied,and the effect of CTS phase mismatch on the pulse compression waveform is analyzed by simulation.And the expander error optimization method is proposed for the problem that the large nonlinear error of the expander leads to the unbalanced response of the CTS system and the serious distortion of the compressed pulse waveform under large bandwidth.It is verified through simulation and experiment that the method is effective for reducing the root mean square error(RMSE)of the phase of the expander from 18.75°to 6.65°,reducing the in-band standard deviation of the CTS frequency resolution index from 8.43 kHz to 4.72 kHz,solving the problem of serious distortion of the compressed pulse waveform,and improving the uneven CTS response under large bandwidth.展开更多
The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical ...The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical electrostatic analyzer accompanied with a Time of Flight(TOF)unit based on ultrathin carbon foil to measure the energy spectra and composition of space plasma.The Time of Flight technique has been used broadly in space plasma measurement.A new type of miniature method for the ion mass spectrometer is introduced.The total mass of the instrument is1.8 kg and the total power consumption is 2.0 W.The calibration results show that the energy measurement range is 8.71~43550eV,the energy resolution is 1.86%and the ion mass from 1 amu(1 amu= 1.67 × 10^(-27)kg) to 58 amu can be resolved by the miniature mass spectrometer.The miniature ion mass spectrometer also has a potential to be increased in the field of view by an electrostatic deflecting system to extend its application in space plasma detection.The miniature ion mass spectrometer has been selected for pre-study of Chinese Strategic Priority Research Program on Space Science.展开更多
In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic int...In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic interference-free cavity. The SXS can cover a wide selection of spectral windows using interchangeable Bragg crystals and by appropriate adjustment of the Bragg angle. The SXS has been used to observe time-re- solved X-ray spectrum in the 2.5 keV to 3.5 keV photon-energy range, resulting in a demonstrated spectral res- olution of about 13 at 2960 eV with a time resolution of 10 ps. The observed time and spectral resolutions dem- onstrate the applicability of the SXS for studies of laser-produced plasmas.展开更多
市场上橄榄油掺假现象屡禁不止,传统鉴定方法存在局限性。本研究利用元素分析仪-稳定同位素比质谱仪(elemental analyzer-isotope ratio mass spectrometer,EA-IRMS)对市场上常见的7种植物油进行氢、碳稳定同位素比值检验,并对测量结果...市场上橄榄油掺假现象屡禁不止,传统鉴定方法存在局限性。本研究利用元素分析仪-稳定同位素比质谱仪(elemental analyzer-isotope ratio mass spectrometer,EA-IRMS)对市场上常见的7种植物油进行氢、碳稳定同位素比值检验,并对测量结果进行显著性差异分析,同时分析橄榄油中氢、碳稳定同位素比值的相关性。结果表明:橄榄油中δD范围为-146.78‰~-125.30‰,δ^(13)C范围为-29.72‰~-28.59‰,与其他品类植物油中氢稳定同位素比值差异显著(P<0.05),与除葵花籽油、野山茶油外的植物油中碳稳定同位素比值差异显著(P<0.05);且橄榄油中氢、碳稳定同位素比值具有较强的相关性(Pearson’s r=0.904)。计算模拟豆油、玉米油对橄榄油掺假的情况,结果表明,氢、碳稳定同位素比结合分析最低能检测出玉米油掺假10%、豆油掺假30%以上的情况。该研究可为橄榄油的掺假鉴定提供方法参考。展开更多
The simulation results of MAT-261 type ion source and ion optics with the SIMION 3D 7.0 software were given. By means of simulation, the ion's trajectory was studied, the cause of low abundance sensitivity was ana...The simulation results of MAT-261 type ion source and ion optics with the SIMION 3D 7.0 software were given. By means of simulation, the ion's trajectory was studied, the cause of low abundance sensitivity was analyzed and the optimal poles' voltage ranges of the ion optics were found. Modifications were made to the LRIMS3000 type mass spectrometer according to result of the simulation. The abundance sensitivity of the mass spectrometer is improved to 2×10-6 from original 5×10-5.展开更多
The international monitoring system (IMS) station transport noble gas sample is analyzed by quadrupole mass spectrometer. The sample is composed by absolute majority of xenon and nitrogen, therefore, it can be calcula...The international monitoring system (IMS) station transport noble gas sample is analyzed by quadrupole mass spectrometer. The sample is composed by absolute majority of xenon and nitrogen, therefore, it can be calculated by the method of equation of state of ideal gas (PTV). The relatively expanded uncertainty of the xenon quantity is 4.5% in 95% confidence level.展开更多
Using quadrupole mass spectrometer,calibration gas PFTBA was turned on in constant flow to get the signal intensity,and off to get the noise value.Different scan time and dwell time was used separately for full scan m...Using quadrupole mass spectrometer,calibration gas PFTBA was turned on in constant flow to get the signal intensity,and off to get the noise value.Different scan time and dwell time was used separately for full scan mode and SIM to find out the effect of scan rate on signal intensity and noise.展开更多
To find out the effect of scan rate on sensitivity in quadrupole mass spectrometer,DDV and 11 common hypnotic drugs were chosen for GC-MS analysis.Different scan time and dwell time was used separately for full scan m...To find out the effect of scan rate on sensitivity in quadrupole mass spectrometer,DDV and 11 common hypnotic drugs were chosen for GC-MS analysis.Different scan time and dwell time was used separately for full scan mode and SIM.Then charasteristic ions were extracted to calculate signal to noise values.展开更多
In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined comp...In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).展开更多
CASEarth satellite is the first space Earth science satellite produced by the Chinese Academy of Sciences.The satellite has three payloads:high-definition Thermal Infrared Spectrometer(TIS),highdefinition Glimmer Imag...CASEarth satellite is the first space Earth science satellite produced by the Chinese Academy of Sciences.The satellite has three payloads:high-definition Thermal Infrared Spectrometer(TIS),highdefinition Glimmer Imager for Urbanization(GIU),and high-definition Multispectral Imager for Inshore(MII).These payloads are used to explore the urbanization level and residential layout,the coastal ecosystem,and new methods and approaches of environmental detection during night-time and even under conditions of polar aurora and provide scientific evidence for the refined depiction of human traces.The CASEarth satellite can provide space observation data for A Project on Big Earth Data Science Engineering as well as scientific and application studies inside and outside China.展开更多
A newest high resolution glow discharge mass spectrometer (HR-GD-MS) was developed by Thermo Electron Bremen Manufactory. Combine of a glow discharge ion source with a successful high resolution mass spectrometer, Ele...A newest high resolution glow discharge mass spectrometer (HR-GD-MS) was developed by Thermo Electron Bremen Manufactory. Combine of a glow discharge ion source with a successful high resolution mass spectrometer, Element GD become the ultimate tool for direct analysis of conductive materials. Every part of Element GD: GD ion source, mass spectrometer, detection system and software are designed for high throughput analysis: measure 50 elements at less than 10-9 within 5 minutes. Application in microelectronics, aerospace, medical/pharmaceutical/food and nuclear will be shown.展开更多
As one of the next generation imaging spectrometers, the interferential spectrometer （iS） possesses the advantages of high throughput, multi-channel and great resolution. The data of IS are produced in the spatial d...As one of the next generation imaging spectrometers, the interferential spectrometer （iS） possesses the advantages of high throughput, multi-channel and great resolution. The data of IS are produced in the spatial domain, but optical applications are in the Fourier domain. Traditional compression methods can only protect the visual quality of interferometer data in the spatial do- main but ignore the distortion in the Fourier domain. The relation between the distortion in the Fourier domain and the compression in the spatial domain is analyzed. By mathematical proof and val- idation with experiments, the relation between spatial and Fourier domains is discovered, and the significance in the Fourier domain is more important as optical path difference （OPD） increasing in the spatial domain. Based on this relation, a novel coding scheme is proposed, which can compress data in the spatial domain while reducing the distortion in the Fourier domain. In this scheme, the bit stream of the set partitioning in hierarchical trees （SPIHT） is truncated by adaptively lifting rate-distortion slopes according to the priorities of OPD based on rate-distortion optimization theory. Experimental results show that the proposed method can provide better protection of spectrum curves in the Fourier domain while maintaining a comparable visual quality in the spatial domain.展开更多
文摘In the field of deep space exploration,the rapid development of terahertz spectrometer has put forward higher requirements to the back-end chirp transform spectrometer(CTS)system.In order to simultaneously meet the measurement requirements of wide bandwidth and high accuracy spectral lines,we built a CTS system with an analysis bandwidth of 1 GHz and a frequency resolution of 100 kHz around the surface acoustic wave(SAW)chirp filter with a bandwidth of 1 GHz.In this paper,the relationship between the CTS nonlinear phase error shift model and the basic measurement parameters is studied,and the effect of CTS phase mismatch on the pulse compression waveform is analyzed by simulation.And the expander error optimization method is proposed for the problem that the large nonlinear error of the expander leads to the unbalanced response of the CTS system and the serious distortion of the compressed pulse waveform under large bandwidth.It is verified through simulation and experiment that the method is effective for reducing the root mean square error(RMSE)of the phase of the expander from 18.75°to 6.65°,reducing the in-band standard deviation of the CTS frequency resolution index from 8.43 kHz to 4.72 kHz,solving the problem of serious distortion of the compressed pulse waveform,and improving the uneven CTS response under large bandwidth.
基金Supported by the Strategic Priority Research Program on Space Science,the Chinese Academy of Sciences(XDA04071700,XDA04060202)
文摘The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical electrostatic analyzer accompanied with a Time of Flight(TOF)unit based on ultrathin carbon foil to measure the energy spectra and composition of space plasma.The Time of Flight technique has been used broadly in space plasma measurement.A new type of miniature method for the ion mass spectrometer is introduced.The total mass of the instrument is1.8 kg and the total power consumption is 2.0 W.The calibration results show that the energy measurement range is 8.71~43550eV,the energy resolution is 1.86%and the ion mass from 1 amu(1 amu= 1.67 × 10^(-27)kg) to 58 amu can be resolved by the miniature mass spectrometer.The miniature ion mass spectrometer also has a potential to be increased in the field of view by an electrostatic deflecting system to extend its application in space plasma detection.The miniature ion mass spectrometer has been selected for pre-study of Chinese Strategic Priority Research Program on Space Science.
文摘In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic interference-free cavity. The SXS can cover a wide selection of spectral windows using interchangeable Bragg crystals and by appropriate adjustment of the Bragg angle. The SXS has been used to observe time-re- solved X-ray spectrum in the 2.5 keV to 3.5 keV photon-energy range, resulting in a demonstrated spectral res- olution of about 13 at 2960 eV with a time resolution of 10 ps. The observed time and spectral resolutions dem- onstrate the applicability of the SXS for studies of laser-produced plasmas.
文摘市场上橄榄油掺假现象屡禁不止,传统鉴定方法存在局限性。本研究利用元素分析仪-稳定同位素比质谱仪(elemental analyzer-isotope ratio mass spectrometer,EA-IRMS)对市场上常见的7种植物油进行氢、碳稳定同位素比值检验,并对测量结果进行显著性差异分析,同时分析橄榄油中氢、碳稳定同位素比值的相关性。结果表明:橄榄油中δD范围为-146.78‰~-125.30‰,δ^(13)C范围为-29.72‰~-28.59‰,与其他品类植物油中氢稳定同位素比值差异显著(P<0.05),与除葵花籽油、野山茶油外的植物油中碳稳定同位素比值差异显著(P<0.05);且橄榄油中氢、碳稳定同位素比值具有较强的相关性(Pearson’s r=0.904)。计算模拟豆油、玉米油对橄榄油掺假的情况,结果表明,氢、碳稳定同位素比结合分析最低能检测出玉米油掺假10%、豆油掺假30%以上的情况。该研究可为橄榄油的掺假鉴定提供方法参考。
文摘The simulation results of MAT-261 type ion source and ion optics with the SIMION 3D 7.0 software were given. By means of simulation, the ion's trajectory was studied, the cause of low abundance sensitivity was analyzed and the optimal poles' voltage ranges of the ion optics were found. Modifications were made to the LRIMS3000 type mass spectrometer according to result of the simulation. The abundance sensitivity of the mass spectrometer is improved to 2×10-6 from original 5×10-5.
文摘The international monitoring system (IMS) station transport noble gas sample is analyzed by quadrupole mass spectrometer. The sample is composed by absolute majority of xenon and nitrogen, therefore, it can be calculated by the method of equation of state of ideal gas (PTV). The relatively expanded uncertainty of the xenon quantity is 4.5% in 95% confidence level.
文摘Using quadrupole mass spectrometer,calibration gas PFTBA was turned on in constant flow to get the signal intensity,and off to get the noise value.Different scan time and dwell time was used separately for full scan mode and SIM to find out the effect of scan rate on signal intensity and noise.
文摘To find out the effect of scan rate on sensitivity in quadrupole mass spectrometer,DDV and 11 common hypnotic drugs were chosen for GC-MS analysis.Different scan time and dwell time was used separately for full scan mode and SIM.Then charasteristic ions were extracted to calculate signal to noise values.
基金Projects(51208333,51078253)supported by the National Natural Science Foundation of China
文摘In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).
基金Supported by Chinese Academy of Sciences Strategic Leading Science and Technology Project(XDA19010000)。
文摘CASEarth satellite is the first space Earth science satellite produced by the Chinese Academy of Sciences.The satellite has three payloads:high-definition Thermal Infrared Spectrometer(TIS),highdefinition Glimmer Imager for Urbanization(GIU),and high-definition Multispectral Imager for Inshore(MII).These payloads are used to explore the urbanization level and residential layout,the coastal ecosystem,and new methods and approaches of environmental detection during night-time and even under conditions of polar aurora and provide scientific evidence for the refined depiction of human traces.The CASEarth satellite can provide space observation data for A Project on Big Earth Data Science Engineering as well as scientific and application studies inside and outside China.
文摘A newest high resolution glow discharge mass spectrometer (HR-GD-MS) was developed by Thermo Electron Bremen Manufactory. Combine of a glow discharge ion source with a successful high resolution mass spectrometer, Element GD become the ultimate tool for direct analysis of conductive materials. Every part of Element GD: GD ion source, mass spectrometer, detection system and software are designed for high throughput analysis: measure 50 elements at less than 10-9 within 5 minutes. Application in microelectronics, aerospace, medical/pharmaceutical/food and nuclear will be shown.
文摘As one of the next generation imaging spectrometers, the interferential spectrometer （iS） possesses the advantages of high throughput, multi-channel and great resolution. The data of IS are produced in the spatial domain, but optical applications are in the Fourier domain. Traditional compression methods can only protect the visual quality of interferometer data in the spatial do- main but ignore the distortion in the Fourier domain. The relation between the distortion in the Fourier domain and the compression in the spatial domain is analyzed. By mathematical proof and val- idation with experiments, the relation between spatial and Fourier domains is discovered, and the significance in the Fourier domain is more important as optical path difference （OPD） increasing in the spatial domain. Based on this relation, a novel coding scheme is proposed, which can compress data in the spatial domain while reducing the distortion in the Fourier domain. In this scheme, the bit stream of the set partitioning in hierarchical trees （SPIHT） is truncated by adaptively lifting rate-distortion slopes according to the priorities of OPD based on rate-distortion optimization theory. Experimental results show that the proposed method can provide better protection of spectrum curves in the Fourier domain while maintaining a comparable visual quality in the spatial domain.
