Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposite...Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposites modified glassy carbon electrode(GCE),which is very efficient and sensitive to detect bisphenol A(BPA).MnFe_(2)O_(4)/graphene(GR)was synthesized by immobilizing the MnFe_(2)O_(4) microspheres on the graphene nanosheets via a simple one-pot solvothermal method.The morphology and structure of the MnFe_(2)O_(4)/GR nanocomposite have been characterized through scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).In addition,electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS)and differential pulse voltammetry(DPV).Under the optimal conditions,the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8-400μmol/L and a detection limit of 0.0235μmol/L(S/N=3)with high sensitivity,good selectivity and high stability.In addition,the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%-104.56%.At present,the synthesis of MnFe_(2)O_(4)/GR provides more opportunities for the electrochemical detection of BPA in practical applications.展开更多
挠曲电效应广泛应用于柔性传感、医疗复健、振动能量收集等领域,然而尚未有研究探讨挠曲形变量对挠曲电响应性能的影响。基于此,以MoS_(2)/PAN复合挠曲电传感薄膜为例,制备MoS_(2)/PAN弯曲传感器,采用X射线衍射仪和扫描电子显微镜对复...挠曲电效应广泛应用于柔性传感、医疗复健、振动能量收集等领域,然而尚未有研究探讨挠曲形变量对挠曲电响应性能的影响。基于此,以MoS_(2)/PAN复合挠曲电传感薄膜为例,制备MoS_(2)/PAN弯曲传感器,采用X射线衍射仪和扫描电子显微镜对复合挠曲电传感薄膜的晶体结构、微观形貌进行表征。在弯曲角度为0.1°、0.5°、1.5°、4°、7°、15°、30°和45°情况下,通过数字源表收集不同弯曲角度下MoS_(2)/PAN弯曲传感器的挠曲响应电压、电流和响应时间,分析挠曲形变量对挠曲电响应性能的影响规律,基于悬臂梁方法测试计算挠曲电系数。结果表明:MoS_(2)/PAN弯曲传感器挠曲电效应显著,挠曲电系数高达1.95 n C/m,当弯曲角度为7°时,MoS_(2)/PAN弯曲传感器获得最优的挠曲电响应,当弯曲角度小于7°时,挠曲电响应随弯曲角度的增大而增大,但是当弯曲角度大于7°时,挠曲电效应减弱。展开更多
The swelling and adsorption properties of the F44-PTU resin for metal ions Cu2+,Pb2+,Cd2+,Hg2+,Pt4+ and Pd2+ were studied, and the adsorption properties and mechanism for nobel metal ions Pt4+ and Pd2+ were studied es...The swelling and adsorption properties of the F44-PTU resin for metal ions Cu2+,Pb2+,Cd2+,Hg2+,Pt4+ and Pd2+ were studied, and the adsorption properties and mechanism for nobel metal ions Pt4+ and Pd2+ were studied especially. The results showed that the resin had the better adsorption properties for Pt4+ and Pd2+ than other metal ions, and also had bigger adsorption velocity. The adsorption process of the resin for Pt4+ fited the langmuir equation, while the adsorption of the resin for Pd2+ fited the Freundich equation. The process of adsorption of the resin for Pt4+ and Pd2+ were all exothermic.展开更多
基金Project(2108085ME184)supported by the Natural Science Foundation of Anhui Province,ChinaProject(2022AH010019)supported by the Innovation Team Project of Anhui Provincial Department of Education,China+1 种基金Project(GXXT-2021-057)supported by the Collaborative Innovation Project of Anhui Provincial Department of Education,ChinaProject(2020QDZ36)supported by the Doctoral Scientific Research Startup Foundation of Anhui Jianzhu University,China。
文摘Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposites modified glassy carbon electrode(GCE),which is very efficient and sensitive to detect bisphenol A(BPA).MnFe_(2)O_(4)/graphene(GR)was synthesized by immobilizing the MnFe_(2)O_(4) microspheres on the graphene nanosheets via a simple one-pot solvothermal method.The morphology and structure of the MnFe_(2)O_(4)/GR nanocomposite have been characterized through scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).In addition,electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS)and differential pulse voltammetry(DPV).Under the optimal conditions,the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8-400μmol/L and a detection limit of 0.0235μmol/L(S/N=3)with high sensitivity,good selectivity and high stability.In addition,the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%-104.56%.At present,the synthesis of MnFe_(2)O_(4)/GR provides more opportunities for the electrochemical detection of BPA in practical applications.
文摘挠曲电效应广泛应用于柔性传感、医疗复健、振动能量收集等领域,然而尚未有研究探讨挠曲形变量对挠曲电响应性能的影响。基于此,以MoS_(2)/PAN复合挠曲电传感薄膜为例,制备MoS_(2)/PAN弯曲传感器,采用X射线衍射仪和扫描电子显微镜对复合挠曲电传感薄膜的晶体结构、微观形貌进行表征。在弯曲角度为0.1°、0.5°、1.5°、4°、7°、15°、30°和45°情况下,通过数字源表收集不同弯曲角度下MoS_(2)/PAN弯曲传感器的挠曲响应电压、电流和响应时间,分析挠曲形变量对挠曲电响应性能的影响规律,基于悬臂梁方法测试计算挠曲电系数。结果表明:MoS_(2)/PAN弯曲传感器挠曲电效应显著,挠曲电系数高达1.95 n C/m,当弯曲角度为7°时,MoS_(2)/PAN弯曲传感器获得最优的挠曲电响应,当弯曲角度小于7°时,挠曲电响应随弯曲角度的增大而增大,但是当弯曲角度大于7°时,挠曲电效应减弱。
文摘The swelling and adsorption properties of the F44-PTU resin for metal ions Cu2+,Pb2+,Cd2+,Hg2+,Pt4+ and Pd2+ were studied, and the adsorption properties and mechanism for nobel metal ions Pt4+ and Pd2+ were studied especially. The results showed that the resin had the better adsorption properties for Pt4+ and Pd2+ than other metal ions, and also had bigger adsorption velocity. The adsorption process of the resin for Pt4+ fited the langmuir equation, while the adsorption of the resin for Pd2+ fited the Freundich equation. The process of adsorption of the resin for Pt4+ and Pd2+ were all exothermic.
