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Characterization of combined blast-and fragments-induced synergetic damage in polyurea coated liquid-filled container
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作者 Chen Tao Chong Ji +3 位作者 Xin Wang Juan Gu Yuting Wang Changxiao Zhao 《Defence Technology(防务技术)》 2025年第1期201-224,共24页
Liquid-filled containers(LFC)are widely used to store and transport petroleum,chemical reagents,and other resources.As an important target of military strikes and terrorist bombings,LFC are vulnerable to blast waves a... Liquid-filled containers(LFC)are widely used to store and transport petroleum,chemical reagents,and other resources.As an important target of military strikes and terrorist bombings,LFC are vulnerable to blast waves and fragments.To explore the protective effect of polyurea elastomer on LFC,the damage characteristics of polyurea coated liquid-filled container(PLFC)under the combined loading of blast shock wave and fragments were studied experimentally.The microstructure of the polyurea layer was observed by scanning electron microscopy,and the fracture and self-healing phenomena were analyzed.The simulation approach was used to explain the combined blast-and fragments-induced on the PLFC in detail.Finally,the effects of shock wave and fragment alone and in combination on the damage of PLFC were comprehensively compared.Results showed that the polyurea reduces the perforation rate of the fragment to the LFC,and the self-healing phenomenon could also reduce the liquid loss rate inside the container.The polyurea reduces the degree of depression in the center of the LFC,resulting in a decrease in the distance between adjacent fragments penetrating the LFC,and an increase in the probability of transfixion and fracture between holes.Under the close-in blast,the detonation shock wave reached the LFC before the fragment.Polyurea does not all have an enhanced effect on the protection of LFC.The presence of internal water enhances the anti-blast performance of the container,and the hydrodynamic ram(HRAM)formed by the fragment impacting the water aggravated the plastic deformation of the container.The combined action has an enhancement effect on the deformation of the LFC.The depth of the container depression was 27%higher than that of the blast shock wave alone;thus,it cannot be simply summarized as linear superposition. 展开更多
关键词 polyurea Prefabricated fragment Liquid-filled container Hydrodynamic ram Cumulative effect
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Experimental investigation on weak shock wave mitigation characteristics of flexible polyurethane foam and polyurea 被引量:2
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作者 Shiyu Jia Cheng Wang +2 位作者 Wenlong Xu Dong Ma Fangfang Qi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期179-191,共13页
In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting conse... In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting consequences.To investigate the protection ability and characteristics of flexible materials and structures under weak shock wave loading,the blast wave produced by TNT explosive is loaded on the polyurethane foam with the density of 200.0 kg/m3(F-200)and 400.0 kg/m3(F-400),polyurea with the density of 1100.0 kg/m^(3)(P-1100)and structures composed of the two materials,which are intended for individual protection.Experimental results indicate that the shock wave is attenuated to weak pressure disturbance after interacting with the flexible materials which are not damaged.The shock wave protective capability of single-layer materials is dependent on their thickness,density and microscopic characteristics.The overpressure,maximum pressure rise rate and impulse of transmitted wave decrease exponentially with increase in sample thickness.For the same thickness,F-400 provides better protective capability than F-200 while P-1100 shows the best protective capability among the three materials.In this study,as the materials are not destroyed,F-200 with a thickness more than10.0 mm,F-400 with a thickness more than 4.0 mm,and P-1100 with a thickness more than 1.0 mm can attenuate the overpressure amplitude more than 90.0%.Further,multi-layer flexible composites are designed.Different layer layouts of designed structures and layer thickness of the single-layer materials can affect the protective performance.Within the research range,the structure in which polyurea is placed on the impact side shows the optimal shock wave protective performance,and the thicknesses of polyurea and polyurethane foam are 1.0 mm and 4.0 mm respectively.The overpressure attenuation rate reached maximum value of 93.3%and impulse attenuation capacity of this structure are better than those of single-layer polyurea and polyurethane foam with higher areal density. 展开更多
关键词 Free-field explosion Weak shock wave mitigation polyurea Polyurethane foam Multi-layered composites
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Explosion resistance performance of reinforced concrete box girder coated with polyurea:Model test and numerical simulation
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作者 Guangpan Zhou Rong Wang +2 位作者 Mingyang Wang Jianguo Ding Yuye Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期1-18,共18页
To study the anti-explosion protection effect of polyurea coating on reinforced concrete box girder,two segmental girder specimens were made at a scale of 1:3,numbered as G(without polyurea coating)and PCG(with polyur... To study the anti-explosion protection effect of polyurea coating on reinforced concrete box girder,two segmental girder specimens were made at a scale of 1:3,numbered as G(without polyurea coating)and PCG(with polyurea coating).The failure characteristics and dynamic responses of the specimens were compared through conducting explosion tests.The reliability of the numerical simulation using LS-DYNA software was verified by the test results.The effects of different scaled distances,reinforcement ratios,concrete strengths,coating thicknesses and ranges of polyurea were studied.The results show that the polyurea coating can effectively enhance the anti-explosion performance of the girder.The top plate of middle chamber in specimen G forms an elliptical penetrating hole,while that in specimen PCG only shows a very slight local dent.The peak vertical displacement and residual displacement of PCG decrease by 74.8% and 73.7%,respectively,compared with those of specimen G.For the TNT explosion with small equivalent,the polyurea coating has a more significant protective effect on reducing the size of fracture.With the increase of TNT equivalent,the protective effect of polyurea on reducing girder displacement becomes more significant.The optimal reinforcement ratio,concrete strength,thickness and range of polyurea coating were also drawn. 展开更多
关键词 Explosive load Explosion resistance performance Model test polyurea Concrete box girder Numerical simulation
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Investigating the dynamic mechanical behaviors of polyurea through experimentation and modeling 被引量:18
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作者 Hao Wang Ximin Deng +3 位作者 Haijun Wu Aiguo Pi Jinzhu Li Fenglei Huang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2019年第6期875-884,共10页
Polyurea is widely employed as a protective coating in many fields because of its superior ability to improve the anti-blast and anti-impact capability of structures.In this study,the mechanical properties of polyurea... Polyurea is widely employed as a protective coating in many fields because of its superior ability to improve the anti-blast and anti-impact capability of structures.In this study,the mechanical properties of polyurea XS-350 were investigated via systematic experimentation over a wide range of strain rates(0.001-7000 s^-1)by using an MTS,Instron VHS,and split-Hopkinson bars.The stress-strain behavior of polyurea was obtained for various strain rates,and the effects of strain rate on the primary mechanical properties were analyzed.Additionally,a modified rate-dependent constitutive model is proposed based on the nine-parameter Mooney-Rivlin model.The results show that the stress-strain curves can be divided into three distinct regions:the linear-elastic stage,the highly elastic stage,and an approximate linear region terminating in fracture.The mechanical properties of the polyurea material were found to be highly dependent on the strain rate.Furthermore,a comparison between model predictions and the experimental stress-strain curves demonstrated that the proposed model can characterize the mechanical properties of polyurea over a wide range of strain rates. 展开更多
关键词 polyurea Strain rate effect Dynamic mechanical properties Constitutive model
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An experimental study on shock wave mitigation capability of polyurea and shear thickening fluid based suspension pads 被引量:8
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作者 Andi Haris Heow Pueh Lee Vincent Beng Chye Tan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2018年第1期12-18,共7页
The present experimental study investigates shock wave mitigation capability of potentially new personal protective equipment(PPE) suspension pads made from polyurea and shear thickening fluid(STF).The shock tube test... The present experimental study investigates shock wave mitigation capability of potentially new personal protective equipment(PPE) suspension pads made from polyurea and shear thickening fluid(STF).The shock tube test results show that when placed behind Twaron fabric systems with thickness ranging from 2 mm to 18 mm, the replacement of conventional flexible foam pad with STF and STF-infused foam pads with the same thickness of 20 mm greatly reduces the normalized peak pressure(by about 72% for each pad). However, this benefit is partially offset by a large increase in the normalized impulse(by about78% for the STF pad and 131% for the STF-infused foam pad) which may cause the shock wave mitigation performance of these two pads to become less effective. Interestingly, the use of 4 mm thick polyurea pad can greatly reduce the normalized peak pressure and impulse as well(by about 74% and 49%, respectively). These results reveal that among the potentially new suspension pads tested, the polyurea pad displays the best shock wave mitigation performance. Therefore, polyurea has potential for use as a suspension pad in personal protective equipment requiring shock wave mitigation capability such as fabric ballistic vests, bomb suits and combat helmets. 展开更多
关键词 Shock wave MITIGATION polyurea Shear THICKENING FLUID SUSPENSION pad Ballistic fabric Primary blast injuries
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Polyurea coating for foamed concrete panel:An efficient way to resist explosion 被引量:16
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作者 Yi-shun Chen Bo Wang +4 位作者 Bei Zhang Qing Zheng Jian-nan Zhou Feng-nian Jin Hua-lin Fan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2020年第1期136-149,共14页
Autoclaved aerated concrete(AAC) panels have ultra-light weight,excellent thermal insulation and energy absorption,so it is an ideal building material for protective structures.To improve the blast resistance of the A... Autoclaved aerated concrete(AAC) panels have ultra-light weight,excellent thermal insulation and energy absorption,so it is an ideal building material for protective structures.To improve the blast resistance of the AAC panels,three schemes are applied to strengthen the AAC panels through spraying 4 mm thick polyurea coating from top,bottom and double-sides.In three-point bending tests,the polyurea-coated AAC panels have much higher ultimate loads than the un-coated panels,but slightly lower than those strengthened by the carbon fiber reinforced plastics(CEFRPs).Close-in explosion experiments reveal the dynamic strengthening effect of the polyurea coating.Critical scaled distances of the strengthened AAC panels are acquired,which are valuable for the engineering application of the AAC panels in the extreme loading conditions.Polyurea coatings efficiently enhance the blast resistance of the bottom and double-sided polyurea-coated AAC panels.It is interesting that the polyurea-coated AAC panels have much more excellent blast resistance than the CFRP reinforced AAC panels,although the latter have better static mechanical properties. 展开更多
关键词 Autoclaved aerated CONCRETE polyurea Explosion FAILURE
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Mechanical behavior and failure mechanism of polyurea nanocomposites under quasi-static and dynamic compressive loading 被引量:10
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作者 Qiang Liu Peng-wan Chen +4 位作者 Yan-song Guo Jian-jun Su Lu Han Ali Arab Jian-fei Yuan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第2期495-504,共10页
Polyurea is an elastomeric material that can be applied to enhance the protection ability of structures under blast and impact loading.In order to study the compressive mechanical properties of SiC/polyurea nanocompos... Polyurea is an elastomeric material that can be applied to enhance the protection ability of structures under blast and impact loading.In order to study the compressive mechanical properties of SiC/polyurea nanocomposites under quasi-static and dynamic loading,a universal testing machine and split Hopkinson pressure bar(SHPB)apparatus were used respectively.The stress-strain curves were obtained on polyurea and its composites at strain rates of 0.001e8000 s1.The results of the experiment suggested that increase in the strain rates led to the rise of the flow stress,compressive strength,strain rate sensitivity and strain energy.This indicates that all of the presented materials were dependent on strain rate.Moreover,these mechanical characters were enhanced by incorporating a small amount of SiC into polyurea matrix.The relation between yield stress and strain rates were established using the power law functions.Finally,in order to investigate the fracture surfaces and inside information of failed specimens,scanning electron microscopy(SEM)and micro X-ray computed tomography(micro-CT)were used respectively.Multiple voids,crazes,micro-cracks and cracking were observed in fracture surfaces.On the other hand,the cracking propagation was found in the micro-CT slice images.It is essential to understand the deformation and failure mechanisms in all the polyurea materials. 展开更多
关键词 polyurea nanocomposites Mechanical properties Strain rate MICRO-CT FAILURE
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Experimental investigations on small-and full-scale ship models with polyurea coatings subjected to underwater explosion 被引量:7
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作者 Jian Liu Feng-jiang An +4 位作者 Cheng Wu Sha-sha Liao Ming-xue Zhou Dong-yu Xue Huan Guo 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第7期1257-1268,共12页
Nowadays, the mitigation of damage to a ship caused by the underwater explosion attracts more and more attention from the modern ship designers. In this study, two kinds of scale tests were conducted to investigate th... Nowadays, the mitigation of damage to a ship caused by the underwater explosion attracts more and more attention from the modern ship designers. In this study, two kinds of scale tests were conducted to investigate the effects of polyurea coatings on the blast resistance of hulls subjected to underwater explosion. Firstly, small-scale model tests with different polyurea coatings were carried out. Results indicate that polyurea has a better blast resistance performance when coated on the front face, which can effectively reduce the maximum deflection of the steel plate by more than 20% and reduce the deformation energy by 35.7%-45.4%. Next, a full-scale ship(approximately 50 m × 9 m) under loadings produced by the detonation of 33 kg of spherical TNT charges was tested, where a part of the ship was coated with polyurea on the front face(8 mm + 24 mm) and not on the contrast area. Damage characteristics on the bottom were statistically analyzed based on a 3D scanning technology, indicating that polyurea contributes to enhancing the blast protection of the ship. However, damage results of this test were different from those of the small-scale tests. Moreover, the deformation area of the bottom with polyurea was greatly increased by 40.1% to disperse explosion energy, a conclusion that cannot be drown from the small-scale tests. 展开更多
关键词 polyurea coatings Small-scale model Full-scale ship Underwater explosion Blast resistance
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Blast response of clay brick masonry unit walls unreinforced and reinforced with polyurea elastomer 被引量:7
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作者 Gang Wu Chong Ji +4 位作者 Xin Wang Fu-yin Gao Chang-xiao Zhao Yu-jun Liu Gui-li Yang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第4期643-662,共20页
Clay brick masonry unit(CBMU) walls are widely used in building structures,and its damage and protection under explosion loads have been a matter of concern in the field of engineering protection.In this paper,a serie... Clay brick masonry unit(CBMU) walls are widely used in building structures,and its damage and protection under explosion loads have been a matter of concern in the field of engineering protection.In this paper,a series of full-scale experiments of the response characteristics of 24 cm CMBU walls unreinforced and reinforced with polyurea elastomer subjected to blast loading were carried out.Through setting 5.0 kg TNT charges at different stand-off distances,the damage characteristics of masonry walls at different scaled distances were obtained.The reinforcement effect of different polyurea coating thicknesses and methods on the blast resistance performance of masonry walls under single and repeated loads were also explored.Five failure grades were summarized according to the dynamic response features of masonry walls.Based on the stress wave propagation pattern in multi-media composite structures,the internal stress distribution of masonry walls were analyzed,and the division basis of the masonry walls’ failure grades was then quantified.Combined with Scanning Electron Microscope(SEM)images,the deformation characteristics of soft and hard segments of polyurea and effects of detonation products on microstructures were revealed respectively,which provides an important reference for the design and application of polyurea in the blast resistance of clay brick masonry walls. 展开更多
关键词 Clay brick masonry unit wall polyurea Blast loading Failure grade Reinforcement mechanism
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Experimental investigation on anti-penetration performance of polyurea-coated ASTM1045 steel plate subjected to projectile impact 被引量:6
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作者 Yu-xiang Sun Xin Wang +5 位作者 Chong Ji Chang-xiao Zhao Pei-li Liu Lei Meng Kun Zhang Tao Jiang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第4期1496-1513,共18页
In this study,the anti-penetration performance of polyurea/ASTM1405-steel composite plate subjected to high velocity projectile was analyzed.Two kinds of modified polyurea material(AMMT-053 and AMMT-055)were selected ... In this study,the anti-penetration performance of polyurea/ASTM1405-steel composite plate subjected to high velocity projectile was analyzed.Two kinds of modified polyurea material(AMMT-053 and AMMT-055)were selected and a ballistic impact testing system including speed measuring target system and high-speed camera was designed.This experiment was conducted with a rifle and 5.8 mm projectile to explore the effects by the polyurea coating thickness,the polyurea coating position and the glass-fiber cloth on the anti-penetration performance of polyurea/ASTM1405-steel composite plate.The result showed that the effects of polyurea coating position were different between two types of polyurea,and that the effects of glass-fiber position were disparate between two types of polyurea as well.For AMMT-053 polyurea material,it was better to be on front face than on rear face;whereas for AMMT-055 polyurea,it was better to be on rear surface although the difference was very subtle.Additionally,formulas had been given to describe the relationship between the effectiveness of polyurea and the thickness of polyurea coating.In general,AMMT-055 had better anti-penetration performance than AMMT-053.Furthermore,five typical damage modes including self-healing,crack,local bulge,spallation and local fragmentation were defined and the failure mechanism was analyzed with the results of SHPB test.Additionally,the bonding strength played an important role in the anti-penetration performance of polyurea/steel composite plate. 展开更多
关键词 polyurea ASTM1045 steel plate High velocity impact PENETRATION SHPB test Damage mechanism
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Analysis and design for the comprehensive ballistic and blast resistance of polyurea-coated steel plate 被引量:6
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作者 Dongyang Chu Yigang Wang +3 位作者 Shanglin Yang Zhijie Li Zhuo Zhuang Zhanli Liu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第1期35-51,共17页
Fragments and blast waves generated by explosions pose a serious threat to protective structures.In this paper,the impact resistance of polyurea-coated steel plate under complex dynamic loading is analyzed and designe... Fragments and blast waves generated by explosions pose a serious threat to protective structures.In this paper,the impact resistance of polyurea-coated steel plate under complex dynamic loading is analyzed and designed for improving comprehensive ballistic and blast resistance using the newly established computational evaluating model.Firstly,according to the thickness and placement effects of the coating on the impact resistance,the steel-core sandwich plates are designed,which are proved to own outstanding comprehensive ballistic and blast resistance.Besides,the distribution diagram of ballistic and blast resistance for different polyurea-coated steel plates is given to guide the design of protective structures applying in different explosion scenarios.Furthermore,the dynamic response of designed plates under two scenarios with combined fragments and blast loading is studied.The results show that the synergistic effect of the combined loading reduces both the ballistic and blast resistance of the polyurea-coated steel plate.Besides,the acting sequence of the fragments and blast affects the structural protective performance heavily.It is found that the first loading inducing structural large deformation or damage is dominant.When fragments impact first,the excellent unit-thickness ballistic performance of the structural front part is strongly needed for improving the comprehensive ballistic and blast resistance. 展开更多
关键词 polyurea Ballistic and blast resistance Combined fragments and blast loading
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Experimental study of polyurea-coated fiber-reinforced cement boards under gas explosions 被引量:1
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作者 Meng Gu Xiao-dong Ling +3 位作者 An-feng Yu Guo-xin Chen Hao-zhe Wang Han-xiang Wang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第5期201-213,共13页
Five types of polyurea elastomers were synthesized by changing the isocyanate component and the mechanical properties of polyurea materials were measured. Fiber-reinforced cement boards(FRCB)strengthened by polyurea w... Five types of polyurea elastomers were synthesized by changing the isocyanate component and the mechanical properties of polyurea materials were measured. Fiber-reinforced cement boards(FRCB)strengthened by polyurea with different formulations were processed, and a series of experiments were carried out on the specimens with gas explosion devices. The results showed that the conventional mechanical properties of different types of polyureas had their own advantages. Based on the gas explosion overpressure criterion, the blast resistances of reinforced plates were quantitatively evaluated,and the best polyurea was selected to guide the formulation design. The three typical failure modes of polyurea-reinforced FRCBs were flexural, shear, and flexural-shear failure. Dynamic thermodynamics and shock wave spectral analysis revealed that the polyurea did not undergo a glass transition in the gas explosion tests but retained its elastic properties, allowing it to effectively wrap the fragments formed by the brittle substrates. 展开更多
关键词 polyurea Fiber-reinforced cement board Gas explosion Failure criterion Glass transition
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Blast responses of polyurea retrofitted utility tunnel reinforced with basalt fibre reinforced polymer bars
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作者 Jian-nan Zhou Xiao-shuo Chen +6 位作者 Yin-zhi Zhou Wen-ye Wang Peng Wang Xin-li Kong Ying Xu Han-sheng Geng Feng-nian Jin 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第5期755-771,共17页
Polyurea coating and carbon fibre reinforced polymer reinforcing techniques were applied to retrofit a severely damaged urban utility tunnel(UUT).The blast responses of the retrofitted UUT were investigated through in... Polyurea coating and carbon fibre reinforced polymer reinforcing techniques were applied to retrofit a severely damaged urban utility tunnel(UUT).The blast responses of the retrofitted UUT were investigated through in-filed explosion experimental tests,and the displacements,strains,accelerations,and damage were compared.The retrofitted UUT exhibited comparable or even better blast resistance than the intact UUT.Although the polyurea coating was flexible,it exhibited excellent performance in improving the blast resistance of the damaged UUT.As the UUT reinforced with basalt fibre reinforce polymer(BFRP)bars has smaller damage compared with the UUT reinforced with steel bars,its retrofitting is simple,and the cost is low.The roof was simplified as an elastically simple support one-way slab.Euler beam theory was adopted to analyse the dynamic responses of UUT roof considering the interaction between soil and structure,which agree well with the experiments in the first three cases. 展开更多
关键词 Urban utility tunnel Retrofitting polyurea CFRP Explosion
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近场爆炸作用下涂覆聚脲混凝土自锚式悬索桥数值模拟研究 被引量:1
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作者 周广盼 陈毅鹏 +2 位作者 王荣 丁建国 董建军 《振动与冲击》 北大核心 2025年第8期276-286,共11页
为研究近场爆炸作用下涂覆聚脲对超宽混凝土自锚式悬索桥最薄弱位置的防护效果,以某超宽混凝土自锚式悬索桥为背景,通过数值模拟方法研究了爆炸作用下自锚式悬索桥破坏特征和动力响应。采用SOLIDWORKS及HYPERMESH软件建立整桥有限元模型... 为研究近场爆炸作用下涂覆聚脲对超宽混凝土自锚式悬索桥最薄弱位置的防护效果,以某超宽混凝土自锚式悬索桥为背景,通过数值模拟方法研究了爆炸作用下自锚式悬索桥破坏特征和动力响应。采用SOLIDWORKS及HYPERMESH软件建立整桥有限元模型,并通过LS-DYNA软件对不同TNT当量、横桥向及纵桥向爆炸位置、不同聚脲厚度进行参数影响分析,对比了爆炸作用下涂覆聚脲前后整桥破坏特征和底板竖向位移。结果表明:聚脲涂层能够有效提高混凝土自锚式悬索桥的抗爆性能;针对横纵桥向不同爆炸位置,最薄弱位置分别为中间箱室和1/2跨中;针对不同聚脲厚度,横纵桥向最薄弱位置最优聚脲厚度分别为8 mm和15 mm。研究成果可为超宽混凝土自锚式悬索桥的战时加固防护提供重要依据。 展开更多
关键词 爆炸荷载 自锚式悬索桥 局部涂覆聚脲 有限元分析 动力响应
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乳化剂对聚脲/石蜡微胶囊的制备及性能影响
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作者 谷亚新 何兴 +1 位作者 刘运学 范兆荣 《化学研究与应用》 北大核心 2025年第6期1777-1784,共8页
为制备适用于建筑工程中具有调温作用的相变微胶囊材料,本文制备了以石蜡为芯材,以甲苯二异氰酸酯(TDI)和二乙烯三胺(DETA)合成聚脲为壁材的相变微胶囊材料,探究乳化剂OP-10和十二烷基苯磺酸钠(SDBS)在不同条件下制备相变微胶囊的收率... 为制备适用于建筑工程中具有调温作用的相变微胶囊材料,本文制备了以石蜡为芯材,以甲苯二异氰酸酯(TDI)和二乙烯三胺(DETA)合成聚脲为壁材的相变微胶囊材料,探究乳化剂OP-10和十二烷基苯磺酸钠(SDBS)在不同条件下制备相变微胶囊的收率、热性能、表面形貌、粒径。OP-10作乳化剂时,当乳化剂占比油相3%,乳化转速为800 rpm,芯壁比为2∶1时获得的微胶囊性能更优,热焓值为115.3 J·g^(-1),包覆率为79.77%,平均粒径为22.31μm;SDBS作乳化剂时,当乳化剂占比油相3%,乳化转速为2000 rpm,芯壁比为1∶1.5时取得的微胶囊,热焓值为77.35 J·g^(-1),包覆率为53.11%,平均粒径为18.67μm。以OP-10为乳化剂得到的微胶囊热焓值较高,受制备条件影响较小,热学性能较稳定;以SDBS为乳化剂得到的微胶囊表面形貌较规整,收率较高。 展开更多
关键词 石蜡 聚脲 相变微胶囊 乳化剂
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聚脲金属复合层板应力-应变特性仿真及验证方法研究
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作者 邹喜红 张艺巍 +5 位作者 袁冬梅 向刚 谭云龙 邱伟本 王秦锋 熊锋 《兵器装备工程学报》 北大核心 2025年第7期303-311,共9页
应力-应变特性是聚脲金属复合层板疲劳强度设计和分析的基础,因此提出了聚脲金属复合层板应力-应变特性仿真及验证方法。在复合层板有限元模型的聚脲层和金属层之间插入cohesive单元模拟两者之间的脱粘工艺;在拉伸试验的基础上,采用Ogde... 应力-应变特性是聚脲金属复合层板疲劳强度设计和分析的基础,因此提出了聚脲金属复合层板应力-应变特性仿真及验证方法。在复合层板有限元模型的聚脲层和金属层之间插入cohesive单元模拟两者之间的脱粘工艺;在拉伸试验的基础上,采用Ogden二阶超弹性模型建立聚脲本构模型,并分别建立金属弹、塑性和损伤阶段的本构模型,将建立的本构模型及参数应用于有限元模型中完成仿真。结果表明:试验与仿真应力-应变曲线的弹性模量、屈服强度和抗拉强度误差均在5%以内。两者的吻合程度较好,验证了建立的聚脲金属复合层板应力-应变特性仿真及验证方法的有效性。 展开更多
关键词 聚脲金属 复合层板 本构模型 应力-应变曲线 仿真验证
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蒙脱土改性聚脲复合电杆防护层耐盐雾性研究
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作者 刘贺晨 肖斯瑶 +2 位作者 张铭嘉 吴鹏 韦斯贶 《绝缘材料》 北大核心 2025年第4期62-72,共11页
对复合电杆的聚脲防护涂层作耐盐碱性改性能够提高复合电杆在盐碱重污秽地区的运行可靠性。本文利用硅烷偶联剂KH550对蒙脱土进行表面处理,分析不同含量蒙脱土改性聚脲树脂对于电杆复合材料的盐雾防护效果。结果表明:盐雾老化28 d后,质... 对复合电杆的聚脲防护涂层作耐盐碱性改性能够提高复合电杆在盐碱重污秽地区的运行可靠性。本文利用硅烷偶联剂KH550对蒙脱土进行表面处理,分析不同含量蒙脱土改性聚脲树脂对于电杆复合材料的盐雾防护效果。结果表明:盐雾老化28 d后,质量分数为1.5%的蒙脱土改性聚脲树脂(样品PFRP-4)性能稳定性较好,其弯曲性能和拉伸性能分别降低了12.77%和25.70%,电气强度和闪络电场强度的保持率分别达到了77.60%和83.83%。盐雾老化后,样品PFRP-4表面破坏程度较小,热失重较低,残留率为67.15%。蒙脱土能有效填充聚脲树脂中的自由体积和裂缝,吸附水分子及腐蚀离子,降低涂层整体的吸水率,样品PFRP-4防护涂层可有效提高复合材料的憎水性和热稳定性,且具有良好的粘接性能,可为复合电杆在高盐雾、高湿度等恶劣环境下的运行提供有力保障。 展开更多
关键词 复合电杆 聚脲涂层 盐雾老化 蒙脱土改性
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CAES硐室FRP-混凝土界面增韧改性效果试验研究
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作者 蒋中明 袁振 +2 位作者 肖喆臻 杨雪 石兆丰 《土木工程学报》 北大核心 2025年第10期55-62,共8页
针对CAES人工硐室储气库FRP-混凝土密封结构层间界面抗剪切变形适应能力不足的问题,提出了在传统环氧树脂黏结剂中加入聚脲进行增韧改性的试验方案。研究针对工程实际需要,提出一种新的界面黏结方案,用于增强界面黏结韧性,提高地下储气... 针对CAES人工硐室储气库FRP-混凝土密封结构层间界面抗剪切变形适应能力不足的问题,提出了在传统环氧树脂黏结剂中加入聚脲进行增韧改性的试验方案。研究针对工程实际需要,提出一种新的界面黏结方案,用于增强界面黏结韧性,提高地下储气库密封结构的安全可靠性,更好地适应地下储气库复杂的赋存环境。通过进行FRP-混凝土界面直剪试验,测试了聚脲改性的环氧黏结剂界面的黏结性能与变形特性,并从宏观与微观的角度综合分析界面破坏形态与增韧机理。研究结果表明:聚脲的加入能极大改善界面的剪切变形适应性能,增大界面的剪切变形滑移量,但同时也将导致界面的抗剪强度降低。因此界面剪切关键力学参数的变化主要取决于添加聚脲的含量,此外聚脲的含量还对界面的破坏形态有重要的影响。 展开更多
关键词 密封结构 环氧树脂 聚脲 增韧改性 界面性能
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聚脲气凝胶的制备及其对轻质复合砂浆的影响
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作者 罗玉梅 周昀 +1 位作者 周易 邵雅菲 《应用化学》 北大核心 2025年第2期238-248,共11页
通过六亚甲基二异氰酸酯型聚异氰酸酯(PHDI)分别与4,4'-二氨基二苯甲烷(MDA)和4,4'-二氨基二苯基醚(ODA)反应制备聚脲(PUA)气凝胶(MDA-PUA、ODA-PUA)。MDA-PUA气凝胶具有较低的线性收缩率和较高的孔隙率,压缩模量为11.4 MPa,导... 通过六亚甲基二异氰酸酯型聚异氰酸酯(PHDI)分别与4,4'-二氨基二苯甲烷(MDA)和4,4'-二氨基二苯基醚(ODA)反应制备聚脲(PUA)气凝胶(MDA-PUA、ODA-PUA)。MDA-PUA气凝胶具有较低的线性收缩率和较高的孔隙率,压缩模量为11.4 MPa,导热系数为0.020 W/(m·K)。MDA-PUA气凝胶的初始分解温度为321℃,残炭率为19.3%。优选MDA-PUA气凝胶等体积取代砂制成复合砂浆。当气凝胶的掺杂体积分数高于30%时,砂浆可以达到轻质标准,导热系数可降低至0.097 W/(m·K),比纯砂浆低94.2%,气凝胶使轻质砂浆具有优异的保温性能。砂浆的抗折强度和抗压强度随着气凝胶用量的增加而降低,但轻质砂浆的28 d抗压强度仍可以满足轻骨料混凝土CL5−CL40级的使用要求。 展开更多
关键词 聚脲气凝胶 轻质砂浆 导热系数 抗压强度
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低速冲击下聚脲涂履瓦楞夹芯板的动态响应仿真研究及优化
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作者 刘艳 李立郑 何强 《兵器装备工程学报》 北大核心 2025年第1期305-313,共9页
为了研究聚脲涂覆瓦楞夹芯板的抗冲击性能,运用LS-DYNA有限元分析软件,对夹芯板在圆柱体冲击作用下的动态响应过程进行数值模拟。分析不同的涂履方式对夹芯板的最大挠度(Defl)、冲击载荷峰值(Peak)和变形模式的影响,对背侧涂覆(B型)结... 为了研究聚脲涂覆瓦楞夹芯板的抗冲击性能,运用LS-DYNA有限元分析软件,对夹芯板在圆柱体冲击作用下的动态响应过程进行数值模拟。分析不同的涂履方式对夹芯板的最大挠度(Defl)、冲击载荷峰值(Peak)和变形模式的影响,对背侧涂覆(B型)结构进行了多目标优化设计,对聚脲的增强机理进行了分析。结果表明:聚脲的涂覆能够有效增强夹芯板的抗冲击性能,相比于无涂覆(O型)结构,Defl降低最多的是B型结构,下降7.17%,Peak降低最多的是冲击侧涂覆(A型)结构,下降了7.87%。优化后的夹芯板与未优化夹芯板相比,Defl减小了49%,同时发现增加聚脲的厚度可以提高夹芯板的抗冲击性能。最后观察到夹芯板抗冲击性能的改进主要归因于聚脲涂覆夹芯板中塑性弯矩和膜力的增强。该研究为提高全金属夹层结构的抗冲击性能提供了一个潜在的新途径。 展开更多
关键词 聚脲弹性体 瓦楞夹芯板 抗冲击性能 数值模拟 响应面法
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