Capacitor-based pulsed power supply(PPS)is widely used in fields related to electromagnetic launch,plasma,and materials'synthesis,modification and processing.As industrial applications place higher requirements on...Capacitor-based pulsed power supply(PPS)is widely used in fields related to electromagnetic launch,plasma,and materials'synthesis,modification and processing.As industrial applications place higher requirements on compact and portable pulsed power supplies,the National Key Laboratory of Transient Physics(NKLTP)recently developed a pulsed power supply consisting of a set of compact pulse-forming units(PFU),each with a capacitor energy storage of 220 kJ.This integrated PPS comes with a complete system configuration,a miniature compact structure,a high rate of repetition,and high power,with energy storage density exceeding 1.2 MJ/m^(3).This paper describes the device-level design of the unit,the system layout,the control system,the thermal management system,and the experimental results of the pulsed power supply.The experimental results verified the good reliability of the PPS at high repetition rates with each unit module delivering an output current of more than 100 kA.Additionally,flexible current pulse shapes can be formed by setting the charging voltage and the trigger sequence of the PFUs.The pulse forming network(PFN)developed from these PFUs was successfully applied to electromagnetic launch.展开更多
Functionalized implants demonstrate an upgraded approach in orthopedic implants,aiming to achieve long term success through improved bio integration.Bioceramic coatings with multifunctionality have arisen as an effect...Functionalized implants demonstrate an upgraded approach in orthopedic implants,aiming to achieve long term success through improved bio integration.Bioceramic coatings with multifunctionality have arisen as an effective substitute for conventional coatings,owing to their combination of various properties that are essential for bio-implants,such as osteointegration and antibacterial character.In the present study,thin hopeite coatings were produced by Pulsed laser deposition(PLD)and radio frequency magnetron sputtering(RFMS)on Ti64 substrates.The obtained hopeite coatings were annealed at 500°C in ambient air and studied in terms of surface morphology,phase composition,surface roughness,adhesion strength,antibacterial efficacy,apatite forming ability,and surface wettability by scanning electron microscope(SEM),X-ray diffraction(XRD),atomic force microscope(AFM),tensometer,fluorescence-activated cell sorting(FACS),simulated body fluid(SBF)immersion test and contact angle goniometer,respectively.Furthermore,based on promising results obtained in the present work it can be summarized that the new generation multifunctional hopeite coating synthesized by two alternative new process routes of PLD and RFMS on Ti64 substrates,provides effective alternatives to conventional coatings,largely attributed to strong osteointegration and antibacterial character of deposited hopeite coating ensuring the overall stability of metallic orthopedic implants.展开更多
Based on our previous pulsed current and internal overvoltage test data and the experience of common commercial high power cables,a 100 kA coaxial pulsed power cable is designed and manufactured to adapt the coaxial e...Based on our previous pulsed current and internal overvoltage test data and the experience of common commercial high power cables,a 100 kA coaxial pulsed power cable is designed and manufactured to adapt the coaxial electric energy breech transmission between the plasma generator and the pulsed power supply(PPS) in electrothermal-chemical(ETC) guns.The index parameters are analyzed and determined.Semi-conductor layers and a shield stiffener are introduced to prevent the deformation and burst of the pulsed power cable structurally.The semi-conductor layer can eliminate the air gap and balance the electric field in the cable.The shield stiffener can multiply the mechanical strength to restrain the strong electrodynamic force produced by the core dislocation of the outer conductor.The multi-coupling of electromagnetic field,stress field and thermal field analysis are established to assist in aided design of electrical strength,mechanical strength and temperature rise characteristics.Both a DC voltage withstand test and pulsed discharge tests are introduced to verify and inspect the performance and dynamic response of the pulsed power cable.The 25 kV/5 min DC voltage withstand test result shows that the sample leakage current is nearly 3 μA and no abnormal phenomena of the pulsed power cable sample occurred.The pulsed discharge tests show that the sample can sustain the 100 kA peak current.Furthermore,this 100 kA coaxial pulsed power cable can satisfy the ETC test requirements.展开更多
This experiment designed the pulsed electric fields （PEF） of high intensity of 100 kV· cm^-1 sterilization system. Fluorescent pseudomonas as target cell was operated 180 s in the PEF. By observing the differen...This experiment designed the pulsed electric fields （PEF） of high intensity of 100 kV· cm^-1 sterilization system. Fluorescent pseudomonas as target cell was operated 180 s in the PEF. By observing the difference of the bacteria before and after the disposal by TEM, it is found that the cell walls of the treated bacteria were broken. Irreversible perforations were formed on the cell membrane. The cell inclusions and cell fragments were leaked. The cell died as a result. The results showed that the PEF sterilization system designed can be used for liquid food sterilization experiments.展开更多
It has been demonstrated that tbe critical role ofbone marrow stromal cells (HMSCs ) is to sustain theselfrenewal of pluripotent hematopoietic stem cells andmaintain the homeostasis of bone marrow hematopoiesismicroen...It has been demonstrated that tbe critical role ofbone marrow stromal cells (HMSCs ) is to sustain theselfrenewal of pluripotent hematopoietic stem cells andmaintain the homeostasis of bone marrow hematopoiesismicroenvironment. BMSC progenitor can differentiateinto several clements including macrophages, endothelialcells, fibroblasts and some other cells. Almost展开更多
Thin films of PrCoO3 were deposited on LaAlO3 substrates by pulsed laser deposition technique.X-ray diffraction result indicates that films are single phase and c-axis textured.To investigate the spin state transition...Thin films of PrCoO3 were deposited on LaAlO3 substrates by pulsed laser deposition technique.X-ray diffraction result indicates that films are single phase and c-axis textured.To investigate the spin state transition,Raman spectroscopy measurements were performed at different temperatures.The position of the Raman modes is found to increase while full width at half maximum(FWHM) of these modes is found to decrease with the decrease of temperature across spin state transition temperature(220 K) of PrCoO3.展开更多
The high-temperature oxidation resistance behavior of 7% （mass fraction） Y203-ZrO2 thermal barrier coatings （TBCs） irradiated by high-intensity pulsed ion beam （HIPIB） was investigated under the cyclic oxidation...The high-temperature oxidation resistance behavior of 7% （mass fraction） Y203-ZrO2 thermal barrier coatings （TBCs） irradiated by high-intensity pulsed ion beam （HIPIB） was investigated under the cyclic oxidation condition of 1 050 ℃ and 1 h. The columnar grains in the TBCs disappear after the HIPIB irradiation at ion current densities of 100-200 A/cm^2 and the irradiated surface becomes smooth and densified after remelting and ablation due to the HIPIB irradiation. The thermally grown oxide （TGO） layer thickness of the irradiated TBCs is smaller than that of the original TBCs. After 15 cycles, the mass gains of the original TBCs and those irradiated by ion current densities of 100 and 200 A/cm^2 due to the oxidation are found to be 0.8-0.9, 0.6-0.7, and 0.3-0.4 mg/cm^2, respectively. The inward diffusion of oxygen through the irradiated TBCs is significantly impeded by the densified top layer formed due to irradiation, which is the main reason for the improved overall oxidation resistance of the irradiated TBCs.展开更多
In this work,the chromium aluminum nitride(CrAlN)coatings were prepared on TC11 titanium alloy by composite magnetic field cathodic arc ion plating with controllable pulse electromagnetic combined with permanent magne...In this work,the chromium aluminum nitride(CrAlN)coatings were prepared on TC11 titanium alloy by composite magnetic field cathodic arc ion plating with controllable pulse electromagnetic combined with permanent magnet.The effects of electromagnetic frequency on the morphology,microstructure,nano-hardness and elastic modulus of the coatings were investigated by scanning electron microscope(SEM),X-ray diffraction(XRD)and nano-indenter.This paper has mainly studied the influence of CrAlN coatings which are prepared at various electromagnetic frequencies on the wear and erosion resistance through a series of wear and solid particle erosion experiments.It was found that the deposition rate of CrAlN coatings increases with the increase of electromagnetic frequency.And CrAlN coatings all preferentially grew along the(111)crystal plane.At 16.7 Hz,with the increase of pulsed electromagnetic frequency,the hardness is the highest(23.6 GPa)and the adhesion is the highest(41.5 N).In addition,the coating deposition exhibited the best wear and solid erosion resistance at 16.7 Hz and 33.3 Hz,the friction coefficient is about 0.35,and the erosion rate is about 0.2μm/g at 30°and less than 1μm/g at 90°,respectively.These results indicate that the CrAlN coating formed at an appropriate pulsed electromagnetic frequency can achieve excellent mechanical properties,wear and solid erosion resistance.展开更多
We introduce our state-of-the art of“vacuum consistent electrochemistry”to an investigation of the interfaces between oxides and ionic liquid(IL).Pulsed laser deposition(PLD)has been one of the powerful and sophisti...We introduce our state-of-the art of“vacuum consistent electrochemistry”to an investigation of the interfaces between oxides and ionic liquid(IL).Pulsed laser deposition(PLD)has been one of the powerful and sophisticated techniques to realize nanoscale preparation of high-quality epitaxial oxide thin films.On the other hand,electrochemistry is a simple,very sensitive,and non-destructive analysis technique for solid-liquid interfaces.To ensure the reproducibility in experiment of the interfaces of such epitaxial oxide films,as well as bulk oxide single-crystals,with IL,we employ a home-built PLD-electrochemical(EC)system with IL as an electrolyte.The system allows one to perform all-in-vacuum experiments during the preparation of well-defined oxide electrode surfaces to their electrochemical analyses.The topics include electrochemical evaluations of the oxide’s own properties,such as carrier density and relative permittivity,and the interfacial properties of oxides in contact with IL,such as flat band potential and electric double layer(EDL)capacitance,ending with future perspectives in all-solid-state electrochemistry.展开更多
This paper introduced a compact high flux polarized neutron beam generator scheme,which used air as the working medium and had low energy consumption.The neutron beam generator adopted a linear three compartment confi...This paper introduced a compact high flux polarized neutron beam generator scheme,which used air as the working medium and had low energy consumption.The neutron beam generator adopted a linear three compartment configuration,sequentially using nitrogen nucleus tandem near range accelerated polarization target spallation nuclear reaction technology,neutron multiplication technology,neutron beam polarization and near range acceleration technology,neutron focusing and shooting control technology.Through design and equivalent verification,it has been proven that the total length of the device does not exceed 5 m,the effective range can reach several hundred kilometers,the neutron flux at the muzzle is not less than 10^(25) n·cm^(-2)·s^(-1),which attenuates to 10^(10) n·cm^(-2)·s^(-1) at a distance of several 100 km,and this flux can effectively strike the target.It can be used as a defensive directed energy weapon with high energy density and has broad application prospects.展开更多
Development of methodologies for fabrications of nanostructured materials that provide control over their microstructural features and compositions represents a fundamental step in the advancement of technologies for ...Development of methodologies for fabrications of nanostructured materials that provide control over their microstructural features and compositions represents a fundamental step in the advancement of technologies for productions of materials with well-defined functional properties.Pulse electrolysis,a top-down electrochemical approach,has been demonstrated to be a viable method for producing nanostructured materials with a particular efficacy in the synthesis of tin oxides.This method allows for significant control over the composition and shape of the resulting tin oxides particles by modifying the anionic composition of the aqueous electrolyte,obviating the need for additional capping agents in the synthesis process and eliminating the requirement for high-temperature post-treatments.The composition and microstructural characteristics of these oxides are found to be contingent upon the differing stabilities of tin fluoride and chloride complexes,as well as the distinct mechanisms of interaction between chloride and fluoride anions with an oxidized tin surface,which is influenced by the varying kosmotropic/chaotropic nature of these anions.The composition and microstructural characteristics of the obtained dispersed tin oxides would thus determine their potential applications as an anode material for lithium-ion batteries,as a photocatalyst,or as an oxyphilic component of a hybrid support for a platinum-containing electrocatalyst.展开更多
Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band lim...Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band limitation are determined directly by the electro-optic crystal and duration of the probe laser pulse.Here,we investigate the performance of the EOS with thin GaSe crystal in the measurement of the mid-infrared few-cycle la⁃ser pulse.The shift of the central frequency and change of the bandwidth induced by the EOS detection are calcu⁃lated,and then the pulse distortions induced in this detection process are discussed.It is found that this technique produces a red-shift of the central frequency and narrowing of the bandwidth.These changings decrease when the laser wavelength increases from 2μm to 10μm.This work can help to estimate the performance of the EOS de⁃tection technique in the mid-infrared band and offer a reference for the related experiment as well.展开更多
This study involved a comprehensive investigation aimed at achieving efficient multi-millijoule THz wave generation by exploiting the unique properties of cylindrical GaAs waveguides as effective mediators of the conv...This study involved a comprehensive investigation aimed at achieving efficient multi-millijoule THz wave generation by exploiting the unique properties of cylindrical GaAs waveguides as effective mediators of the conversion of laser energy into THz waves.Through meticulous investigation,valuable insights into optimizing THz generation processes for practical applications were unearthed.By investigating Hertz potentials,an eigen-value equation for the solutions of the guided modes(i.e.,eigenvalues)was found.The effects of various param-eters,including the effective mode index and the laser pulse power,on the electric field components of THz radia-tion,including the fundamental TE(transverse electric)and TM(transverse magnetic)modes,were evaluated.By analyzing these factors,this research elucidated the nuanced mechanisms governing THz wave generation within cylindrical GaAs waveguides,paving the way for refined methodologies and enhanced efficiency.The sig-nificance of cylindrical GaAs waveguides extends beyond their roles as mere facilitators of THz generation;their design and fabrication hold the key to unlocking the potential for compact and portable THz systems.This trans-formative capability not only amplifies the efficiency of THz generation but also broadens the horizons of practical applications.展开更多
In this study,the potential application of shaped charge jets as transient antennas for electromagnetic signal transmission was explored and an electromagnetic pulse radiation system with a shaped charge jet as a tran...In this study,the potential application of shaped charge jets as transient antennas for electromagnetic signal transmission was explored and an electromagnetic pulse radiation system with a shaped charge jet as a transient antenna was proposed.During the research,crucial characteristics of the transient antenna formed by a shaped charge with a 30 mm diameter,such as resonant frequency,radiation pattern,and radiation efficiency,were evaluated.The typical shaped charge jet morphology was obtained based on the simulations,in which it could insight the dynamic behavior of the shaped charge jet selected.An equivalent model experiment was employed to test the radiation efficiency,and it showed that a shorting pin loading method could increase the relative bandwidth of the jet antenna to 32.8%,and the experimental results correlate with the theoretical predictions for half-wave dipole antennas reasonably well.Additionally,variations in the diameter of the shaped charge jet were found to affect the input impedance and impedance bandwidth,while the length of the jet influenced the resonant frequency of the antenna.This suggests that altering these parameters can achieve reconfigurability of the jet antenna.展开更多
Accurate target angle estimation is one of the chal-lenges for wideband radars due to the fact that target occupies multiple range bins,resulting in lower energy or signal to noise ratio in a single range bin.This pap...Accurate target angle estimation is one of the chal-lenges for wideband radars due to the fact that target occupies multiple range bins,resulting in lower energy or signal to noise ratio in a single range bin.This paper proposes a processing technique for enhanced accuracy of target angle estimates for wideband monopulse radars.Firstly,to accumulate the energy of the received echo signals from different scatterers on a target,the phase difference between different scatterers on a target is estimated using the minimum entropy phase estimation method combining with the correlation between adjacent pulses.Then,the monopulse ratio is obtained by using the signals from the accumulated sum and difference channels.The target angle is estimated by weighting the accumulated echo energy for accu-racy enhancement.Experimental results based on both numeri-cal simulation and measured data are presented to validate the effectiveness of the proposed technique.展开更多
Breakage is an important step in the resource processing chain.However,the mechanical crushing methods commonly used today suffer from low energy efficiency and high dust levels.Promoting environmental protection and ...Breakage is an important step in the resource processing chain.However,the mechanical crushing methods commonly used today suffer from low energy efficiency and high dust levels.Promoting environmental protection and improving energy efficiency are crucial to advancing China’s circular economy.Mining companies are actively exploring novel and innovative technologies to significantly cut down on operating costs and minimize emissions of dust and pollutants generated during processing.Recently,high voltage pulse discharge(HVPD)technology has received widespread attention and has been reported to have good application prospects in resource processing.This paper presents an extensive review of the operational principles of HVPD and the unique characteristics it engenders,such as non-polluting,selective material fragmentation,pre-weakening,pre-concentration,and enhanced permeability of coal seams.Additionally,this review explores the potential and obstacles confronting HVPD in industrial contexts,offering fresh insights for HVPD optimization and providing guidance and prospects for industrial deployment and further development.展开更多
High-energy continuous wave(CW)lasers are mostly used in laser damage applications,but efficient laser ablation of transparent materials is challenging due to low optical absorption.Considering the potential of femtos...High-energy continuous wave(CW)lasers are mostly used in laser damage applications,but efficient laser ablation of transparent materials is challenging due to low optical absorption.Considering the potential of femtosecond(fs)laser-induced air filament for high-peak laser transmission over long distances,femtosecond(fs)laser-induced air filaments are combined with a millisecond(ms)laser to form an fs-ms CPL,enhancing the efficiency of sapphire ablation through synchronized spatial-temporal focusing.Experimental results show that ablation efficiency increases with the ms peak power and duty ratio.Excessive thermal stress leads to fragmentation of the sapphire when the ms duty ratio is over 30%at the peak power of 800 W,or when the peak power is over 500 W at a duty ratio of 100%.Also,the mechanism of high-efficiency damage is revealed through in-situ high-speed imaging.According to it,the ablation process went through 4 stages within 1.5 ms:defect-creating,melting and ablation,spattering,and fragmentation.Finally,the equivalent ablation efficiency of the fs-ms CPL is as high as 1.73×10^(7)μm^(3)/J,about 28 times higher compared to the fs laser only.The CPL damage method explored in this paper can provide theoretical guidance for efficient laser damage of transparent materials.展开更多
This work aimed to(i)understand conventional and pulse gas tungsten arc welding(GTAW)of AZ31B,and(ii)explore high frequency welding(100 Hz-1500 Hz).GTA welding with alternating current(AC)and direct current electrode ...This work aimed to(i)understand conventional and pulse gas tungsten arc welding(GTAW)of AZ31B,and(ii)explore high frequency welding(100 Hz-1500 Hz).GTA welding with alternating current(AC)and direct current electrode positive(DCEP)polarities yielded crack-free partial penetration welds for6 mm thick AZ31B alloy sheet.Welding under direct current electrode negative(DCEN)polarity with identical parameters as that for AC and DCEP resulted in full penetration welds that had microcracks.Defect-free full-penetration welds could be accomplished with pulse GTA welding using DCEN polarity at a pulse frequency of 1 Hz with a pulse duration ratio of 1:1.The resultant DCEN P 1:1 weld metal had a microstructure finer than the conventional DCEN weld.Welds produced with pulse duration ratios of 1:2and 1:4 lacked penetration but had a much finer microstructures because of the lower heat input.The arc constriction by the high frequency pulsing in the Activ Arc■-High frequency(AA-HF)mode welding was responsible for deeper penetration.Welds produced under DCEN pulsing and AA-HF conditions had hardness higher than conventional DCEN,DCEP and AC GTA welds,attributed to the finer microstructure.AA-HF GTA welding produced defect free deeper penetration welds with good microstructural features/mechanical properties and also gave an advantage of 50%enhanced productivity when welded at1500 Hz.展开更多
基金financial support from the National Key Laboratory of Transient Physics,Nanjing University of Science and Technology(Grant No.6142604230101)Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(Grant Nos.KYCX20_0321 and KYCX20_0322).
文摘Capacitor-based pulsed power supply(PPS)is widely used in fields related to electromagnetic launch,plasma,and materials'synthesis,modification and processing.As industrial applications place higher requirements on compact and portable pulsed power supplies,the National Key Laboratory of Transient Physics(NKLTP)recently developed a pulsed power supply consisting of a set of compact pulse-forming units(PFU),each with a capacitor energy storage of 220 kJ.This integrated PPS comes with a complete system configuration,a miniature compact structure,a high rate of repetition,and high power,with energy storage density exceeding 1.2 MJ/m^(3).This paper describes the device-level design of the unit,the system layout,the control system,the thermal management system,and the experimental results of the pulsed power supply.The experimental results verified the good reliability of the PPS at high repetition rates with each unit module delivering an output current of more than 100 kA.Additionally,flexible current pulse shapes can be formed by setting the charging voltage and the trigger sequence of the PFUs.The pulse forming network(PFN)developed from these PFUs was successfully applied to electromagnetic launch.
文摘Functionalized implants demonstrate an upgraded approach in orthopedic implants,aiming to achieve long term success through improved bio integration.Bioceramic coatings with multifunctionality have arisen as an effective substitute for conventional coatings,owing to their combination of various properties that are essential for bio-implants,such as osteointegration and antibacterial character.In the present study,thin hopeite coatings were produced by Pulsed laser deposition(PLD)and radio frequency magnetron sputtering(RFMS)on Ti64 substrates.The obtained hopeite coatings were annealed at 500°C in ambient air and studied in terms of surface morphology,phase composition,surface roughness,adhesion strength,antibacterial efficacy,apatite forming ability,and surface wettability by scanning electron microscope(SEM),X-ray diffraction(XRD),atomic force microscope(AFM),tensometer,fluorescence-activated cell sorting(FACS),simulated body fluid(SBF)immersion test and contact angle goniometer,respectively.Furthermore,based on promising results obtained in the present work it can be summarized that the new generation multifunctional hopeite coating synthesized by two alternative new process routes of PLD and RFMS on Ti64 substrates,provides effective alternatives to conventional coatings,largely attributed to strong osteointegration and antibacterial character of deposited hopeite coating ensuring the overall stability of metallic orthopedic implants.
基金supported by the United Foundation of China Ordnance Industry(Grant No.6141B010220)
文摘Based on our previous pulsed current and internal overvoltage test data and the experience of common commercial high power cables,a 100 kA coaxial pulsed power cable is designed and manufactured to adapt the coaxial electric energy breech transmission between the plasma generator and the pulsed power supply(PPS) in electrothermal-chemical(ETC) guns.The index parameters are analyzed and determined.Semi-conductor layers and a shield stiffener are introduced to prevent the deformation and burst of the pulsed power cable structurally.The semi-conductor layer can eliminate the air gap and balance the electric field in the cable.The shield stiffener can multiply the mechanical strength to restrain the strong electrodynamic force produced by the core dislocation of the outer conductor.The multi-coupling of electromagnetic field,stress field and thermal field analysis are established to assist in aided design of electrical strength,mechanical strength and temperature rise characteristics.Both a DC voltage withstand test and pulsed discharge tests are introduced to verify and inspect the performance and dynamic response of the pulsed power cable.The 25 kV/5 min DC voltage withstand test result shows that the sample leakage current is nearly 3 μA and no abnormal phenomena of the pulsed power cable sample occurred.The pulsed discharge tests show that the sample can sustain the 100 kA peak current.Furthermore,this 100 kA coaxial pulsed power cable can satisfy the ETC test requirements.
基金the Youth Science Fund of Heilongjiang Province (QC07C39)Postdoctoral Fund of Heilongjiang (LBH-Z06163)Science Research Fund of Northeast Agricultural University
文摘This experiment designed the pulsed electric fields （PEF） of high intensity of 100 kV· cm^-1 sterilization system. Fluorescent pseudomonas as target cell was operated 180 s in the PEF. By observing the difference of the bacteria before and after the disposal by TEM, it is found that the cell walls of the treated bacteria were broken. Irreversible perforations were formed on the cell membrane. The cell inclusions and cell fragments were leaked. The cell died as a result. The results showed that the PEF sterilization system designed can be used for liquid food sterilization experiments.
文摘The moditication of tumor cells or effcor cellsusing cytokine genes as a strategy to enhance hostantitumor immunity has been studied intensively over
文摘It has been demonstrated that tbe critical role ofbone marrow stromal cells (HMSCs ) is to sustain theselfrenewal of pluripotent hematopoietic stem cells andmaintain the homeostasis of bone marrow hematopoiesismicroenvironment. BMSC progenitor can differentiateinto several clements including macrophages, endothelialcells, fibroblasts and some other cells. Almost
基金Project supported by the Second Stage of Brain Korea 21 Project
文摘Thin films of PrCoO3 were deposited on LaAlO3 substrates by pulsed laser deposition technique.X-ray diffraction result indicates that films are single phase and c-axis textured.To investigate the spin state transition,Raman spectroscopy measurements were performed at different temperatures.The position of the Raman modes is found to increase while full width at half maximum(FWHM) of these modes is found to decrease with the decrease of temperature across spin state transition temperature(220 K) of PrCoO3.
基金Projects supported by The 2nd Stage of Brain Korea and Korea Research Foundation
文摘The high-temperature oxidation resistance behavior of 7% （mass fraction） Y203-ZrO2 thermal barrier coatings （TBCs） irradiated by high-intensity pulsed ion beam （HIPIB） was investigated under the cyclic oxidation condition of 1 050 ℃ and 1 h. The columnar grains in the TBCs disappear after the HIPIB irradiation at ion current densities of 100-200 A/cm^2 and the irradiated surface becomes smooth and densified after remelting and ablation due to the HIPIB irradiation. The thermally grown oxide （TGO） layer thickness of the irradiated TBCs is smaller than that of the original TBCs. After 15 cycles, the mass gains of the original TBCs and those irradiated by ion current densities of 100 and 200 A/cm^2 due to the oxidation are found to be 0.8-0.9, 0.6-0.7, and 0.3-0.4 mg/cm^2, respectively. The inward diffusion of oxygen through the irradiated TBCs is significantly impeded by the densified top layer formed due to irradiation, which is the main reason for the improved overall oxidation resistance of the irradiated TBCs.
基金Projects(2017GDAS CX-0202,2017GDAS CX-0111,2018 GDAS CX-0402) supported by Guangdong Academy of Science’ Special Project of Science and Technology Development,ChinaProject(2014B070705007) supported by Guangdong Science and Technology Plan Project,China+1 种基金Project(2016A030312015) supported by Scientific Research Fund of Guangdong Province,ChinaProject(2017A070701027) supported by Guangdong Science and Technology Program,China。
文摘In this work,the chromium aluminum nitride(CrAlN)coatings were prepared on TC11 titanium alloy by composite magnetic field cathodic arc ion plating with controllable pulse electromagnetic combined with permanent magnet.The effects of electromagnetic frequency on the morphology,microstructure,nano-hardness and elastic modulus of the coatings were investigated by scanning electron microscope(SEM),X-ray diffraction(XRD)and nano-indenter.This paper has mainly studied the influence of CrAlN coatings which are prepared at various electromagnetic frequencies on the wear and erosion resistance through a series of wear and solid particle erosion experiments.It was found that the deposition rate of CrAlN coatings increases with the increase of electromagnetic frequency.And CrAlN coatings all preferentially grew along the(111)crystal plane.At 16.7 Hz,with the increase of pulsed electromagnetic frequency,the hardness is the highest(23.6 GPa)and the adhesion is the highest(41.5 N).In addition,the coating deposition exhibited the best wear and solid erosion resistance at 16.7 Hz and 33.3 Hz,the friction coefficient is about 0.35,and the erosion rate is about 0.2μm/g at 30°and less than 1μm/g at 90°,respectively.These results indicate that the CrAlN coating formed at an appropriate pulsed electromagnetic frequency can achieve excellent mechanical properties,wear and solid erosion resistance.
文摘We introduce our state-of-the art of“vacuum consistent electrochemistry”to an investigation of the interfaces between oxides and ionic liquid(IL).Pulsed laser deposition(PLD)has been one of the powerful and sophisticated techniques to realize nanoscale preparation of high-quality epitaxial oxide thin films.On the other hand,electrochemistry is a simple,very sensitive,and non-destructive analysis technique for solid-liquid interfaces.To ensure the reproducibility in experiment of the interfaces of such epitaxial oxide films,as well as bulk oxide single-crystals,with IL,we employ a home-built PLD-electrochemical(EC)system with IL as an electrolyte.The system allows one to perform all-in-vacuum experiments during the preparation of well-defined oxide electrode surfaces to their electrochemical analyses.The topics include electrochemical evaluations of the oxide’s own properties,such as carrier density and relative permittivity,and the interfacial properties of oxides in contact with IL,such as flat band potential and electric double layer(EDL)capacitance,ending with future perspectives in all-solid-state electrochemistry.
基金sponsored by National Natural Science Foundation of China (Grant No. 12405215)
文摘This paper introduced a compact high flux polarized neutron beam generator scheme,which used air as the working medium and had low energy consumption.The neutron beam generator adopted a linear three compartment configuration,sequentially using nitrogen nucleus tandem near range accelerated polarization target spallation nuclear reaction technology,neutron multiplication technology,neutron beam polarization and near range acceleration technology,neutron focusing and shooting control technology.Through design and equivalent verification,it has been proven that the total length of the device does not exceed 5 m,the effective range can reach several hundred kilometers,the neutron flux at the muzzle is not less than 10^(25) n·cm^(-2)·s^(-1),which attenuates to 10^(10) n·cm^(-2)·s^(-1) at a distance of several 100 km,and this flux can effectively strike the target.It can be used as a defensive directed energy weapon with high energy density and has broad application prospects.
基金supported by the Ministry of Science and Higher Education of the Russian Federation under Project FENN-2024-0002.
文摘Development of methodologies for fabrications of nanostructured materials that provide control over their microstructural features and compositions represents a fundamental step in the advancement of technologies for productions of materials with well-defined functional properties.Pulse electrolysis,a top-down electrochemical approach,has been demonstrated to be a viable method for producing nanostructured materials with a particular efficacy in the synthesis of tin oxides.This method allows for significant control over the composition and shape of the resulting tin oxides particles by modifying the anionic composition of the aqueous electrolyte,obviating the need for additional capping agents in the synthesis process and eliminating the requirement for high-temperature post-treatments.The composition and microstructural characteristics of these oxides are found to be contingent upon the differing stabilities of tin fluoride and chloride complexes,as well as the distinct mechanisms of interaction between chloride and fluoride anions with an oxidized tin surface,which is influenced by the varying kosmotropic/chaotropic nature of these anions.The composition and microstructural characteristics of the obtained dispersed tin oxides would thus determine their potential applications as an anode material for lithium-ion batteries,as a photocatalyst,or as an oxyphilic component of a hybrid support for a platinum-containing electrocatalyst.
基金Supported by the National Natural Science Foundation of China(12064028)Jiangxi Provincial Natural Science Foundation(20232BAB201045).
文摘Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band limitation are determined directly by the electro-optic crystal and duration of the probe laser pulse.Here,we investigate the performance of the EOS with thin GaSe crystal in the measurement of the mid-infrared few-cycle la⁃ser pulse.The shift of the central frequency and change of the bandwidth induced by the EOS detection are calcu⁃lated,and then the pulse distortions induced in this detection process are discussed.It is found that this technique produces a red-shift of the central frequency and narrowing of the bandwidth.These changings decrease when the laser wavelength increases from 2μm to 10μm.This work can help to estimate the performance of the EOS de⁃tection technique in the mid-infrared band and offer a reference for the related experiment as well.
文摘This study involved a comprehensive investigation aimed at achieving efficient multi-millijoule THz wave generation by exploiting the unique properties of cylindrical GaAs waveguides as effective mediators of the conversion of laser energy into THz waves.Through meticulous investigation,valuable insights into optimizing THz generation processes for practical applications were unearthed.By investigating Hertz potentials,an eigen-value equation for the solutions of the guided modes(i.e.,eigenvalues)was found.The effects of various param-eters,including the effective mode index and the laser pulse power,on the electric field components of THz radia-tion,including the fundamental TE(transverse electric)and TM(transverse magnetic)modes,were evaluated.By analyzing these factors,this research elucidated the nuanced mechanisms governing THz wave generation within cylindrical GaAs waveguides,paving the way for refined methodologies and enhanced efficiency.The sig-nificance of cylindrical GaAs waveguides extends beyond their roles as mere facilitators of THz generation;their design and fabrication hold the key to unlocking the potential for compact and portable THz systems.This trans-formative capability not only amplifies the efficiency of THz generation but also broadens the horizons of practical applications.
基金supported by the"Fundamental Research Funds for the Central Universities"(Grant No.30924010801).
文摘In this study,the potential application of shaped charge jets as transient antennas for electromagnetic signal transmission was explored and an electromagnetic pulse radiation system with a shaped charge jet as a transient antenna was proposed.During the research,crucial characteristics of the transient antenna formed by a shaped charge with a 30 mm diameter,such as resonant frequency,radiation pattern,and radiation efficiency,were evaluated.The typical shaped charge jet morphology was obtained based on the simulations,in which it could insight the dynamic behavior of the shaped charge jet selected.An equivalent model experiment was employed to test the radiation efficiency,and it showed that a shorting pin loading method could increase the relative bandwidth of the jet antenna to 32.8%,and the experimental results correlate with the theoretical predictions for half-wave dipole antennas reasonably well.Additionally,variations in the diameter of the shaped charge jet were found to affect the input impedance and impedance bandwidth,while the length of the jet influenced the resonant frequency of the antenna.This suggests that altering these parameters can achieve reconfigurability of the jet antenna.
文摘Accurate target angle estimation is one of the chal-lenges for wideband radars due to the fact that target occupies multiple range bins,resulting in lower energy or signal to noise ratio in a single range bin.This paper proposes a processing technique for enhanced accuracy of target angle estimates for wideband monopulse radars.Firstly,to accumulate the energy of the received echo signals from different scatterers on a target,the phase difference between different scatterers on a target is estimated using the minimum entropy phase estimation method combining with the correlation between adjacent pulses.Then,the monopulse ratio is obtained by using the signals from the accumulated sum and difference channels.The target angle is estimated by weighting the accumulated echo energy for accu-racy enhancement.Experimental results based on both numeri-cal simulation and measured data are presented to validate the effectiveness of the proposed technique.
基金Foundation item:Project(2023YFC2909000) supported by the National Key R&D Program for Young Scientists,ChinaProject(2023JH3/10200010) supported by the Excellent Youth Natural Science Foundation of Liaoning Province,China+3 种基金Project (XLYC2203167) supported by the Liaoning Revitalization Talents Program,ChinaProject(RC231175) supported by the Mid-career and Young Scientific and Technological Talents Program of Shenyang,ChinaProject(2023A03003-2) supported by the Key Special Program of Xinjiang,ChinaProject(N2301026) supported by the Fundamental Research Funds for the Central Universities,China。
文摘Breakage is an important step in the resource processing chain.However,the mechanical crushing methods commonly used today suffer from low energy efficiency and high dust levels.Promoting environmental protection and improving energy efficiency are crucial to advancing China’s circular economy.Mining companies are actively exploring novel and innovative technologies to significantly cut down on operating costs and minimize emissions of dust and pollutants generated during processing.Recently,high voltage pulse discharge(HVPD)technology has received widespread attention and has been reported to have good application prospects in resource processing.This paper presents an extensive review of the operational principles of HVPD and the unique characteristics it engenders,such as non-polluting,selective material fragmentation,pre-weakening,pre-concentration,and enhanced permeability of coal seams.Additionally,this review explores the potential and obstacles confronting HVPD in industrial contexts,offering fresh insights for HVPD optimization and providing guidance and prospects for industrial deployment and further development.
基金Project(52105498) supported by the National Natural Science Foundation of ChinaProject(2021RC3074) supported by the Science and Technology Innovation Program of Hunan Province,China+2 种基金Project(2023YFB4605500) supported by the National Key Research and Development Program of ChinaProject(AHL2022KF04) supported by the Advanced Laser Technology Laboratory of Anhui Province,ChinaProject(kq2402089) supported by the Changsha Natural Science Foundation,China。
文摘High-energy continuous wave(CW)lasers are mostly used in laser damage applications,but efficient laser ablation of transparent materials is challenging due to low optical absorption.Considering the potential of femtosecond(fs)laser-induced air filament for high-peak laser transmission over long distances,femtosecond(fs)laser-induced air filaments are combined with a millisecond(ms)laser to form an fs-ms CPL,enhancing the efficiency of sapphire ablation through synchronized spatial-temporal focusing.Experimental results show that ablation efficiency increases with the ms peak power and duty ratio.Excessive thermal stress leads to fragmentation of the sapphire when the ms duty ratio is over 30%at the peak power of 800 W,or when the peak power is over 500 W at a duty ratio of 100%.Also,the mechanism of high-efficiency damage is revealed through in-situ high-speed imaging.According to it,the ablation process went through 4 stages within 1.5 ms:defect-creating,melting and ablation,spattering,and fragmentation.Finally,the equivalent ablation efficiency of the fs-ms CPL is as high as 1.73×10^(7)μm^(3)/J,about 28 times higher compared to the fs laser only.The CPL damage method explored in this paper can provide theoretical guidance for efficient laser damage of transparent materials.
文摘This work aimed to(i)understand conventional and pulse gas tungsten arc welding(GTAW)of AZ31B,and(ii)explore high frequency welding(100 Hz-1500 Hz).GTA welding with alternating current(AC)and direct current electrode positive(DCEP)polarities yielded crack-free partial penetration welds for6 mm thick AZ31B alloy sheet.Welding under direct current electrode negative(DCEN)polarity with identical parameters as that for AC and DCEP resulted in full penetration welds that had microcracks.Defect-free full-penetration welds could be accomplished with pulse GTA welding using DCEN polarity at a pulse frequency of 1 Hz with a pulse duration ratio of 1:1.The resultant DCEN P 1:1 weld metal had a microstructure finer than the conventional DCEN weld.Welds produced with pulse duration ratios of 1:2and 1:4 lacked penetration but had a much finer microstructures because of the lower heat input.The arc constriction by the high frequency pulsing in the Activ Arc■-High frequency(AA-HF)mode welding was responsible for deeper penetration.Welds produced under DCEN pulsing and AA-HF conditions had hardness higher than conventional DCEN,DCEP and AC GTA welds,attributed to the finer microstructure.AA-HF GTA welding produced defect free deeper penetration welds with good microstructural features/mechanical properties and also gave an advantage of 50%enhanced productivity when welded at1500 Hz.
