Superhydrophobic glass has inspiring development prospects in endoscopes,solar panels and other engineering and medical fields.However,the surface topography required to achieve superhydrophobicity will inevitably aff...Superhydrophobic glass has inspiring development prospects in endoscopes,solar panels and other engineering and medical fields.However,the surface topography required to achieve superhydrophobicity will inevitably affect the surface transparency and limit the application of glass materials.To resolve the contradiction between the surface transparency and the robust superhydrophobicity,an efficient and low-cost laser-chemical surface functionalization process was utilized to fabricate superhydrophobic glass surface.The results show that the air can be effectively trapped in surface micro/nanostructure induced by laser texturing,thus reducing the solid-liquid contact area and interfacial tension.The deposition of hydrophobic carbon-containing groups on the surface can be accelerated by chemical treatment,and the surface energy is significantly reduced.The glass surface exhibits marvelous robust superhydrophobicity with a contact angle of 155.8°and a roll-off angle of 7.2°under the combination of hierarchical micro/nanostructure and low surface energy.Moreover,the surface transparency of the prepared superhydrophobic glass was only 5.42%lower than that of the untreated surface.This superhydrophobic glass with high transparency still maintains excellent superhydrophobicity after durability and stability tests.The facile fabrication of superhydrophobic glass with high transparency and robustness provides a strong reference for further expanding the application value of glass materials.展开更多
基金Projects(52105175,52305149)supported by the National Natural Science Foundation of ChinaProject(2242024RCB0035)supported by the Zhishan Young Scholar Program of Southeast University,China+5 种基金Project(BK20210235)supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(2023MK042)supported by the State Administration for Market Regulation,ChinaProject(KJ2023003)supported by the Jiangsu Administration for Market Regulation,ChinaProjects(KJ(Y)202429,KJ(YJ)2023001)supported by the Jiangsu Province Special Equipment Safety Supervision Inspection Institute,ChinaProject(JSSCBS20210121)supported by the Jiangsu Provincial Innovative and Entrepreneurial Doctor Program,ChinaProject(1102002310)supported by the Technology Innovation Project for Returnees in Nanjing,China。
文摘Superhydrophobic glass has inspiring development prospects in endoscopes,solar panels and other engineering and medical fields.However,the surface topography required to achieve superhydrophobicity will inevitably affect the surface transparency and limit the application of glass materials.To resolve the contradiction between the surface transparency and the robust superhydrophobicity,an efficient and low-cost laser-chemical surface functionalization process was utilized to fabricate superhydrophobic glass surface.The results show that the air can be effectively trapped in surface micro/nanostructure induced by laser texturing,thus reducing the solid-liquid contact area and interfacial tension.The deposition of hydrophobic carbon-containing groups on the surface can be accelerated by chemical treatment,and the surface energy is significantly reduced.The glass surface exhibits marvelous robust superhydrophobicity with a contact angle of 155.8°and a roll-off angle of 7.2°under the combination of hierarchical micro/nanostructure and low surface energy.Moreover,the surface transparency of the prepared superhydrophobic glass was only 5.42%lower than that of the untreated surface.This superhydrophobic glass with high transparency still maintains excellent superhydrophobicity after durability and stability tests.The facile fabrication of superhydrophobic glass with high transparency and robustness provides a strong reference for further expanding the application value of glass materials.
