Building a lunar human base is one of the important goals of human lunar exploration.This paper proposes a method for the production of oxygen by combining photothermal synergistic water decomposition with high-temper...Building a lunar human base is one of the important goals of human lunar exploration.This paper proposes a method for the production of oxygen by combining photothermal synergistic water decomposition with high-temperature carbon dioxide electrolysis,utilizing the full solar spectrum.The optimal oxygen production rates under different solid oxide electrolysis cell inlet temperatures T_(e),ultraviolet(UV)separation wavelengths λ_(2),infrared(IR)separation wavelengths,and photovoltaic cell materials were explored.The results indicate that the inlet temperature of the solid oxide electrolysis cell should be as high as possible so that more carbon dioxide can be converted into carbon monoxide and oxygen.Furthermore,when the ultraviolet separation wavelength is approximately 385 nm,the proportion of solar energy allocated to the photoreaction and electrolysis cell is optimal,and the oxygen production rate is highest at 2.754×10^(-4) mol/s.Moreover,the infrared separation wavelength should be increased as much as possible within the allowable range to increase the amount of solar radiation allocated to the electrolysis cell to improve the rate of oxygen generation.In addition,copper indium gallium selenide(CIGS)has a relatively large separation wavelength,which can result in a high oxygen production rate of 3.560×10^(-4) mol/s.The proposed integrated oxygen production method can provide a feasible solution for supplying oxygen to a lunar human base.展开更多
The nitrate reduction reaction(NtRR)has been demonstrated to be a promising way for obtaining ammonia(NH_(3))by converting NO3-to NH3.Here we report the controlled synthesis of cobalt tetroxide/graphdiyne heterostruct...The nitrate reduction reaction(NtRR)has been demonstrated to be a promising way for obtaining ammonia(NH_(3))by converting NO3-to NH3.Here we report the controlled synthesis of cobalt tetroxide/graphdiyne heterostructured nanowires(Co_(3)O_(4)/GDY NWs)by a simple two-step process including the synthesis of Co_(3)O_(4)NWs and the following growth of GDY using hex-aethynylbenzene as the precursor at 110°C for 10 h.Detailed scanning electron microscopy,high resolution transmission electron microscopy,X-ray photoelectron spectroscopy,and Raman characterization confirmed the synthesis of a Co_(3)O_(4)/GDY heterointerface with the formation of sp-C-Co bonds at the interface and incomplete charge transfer between GDY and Co,which provide a con-tinuous supply of electrons for the catalytic reaction and ensure a rapid NtRR.Because of these advantages,Co_(3)O_(4)/GDY NWs had an excellent NtRR performance with a high NH3 yield rate(YNH3)of 0.78 mmol h^(-1)cm^(-2)and a Faraday efficiency(FE)of 92.45%at-1.05 V(vs.RHE).This work provides a general approach for synthesizing heterostructures that can drive high-performance ammo-nia production from wastewater under ambient conditions.展开更多
In order to promote agricultural production and trade cooperation among BRICS countries,and ensure the security and stability of the oils and oilseeds industrial and supply chains in China and the world,the production...In order to promote agricultural production and trade cooperation among BRICS countries,and ensure the security and stability of the oils and oilseeds industrial and supply chains in China and the world,the production,consumption,trade trend,and cooperation potential of oils and oilseeds in BRICS countries were expounded,and relevant policy recommendations were put forward.Most of the BRICS countries are major agricultural producers,and they are also important agricultural product consumption markets in the world.In 2023/2024,the production and consumption of oilseeds in BRICS countries account for nearly half of the world's total;the production of vegetable oils exceeds a quarter of the world's total,and the consumption of vegetable oils accounts for 40%of the world's total.In 2023/2024,the import and export volume of oilseeds exceeds half of the world's total;vegetable oil imports account for 40%of the world's total,and exports account for about one tenth of the world's total.China's imports of oilseeds and oils from BRICS countries account for 68%and 29%of its global imports in 2023,respectively.BRICS countries are rich in agricultural land resources,have great potential for oils and oilseeds production,obvious complementary advantages in trade structure,and huge space for future cooperation.It is suggested that Brazil should be included in the"Belt and Road"co-construction category to promote the continuous deepening of agricultural cooperation between China and Brazil.It is suggested to explore regional agricultural trade agreements among BRICS countries,promote currency settlement and exchange among BRICS countries,and enhance the facilitation and stability of BRICS trade.It is suggested that China should increase its investment in BRICS countries and export advanced technology and management experience to benefit local agricultural development and achieve a mutually beneficial and win-win situation.展开更多
In this study,Ni_(2)P/CdS composites were constructed by depositing non-precious metal co-catalyst Ni_(2)P on a one-dimensional network of CdS using a simple in-situ photodeposition method.The prepared photocatalysts ...In this study,Ni_(2)P/CdS composites were constructed by depositing non-precious metal co-catalyst Ni_(2)P on a one-dimensional network of CdS using a simple in-situ photodeposition method.The prepared photocatalysts promoted the decomposition of ethanol into high-value-added products while generating hydrogen.The composite photoanodes loaded with the Ni_(2)P co-catalysts showed significantly higher ethanol conversion and hydrogen production in the visible light region,which was almost three times higher than that of pure CdS.The main products of photocatalytic ethanol production are acetaldehyde(AA)and 2,3-butanediol(2,3-BDA).Compared with CdS,the selectivity of the composite photocatalysts for converting ethanol to acetaldehyde was significantly improved(62% to 78%).Characterization of the prepared photocatalysts confirmed that the loading of Ni_(2)P co-catalysts on CdS not only broadened the optical region of the catalysts for trapping light but also effectively promoted the separation and transfer of charge carriers,which significantly improved the photocatalytic efficiency of ethanol conversion and hydrogen production in the catalysts.It has been proven through Electron Paramagnetic Resonance testing that loading a Ni_(2)P co-catalyst on CdS is beneficial for the adsorption of hydroxyethyl radicals(*CH(OH)CH_(3)),thereby further improving the selectivity of acetaldehyde.This study plays an important role in the rational design of composite catalyst structures and the introduction of co-catalysts to improve catalyst performance,promote green chemistry,advocate a low-carbon society,and promote sustainable development.展开更多
Under the condition of the market competition becom in g more and more drastic, the demands of market take on some new features such as individuation, diversification, small batch, unstableness and quick delivery et c...Under the condition of the market competition becom in g more and more drastic, the demands of market take on some new features such as individuation, diversification, small batch, unstableness and quick delivery et c. The Make-to-Stock mode is usually adopted by many enterprises to improve th e balance and stableness of production process. In such enterprises, order batch , production batch and sales batch are the important factors, which affect the s atisfaction of clients, efficiency and benefit of the enterprise. It takes purch ase, production and sales into account respectively when optimizing product batc h in traditional way. However, it ignored the influences of relations between ea ch links of whole system. It is assumed that the consumption and market demand a re continuous process whereas the factual demands are batched when economic batc h is determined. So there exist some deviations between the economic batch deter mined by traditional way and that by integral optimization. Through the integral analysis of Logistics in the production system, we know that from materials are purchased, then manufactured, finally sold, the material changed in appearance and value, it still exist in different links of production system. The amount of materials occupied varies just in different status, from stock status to produc tion status, then to waiting-be-sold status, there is not any substantial chan ge in quantity until they are sold. So we must comprehensively analyze the relat ions among each link based on integral production system, to optimize the materi al batch and cut short production cycle in order to optimize the whole system. In this paper, the production system is taken as a global entity, and in which m aterials variation law and their relations of each link are analyzed; To optimiz e the whole materials flow, a new model of multi-product systems’ economic orde r batch, economic production batch and optimal sale lot multi-product syste ms’ is developed which based on the limit of capitals and stock area.展开更多
A mathematical model to determine the optimal production lot size for a deteriorating production system under an extended product inspection policy is developed. The last-K product inspection policy is considered so t...A mathematical model to determine the optimal production lot size for a deteriorating production system under an extended product inspection policy is developed. The last-K product inspection policy is considered so that the nonconforming items can be reduced, under which the last K products in a production lot are inspected and the nonconforming items from those inspected are reworked. Consider that the products produced towards the end of a production lot are more likely to be nonconforming, is proposed an extended product inspection policy for a deteriorating production system. That is, in a production lot, product inspections are performed among the middle K1 items and after inspections, all of the last K2 products are directly reworked without inspections. Our objective here is the joint optimization of the production lot size and the corresponding extended inspection policy such that the expected total cost per unit time is minimized. Since there is no closed form expression for our optimal policy, the existence for the optimal production inspection policy and an upper bound for the optimal lot size are obtained. Furthermore, an efficient solution procedure is provided to search for the optimal policy. Finally, numerical examples are given to illustrate the proposed model and indicate that the expected total cost per unit time of our product inspection model is less than that of the last-K inspection policy.展开更多
Developing production and operation in scales in the major grain producing areas is the direction of the paper. Seizing the opportunity of modem agriculture comprehensive reform in two plains （Songnen Plain and Sanji...Developing production and operation in scales in the major grain producing areas is the direction of the paper. Seizing the opportunity of modem agriculture comprehensive reform in two plains （Songnen Plain and Sanjiang Plain） of Heilongjiang Province and supporting to build a new type of production and management based on the big grain production householding, which plays demonstration and leading roles, have an important strategic position in improving agricultural comprehensive production capacity and ensuring national food security. In this paper, based on the survey data about the big grain production households production operations and analyses of the obstacles in expansion of production in Heilongjiang Province, specific suggestions in supporting the development of the big grain production household were put forward, such as, increasing agricultural production socialized level; perfecting the service system of land transferring; improving financial policies and farmer-friendly policy measures and perfecting the agriculture socialized service system.展开更多
To improve antagonistic metabolites production of Bacillus subtilis strain BS501a, physical parameters of fermentation and metal inorganic salts in medium, namely initial pH value, culture temperature, fermentation ti...To improve antagonistic metabolites production of Bacillus subtilis strain BS501a, physical parameters of fermentation and metal inorganic salts in medium, namely initial pH value, culture temperature, fermentation time, concentrations of CaC12, FeSO4, ZnSO4, MnSO4 and MgSO4, were optimized using one-factor-at-a-time and orthogonal tests. The results show that the optimal physical parameters of fermentation are an initial pH of 7.0, a culture temperature of 30 ~C, and a fermentation time of 48 h. The optimal concentrations of metal inorganic salts in basal medium are 10.2 mmol/L CaCl2, 0.4 mmol/L FeSO4, 3.5 mmol/L ZnSO4, 0.6 mmol/L MnSO4 and 2.0 mmol/L MgSO4. Among the metal inorganic salts, MgSO4 and MnSO4 play important roles in the improvement of the antagonistic metabolites production of B. subtilis strain BS501a; especially, MgSO4 contributes a highly significant effect. The average diameter of inhibition zone of the BS501a filtered fermentation supernatant （FFS） cultured in the optimal fermentation conditions against Magnaporthe grisea DWBJ329 reaches 71.4 mm, and there is 2.4-fold increase in antifungal activity as compared with 21.2 mm under the pre-optimized conditions.展开更多
Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the e...Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the earth. And it will be the most important energy for the 21st century. The energy balance and numerical simulation are applied to study the schemes of the natural gas hydrates production in this paper,and it is considered that both depressurization and thermal stimulation are effective methods for exploiting natural gas hydrates, and that the gas production of the thermal stimulation is higher than that of the depressurization. But thermal stimulation is non-economic because it requires large amounts of energy.Therefore the combination of the two methods is a preferable method for the current development of the natural gas hydrates. The main factors which influence the production of natural gas hydrates are: the temperature of injected water, the injection rate, the initial saturation of the hydrates and the initial temperature of the reservoir which is the most important factor.展开更多
In order to increase productivity and reduce energy consumption of steelmaking-continuous casting(SCC) production process, especially with complicated technological routes, the cross entropy(CE) method was adopted to ...In order to increase productivity and reduce energy consumption of steelmaking-continuous casting(SCC) production process, especially with complicated technological routes, the cross entropy(CE) method was adopted to optimize the SCC production scheduling(SCCPS) problem. Based on the CE method, a matrix encoding scheme was proposed and a backward decoding method was used to generate a reasonable schedule. To describe the distribution of the solution space, a probability distribution model was built and used to generate individuals. In addition, the probability updating mechanism of the probability distribution model was proposed which helps to find the optimal individual gradually. Because of the poor stability and premature convergence of the standard cross entropy(SCE) algorithm, the improved cross entropy(ICE) algorithm was proposed with the following improvements: individual generation mechanism combined with heuristic rules, retention mechanism of the optimal individual, local search mechanism and dynamic parameters of the algorithm. Simulation experiments validate that the CE method is effective in solving the SCCPS problem with complicated technological routes and the ICE algorithm proposed has superior performance to the SCE algorithm and the genetic algorithm(GA).展开更多
Phosphorus is an essential element in agricultural production and chemical industry. However, since the risk of casualties and economic loss by mining accidents, the application of clean and safe production in phospho...Phosphorus is an essential element in agricultural production and chemical industry. However, since the risk of casualties and economic loss by mining accidents, the application of clean and safe production in phosphorus mines encounters great challenges. For this purpose, a man-machine-environment system composed of evaluation indexes was established, and the grading standards of indexes were defined. Firstly, the measurements of 39 qualitative indexes were obtained through the survey data. According to the measured values of 31 quantitative indexes, the measurements of quantitative indexes were calculated by linear measurement function(LM) and other three functions. Then the singleindex measurement evaluation matrixes were established. Secondly, the entropy weight method was used to determine the weights of each index directly. The analytic hierarchy process(AHP) was also applied to calculate the weights of index and index factor hierarchies after the established hierarchical model. The weights of system hierarchies were given by the grid-based fuzzy Borda method(GFB). The comprehensive weights were determined by the combination method of AHP and GFB(CAG). Furthermore, the multi-index comprehensive measurement evaluation vectors were obtained.Thirdly, the vectors were evaluated by the credible degree recognition(CDR) and the maximum membership(TMM)criteria. Based on the above functions, methods, and criteria, 16 combination evaluation methods were recommended.Finally, the clean and safe production grade of Kaiyang phosphate mine in China was evaluated. The results show that the LM-CAG-CDR is the most reasonable method, which can not only determine the clean and safe production grade of phosphorus mines, but also improve the development level of clean and safe mining of phosphorus mines for guidance.In addition, some beneficial suggestions and measures were also proposed to advance the clean and safe production grade of Kaiyang phosphorus mine.展开更多
Several methods of deep desulfurization in alumina production process were studied, and the costs of these methods were compared. It is found that most of the S2- in sodium aluminate solution can be removed by adding ...Several methods of deep desulfurization in alumina production process were studied, and the costs of these methods were compared. It is found that most of the S2- in sodium aluminate solution can be removed by adding sodium nitrate or hydrogen peroxide in digestion process, and in this way the effect of S2- on alumina product quality is eliminated. However, the removal efficiency of 2?32OS in sodium aluminate solution is very low by this method. Both S2- and 2?32OS in sodium aluminate solution can be removed completely by wet oxidation method in digestion process. The cost of desulfurization by wet oxidation is lower than by adding sodium nitrate or hydrogen peroxide. The results of this research reveal that wet oxidation is an economical and feasible method for the removal of sulfur in alumina production process to improve alumina quality, and provide valuable guidelines for alumina production by high-sulfur bauxite.展开更多
Production decline analysis has been considered as an important method to obtain the flow parameters, reservoir properties and original gas in place. Although advanced Blasingame production decline analysis methods fo...Production decline analysis has been considered as an important method to obtain the flow parameters, reservoir properties and original gas in place. Although advanced Blasingame production decline analysis methods for vertical wells, fractured wells and horizontal wells are widely used, limited study has conducted on Blasingame production decline type curves for multi-fractured horizontal well(MFHW). Based on the perpendicular bisection(PEBI) grids, a numerical model was developed and the solution was obtained using control volume finite element method and the fully implicit method. Blasingame production decline-type curves of the infinitely conductive MFHW were plotted through computer programming. A field case was presented to analyse and verify the model developed. Five flow regimes, including early formation linear flow, early radial flow, compound linear flow, transient flow and pseudo-radial flow, are recognized. Fracture spacing is the main factor that affects early radial flow, compound linear flow and transient flow, the distance from the well to the circular boundary affects the pseudo-radial flow, and the type curves are also significantly affected by the formation permeability, fracture number and fracture half-length. The validation of field case suggests that the Blasingame production decline type curves proposed in this work can be applied to the production decline analysis for MFHW in tight gas reservoirs.展开更多
In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dump...In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dumped with perished orange in Changde City, Hunan Province of China. The strain CD-01 had the same morphology and 28S rRNA gene sequence （FJ184995） as that of Aspergillus niger （ATCC 64028）. It was thus identified and named as Aspergillus niger CD-01. The fermentation condition was optimized based on L9（34） orthogonal experimental design and the variances analyses. The results show that the optimal condition for producing pectin is as follows： time 36 h, temperature 35 ℃, pH 5, and urea as the nitrogen source. Under this condition, the pectin yield can reach up to 24.5%. This shows a great potential of Aspergillus niger CD-01 in pectin extraction from citrus.展开更多
In order to ensure overall optimization of the underground metal mine production scale, multidisciplinary design optimization model of production scale which covers the subsystem objective function of income of produc...In order to ensure overall optimization of the underground metal mine production scale, multidisciplinary design optimization model of production scale which covers the subsystem objective function of income of production, safety and environmental impact in the underground metal mine was established by using multidisciplinary design optimization method. The coupling effects from various disciplines were fully considered, and adaptive mutative scale chaos immunization optimization algorithm was adopted to solve multidisciplinary design optimization model of underground metal mine production scale. Practical results show that multidisciplinary design optimization on production scale of an underground lead and zinc mine reflect the actual operating conditions more realistically, the production scale is about 1.25 Mt/a (Lead and zinc metal content of 160 000 t/a), the economic life is approximately 14 a, corresponding coefficient of production profits can be increased to 15.13%, safety factor can be increased to 5.4% and environmental impact coefficient can be reduced by 9.52%.展开更多
According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which co...According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which consists of safety diagnosis fuzzifier, defuzzifier, fuzzy rules base and inference engine. Through the safety diagnosis on coal mine roadway rail transportation system, the result shows that the unsafe probability is about 0.5 influenced by no speed reduction and over quick turnout on roadway, which is the most possible reason leading to the accident of roadway rail transportation system.展开更多
Heilongjiang Province is an important marketable grain depot in China. Since the reform and opening up, Heilongjiang Province production capacity of foodstuff is increasingly growing into a new level. This paper start...Heilongjiang Province is an important marketable grain depot in China. Since the reform and opening up, Heilongjiang Province production capacity of foodstuff is increasingly growing into a new level. This paper started with the actuality of Heilongjiang Province integrated production capacity of foodstuff, and analyzed its major factors empirically through the mathematical model, then proposed some measures to enhance Heilongjiang Province production capacity of foodstuff which ensured China foodstuff security展开更多
Molasses wastewater was evaluated as substrate for biohydrogen production by anaerobic fermentation in a novel continuous mixed attached growth reactor ( CMAGR ) with aeration pretreated sludge attached onto granular ...Molasses wastewater was evaluated as substrate for biohydrogen production by anaerobic fermentation in a novel continuous mixed attached growth reactor ( CMAGR ) with aeration pretreated sludge attached onto granular activated carbon under continuous flow condition.It was indicated that the CMAGR system was operated at the conditions of influent COD of 2000～6000mg / L , hydraulic retention time ( HRT ) of 6hand temperature of 35 ℃ , when the pH value and oxidation-reduction potential ( ORP ) ranged from 4.16and-434 mV respectively , stable ethanol-type fermentation was formed with the sum of ethanol and acetate concentration ratio of 89.3%to the total liquid products after 40days operation.The H 2 content in biogas and chemical oxygen demand ( COD ) removal were estimated to be 46.6% and 13% , respectively.It was also investigated that the effects of organic loading rates ( OLRs ) on CMAGR hydrogen production system.It was found that hydrogen production yield increased from 3.72 mmol / hL to 12.51 mmol / hL as OLRs increased from 8 kg / m 3 d to 32 kg / m 3 d.The maximum hydrogen production rate of 12.51mmol / hL at a OLR of 32kg / m 3 d and the maximum hydrogen yield by substrate consumed was 130.57 mmol / mol happened at OLR of 16 kg / m 3 d.Greater pHs appeared to be favour to butyrate production and the maximum of 0.51mol / mol was obtained at pH of 4.14.However , ethanol / acetate ratio was greater than 1.1at pH fluctuated between 3.4 - 3.6and 4.1 - 4.4which indicated that these pHs were favour to ethanol type fermentation.Therefore , the continuous mixed attached growth reactor ( CMAGR ) could be a promising attached growth system for biohydrogen fermentation.展开更多
DEA is a nonparametric method used in operation researches and economics fields for the evaluation of the production frontier. It has distinct intrinsic which is worth coping with assessment problems with multiple inp...DEA is a nonparametric method used in operation researches and economics fields for the evaluation of the production frontier. It has distinct intrinsic which is worth coping with assessment problems with multiple inputs in particular with multiple outputs. This paper used D~ C2 R model of DEA to assess the comparative efficiency of the multiple schemes of agricultural industrial structure, at the end we chose the most favorable also known as ＂OPTIMAL＂ scheme. In addition to this, using some functional insights from DEA model non optimal schemes or less optimal schemes had also been improved to some extent. Assessment and selection of optimal schemes of agricultural industrial structure using DEA model gave a greater and better insight of agricultural industrial structure and was the first of such researches in Pakistan.展开更多
Value analysis of grain production influencing factors is a complex decision problem. This paper introduced a modified Analytic Hierarchy Process （AHP） accumulation factor, namely Solving Weight by AHP＇s Accumulati...Value analysis of grain production influencing factors is a complex decision problem. This paper introduced a modified Analytic Hierarchy Process （AHP） accumulation factor, namely Solving Weight by AHP＇s Accumulation Factor Sequence Evaluating Data. We used the arithmetical average to replace the expert marking, so that the possible decision mistakes by the subjective judgments could be avoided. We computed the case with this method, which obtained attribute value of 17 influencing factors of the potential food production in Heilongjiang Province, and the result of which was reasonable展开更多
基金supported by the National Natural Science Foundation of China(52106276 and 52130601).
文摘Building a lunar human base is one of the important goals of human lunar exploration.This paper proposes a method for the production of oxygen by combining photothermal synergistic water decomposition with high-temperature carbon dioxide electrolysis,utilizing the full solar spectrum.The optimal oxygen production rates under different solid oxide electrolysis cell inlet temperatures T_(e),ultraviolet(UV)separation wavelengths λ_(2),infrared(IR)separation wavelengths,and photovoltaic cell materials were explored.The results indicate that the inlet temperature of the solid oxide electrolysis cell should be as high as possible so that more carbon dioxide can be converted into carbon monoxide and oxygen.Furthermore,when the ultraviolet separation wavelength is approximately 385 nm,the proportion of solar energy allocated to the photoreaction and electrolysis cell is optimal,and the oxygen production rate is highest at 2.754×10^(-4) mol/s.Moreover,the infrared separation wavelength should be increased as much as possible within the allowable range to increase the amount of solar radiation allocated to the electrolysis cell to improve the rate of oxygen generation.In addition,copper indium gallium selenide(CIGS)has a relatively large separation wavelength,which can result in a high oxygen production rate of 3.560×10^(-4) mol/s.The proposed integrated oxygen production method can provide a feasible solution for supplying oxygen to a lunar human base.
文摘The nitrate reduction reaction(NtRR)has been demonstrated to be a promising way for obtaining ammonia(NH_(3))by converting NO3-to NH3.Here we report the controlled synthesis of cobalt tetroxide/graphdiyne heterostructured nanowires(Co_(3)O_(4)/GDY NWs)by a simple two-step process including the synthesis of Co_(3)O_(4)NWs and the following growth of GDY using hex-aethynylbenzene as the precursor at 110°C for 10 h.Detailed scanning electron microscopy,high resolution transmission electron microscopy,X-ray photoelectron spectroscopy,and Raman characterization confirmed the synthesis of a Co_(3)O_(4)/GDY heterointerface with the formation of sp-C-Co bonds at the interface and incomplete charge transfer between GDY and Co,which provide a con-tinuous supply of electrons for the catalytic reaction and ensure a rapid NtRR.Because of these advantages,Co_(3)O_(4)/GDY NWs had an excellent NtRR performance with a high NH3 yield rate(YNH3)of 0.78 mmol h^(-1)cm^(-2)and a Faraday efficiency(FE)of 92.45%at-1.05 V(vs.RHE).This work provides a general approach for synthesizing heterostructures that can drive high-performance ammo-nia production from wastewater under ambient conditions.
文摘In order to promote agricultural production and trade cooperation among BRICS countries,and ensure the security and stability of the oils and oilseeds industrial and supply chains in China and the world,the production,consumption,trade trend,and cooperation potential of oils and oilseeds in BRICS countries were expounded,and relevant policy recommendations were put forward.Most of the BRICS countries are major agricultural producers,and they are also important agricultural product consumption markets in the world.In 2023/2024,the production and consumption of oilseeds in BRICS countries account for nearly half of the world's total;the production of vegetable oils exceeds a quarter of the world's total,and the consumption of vegetable oils accounts for 40%of the world's total.In 2023/2024,the import and export volume of oilseeds exceeds half of the world's total;vegetable oil imports account for 40%of the world's total,and exports account for about one tenth of the world's total.China's imports of oilseeds and oils from BRICS countries account for 68%and 29%of its global imports in 2023,respectively.BRICS countries are rich in agricultural land resources,have great potential for oils and oilseeds production,obvious complementary advantages in trade structure,and huge space for future cooperation.It is suggested that Brazil should be included in the"Belt and Road"co-construction category to promote the continuous deepening of agricultural cooperation between China and Brazil.It is suggested to explore regional agricultural trade agreements among BRICS countries,promote currency settlement and exchange among BRICS countries,and enhance the facilitation and stability of BRICS trade.It is suggested that China should increase its investment in BRICS countries and export advanced technology and management experience to benefit local agricultural development and achieve a mutually beneficial and win-win situation.
基金supported by the National Natural Science Foundation of China(22075197,22278290)the Shanxi Provincial Natural Science Foundation of China(202103021224079,201903D421081)the Research and Development Project of Key Core and Common Technology of Shanxi Province(20201102018)。
文摘In this study,Ni_(2)P/CdS composites were constructed by depositing non-precious metal co-catalyst Ni_(2)P on a one-dimensional network of CdS using a simple in-situ photodeposition method.The prepared photocatalysts promoted the decomposition of ethanol into high-value-added products while generating hydrogen.The composite photoanodes loaded with the Ni_(2)P co-catalysts showed significantly higher ethanol conversion and hydrogen production in the visible light region,which was almost three times higher than that of pure CdS.The main products of photocatalytic ethanol production are acetaldehyde(AA)and 2,3-butanediol(2,3-BDA).Compared with CdS,the selectivity of the composite photocatalysts for converting ethanol to acetaldehyde was significantly improved(62% to 78%).Characterization of the prepared photocatalysts confirmed that the loading of Ni_(2)P co-catalysts on CdS not only broadened the optical region of the catalysts for trapping light but also effectively promoted the separation and transfer of charge carriers,which significantly improved the photocatalytic efficiency of ethanol conversion and hydrogen production in the catalysts.It has been proven through Electron Paramagnetic Resonance testing that loading a Ni_(2)P co-catalyst on CdS is beneficial for the adsorption of hydroxyethyl radicals(*CH(OH)CH_(3)),thereby further improving the selectivity of acetaldehyde.This study plays an important role in the rational design of composite catalyst structures and the introduction of co-catalysts to improve catalyst performance,promote green chemistry,advocate a low-carbon society,and promote sustainable development.
文摘Under the condition of the market competition becom in g more and more drastic, the demands of market take on some new features such as individuation, diversification, small batch, unstableness and quick delivery et c. The Make-to-Stock mode is usually adopted by many enterprises to improve th e balance and stableness of production process. In such enterprises, order batch , production batch and sales batch are the important factors, which affect the s atisfaction of clients, efficiency and benefit of the enterprise. It takes purch ase, production and sales into account respectively when optimizing product batc h in traditional way. However, it ignored the influences of relations between ea ch links of whole system. It is assumed that the consumption and market demand a re continuous process whereas the factual demands are batched when economic batc h is determined. So there exist some deviations between the economic batch deter mined by traditional way and that by integral optimization. Through the integral analysis of Logistics in the production system, we know that from materials are purchased, then manufactured, finally sold, the material changed in appearance and value, it still exist in different links of production system. The amount of materials occupied varies just in different status, from stock status to produc tion status, then to waiting-be-sold status, there is not any substantial chan ge in quantity until they are sold. So we must comprehensively analyze the relat ions among each link based on integral production system, to optimize the materi al batch and cut short production cycle in order to optimize the whole system. In this paper, the production system is taken as a global entity, and in which m aterials variation law and their relations of each link are analyzed; To optimiz e the whole materials flow, a new model of multi-product systems’ economic orde r batch, economic production batch and optimal sale lot multi-product syste ms’ is developed which based on the limit of capitals and stock area.
基金supported by the National Natural Science Foundation of China(60874034).
文摘A mathematical model to determine the optimal production lot size for a deteriorating production system under an extended product inspection policy is developed. The last-K product inspection policy is considered so that the nonconforming items can be reduced, under which the last K products in a production lot are inspected and the nonconforming items from those inspected are reworked. Consider that the products produced towards the end of a production lot are more likely to be nonconforming, is proposed an extended product inspection policy for a deteriorating production system. That is, in a production lot, product inspections are performed among the middle K1 items and after inspections, all of the last K2 products are directly reworked without inspections. Our objective here is the joint optimization of the production lot size and the corresponding extended inspection policy such that the expected total cost per unit time is minimized. Since there is no closed form expression for our optimal policy, the existence for the optimal production inspection policy and an upper bound for the optimal lot size are obtained. Furthermore, an efficient solution procedure is provided to search for the optimal policy. Finally, numerical examples are given to illustrate the proposed model and indicate that the expected total cost per unit time of our product inspection model is less than that of the last-K inspection policy.
基金Supported by the Stage Achievement of Social Science Fund Project of Heilongjiang Province and the Application of Technology Research(12C053)the Development Project in Heilongjiang Province(2013R0242)
文摘Developing production and operation in scales in the major grain producing areas is the direction of the paper. Seizing the opportunity of modem agriculture comprehensive reform in two plains （Songnen Plain and Sanjiang Plain） of Heilongjiang Province and supporting to build a new type of production and management based on the big grain production householding, which plays demonstration and leading roles, have an important strategic position in improving agricultural comprehensive production capacity and ensuring national food security. In this paper, based on the survey data about the big grain production households production operations and analyses of the obstacles in expansion of production in Heilongjiang Province, specific suggestions in supporting the development of the big grain production household were put forward, such as, increasing agricultural production socialized level; perfecting the service system of land transferring; improving financial policies and farmer-friendly policy measures and perfecting the agriculture socialized service system.
基金Project(2010A210003) supported by Henan Province Natural Sciences Research PlanProject(0910SGYS34370-2) supported by Zhengzhou City Science and Technology Research PlanProject supported by the Youth Backbone Teacher of Universities in Henan Province Grants Plan
文摘To improve antagonistic metabolites production of Bacillus subtilis strain BS501a, physical parameters of fermentation and metal inorganic salts in medium, namely initial pH value, culture temperature, fermentation time, concentrations of CaC12, FeSO4, ZnSO4, MnSO4 and MgSO4, were optimized using one-factor-at-a-time and orthogonal tests. The results show that the optimal physical parameters of fermentation are an initial pH of 7.0, a culture temperature of 30 ~C, and a fermentation time of 48 h. The optimal concentrations of metal inorganic salts in basal medium are 10.2 mmol/L CaCl2, 0.4 mmol/L FeSO4, 3.5 mmol/L ZnSO4, 0.6 mmol/L MnSO4 and 2.0 mmol/L MgSO4. Among the metal inorganic salts, MgSO4 and MnSO4 play important roles in the improvement of the antagonistic metabolites production of B. subtilis strain BS501a; especially, MgSO4 contributes a highly significant effect. The average diameter of inhibition zone of the BS501a filtered fermentation supernatant （FFS） cultured in the optimal fermentation conditions against Magnaporthe grisea DWBJ329 reaches 71.4 mm, and there is 2.4-fold increase in antifungal activity as compared with 21.2 mm under the pre-optimized conditions.
文摘Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the earth. And it will be the most important energy for the 21st century. The energy balance and numerical simulation are applied to study the schemes of the natural gas hydrates production in this paper,and it is considered that both depressurization and thermal stimulation are effective methods for exploiting natural gas hydrates, and that the gas production of the thermal stimulation is higher than that of the depressurization. But thermal stimulation is non-economic because it requires large amounts of energy.Therefore the combination of the two methods is a preferable method for the current development of the natural gas hydrates. The main factors which influence the production of natural gas hydrates are: the temperature of injected water, the injection rate, the initial saturation of the hydrates and the initial temperature of the reservoir which is the most important factor.
基金Project(ZR2014FM036)supported by Shandong Provincial Natural Science Foundation of ChinaProject(ZR2010FZ001)supported by the Key Program of Shandong Provincial Natural Science Foundation of China
文摘In order to increase productivity and reduce energy consumption of steelmaking-continuous casting(SCC) production process, especially with complicated technological routes, the cross entropy(CE) method was adopted to optimize the SCC production scheduling(SCCPS) problem. Based on the CE method, a matrix encoding scheme was proposed and a backward decoding method was used to generate a reasonable schedule. To describe the distribution of the solution space, a probability distribution model was built and used to generate individuals. In addition, the probability updating mechanism of the probability distribution model was proposed which helps to find the optimal individual gradually. Because of the poor stability and premature convergence of the standard cross entropy(SCE) algorithm, the improved cross entropy(ICE) algorithm was proposed with the following improvements: individual generation mechanism combined with heuristic rules, retention mechanism of the optimal individual, local search mechanism and dynamic parameters of the algorithm. Simulation experiments validate that the CE method is effective in solving the SCCPS problem with complicated technological routes and the ICE algorithm proposed has superior performance to the SCE algorithm and the genetic algorithm(GA).
基金Project(51974362) supported by the National Natural Science Foundation of ChinaProject(2282020cxqd055) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2021-QYC-10050-25631) supported by the Department of Emergency Management of Hunan Province,China。
文摘Phosphorus is an essential element in agricultural production and chemical industry. However, since the risk of casualties and economic loss by mining accidents, the application of clean and safe production in phosphorus mines encounters great challenges. For this purpose, a man-machine-environment system composed of evaluation indexes was established, and the grading standards of indexes were defined. Firstly, the measurements of 39 qualitative indexes were obtained through the survey data. According to the measured values of 31 quantitative indexes, the measurements of quantitative indexes were calculated by linear measurement function(LM) and other three functions. Then the singleindex measurement evaluation matrixes were established. Secondly, the entropy weight method was used to determine the weights of each index directly. The analytic hierarchy process(AHP) was also applied to calculate the weights of index and index factor hierarchies after the established hierarchical model. The weights of system hierarchies were given by the grid-based fuzzy Borda method(GFB). The comprehensive weights were determined by the combination method of AHP and GFB(CAG). Furthermore, the multi-index comprehensive measurement evaluation vectors were obtained.Thirdly, the vectors were evaluated by the credible degree recognition(CDR) and the maximum membership(TMM)criteria. Based on the above functions, methods, and criteria, 16 combination evaluation methods were recommended.Finally, the clean and safe production grade of Kaiyang phosphate mine in China was evaluated. The results show that the LM-CAG-CDR is the most reasonable method, which can not only determine the clean and safe production grade of phosphorus mines, but also improve the development level of clean and safe mining of phosphorus mines for guidance.In addition, some beneficial suggestions and measures were also proposed to advance the clean and safe production grade of Kaiyang phosphorus mine.
基金Project(51404121)supported by the National Natural Science Foundation of ChinaProject(KKSY201452041)supported by Yunnan Provincal Personnel Training Funds for Kunming University of Science and Technology,China
文摘Several methods of deep desulfurization in alumina production process were studied, and the costs of these methods were compared. It is found that most of the S2- in sodium aluminate solution can be removed by adding sodium nitrate or hydrogen peroxide in digestion process, and in this way the effect of S2- on alumina product quality is eliminated. However, the removal efficiency of 2?32OS in sodium aluminate solution is very low by this method. Both S2- and 2?32OS in sodium aluminate solution can be removed completely by wet oxidation method in digestion process. The cost of desulfurization by wet oxidation is lower than by adding sodium nitrate or hydrogen peroxide. The results of this research reveal that wet oxidation is an economical and feasible method for the removal of sulfur in alumina production process to improve alumina quality, and provide valuable guidelines for alumina production by high-sulfur bauxite.
基金Project(2013CB228005)supported by the National Basic Research Program of China
文摘Production decline analysis has been considered as an important method to obtain the flow parameters, reservoir properties and original gas in place. Although advanced Blasingame production decline analysis methods for vertical wells, fractured wells and horizontal wells are widely used, limited study has conducted on Blasingame production decline type curves for multi-fractured horizontal well(MFHW). Based on the perpendicular bisection(PEBI) grids, a numerical model was developed and the solution was obtained using control volume finite element method and the fully implicit method. Blasingame production decline-type curves of the infinitely conductive MFHW were plotted through computer programming. A field case was presented to analyse and verify the model developed. Five flow regimes, including early formation linear flow, early radial flow, compound linear flow, transient flow and pseudo-radial flow, are recognized. Fracture spacing is the main factor that affects early radial flow, compound linear flow and transient flow, the distance from the well to the circular boundary affects the pseudo-radial flow, and the type curves are also significantly affected by the formation permeability, fracture number and fracture half-length. The validation of field case suggests that the Blasingame production decline type curves proposed in this work can be applied to the production decline analysis for MFHW in tight gas reservoirs.
基金Projects(50621063, 50674101) supported by the National Natural Science Foundation of China
文摘In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dumped with perished orange in Changde City, Hunan Province of China. The strain CD-01 had the same morphology and 28S rRNA gene sequence （FJ184995） as that of Aspergillus niger （ATCC 64028）. It was thus identified and named as Aspergillus niger CD-01. The fermentation condition was optimized based on L9（34） orthogonal experimental design and the variances analyses. The results show that the optimal condition for producing pectin is as follows： time 36 h, temperature 35 ℃, pH 5, and urea as the nitrogen source. Under this condition, the pectin yield can reach up to 24.5%. This shows a great potential of Aspergillus niger CD-01 in pectin extraction from citrus.
基金Project(2012BAK09B02-05) supported by the National "Twelfth Five-year" Science & Technology Support Plan of China
文摘In order to ensure overall optimization of the underground metal mine production scale, multidisciplinary design optimization model of production scale which covers the subsystem objective function of income of production, safety and environmental impact in the underground metal mine was established by using multidisciplinary design optimization method. The coupling effects from various disciplines were fully considered, and adaptive mutative scale chaos immunization optimization algorithm was adopted to solve multidisciplinary design optimization model of underground metal mine production scale. Practical results show that multidisciplinary design optimization on production scale of an underground lead and zinc mine reflect the actual operating conditions more realistically, the production scale is about 1.25 Mt/a (Lead and zinc metal content of 160 000 t/a), the economic life is approximately 14 a, corresponding coefficient of production profits can be increased to 15.13%, safety factor can be increased to 5.4% and environmental impact coefficient can be reduced by 9.52%.
基金Project(2006BAK04B0302)supported by the National Science and Technology Pillar Program during the 11th Five-year Plan of China
文摘According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which consists of safety diagnosis fuzzifier, defuzzifier, fuzzy rules base and inference engine. Through the safety diagnosis on coal mine roadway rail transportation system, the result shows that the unsafe probability is about 0.5 influenced by no speed reduction and over quick turnout on roadway, which is the most possible reason leading to the accident of roadway rail transportation system.
基金Supported by the Achievement of Program for New Century Excellent Talents in Heilongjiang Province (1153-NCET-004)Project of Postdoctoral Scientific Research Launch Foundation in Heilongjiang Province
文摘Heilongjiang Province is an important marketable grain depot in China. Since the reform and opening up, Heilongjiang Province production capacity of foodstuff is increasingly growing into a new level. This paper started with the actuality of Heilongjiang Province integrated production capacity of foodstuff, and analyzed its major factors empirically through the mathematical model, then proposed some measures to enhance Heilongjiang Province production capacity of foodstuff which ensured China foodstuff security
基金support from the National Hi-Tech R&D Program(863 Program)Ministry of Science & Technology,China(2006AA05Z109)+2 种基金Shanghai Science and Technology Bureau(071605122)Shanghai Education Committee(07ZZ156)GRAP09,Northeast Forestry University are gratefully acknowledged
文摘Molasses wastewater was evaluated as substrate for biohydrogen production by anaerobic fermentation in a novel continuous mixed attached growth reactor ( CMAGR ) with aeration pretreated sludge attached onto granular activated carbon under continuous flow condition.It was indicated that the CMAGR system was operated at the conditions of influent COD of 2000～6000mg / L , hydraulic retention time ( HRT ) of 6hand temperature of 35 ℃ , when the pH value and oxidation-reduction potential ( ORP ) ranged from 4.16and-434 mV respectively , stable ethanol-type fermentation was formed with the sum of ethanol and acetate concentration ratio of 89.3%to the total liquid products after 40days operation.The H 2 content in biogas and chemical oxygen demand ( COD ) removal were estimated to be 46.6% and 13% , respectively.It was also investigated that the effects of organic loading rates ( OLRs ) on CMAGR hydrogen production system.It was found that hydrogen production yield increased from 3.72 mmol / hL to 12.51 mmol / hL as OLRs increased from 8 kg / m 3 d to 32 kg / m 3 d.The maximum hydrogen production rate of 12.51mmol / hL at a OLR of 32kg / m 3 d and the maximum hydrogen yield by substrate consumed was 130.57 mmol / mol happened at OLR of 16 kg / m 3 d.Greater pHs appeared to be favour to butyrate production and the maximum of 0.51mol / mol was obtained at pH of 4.14.However , ethanol / acetate ratio was greater than 1.1at pH fluctuated between 3.4 - 3.6and 4.1 - 4.4which indicated that these pHs were favour to ethanol type fermentation.Therefore , the continuous mixed attached growth reactor ( CMAGR ) could be a promising attached growth system for biohydrogen fermentation.
文摘DEA is a nonparametric method used in operation researches and economics fields for the evaluation of the production frontier. It has distinct intrinsic which is worth coping with assessment problems with multiple inputs in particular with multiple outputs. This paper used D~ C2 R model of DEA to assess the comparative efficiency of the multiple schemes of agricultural industrial structure, at the end we chose the most favorable also known as ＂OPTIMAL＂ scheme. In addition to this, using some functional insights from DEA model non optimal schemes or less optimal schemes had also been improved to some extent. Assessment and selection of optimal schemes of agricultural industrial structure using DEA model gave a greater and better insight of agricultural industrial structure and was the first of such researches in Pakistan.
文摘Value analysis of grain production influencing factors is a complex decision problem. This paper introduced a modified Analytic Hierarchy Process （AHP） accumulation factor, namely Solving Weight by AHP＇s Accumulation Factor Sequence Evaluating Data. We used the arithmetical average to replace the expert marking, so that the possible decision mistakes by the subjective judgments could be avoided. We computed the case with this method, which obtained attribute value of 17 influencing factors of the potential food production in Heilongjiang Province, and the result of which was reasonable
