The selective catalytic reduction(SCR) of NOx using MnOx and CeO2 supported on viscose-based active carbon fibers(ACF) at 120 ℃～270 ℃ relatively lower than the temperature when using V2O5/TiO2-anatase catalyst was ...The selective catalytic reduction(SCR) of NOx using MnOx and CeO2 supported on viscose-based active carbon fibers(ACF) at 120 ℃～270 ℃ relatively lower than the temperature when using V2O5/TiO2-anatase catalyst was studied.As a result,CeO2/ACF shows a better catalysis than MNOx/ACF,which is not affected by the reaction temperature. NO conversion of 85% is reached with the 10%-CeO2/ACF catalyst at the whole temperature window.Furthermore,a series of MnOx-CeO2/ACF composite catalysts were studied.The results show that the loading method of catalyst affects its activity.展开更多
为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h...为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h情况下,NO_(x)转化率随排气温度升高呈现先增后减的趋势,不同温度下NO_(x)转化率最大差值为43.4百分点;NH_(3)泄漏量随着温度的升高大体上呈下降趋势,不同温度下NH_(3)泄漏量最大差值为328×10^(-6);NO_(x)转化率随排气流量升高呈现先增后减的趋势,在250℃时,不同排气流量下NO_(x)转化效率最大相差21.5百分点;NH_(3)泄漏量随排气流量的增大而增加,在250℃时,不同排气流量下NH_(3)泄漏量最大差值为90.8×10^(-6)。相同工况下,海拔越高,NO_(x)转化率越高,NH_(3)泄漏量越小,大气压力为80和100 k Pa下NO_(x)转化率最大相差20.1百分点,NH_(3)泄漏量最大相差54.6×10^(-6)。展开更多
In this work,a kinetic study of the selective catalytic reduction of NO with NH3 has been carried out.After proving the operating condition that the effect of intraphase diffusion and interphase mass-transfer processe...In this work,a kinetic study of the selective catalytic reduction of NO with NH3 has been carried out.After proving the operating condition that the effect of intraphase diffusion and interphase mass-transfer processes can be ignored,the selective catalytic reduction of NO with NH3 on the catalytic activity of V2O5-WO3/TiO2 has been carried out with fixing the feed gas flow rate and composition（NO,NH3,O2） while varying the catalyst loading.Based on the experimental results of NO removal efficiency,the empirical catalytic reaction rate equation of NO with NH3 has been obtained using differential analysis.The experimental result is further proved by the graphic integral method at the temperature from 320℃ to 400℃.The reaction order is 1 to NO and zero to NH3.The reaction follows the Eley-Rideal mechanism model.展开更多
文摘The selective catalytic reduction(SCR) of NOx using MnOx and CeO2 supported on viscose-based active carbon fibers(ACF) at 120 ℃～270 ℃ relatively lower than the temperature when using V2O5/TiO2-anatase catalyst was studied.As a result,CeO2/ACF shows a better catalysis than MNOx/ACF,which is not affected by the reaction temperature. NO conversion of 85% is reached with the 10%-CeO2/ACF catalyst at the whole temperature window.Furthermore,a series of MnOx-CeO2/ACF composite catalysts were studied.The results show that the loading method of catalyst affects its activity.
文摘为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h情况下,NO_(x)转化率随排气温度升高呈现先增后减的趋势,不同温度下NO_(x)转化率最大差值为43.4百分点;NH_(3)泄漏量随着温度的升高大体上呈下降趋势,不同温度下NH_(3)泄漏量最大差值为328×10^(-6);NO_(x)转化率随排气流量升高呈现先增后减的趋势,在250℃时,不同排气流量下NO_(x)转化效率最大相差21.5百分点;NH_(3)泄漏量随排气流量的增大而增加,在250℃时,不同排气流量下NH_(3)泄漏量最大差值为90.8×10^(-6)。相同工况下,海拔越高,NO_(x)转化率越高,NH_(3)泄漏量越小,大气压力为80和100 k Pa下NO_(x)转化率最大相差20.1百分点,NH_(3)泄漏量最大相差54.6×10^(-6)。
文摘In this work,a kinetic study of the selective catalytic reduction of NO with NH3 has been carried out.After proving the operating condition that the effect of intraphase diffusion and interphase mass-transfer processes can be ignored,the selective catalytic reduction of NO with NH3 on the catalytic activity of V2O5-WO3/TiO2 has been carried out with fixing the feed gas flow rate and composition（NO,NH3,O2） while varying the catalyst loading.Based on the experimental results of NO removal efficiency,the empirical catalytic reaction rate equation of NO with NH3 has been obtained using differential analysis.The experimental result is further proved by the graphic integral method at the temperature from 320℃ to 400℃.The reaction order is 1 to NO and zero to NH3.The reaction follows the Eley-Rideal mechanism model.
