This paper proposed an efficient method of image overlapping relationship analysis based on spatial index of KD tree fast search for disordered and large-scale asteroid images.In this study,the image data from asteroi...This paper proposed an efficient method of image overlapping relationship analysis based on spatial index of KD tree fast search for disordered and large-scale asteroid images.In this study,the image data from asteroid exploration missions such as Bennu,Vesta,and Ryugu were used for experiments,and the proposed image matching pairs determination algorithm was comprehensively compared with the corresponding modules of USGS ISIS in order to evaluate its performance in terms of efficiency and accuracy.The results show that when processing more than a thousand images,the proposed method greatly improves the efficiency of acquiring image matching pairs while ensuring the correctness of image overlapping relationships and accuracy of bundle adjustment.At the same time,according to the obtained image matching pairs,images that meet the requirements of Stereo Photoclinometry can be quickly selected,effectively improving the quality of 3D reconstruction models of asteroid images.展开更多
Heterogeneous solid frustrated-Lewis-pair(FLP)catalyst is of great promise in practical hydrogenation applications.It has been found that all-solid FLPs can be created on ceria via surface oxygen vacancy regulation.Co...Heterogeneous solid frustrated-Lewis-pair(FLP)catalyst is of great promise in practical hydrogenation applications.It has been found that all-solid FLPs can be created on ceria via surface oxygen vacancy regulation.Consequently,it is desired to investigate the mechanisms of the FLP-catalyzed hydrogenation of C=C and C=O and provide insight into the modification of CeO_(2)catalysts for the selective hydrogenation.In this work,the reaction mechanism of the hydrogenation of CH_(2)=CH_(2)and CH_(3)CH=O at the FLP sites constructed on CeO_(2)(110)surface was investigated by density functional theory(DFT),with the classical Lewis acid-base pairs(CLP)site as the reference.The results illustrate that at the CLP site,the dissociated hydride(H^(δ−))forms a stable H−O bond with the surface O atom,while at the FLP site,H^(δ−)is stabilized by Ce,displaying higher activity on the one hand.On the other hand,the electron cloud density of the Ce atom at the FLP site is higher,which can transfer more electrons to the adsorbed C_(C=C)and O_(C=O)atoms,leading to a higher degree of activation for C=C and C=O bonds,as indicated by the Bader charge analysis.Therefore,compared to the CLP site,the FLP site exhibits higher hydrogenation activity for CH_(2)=CH_(2)and CH_(3)CH=O.Furthermore,at the FLP sites,it demonstrates high efficiency in catalyzing the hydrogenation of CH_(2)=CH_(2)with the rate-determining barrier of 1.04 eV,but it shows limited activity for the hydrogenation of CH_(3)CH=O with the rate-determining barrier of 1.94 eV.It means that the selective hydrogenation of C=C can be effectively achieved at the FLP sites concerning selective hydrogenation catalysis.The insights shown in this work help to clarify the reaction mechanism of the hydrogenation of C=C and C=O at FLP site on CeO_(2)(110)and reveal the relationship between the catalytic performance and the nature of the active site,which is of great benefit to development of rational design of heterogeneous FLP catalysts.展开更多
The concept of the binary sequence pair is generalized from a single binary sequence. Binary sequence pairs are applied in many fields of radar, sonar or communication systems, in which signals with optimal periodic c...The concept of the binary sequence pair is generalized from a single binary sequence. Binary sequence pairs are applied in many fields of radar, sonar or communication systems, in which signals with optimal periodic correlation are required. Several types of almost perfect binary sequence pairs of length T = 2q are constructed, where q is an odd number. These almost perfect binary sequence pairs are based on binary ideal sequence or binary ideal two-level correlation sequence pairs by using Chinese remainder theorem. For these almost perfect binary sequence pairs with good balanced property, their corresponding divisible difference set pairs(DDSPs) are also derived.展开更多
目前我国证券市场尚未成熟,风险对冲手段单一,因此构建一个期货对多资产进行套期保值策略对于投资组合的风险管理尤为重要.本文构建了基于线性规划的最小CVaR (Conditional Value at Risk)套期保值模型,同时运用R-藤Pair CopulaGARCH模...目前我国证券市场尚未成熟,风险对冲手段单一,因此构建一个期货对多资产进行套期保值策略对于投资组合的风险管理尤为重要.本文构建了基于线性规划的最小CVaR (Conditional Value at Risk)套期保值模型,同时运用R-藤Pair CopulaGARCH模型结合蒙特卡洛模拟生成投资组合中各资产收益率的情景和概率,将结果用于基于线性规划的最小CVaR套期保值模型,可确定投资组合的最优套期保值比例.针对沪深300指数和5支沪深300成分股的实证研究表明,相对改良后的正态假定模型,经本文模型套期保值后的投资组合在风险和收益上均有更好的表现.展开更多
基金Space Optoelectronic Measurement and Perception Lab(LabSOMP-2023-07)the National Natural Science Foundation ofChina(42241147)+1 种基金the State Key Laboratory of Geo-Information Engineering(SKLGIE2021-Z-3-1)and the Open Program of Collaborativeinnovation Center of Geo-information(2023C002)。
文摘This paper proposed an efficient method of image overlapping relationship analysis based on spatial index of KD tree fast search for disordered and large-scale asteroid images.In this study,the image data from asteroid exploration missions such as Bennu,Vesta,and Ryugu were used for experiments,and the proposed image matching pairs determination algorithm was comprehensively compared with the corresponding modules of USGS ISIS in order to evaluate its performance in terms of efficiency and accuracy.The results show that when processing more than a thousand images,the proposed method greatly improves the efficiency of acquiring image matching pairs while ensuring the correctness of image overlapping relationships and accuracy of bundle adjustment.At the same time,according to the obtained image matching pairs,images that meet the requirements of Stereo Photoclinometry can be quickly selected,effectively improving the quality of 3D reconstruction models of asteroid images.
基金supported by the National Natural Science Foundation of China(22302115,22072079)the Fundamental Research Program of Shanxi Province(202303021221056).
文摘Heterogeneous solid frustrated-Lewis-pair(FLP)catalyst is of great promise in practical hydrogenation applications.It has been found that all-solid FLPs can be created on ceria via surface oxygen vacancy regulation.Consequently,it is desired to investigate the mechanisms of the FLP-catalyzed hydrogenation of C=C and C=O and provide insight into the modification of CeO_(2)catalysts for the selective hydrogenation.In this work,the reaction mechanism of the hydrogenation of CH_(2)=CH_(2)and CH_(3)CH=O at the FLP sites constructed on CeO_(2)(110)surface was investigated by density functional theory(DFT),with the classical Lewis acid-base pairs(CLP)site as the reference.The results illustrate that at the CLP site,the dissociated hydride(H^(δ−))forms a stable H−O bond with the surface O atom,while at the FLP site,H^(δ−)is stabilized by Ce,displaying higher activity on the one hand.On the other hand,the electron cloud density of the Ce atom at the FLP site is higher,which can transfer more electrons to the adsorbed C_(C=C)and O_(C=O)atoms,leading to a higher degree of activation for C=C and C=O bonds,as indicated by the Bader charge analysis.Therefore,compared to the CLP site,the FLP site exhibits higher hydrogenation activity for CH_(2)=CH_(2)and CH_(3)CH=O.Furthermore,at the FLP sites,it demonstrates high efficiency in catalyzing the hydrogenation of CH_(2)=CH_(2)with the rate-determining barrier of 1.04 eV,but it shows limited activity for the hydrogenation of CH_(3)CH=O with the rate-determining barrier of 1.94 eV.It means that the selective hydrogenation of C=C can be effectively achieved at the FLP sites concerning selective hydrogenation catalysis.The insights shown in this work help to clarify the reaction mechanism of the hydrogenation of C=C and C=O at FLP site on CeO_(2)(110)and reveal the relationship between the catalytic performance and the nature of the active site,which is of great benefit to development of rational design of heterogeneous FLP catalysts.
基金supported by the National Natural Science Foundation of China(6160140161501395+6 种基金6160139961671402)Natural Science Foundation of Hebei Province(F2015203150F2016203293F2016203312)Natural Science Research Programs of Hebei Educational Committee(QN2016120)the Independent Research Programs for Young Teachers of Yanshan University(15LGB013)
文摘The concept of the binary sequence pair is generalized from a single binary sequence. Binary sequence pairs are applied in many fields of radar, sonar or communication systems, in which signals with optimal periodic correlation are required. Several types of almost perfect binary sequence pairs of length T = 2q are constructed, where q is an odd number. These almost perfect binary sequence pairs are based on binary ideal sequence or binary ideal two-level correlation sequence pairs by using Chinese remainder theorem. For these almost perfect binary sequence pairs with good balanced property, their corresponding divisible difference set pairs(DDSPs) are also derived.
文摘目前我国证券市场尚未成熟,风险对冲手段单一,因此构建一个期货对多资产进行套期保值策略对于投资组合的风险管理尤为重要.本文构建了基于线性规划的最小CVaR (Conditional Value at Risk)套期保值模型,同时运用R-藤Pair CopulaGARCH模型结合蒙特卡洛模拟生成投资组合中各资产收益率的情景和概率,将结果用于基于线性规划的最小CVaR套期保值模型,可确定投资组合的最优套期保值比例.针对沪深300指数和5支沪深300成分股的实证研究表明,相对改良后的正态假定模型,经本文模型套期保值后的投资组合在风险和收益上均有更好的表现.
