The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the second...The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the secondary cell and its other dynamic behaviors,the experiment and some numerical simulations were carried out based on single reference impact testing.Then,an equivalent constitutive relationship of the secondary cell was proposed to reveal the dynamic properties and used to guide the safety estimation of the battery pack.As the input parameter to the finite element model,the equivalent constitutive relationship,including but not limited to the elastic modulus and stain-stress curve,determines the simulation precision of the battery packs.Compared to the experimental results of the natural frequency of the battery pack,the simulation error is below 2%when the elastic modulus of the secondary cell in the battery pack has been verified.展开更多
In order to eliminate the settlement underestimation in surcharge preload engineering, a study based on Bjerrum's creep diagram and the tangent slope definition of secondary consolidation coefficient was carried o...In order to eliminate the settlement underestimation in surcharge preload engineering, a study based on Bjerrum's creep diagram and the tangent slope definition of secondary consolidation coefficient was carried out to analyze the time effect of secondary consolidation coefficient of over consolidated soil, and a time–growth model for it was formulated. As Bjerrum's creep diagram is an idealized model, oedometer tests were performed to improve the above time–growth model of secondary consolidation coefficient for the purpose of achieving a better agreement with the actual ground situations. It is found that secondary consolidation coefficient of over consolidated soil not only decreases with the ratio of historical maximum to current effective stress of soil(OCR), but also increases with the development time of secondary consolidation. No matter how large OCR is, the long-term time effect of secondary consolidation coefficient of over consolidated soil is all significant. Based on the above results, a model for settlement estimation was formulated and a case study to estimate it indicates that the settlement estimated by our method is 2–5 times larger than that estimated by the previous method. Moreover, the larger the OCR is as well as the longer the service life is, the larger the difference between our method and the previous method is. Thus, the post-construction secondary settlement in surcharge preload engineering will be underestimated when neglecting the time effect of secondary consolidation coefficient in over consolidated state.展开更多
A new process of AlN removal from secondary aluminum dross(SAD)by pyrometallurgical treatment with added cryolite was applied for solving the problem of recycling the secondary aluminum dross.The response surface meth...A new process of AlN removal from secondary aluminum dross(SAD)by pyrometallurgical treatment with added cryolite was applied for solving the problem of recycling the secondary aluminum dross.The response surface methodology(RSM)was used to design experiments and optimize parameters.The results show that adding the appropriate amount of cryolite can effectively promote the oxidation of AlN in the SAD,and too much cryolite will reduce the promotion effect.The effects of roasting temperature and cryolite on the denitrification rate are the most significant(p<0.0001)followed by holding time.Predicted values of the denitrification rate are found to be in good agreement with experimental values(R^(2)=0.9894 and R_(adj)^(2)=0.9775),which confirms the validity of the model employed.The optimum conditions of roasting temperature of 750°C,holding time of 194 min,mass fraction of cryolite of 17.7%are obtained according to the quadratic model.Under these conditions,the maximum actual denitrification rate reaches 94.71%and the AlN content in the SAD is only 0.55 wt%.The unfired brick with compressive strength of 18.62 MPa(GB/T 2542−2012)was prepared based on the roasted SAD.展开更多
China is extremely poor in mineral resources of Platinum Group Metals (PGMs), productive output of PGMs from mineral resource is 2.5 tons per year. At the same time, China is the biggest PGMs consumption country in th...China is extremely poor in mineral resources of Platinum Group Metals (PGMs), productive output of PGMs from mineral resource is 2.5 tons per year. At the same time, China is the biggest PGMs consumption country in the world, the mineral resource of PGMs is critical shortage, it shows the importance of recycling the secondary resource of PGMs. Sino-Platinum Metals Resource (Yimen) Co., Ltd. is the leader in recycling of PGMs from secondary resource, and has made outstanding contributions to China PGMs secondary resources recycling. This article elucidates the current situation of secondary resources recovery and development of metallurgical technology for PGMs.展开更多
In order to control the locomotive wheel(axle) load distribution, a shimming process to adjust the locomotive secondary spring loads was heretofore developed. An immune dominance clonal selection multi-objective algor...In order to control the locomotive wheel(axle) load distribution, a shimming process to adjust the locomotive secondary spring loads was heretofore developed. An immune dominance clonal selection multi-objective algorithm based on the artificial immune system was presented to further improve the performance of the optimization algorithm for locomotive secondary spring load adjustment, especially to solve the lack of control on the output shim quantity. The algorithm was designed into a two-level optimization structure according to the preferences of the problem, and the priori knowledge of the problem was used as the immune dominance. Experiments on various types of locomotives show that owing to the novel algorithm, the shim quantity is cut down by 30% 60% and the calculation time is about 90% less while the secondary spring load distribution is controlled on the same level as before. The application of this optimization algorithm can significantly improve the availability and efficiency of the secondary spring adjustment process.展开更多
The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device,muzzle brake,on the muzzle hazard phenomena,such as flash and blast waves...The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device,muzzle brake,on the muzzle hazard phenomena,such as flash and blast waves.The correlation of the chemical reactions with the characteristics of the muzzle flow field is analyzed by the simulation for a further understanding of the secondary combustion phenomenon of the muzzle flow.The novel structure of muzzle flow caused by the muzzle brake is presented by the simultaneous solution of the interior ballistics model and multi-species Navier-Stokes equations in order to analyze the influence of the muzzle brake structure on the chemical reactions.The secondary combustion of the muzzle flow due to the oxygen-supplement chemical reactions is obtained by the chemical reaction kinetic model.The interaction of the blast waves released from the muzzle brake is illustrated in detail and the mechanism of the formation of muzzle flash is analyzed.This research provides a reference for the studies on the suppression of the muzzle flash.展开更多
A weakly nonlinear oscillator was modeled by a sort of differential equation, a saddle-node bifurcation was found in case of primary and secondary resonance. To control the jumping phenomena and the unstable region of...A weakly nonlinear oscillator was modeled by a sort of differential equation, a saddle-node bifurcation was found in case of primary and secondary resonance. To control the jumping phenomena and the unstable region of the nonlinear oscillator, feedback controllers were designed. Bifurcation control equations were obtained by using the multiple scales method. And through the numerical analysis, good controller could be obtained by changing the feedback control gain. Then a feasible way of further research of saddle-node bifurcation was provided. Finally, an example shows that the feedback control method applied to the hanging bridge system of gas turbine is doable.展开更多
Proteolysis is one of the most important biochemical reactions during cheese ripening.Studies on the secondary structure of proteins during ripening would be helpful for characterizing protein changes for assessing ch...Proteolysis is one of the most important biochemical reactions during cheese ripening.Studies on the secondary structure of proteins during ripening would be helpful for characterizing protein changes for assessing cheese quality.Fourier transform infrared spectroscopy(FTIR),with self-deconvolution,second derivative analysis and band curve-fitting,was used to characterize the secondary structure of proteins in Cheddar cheese during ripening.The spectra of the amide I region showed great similarity,while the relative contents of the secondary structures underwent a series of changes.As ripening progressed,the α-helix content decreased and the β-sheet content increased.This structural shift was attributed to the strengthening of hydrogen bonds that resulted from hydrolysis of caseins.In summary,FTIR could provide the basis for rapid characterization of cheese that is undergoing ripening.展开更多
Based on consideration of the differential relations between the immeasurable variables and measurable variables in electro-hydraulic servo system,adaptive dynamic recurrent fuzzy neural networks(ADRFNNs) were employe...Based on consideration of the differential relations between the immeasurable variables and measurable variables in electro-hydraulic servo system,adaptive dynamic recurrent fuzzy neural networks(ADRFNNs) were employed to identify the primary uncertainty and the mathematic model of the system was turned into an equivalent linear model with terms of secondary uncertainty.At the same time,gain adaptive sliding mode variable structure control(GASMVSC) was employed to synthesize the control effort.The results show that the unrealization problem caused by some system's immeasurable state variables in traditional fuzzy neural networks(TFNN) taking all state variables as its inputs is overcome.On the other hand,the identification by the ADRFNNs online with high accuracy and the adaptive function of the correction term's gain in the GASMVSC make the system possess strong robustness and improved steady accuracy,and the chattering phenomenon of the control effort is also suppressed effectively.展开更多
An EMU train with detailed cabin structural is established based on the finite element method.The secondary impact between train driver and control desk is fully analysed and two measures are proposed to reduce the dr...An EMU train with detailed cabin structural is established based on the finite element method.The secondary impact between train driver and control desk is fully analysed and two measures are proposed to reduce the driver injury severity,such as the multi-objective optimization of the driver seat position and equipping the train with three-point seat belt.Simulation results indicate that the driver seat position has a significant effect on the driver injury severity during a secondary impact.According to the multi-objective optimization,some Pareto solutions are suggested to design the driver seat position.Besides that,it is also indicated although the chest and leg are well protected when the driver wears a two-point seat belt,it increases the head injure during a secondary impact.On the other hand,the three-point seat belt can supply the train driver with an overall protection against the secondary impact.The injury criteria(HIC,VC,TI)of the driver with the three-point seat belt is significantly lower than those of the driver without seat belt.Moreover,according to the simulation analysis,the limited load of the three-point seat belt is suggested about 1.5 kN.展开更多
To ensure running safety,the secondary spring loads of railway vehicles must be well equalized.Due to the coupling interactive effects of these hyper static suspended structures,the equalization adjustment through shi...To ensure running safety,the secondary spring loads of railway vehicles must be well equalized.Due to the coupling interactive effects of these hyper static suspended structures,the equalization adjustment through shimming procedure is quite complex.Therefore,an effective and reliable method in application is developed in this paper.Firstly,the best regulation of spring load is solved based on a mechanical model of the secondary suspension system,providing a target for actual adjustment.To reveal the relationship between secondary spring load distribution and shim quantity sequence,a forecasting model is constructed and then modified experimentally with consideration of car body’s elastic deformation.Further,a gradient-based algorithm with a momentum operation is proposed for the load optimization.Effectiveness of the whole method has been verified on a test rig.It is experimentally confirmed that this research provides an important basis for achieving an optimal regulation of spring load distribution for multiple types of railway vehicles.展开更多
Textile reinforced concrete(TRC)has good bearing capacity,crack resistance and corrosion resistance and it is suitable for repairing and reinforcing concrete structures in harsh marine environments.The four-point bend...Textile reinforced concrete(TRC)has good bearing capacity,crack resistance and corrosion resistance and it is suitable for repairing and reinforcing concrete structures in harsh marine environments.The four-point bending method was used to analyze the influence of the salt concentration,the damage degree and the coupled effect of the environment and load on the bending performance of TRC-strengthened beams with a secondary load.The results showed that as the salt concentration increased,the crack width and mid-span deflection of the beam quickly increased,and its bearing capacity decreased.As the damage degree increased,the early-stage crack development and mid-span deflection of the beam were less affected and the ultimate bearing capacity significantly decreased.In addition,the coupled effect of the environment and load on the beams with a secondary load was significant.As the sustained load increased,the ultimate bearing capacity of the strengthened beam decreased,and cracks developed faster in the later stage.In addition,the mid-span deflection of the beam decreased at the same load level because of the influence of the initial deflection due to the sustained load corrosion.展开更多
Geotechnical engineering that relates to the energy and environmental problem is receiving more and more attention worldwide.It is of great theoretical and practical value to study the properties of soil under thermal...Geotechnical engineering that relates to the energy and environmental problem is receiving more and more attention worldwide.It is of great theoretical and practical value to study the properties of soil under thermal mechanical coupling and its mathematical description.Firstly,based on the general function,a unified primary and secondary consolidation model of saturated soil considering heating temperature is deduced.Combining the existing research achievements,a practical model is obtained which comprehensively reflects the effective stress change,creep and heating effects.After that,a series of thermo-consolidation tests are carried out using a temperature controlled consolidation instrument to study the effects of effective stress,temperature and consolidation duration on saturated soils.The corresponding functional formulas and parameters are obtained thusly.On this basis,the calculation and analysis are carried out to check the reliability and applicability of the newly proposed model.The new model is simple and practical and the parameters are easy to be obtained.And it describes the main law of consolidation compression of saturated soils under the thermal mechanical coupling effect.Therefore,it is suggested for theoretical analysis of thermal geotechnical engineering problems.展开更多
The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantag...The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantages against the conventional recovery procedures. This paper presents a review of the advances in microwave technology applied to the recovery of precious metals from the secondary resources. Many different applications are considered, including microwave-assisted leaching, microwave augmented ashing and microwave pyrolysis. In general, microwave enhanced recovery of precious metals from secondary resources.展开更多
In order to obtain the earth pressure coefficient at rest (K0) at higher consolidation pressures during secondary compression, a series of K0 tests for saturated reconstituted clay were conducted. The results indicate...In order to obtain the earth pressure coefficient at rest (K0) at higher consolidation pressures during secondary compression, a series of K0 tests for saturated reconstituted clay were conducted. The results indicate that the measured K0 in secondary compression can be described by equations related to internal friction angle, secondary compression coefficient, compression index, recompression index, and sediment time. Effects of consolidation pressures and sediment time on K0 during secondary compression can be attributed to cementation (part of cohesion) increase and internal friction angle decrease. Cementation increase leads to nonlinear variation for K0 and internal friction angle decrease results in increase of K0. K0 computed by equations associated with internal friction angle is overestimated at apparent lower consolidation pressures with different sediment time, which agrees with the measured values well at apparent higher consolidation pressures.展开更多
Formation and dissolution of secondary arsenic minerals often play significant roles in controlling arsenic mobility in contaminated environments, especially in sulfide mines. Weathering of the orpiment and realgar-be...Formation and dissolution of secondary arsenic minerals often play significant roles in controlling arsenic mobility in contaminated environments, especially in sulfide mines. Weathering of the orpiment and realgar-bearing tailings from the Shimen realgar deposit, the largest realgar deposit in Asia, were studied. An integrated mineralogical analysis by using X-ray powder diffraction (XRD), Raman spectrum, scanning electron microscope (SEM) and transmission electron microscope (TEM) reveals four kinds of As-bearing secondary minerals including arsenic oxides, arsenates, As-gypsum, and As-Fe minerals. The precipitation of arsenates is due to interaction of As-bearing run-off waters and the underlying carbonate rocks, or the transformation of gypsum into arsenates or As-bearing gypsum through SO42-/HAsO42- substitution. Ca-arsenates are mainly weilite and pharmacolite with Ca/As atomic ratio of 1. Scanning transmission X-ray microscope (STXM) and X-ray absorption fine structure (XAFS) reveal that the valence of arsenic is mainly +3 and +5.展开更多
Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism （CD） and secondary structure changes of α-amylase under the condition of microwave irradiation an...Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism （CD） and secondary structure changes of α-amylase under the condition of microwave irradiation and water bath were studied by circular dichroism spectra. The results showed that, both the peak heights （at 2=193 nm） of the CD spectra of the samples treated by microwave irradiation and water bath reduced. The reduced rate by microwave irradiation ranged from 140% to 220%, while the reduced rate by water bath ranged from 60% to 140%. The peak of the sample treated by microwave irradiation for 60 min disappeared at λ=193 nm, while the sample showed a wake peak by water bath. The peak position by microwave irradiation emerged a blue shift in the range of 5-8 nm at λ=204 nm and λ=220 nm, while it emerged in the range of 3-5 nm by water bath. With time going on, the microwave irradiation and water bath have prompted the secondary structure of α-helix, β-sheet, β-turn and the mutual transformations of random coil, but the trends were different.展开更多
In order to investigate the compressibility, particularly the secondary compression behaviour, soil structure and undrained shear strength of Shanghai Clay, a series of one-dimensional consolidation tests （some up to...In order to investigate the compressibility, particularly the secondary compression behaviour, soil structure and undrained shear strength of Shanghai Clay, a series of one-dimensional consolidation tests （some up to 70 d） and undrained triaxial tests on high-quality intact and reconstituted soil specimens were carried out. Shanghai Clay is a lightly overconsolidated soil （OCR=1.2-1.3） with true cohesion or bonding. Due to the influence of soil structures, the secondary compression index Ca varies significantly with consolidation stress and the maximum value of C~ occurs in the vicinity of preconsolidation stress. Measured coefficients of secondary compression generally fall in the range of 0.2%-0.8% based on which Shanghai Clay can be classified as a soil with low to medium secondary compressibility. The effect of soil structures on the compressibility of Shanghai Clay is found to reduce with an increase in depth. Soil structure has an important influence on initial soil stiffness, but does not appear to affect undrained shear strength significantly. Undrained shear strengths of intact Shanghai Clay from compression tests are approximately 20% higher than those from extension tests.展开更多
In district heating(DH) system with gas-fired peak load regulating boiler in the secondary network,by prolonging run time of base load plants under rated condition,the mean energy efficiency could be increased. The fu...In district heating(DH) system with gas-fired peak load regulating boiler in the secondary network,by prolonging run time of base load plants under rated condition,the mean energy efficiency could be increased. The fuels of the system,including coal and gas,would cause different environmental impacts. Meanwhile,the reliability of the heating networks would be changed because the peak load regulating boiler could work as a standby heat source. A model for assessment of heating system was established by value analysis to optimize this kind of system. Energy consumption,greenhouse gas emission,pollution emission and system reliability were selected as functional assessment indexes in the model. Weights of each function were determined by analytical hierarchy process (AHP) and experts consultation. Life cycle cost was used as the cost in the model. A real case as an example was discussed to obtain the optimal base load ratio. The result shows that the optimal base load ratio of the case is 0.77.展开更多
基金supported by the 2019 Postdoctoral Research Project funded by Hefei Municipal Bureau of Human Resources and Social Security and the National key R&D Program of China(2017YFB0102101).
文摘The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the secondary cell and its other dynamic behaviors,the experiment and some numerical simulations were carried out based on single reference impact testing.Then,an equivalent constitutive relationship of the secondary cell was proposed to reveal the dynamic properties and used to guide the safety estimation of the battery pack.As the input parameter to the finite element model,the equivalent constitutive relationship,including but not limited to the elastic modulus and stain-stress curve,determines the simulation precision of the battery packs.Compared to the experimental results of the natural frequency of the battery pack,the simulation error is below 2%when the elastic modulus of the secondary cell in the battery pack has been verified.
基金Project(51178419)supported by the National Natural Science Foundation of China
文摘In order to eliminate the settlement underestimation in surcharge preload engineering, a study based on Bjerrum's creep diagram and the tangent slope definition of secondary consolidation coefficient was carried out to analyze the time effect of secondary consolidation coefficient of over consolidated soil, and a time–growth model for it was formulated. As Bjerrum's creep diagram is an idealized model, oedometer tests were performed to improve the above time–growth model of secondary consolidation coefficient for the purpose of achieving a better agreement with the actual ground situations. It is found that secondary consolidation coefficient of over consolidated soil not only decreases with the ratio of historical maximum to current effective stress of soil(OCR), but also increases with the development time of secondary consolidation. No matter how large OCR is, the long-term time effect of secondary consolidation coefficient of over consolidated soil is all significant. Based on the above results, a model for settlement estimation was formulated and a case study to estimate it indicates that the settlement estimated by our method is 2–5 times larger than that estimated by the previous method. Moreover, the larger the OCR is as well as the longer the service life is, the larger the difference between our method and the previous method is. Thus, the post-construction secondary settlement in surcharge preload engineering will be underestimated when neglecting the time effect of secondary consolidation coefficient in over consolidated state.
基金Project(2017YFB0306001)supported by National Key R&D Program of China。
文摘A new process of AlN removal from secondary aluminum dross(SAD)by pyrometallurgical treatment with added cryolite was applied for solving the problem of recycling the secondary aluminum dross.The response surface methodology(RSM)was used to design experiments and optimize parameters.The results show that adding the appropriate amount of cryolite can effectively promote the oxidation of AlN in the SAD,and too much cryolite will reduce the promotion effect.The effects of roasting temperature and cryolite on the denitrification rate are the most significant(p<0.0001)followed by holding time.Predicted values of the denitrification rate are found to be in good agreement with experimental values(R^(2)=0.9894 and R_(adj)^(2)=0.9775),which confirms the validity of the model employed.The optimum conditions of roasting temperature of 750°C,holding time of 194 min,mass fraction of cryolite of 17.7%are obtained according to the quadratic model.Under these conditions,the maximum actual denitrification rate reaches 94.71%and the AlN content in the SAD is only 0.55 wt%.The unfired brick with compressive strength of 18.62 MPa(GB/T 2542−2012)was prepared based on the roasted SAD.
基金the National High Technology Research and Development Program of China(863 Program) (2012AA063203)Funded by Science and Technology Department of Yunnan Province (2011AA004)
文摘China is extremely poor in mineral resources of Platinum Group Metals (PGMs), productive output of PGMs from mineral resource is 2.5 tons per year. At the same time, China is the biggest PGMs consumption country in the world, the mineral resource of PGMs is critical shortage, it shows the importance of recycling the secondary resource of PGMs. Sino-Platinum Metals Resource (Yimen) Co., Ltd. is the leader in recycling of PGMs from secondary resource, and has made outstanding contributions to China PGMs secondary resources recycling. This article elucidates the current situation of secondary resources recovery and development of metallurgical technology for PGMs.
基金Project(51305467)supported by the National Natural Science Foundation of ChinaProject(12JJ4050)supported by the Natural Science Foundation of Hunan Province,China
文摘In order to control the locomotive wheel(axle) load distribution, a shimming process to adjust the locomotive secondary spring loads was heretofore developed. An immune dominance clonal selection multi-objective algorithm based on the artificial immune system was presented to further improve the performance of the optimization algorithm for locomotive secondary spring load adjustment, especially to solve the lack of control on the output shim quantity. The algorithm was designed into a two-level optimization structure according to the preferences of the problem, and the priori knowledge of the problem was used as the immune dominance. Experiments on various types of locomotives show that owing to the novel algorithm, the shim quantity is cut down by 30% 60% and the calculation time is about 90% less while the secondary spring load distribution is controlled on the same level as before. The application of this optimization algorithm can significantly improve the availability and efficiency of the secondary spring adjustment process.
文摘The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device,muzzle brake,on the muzzle hazard phenomena,such as flash and blast waves.The correlation of the chemical reactions with the characteristics of the muzzle flow field is analyzed by the simulation for a further understanding of the secondary combustion phenomenon of the muzzle flow.The novel structure of muzzle flow caused by the muzzle brake is presented by the simultaneous solution of the interior ballistics model and multi-species Navier-Stokes equations in order to analyze the influence of the muzzle brake structure on the chemical reactions.The secondary combustion of the muzzle flow due to the oxygen-supplement chemical reactions is obtained by the chemical reaction kinetic model.The interaction of the blast waves released from the muzzle brake is illustrated in detail and the mechanism of the formation of muzzle flash is analyzed.This research provides a reference for the studies on the suppression of the muzzle flash.
基金Project(10672053) supported by the National Natural Science Foundation of ChinaProject(2002AA503010) supported by the National High-Tech Research and Development Program of China
文摘A weakly nonlinear oscillator was modeled by a sort of differential equation, a saddle-node bifurcation was found in case of primary and secondary resonance. To control the jumping phenomena and the unstable region of the nonlinear oscillator, feedback controllers were designed. Bifurcation control equations were obtained by using the multiple scales method. And through the numerical analysis, good controller could be obtained by changing the feedback control gain. Then a feasible way of further research of saddle-node bifurcation was provided. Finally, an example shows that the feedback control method applied to the hanging bridge system of gas turbine is doable.
基金financially supported by Beijing Municipal Commission of Education Co-Constructed Programand Chinese Universities Scientific Fund(2009-4-25)
文摘Proteolysis is one of the most important biochemical reactions during cheese ripening.Studies on the secondary structure of proteins during ripening would be helpful for characterizing protein changes for assessing cheese quality.Fourier transform infrared spectroscopy(FTIR),with self-deconvolution,second derivative analysis and band curve-fitting,was used to characterize the secondary structure of proteins in Cheddar cheese during ripening.The spectra of the amide I region showed great similarity,while the relative contents of the secondary structures underwent a series of changes.As ripening progressed,the α-helix content decreased and the β-sheet content increased.This structural shift was attributed to the strengthening of hydrogen bonds that resulted from hydrolysis of caseins.In summary,FTIR could provide the basis for rapid characterization of cheese that is undergoing ripening.
基金Project(60634020) supported by the National Natural Science Foundation of China
文摘Based on consideration of the differential relations between the immeasurable variables and measurable variables in electro-hydraulic servo system,adaptive dynamic recurrent fuzzy neural networks(ADRFNNs) were employed to identify the primary uncertainty and the mathematic model of the system was turned into an equivalent linear model with terms of secondary uncertainty.At the same time,gain adaptive sliding mode variable structure control(GASMVSC) was employed to synthesize the control effort.The results show that the unrealization problem caused by some system's immeasurable state variables in traditional fuzzy neural networks(TFNN) taking all state variables as its inputs is overcome.On the other hand,the identification by the ADRFNNs online with high accuracy and the adaptive function of the correction term's gain in the GASMVSC make the system possess strong robustness and improved steady accuracy,and the chattering phenomenon of the control effort is also suppressed effectively.
基金Project(51805374) supported by the National Natural Science Foundation of ChinaProject(22120180531) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(16PJ1409500) supported by the Shanghai Pujiang Program,China
文摘An EMU train with detailed cabin structural is established based on the finite element method.The secondary impact between train driver and control desk is fully analysed and two measures are proposed to reduce the driver injury severity,such as the multi-objective optimization of the driver seat position and equipping the train with three-point seat belt.Simulation results indicate that the driver seat position has a significant effect on the driver injury severity during a secondary impact.According to the multi-objective optimization,some Pareto solutions are suggested to design the driver seat position.Besides that,it is also indicated although the chest and leg are well protected when the driver wears a two-point seat belt,it increases the head injure during a secondary impact.On the other hand,the three-point seat belt can supply the train driver with an overall protection against the secondary impact.The injury criteria(HIC,VC,TI)of the driver with the three-point seat belt is significantly lower than those of the driver without seat belt.Moreover,according to the simulation analysis,the limited load of the three-point seat belt is suggested about 1.5 kN.
基金Project(51305467)supported by the National Natural Science Foundation of ChinaProject(12JJ4050)supported by the Natural Science Foundation of Hunan Province,China
文摘To ensure running safety,the secondary spring loads of railway vehicles must be well equalized.Due to the coupling interactive effects of these hyper static suspended structures,the equalization adjustment through shimming procedure is quite complex.Therefore,an effective and reliable method in application is developed in this paper.Firstly,the best regulation of spring load is solved based on a mechanical model of the secondary suspension system,providing a target for actual adjustment.To reveal the relationship between secondary spring load distribution and shim quantity sequence,a forecasting model is constructed and then modified experimentally with consideration of car body’s elastic deformation.Further,a gradient-based algorithm with a momentum operation is proposed for the load optimization.Effectiveness of the whole method has been verified on a test rig.It is experimentally confirmed that this research provides an important basis for achieving an optimal regulation of spring load distribution for multiple types of railway vehicles.
基金Project(2017XKZD09)supported by the Fundamental Research Funds for the Central Universities,China
文摘Textile reinforced concrete(TRC)has good bearing capacity,crack resistance and corrosion resistance and it is suitable for repairing and reinforcing concrete structures in harsh marine environments.The four-point bending method was used to analyze the influence of the salt concentration,the damage degree and the coupled effect of the environment and load on the bending performance of TRC-strengthened beams with a secondary load.The results showed that as the salt concentration increased,the crack width and mid-span deflection of the beam quickly increased,and its bearing capacity decreased.As the damage degree increased,the early-stage crack development and mid-span deflection of the beam were less affected and the ultimate bearing capacity significantly decreased.In addition,the coupled effect of the environment and load on the beams with a secondary load was significant.As the sustained load increased,the ultimate bearing capacity of the strengthened beam decreased,and cracks developed faster in the later stage.In addition,the mid-span deflection of the beam decreased at the same load level because of the influence of the initial deflection due to the sustained load corrosion.
基金Project(51608281)supported by the National Natural Science Foundation of ChinaProject(LGG21E080005)supported by the Provincial Natural Science Foundation of Zhejiang Province,China。
文摘Geotechnical engineering that relates to the energy and environmental problem is receiving more and more attention worldwide.It is of great theoretical and practical value to study the properties of soil under thermal mechanical coupling and its mathematical description.Firstly,based on the general function,a unified primary and secondary consolidation model of saturated soil considering heating temperature is deduced.Combining the existing research achievements,a practical model is obtained which comprehensively reflects the effective stress change,creep and heating effects.After that,a series of thermo-consolidation tests are carried out using a temperature controlled consolidation instrument to study the effects of effective stress,temperature and consolidation duration on saturated soils.The corresponding functional formulas and parameters are obtained thusly.On this basis,the calculation and analysis are carried out to check the reliability and applicability of the newly proposed model.The new model is simple and practical and the parameters are easy to be obtained.And it describes the main law of consolidation compression of saturated soils under the thermal mechanical coupling effect.Therefore,it is suggested for theoretical analysis of thermal geotechnical engineering problems.
文摘The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantages against the conventional recovery procedures. This paper presents a review of the advances in microwave technology applied to the recovery of precious metals from the secondary resources. Many different applications are considered, including microwave-assisted leaching, microwave augmented ashing and microwave pyrolysis. In general, microwave enhanced recovery of precious metals from secondary resources.
基金Projects(50534040, 50974117) supported by the National Natural Science Foundation of ChinaProject(20110491489) supported by China Postdoctoral Science FoundationProject(2011QNA03) supported by Fundamental Research Funds for Central Universities, China
文摘In order to obtain the earth pressure coefficient at rest (K0) at higher consolidation pressures during secondary compression, a series of K0 tests for saturated reconstituted clay were conducted. The results indicate that the measured K0 in secondary compression can be described by equations related to internal friction angle, secondary compression coefficient, compression index, recompression index, and sediment time. Effects of consolidation pressures and sediment time on K0 during secondary compression can be attributed to cementation (part of cohesion) increase and internal friction angle decrease. Cementation increase leads to nonlinear variation for K0 and internal friction angle decrease results in increase of K0. K0 computed by equations associated with internal friction angle is overestimated at apparent lower consolidation pressures with different sediment time, which agrees with the measured values well at apparent higher consolidation pressures.
文摘Formation and dissolution of secondary arsenic minerals often play significant roles in controlling arsenic mobility in contaminated environments, especially in sulfide mines. Weathering of the orpiment and realgar-bearing tailings from the Shimen realgar deposit, the largest realgar deposit in Asia, were studied. An integrated mineralogical analysis by using X-ray powder diffraction (XRD), Raman spectrum, scanning electron microscope (SEM) and transmission electron microscope (TEM) reveals four kinds of As-bearing secondary minerals including arsenic oxides, arsenates, As-gypsum, and As-Fe minerals. The precipitation of arsenates is due to interaction of As-bearing run-off waters and the underlying carbonate rocks, or the transformation of gypsum into arsenates or As-bearing gypsum through SO42-/HAsO42- substitution. Ca-arsenates are mainly weilite and pharmacolite with Ca/As atomic ratio of 1. Scanning transmission X-ray microscope (STXM) and X-ray absorption fine structure (XAFS) reveal that the valence of arsenic is mainly +3 and +5.
基金Project(08A080) supported by the Scientific Research Fund of Hunan Provincial Education Department,China
文摘Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism （CD） and secondary structure changes of α-amylase under the condition of microwave irradiation and water bath were studied by circular dichroism spectra. The results showed that, both the peak heights （at 2=193 nm） of the CD spectra of the samples treated by microwave irradiation and water bath reduced. The reduced rate by microwave irradiation ranged from 140% to 220%, while the reduced rate by water bath ranged from 60% to 140%. The peak of the sample treated by microwave irradiation for 60 min disappeared at λ=193 nm, while the sample showed a wake peak by water bath. The peak position by microwave irradiation emerged a blue shift in the range of 5-8 nm at λ=204 nm and λ=220 nm, while it emerged in the range of 3-5 nm by water bath. With time going on, the microwave irradiation and water bath have prompted the secondary structure of α-helix, β-sheet, β-turn and the mutual transformations of random coil, but the trends were different.
基金Project(GRF618006) supported by the Research Grants Council of the Hong Kong Special Administrative Region, China
文摘In order to investigate the compressibility, particularly the secondary compression behaviour, soil structure and undrained shear strength of Shanghai Clay, a series of one-dimensional consolidation tests （some up to 70 d） and undrained triaxial tests on high-quality intact and reconstituted soil specimens were carried out. Shanghai Clay is a lightly overconsolidated soil （OCR=1.2-1.3） with true cohesion or bonding. Due to the influence of soil structures, the secondary compression index Ca varies significantly with consolidation stress and the maximum value of C~ occurs in the vicinity of preconsolidation stress. Measured coefficients of secondary compression generally fall in the range of 0.2%-0.8% based on which Shanghai Clay can be classified as a soil with low to medium secondary compressibility. The effect of soil structures on the compressibility of Shanghai Clay is found to reduce with an increase in depth. Soil structure has an important influence on initial soil stiffness, but does not appear to affect undrained shear strength significantly. Undrained shear strengths of intact Shanghai Clay from compression tests are approximately 20% higher than those from extension tests.
文摘In district heating(DH) system with gas-fired peak load regulating boiler in the secondary network,by prolonging run time of base load plants under rated condition,the mean energy efficiency could be increased. The fuels of the system,including coal and gas,would cause different environmental impacts. Meanwhile,the reliability of the heating networks would be changed because the peak load regulating boiler could work as a standby heat source. A model for assessment of heating system was established by value analysis to optimize this kind of system. Energy consumption,greenhouse gas emission,pollution emission and system reliability were selected as functional assessment indexes in the model. Weights of each function were determined by analytical hierarchy process (AHP) and experts consultation. Life cycle cost was used as the cost in the model. A real case as an example was discussed to obtain the optimal base load ratio. The result shows that the optimal base load ratio of the case is 0.77.
