The reactive process for Al/SiC P composite was studied. SiC particles were in situ coated by the exothermal reaction of SiC Ti powder compact in Al melt bath, and easily incorporated into Al melt. The detailed study ...The reactive process for Al/SiC P composite was studied. SiC particles were in situ coated by the exothermal reaction of SiC Ti powder compact in Al melt bath, and easily incorporated into Al melt. The detailed study was carried out to understand the microstructures of the reacted SiC particles. During the reaction and consequent mixing, the successive processes include in situ coating on the reacted SiC particles, coat dissolution and SiC P splitting. The tensile mechanical properties of 6013Al/SiC P composite processed by the present technology showed that the reacted SiC P considerably reinforced the 6013 matrix.展开更多
Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry slid...Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry sliding wear tests were carried out using a block-on-ring wear machine to investigate the effect of applied load range of 10-220 N on the wear and friction behavior of these composites sliding against SAE 52100 grade bearing steel. Scanning electron microscopy(SEM) and energy-dispersive X-ray microanalysis(EDAX) were utilized to examine the morphologies of the worn surfaces in order to observe the wear characteristics and investigate the wear mechanism. The results show that the wear behavior of these composites is dependent on the silicon content in the matrix alloy and the applied load. Al-Si/15%SiCp composites with higher silicon content exhibit better wear resistance in the applied load range. Under lower loads, the major wear mechanisms are oxidation wear and abrasive wear for all tested composites. Under higher loads, severe adhesive wear becomes the main wear mechanisms for Al-7Si/15%SiCp and Al-13Si/15%SiCp composites, while Al-20Si/15%SiCp presents a compound wear mechanism, consisting of oxidation, abrasive wear and adhesion wear.展开更多
concentrating sulfuric acid by membrane distillation in a flat sheet direct contact membrane distillation device with a self made metal PTFE composite membrane has been studied. The effect of sulfuric acid concentrati...concentrating sulfuric acid by membrane distillation in a flat sheet direct contact membrane distillation device with a self made metal PTFE composite membrane has been studied. The effect of sulfuric acid concentration of feed, the flowrate and liquor temperature in high temperature side and low temperature side on the flux and separation efficiency is investigated. The stability of this composite membrane is also inspected. The experimental results show that the metal PTFE composite membrane can be used in membrane distillation, and its properties are very stable. It is feasible to concentrate sulfuric acid by membrane distillation with this membrane.展开更多
As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In thi...As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In this work,the radial gradient(RG)structure of PTFE/Al cylinders with three different PTFE morphologies(200 nm and 5μm particles and 5μm fiber)and content changes are prepared by 3D printing technology.The effect of radial gradient structure on the pressure output of PTFE/Al has been studied.Compared with the morphology change of PTFE,the change of component content in the gradient structure has an obvious effect on the pressure output of the PTFE/Al cylinder.Furthermore,the relationships of the morphology,content of PTFE and the combustion reaction of the PTFE/Al cylinder reveal that the cylinder shows a more complex flame propagation process than others.These results could provide a strategy to improve the combustion and pressure output of PTFE/Al.展开更多
The effects of magnesium/polytetrafluoroethylene(Mg/PTFE)pyrotechnic compositions on the coupled flow field and reignition mechanism are important aspects governing the perfommance and range of base bleed projectiles(...The effects of magnesium/polytetrafluoroethylene(Mg/PTFE)pyrotechnic compositions on the coupled flow field and reignition mechanism are important aspects governing the perfommance and range of base bleed projectiles(BBPs).Owing to a decrease in pressure and temperature when the BBP leaves the muzzle,rapid depressurization occurs,which extinguishes the base bleed propellant.The Mg/PTFE py-rotechnic composition pressed in the igniter of the base bleed unit(BBU)provides additional energy to the BBU via a chemical reaction.Thus,the extinguished base bleed propellant is reignited under the effect of high-temperature combustion gas jets from the igniter.In this study,a numerical analysis is conducted to evaluate the effects of PTFE and Mg granularity as well as Mg/PTFE pyrotechnic compo-sitions.Owing to the rapid depressurization,the temperature and pressure was found to decrease fordifferent Mg/PIFE pyrotechnic compositions.However,the depressurization time increased as the PTFE granularity increased,the Mg granularity decreased,and the Mg content increased.When the pressure in the combustion chamber of the BBU decreased to the atmospheric pressure,the combustion gas jets from the igniter expand upstream(rather than downstream).However,these combustion gas jets exhibit different axial and radial expansion characteristics depending on the pyrotechnic compositions used,The results show that the reignition delay time,ta,of the base bleed propellant was 377.608,94.27,387.243,523.966,and 221.094 ms for cases A-E,respectively.Therefore,it was concluded that the Mg/PTFE pyrotechnic composition of case B was the most beneficial for the reignition of the base bleed propellant,with the earliest addition of energy and mass to the BBP.展开更多
文摘The reactive process for Al/SiC P composite was studied. SiC particles were in situ coated by the exothermal reaction of SiC Ti powder compact in Al melt bath, and easily incorporated into Al melt. The detailed study was carried out to understand the microstructures of the reacted SiC particles. During the reaction and consequent mixing, the successive processes include in situ coating on the reacted SiC particles, coat dissolution and SiC P splitting. The tensile mechanical properties of 6013Al/SiC P composite processed by the present technology showed that the reacted SiC P considerably reinforced the 6013 matrix.
基金Project(2013GK3021)supported by the Science and Technology Plan of Hunan Province,ChinaProject supported by Young Teacher Growth Plan of Hunan University,China
文摘Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry sliding wear tests were carried out using a block-on-ring wear machine to investigate the effect of applied load range of 10-220 N on the wear and friction behavior of these composites sliding against SAE 52100 grade bearing steel. Scanning electron microscopy(SEM) and energy-dispersive X-ray microanalysis(EDAX) were utilized to examine the morphologies of the worn surfaces in order to observe the wear characteristics and investigate the wear mechanism. The results show that the wear behavior of these composites is dependent on the silicon content in the matrix alloy and the applied load. Al-Si/15%SiCp composites with higher silicon content exhibit better wear resistance in the applied load range. Under lower loads, the major wear mechanisms are oxidation wear and abrasive wear for all tested composites. Under higher loads, severe adhesive wear becomes the main wear mechanisms for Al-7Si/15%SiCp and Al-13Si/15%SiCp composites, while Al-20Si/15%SiCp presents a compound wear mechanism, consisting of oxidation, abrasive wear and adhesion wear.
文摘concentrating sulfuric acid by membrane distillation in a flat sheet direct contact membrane distillation device with a self made metal PTFE composite membrane has been studied. The effect of sulfuric acid concentration of feed, the flowrate and liquor temperature in high temperature side and low temperature side on the flux and separation efficiency is investigated. The stability of this composite membrane is also inspected. The experimental results show that the metal PTFE composite membrane can be used in membrane distillation, and its properties are very stable. It is feasible to concentrate sulfuric acid by membrane distillation with this membrane.
基金supported by the National Natural Science Foundation of China(Grant Nos.11872341 and 22075261)。
文摘As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In this work,the radial gradient(RG)structure of PTFE/Al cylinders with three different PTFE morphologies(200 nm and 5μm particles and 5μm fiber)and content changes are prepared by 3D printing technology.The effect of radial gradient structure on the pressure output of PTFE/Al has been studied.Compared with the morphology change of PTFE,the change of component content in the gradient structure has an obvious effect on the pressure output of the PTFE/Al cylinder.Furthermore,the relationships of the morphology,content of PTFE and the combustion reaction of the PTFE/Al cylinder reveal that the cylinder shows a more complex flame propagation process than others.These results could provide a strategy to improve the combustion and pressure output of PTFE/Al.
基金This work was supported by the Fundamental Research Funds for the Central Universities(No.30918011324).
文摘The effects of magnesium/polytetrafluoroethylene(Mg/PTFE)pyrotechnic compositions on the coupled flow field and reignition mechanism are important aspects governing the perfommance and range of base bleed projectiles(BBPs).Owing to a decrease in pressure and temperature when the BBP leaves the muzzle,rapid depressurization occurs,which extinguishes the base bleed propellant.The Mg/PTFE py-rotechnic composition pressed in the igniter of the base bleed unit(BBU)provides additional energy to the BBU via a chemical reaction.Thus,the extinguished base bleed propellant is reignited under the effect of high-temperature combustion gas jets from the igniter.In this study,a numerical analysis is conducted to evaluate the effects of PTFE and Mg granularity as well as Mg/PTFE pyrotechnic compo-sitions.Owing to the rapid depressurization,the temperature and pressure was found to decrease fordifferent Mg/PIFE pyrotechnic compositions.However,the depressurization time increased as the PTFE granularity increased,the Mg granularity decreased,and the Mg content increased.When the pressure in the combustion chamber of the BBU decreased to the atmospheric pressure,the combustion gas jets from the igniter expand upstream(rather than downstream).However,these combustion gas jets exhibit different axial and radial expansion characteristics depending on the pyrotechnic compositions used,The results show that the reignition delay time,ta,of the base bleed propellant was 377.608,94.27,387.243,523.966,and 221.094 ms for cases A-E,respectively.Therefore,it was concluded that the Mg/PTFE pyrotechnic composition of case B was the most beneficial for the reignition of the base bleed propellant,with the earliest addition of energy and mass to the BBP.
