Instead of pure bacteria, induction mutation of activated sludge by ultraviolet (Uv) was studied and used to treat pulping wastewater by continuous- flow. The result showed the mutagenic activated sludge had remarkabl...Instead of pure bacteria, induction mutation of activated sludge by ultraviolet (Uv) was studied and used to treat pulping wastewater by continuous- flow. The result showed the mutagenic activated sludge had remarkable effect and application potential in pulping wastewater treatment. Comparing with common activated sludge, the mutagenic activated sludge was more suitable for lignose decomposition and had high decomposing efficiency.展开更多
275 EDITORIAL Nanocellulose:What’s next?Arthur J.Ragauskas and Colleen Walker,279 DISSOLVING PULP A novel approach for determining the reactivity of dissolving pulp based on the COD method Chen Gong,Shi Yu,Liu Yan-Zh...275 EDITORIAL Nanocellulose:What’s next?Arthur J.Ragauskas and Colleen Walker,279 DISSOLVING PULP A novel approach for determining the reactivity of dissolving pulp based on the COD method Chen Gong,Shi Yu,Liu Yan-Zhao,Ni Jian-Ping,Yang Xiao-Bo,and Tian Chao,287 NONWOOD PULPING Prehydrolysis kraft pulping of jute cutting and caddis mixture for rayon production Jannatun Nayeem,M.Sarwar Jahan,Razia Sultana Popy,M.Nashir Uddin,and M.A.Quaiyyum.展开更多
The floatability of different crystalline structures of pyrrhotite(monoclinic and hexagonal) was studied.It is shown that the floatability of monoclinic and hexagonal has obvious difference,and that the flotation reco...The floatability of different crystalline structures of pyrrhotite(monoclinic and hexagonal) was studied.It is shown that the floatability of monoclinic and hexagonal has obvious difference,and that the flotation recovery of monoclinic pyrrhotite is larger than that of hexagonal pyrrhotite using different collectors.When butyl dithiophosphate is used as the collector,the recovery is larger than that by sodium butyl xanthate and sodium diethyl dithiocarbamate.At the pH values ranging from 6 to 9,monoclinic pyrrhotite can be floated well,and the flotation recovery is higher than 90%.Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions.But Cu2+ cannot activate hexagonal pyrrhotite using sodium diethyldithiocarbamate as the collector.By the measurement of contact angle,it is indicated that monoclinic and hexagonal pyrrhotites float well and are easily activated by Cu2+ when dithiophosphate is used as the collector.Using sodium diethyl dithiocarbamate as a collector,the relationship between potential and pH range for pyrrhotite flotation is established.At pH 5,the optimal potential range for flotation of monoclinic pyrrhotite is about 125-580 mV(vs SHE),with the maximum flotation occurring at about 350 mV(vs SHE);the optimal potential range for flotation of hexagonal pyrrhotite is 200?580 mV(vs SHE),with the maximum flotation occurring at about 300 mV(vs SHE).展开更多
In the thermodynamics, for flotation separation of the SbAs bulk concentrate system there is no potential extent using butyl xanthate as collector. However in the kinetics, there exists 150 mV in reducing potential of...In the thermodynamics, for flotation separation of the SbAs bulk concentrate system there is no potential extent using butyl xanthate as collector. However in the kinetics, there exists 150 mV in reducing potential of butyl dixanthogen on the surface of stibnite and arsenopyrite. In this paper, their reducing kinetic difference of electrochemistry was confirmed by pure mineral flotation under controlled potential, the artificial SbAs bulk concentrate flotation separation and UVspectrophotometic analysis. The electrochemical separation of SbAs bulk concentrate has been carried out. qualified concentrate has been obtained. Sbconcentrate contains Sb 4944 %, As 044 %, Sbrecovery is 8783 % and Asconcentrate contains As 1096 %, Asrecovery is 9466 %.展开更多
A batch experiment was conducted to investigate the adsorption of trivalent chromium (Cr(Ⅲ)) from aqueous solutions by sugarcane pulp residue (SPR) and biochar. The results show that Cr(Ⅲ) adsorption by SPR ...A batch experiment was conducted to investigate the adsorption of trivalent chromium (Cr(Ⅲ)) from aqueous solutions by sugarcane pulp residue (SPR) and biochar. The results show that Cr(Ⅲ) adsorption by SPR and biochar is highly pH-dependent and Cr(Ⅲ) adsorption amount increases with the increase of pH. The adsorption kinetics of Cr(Ⅲ) fits well with the pseudo-second-order model. The maximum Cr(Ⅲ) adsorption capacities of 15.85 mg/g and 3.43 mg/g for biochar and SPR were calculated by Langmuir model. This indicates that biochar has a larger ability for Cr(Ⅲ) adsorption than SPR. The free energy change value (AG) reveals a spontaneous sorption process of Cr(Ⅲ) onto SPR and non-spontaneous sorption process onto biochar. The entropy change (AS) and enthalpy change (AH) are found to be 66.27 J/(mol'K) and 17.13 kJ/mol for SPR and 91.59 J/(mol-K) and 30.875 kJ/mol for biochar which further reflect an affinity of Cr(Ⅲ) onto SPR and biochar. It is suggested that biochar has potential to be an efficient adsorbent in the removal of Cr(Ⅲ) from industrial wastewater.展开更多
Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of...Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of Cr(Ⅲ) and Cr(V[) adsorption and their removal by SPR were investigated. The results show that the removal percentages of Cr(Ⅵ) and Cr(Ⅲ) increase with increasing SPR dosage and temperature and decrease with increasing SPR particle size and the initial concentration of chromium ions. However, the influence of pH value on the Cr(Ⅵ) removal differs from that of the Cr(Ⅲ) removal. The Cr(Ⅵ) removal percentage decreases with increasing pH values, while the Cr(Ⅲ) removal percentage increases with increasing pH value. The adsorption kinetics of Cr(Ⅵ) and Cr(Ⅲ) well fits with pseudo-second-order model. Langmuir adsorption isotherm can well describe the adsorption phenomena of chromium ions with the maximum adsorption capacity of 0.567 mg/g for Cr(Ⅵ) and 3.446 mg/g for Cr(Ⅲ). Moreover, SPR reveals higher adsorption capacity for Cr(Ⅲ) than that for Cr(Ⅵ), which implies that SPR has more potential application for Cr(Ⅲ)-containing wastewater treatment than that for Cr(Ⅵ)-containing wastewater treatment.展开更多
The effect of mineral particle size, pulp potential and category of oxidant on pyrite leaching was studied. The results show that a smaller mineral particle size leads to a higher leaching rate of pyrite, and the opti...The effect of mineral particle size, pulp potential and category of oxidant on pyrite leaching was studied. The results show that a smaller mineral particle size leads to a higher leaching rate of pyrite, and the optimum result with pyrite leaching rate of 2.92% is obtained when mineral particle size is less than 0.037 mm. The pulp potential reflects the leaching process. The increase of pulp potential can improve pyrite leaching. The leaching rate and velocity of pyrite can be enhanced rapidly by adding strong oxidant. The kind and the method of adding oxidant have important effect on the pyrite leaching. Appropriate concentration of Fe3+ can enhance pyrite leaching but the precipitation generated by high concentration of ferric ion covers the surface of pyrites and prevents the leaching process. The leaching rate increases with the constant addition of H2O2.展开更多
To improve heating uniformity and anthocyanin content of the blueberry pulp under microwave heating,the intermittent variable power microwave heating technology was introduced in the study.The effects of technology pa...To improve heating uniformity and anthocyanin content of the blueberry pulp under microwave heating,the intermittent variable power microwave heating technology was introduced in the study.The effects of technology parameters in terms of high microwave intensity heating time,intermittent time,low microwave intensity and low microwave intensity heating time on the blueberry pulp quality parameters(heating uniformity,average moisture content,the highest temperature and anthocyanin content)were investigated by using the response surface method.The results showed that the longer heating time under different microwave intensities resulted in the poorer heating uniformity.The intermittent stage promoted heat and mass transfer within the pulp and reduced the temperature difference and moisture gradient within the pulp,which enhanced desired uniformity of temperature and moisture distribution before entering the low microwave intensity heating stage.Therefore,the longer the intermittent time,the greater the heating uniformity.The optimal parameters were developed as high microwave intensity of 4 W·g^(-1),high microwave intensity heating time of 9.86 min,intermittent time of 10 min,low microwave intensity of 2.2 W·g^(-1)and low microwave intensity heating time of 6 min.This research might provide guidance for microwave heating berry fruits.展开更多
The stability was studied of the pigment in red pulp plum (Prunus salicina Lindl). The results showed that the pigment had a high resistance to heat and it′s stability seemed to be affected greatly by pH, and red pu...The stability was studied of the pigment in red pulp plum (Prunus salicina Lindl). The results showed that the pigment had a high resistance to heat and it′s stability seemed to be affected greatly by pH, and red pulp plum was suitable to be applied for making acid food. Several kinds of metallic ions including Na + 、Zn 2+ had an effect of reinforcement on its tone, however Fe 3+ had a disruptive effect. Sucrose had no undesirable effect, but vitamin C had a significant undesirable effect. Also the preservative of sodium benzoate had a definite undesirable effect. The pigment showed strong resistance to reducer sodium sulfite but was very weak in resistance to oxidizer hydrogen peroxide.展开更多
文摘Instead of pure bacteria, induction mutation of activated sludge by ultraviolet (Uv) was studied and used to treat pulping wastewater by continuous- flow. The result showed the mutagenic activated sludge had remarkable effect and application potential in pulping wastewater treatment. Comparing with common activated sludge, the mutagenic activated sludge was more suitable for lignose decomposition and had high decomposing efficiency.
文摘275 EDITORIAL Nanocellulose:What’s next?Arthur J.Ragauskas and Colleen Walker,279 DISSOLVING PULP A novel approach for determining the reactivity of dissolving pulp based on the COD method Chen Gong,Shi Yu,Liu Yan-Zhao,Ni Jian-Ping,Yang Xiao-Bo,and Tian Chao,287 NONWOOD PULPING Prehydrolysis kraft pulping of jute cutting and caddis mixture for rayon production Jannatun Nayeem,M.Sarwar Jahan,Razia Sultana Popy,M.Nashir Uddin,and M.A.Quaiyyum.
基金Project(50774094) supported by the National Natural Science Foundation of China
文摘The floatability of different crystalline structures of pyrrhotite(monoclinic and hexagonal) was studied.It is shown that the floatability of monoclinic and hexagonal has obvious difference,and that the flotation recovery of monoclinic pyrrhotite is larger than that of hexagonal pyrrhotite using different collectors.When butyl dithiophosphate is used as the collector,the recovery is larger than that by sodium butyl xanthate and sodium diethyl dithiocarbamate.At the pH values ranging from 6 to 9,monoclinic pyrrhotite can be floated well,and the flotation recovery is higher than 90%.Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions.But Cu2+ cannot activate hexagonal pyrrhotite using sodium diethyldithiocarbamate as the collector.By the measurement of contact angle,it is indicated that monoclinic and hexagonal pyrrhotites float well and are easily activated by Cu2+ when dithiophosphate is used as the collector.Using sodium diethyl dithiocarbamate as a collector,the relationship between potential and pH range for pyrrhotite flotation is established.At pH 5,the optimal potential range for flotation of monoclinic pyrrhotite is about 125-580 mV(vs SHE),with the maximum flotation occurring at about 350 mV(vs SHE);the optimal potential range for flotation of hexagonal pyrrhotite is 200?580 mV(vs SHE),with the maximum flotation occurring at about 300 mV(vs SHE).
文摘In the thermodynamics, for flotation separation of the SbAs bulk concentrate system there is no potential extent using butyl xanthate as collector. However in the kinetics, there exists 150 mV in reducing potential of butyl dixanthogen on the surface of stibnite and arsenopyrite. In this paper, their reducing kinetic difference of electrochemistry was confirmed by pure mineral flotation under controlled potential, the artificial SbAs bulk concentrate flotation separation and UVspectrophotometic analysis. The electrochemical separation of SbAs bulk concentrate has been carried out. qualified concentrate has been obtained. Sbconcentrate contains Sb 4944 %, As 044 %, Sbrecovery is 8783 % and Asconcentrate contains As 1096 %, Asrecovery is 9466 %.
基金Project(50925417) supported by the National Funds for Distinguished Young Scientist,ChinaProject(50830301) supported by the Key Program of National Natural Science Foundation of ChinaProject(51074191) supported by the National Natural Science Foundation of China
文摘A batch experiment was conducted to investigate the adsorption of trivalent chromium (Cr(Ⅲ)) from aqueous solutions by sugarcane pulp residue (SPR) and biochar. The results show that Cr(Ⅲ) adsorption by SPR and biochar is highly pH-dependent and Cr(Ⅲ) adsorption amount increases with the increase of pH. The adsorption kinetics of Cr(Ⅲ) fits well with the pseudo-second-order model. The maximum Cr(Ⅲ) adsorption capacities of 15.85 mg/g and 3.43 mg/g for biochar and SPR were calculated by Langmuir model. This indicates that biochar has a larger ability for Cr(Ⅲ) adsorption than SPR. The free energy change value (AG) reveals a spontaneous sorption process of Cr(Ⅲ) onto SPR and non-spontaneous sorption process onto biochar. The entropy change (AS) and enthalpy change (AH) are found to be 66.27 J/(mol'K) and 17.13 kJ/mol for SPR and 91.59 J/(mol-K) and 30.875 kJ/mol for biochar which further reflect an affinity of Cr(Ⅲ) onto SPR and biochar. It is suggested that biochar has potential to be an efficient adsorbent in the removal of Cr(Ⅲ) from industrial wastewater.
基金Projects(2006AA06Z374, 2007AA021304) supported by the National High-Tech Research and Development Program of ChinaProject(2008SK2007) supported by the Key Program of Science and Technology of Hunan Province, China
文摘Sugarcane pulp residue (SPR), a waste from sugar-refinery, which possesses a large surface area, can be used for removing chromium (Cr(Ⅲ) and Cr(Ⅵ)) from wastewater. In this work, the kinetics, isotherms of Cr(Ⅲ) and Cr(V[) adsorption and their removal by SPR were investigated. The results show that the removal percentages of Cr(Ⅵ) and Cr(Ⅲ) increase with increasing SPR dosage and temperature and decrease with increasing SPR particle size and the initial concentration of chromium ions. However, the influence of pH value on the Cr(Ⅵ) removal differs from that of the Cr(Ⅲ) removal. The Cr(Ⅵ) removal percentage decreases with increasing pH values, while the Cr(Ⅲ) removal percentage increases with increasing pH value. The adsorption kinetics of Cr(Ⅵ) and Cr(Ⅲ) well fits with pseudo-second-order model. Langmuir adsorption isotherm can well describe the adsorption phenomena of chromium ions with the maximum adsorption capacity of 0.567 mg/g for Cr(Ⅵ) and 3.446 mg/g for Cr(Ⅲ). Moreover, SPR reveals higher adsorption capacity for Cr(Ⅲ) than that for Cr(Ⅵ), which implies that SPR has more potential application for Cr(Ⅲ)-containing wastewater treatment than that for Cr(Ⅵ)-containing wastewater treatment.
基金Project(2004CB619204) supported by the National Key Fundamental Research and Development Program of ChinaProjects(50321402, 50574101) supported by the National Natural Science Foundation of China
文摘The effect of mineral particle size, pulp potential and category of oxidant on pyrite leaching was studied. The results show that a smaller mineral particle size leads to a higher leaching rate of pyrite, and the optimum result with pyrite leaching rate of 2.92% is obtained when mineral particle size is less than 0.037 mm. The pulp potential reflects the leaching process. The increase of pulp potential can improve pyrite leaching. The leaching rate and velocity of pyrite can be enhanced rapidly by adding strong oxidant. The kind and the method of adding oxidant have important effect on the pyrite leaching. Appropriate concentration of Fe3+ can enhance pyrite leaching but the precipitation generated by high concentration of ferric ion covers the surface of pyrites and prevents the leaching process. The leaching rate increases with the constant addition of H2O2.
基金Supported by the National Natural Science Foundation of China(32072352)。
文摘To improve heating uniformity and anthocyanin content of the blueberry pulp under microwave heating,the intermittent variable power microwave heating technology was introduced in the study.The effects of technology parameters in terms of high microwave intensity heating time,intermittent time,low microwave intensity and low microwave intensity heating time on the blueberry pulp quality parameters(heating uniformity,average moisture content,the highest temperature and anthocyanin content)were investigated by using the response surface method.The results showed that the longer heating time under different microwave intensities resulted in the poorer heating uniformity.The intermittent stage promoted heat and mass transfer within the pulp and reduced the temperature difference and moisture gradient within the pulp,which enhanced desired uniformity of temperature and moisture distribution before entering the low microwave intensity heating stage.Therefore,the longer the intermittent time,the greater the heating uniformity.The optimal parameters were developed as high microwave intensity of 4 W·g^(-1),high microwave intensity heating time of 9.86 min,intermittent time of 10 min,low microwave intensity of 2.2 W·g^(-1)and low microwave intensity heating time of 6 min.This research might provide guidance for microwave heating berry fruits.
文摘The stability was studied of the pigment in red pulp plum (Prunus salicina Lindl). The results showed that the pigment had a high resistance to heat and it′s stability seemed to be affected greatly by pH, and red pulp plum was suitable to be applied for making acid food. Several kinds of metallic ions including Na + 、Zn 2+ had an effect of reinforcement on its tone, however Fe 3+ had a disruptive effect. Sucrose had no undesirable effect, but vitamin C had a significant undesirable effect. Also the preservative of sodium benzoate had a definite undesirable effect. The pigment showed strong resistance to reducer sodium sulfite but was very weak in resistance to oxidizer hydrogen peroxide.