Carbon fiber oxidized by KMnO4 was combined with ethylene vinyl acetate（EVA） copolymer,the obtained composite shows a fine stability of thermal cycles and nearly unchanged switching temperature under thermal（cycles...Carbon fiber oxidized by KMnO4 was combined with ethylene vinyl acetate（EVA） copolymer,the obtained composite shows a fine stability of thermal cycles and nearly unchanged switching temperature under thermal（cycles）,at the same time negative temperature coefficient（NTC） phenomenon is eliminated.Solvent-extraction method is used to examine the interaction between EVA and CF and insolublity with the gel structure were found.The crosslinking network in the gel adsorb CF intensely which makes CF disperse in EVA uniformly,orientate consistently,combine with EVA tightly and shows the elimination of NTC phenomenon.The（switching） temperature of the composite in the heating process is not identical with that of the composite in the cooling process absolutely,but the temperatures in the above two processes are consistent with the outset of melting temperature and the end of crystallization temperature respectively.展开更多
文摘为提高聚乙烯/炭黑导电复合材料的PTC性能,将高分子PTC复合材料热处理一定时间后,再分别通过淬火、慢火、空气冷却等方式进行处理,室温放置一定时间后进行电气性能测试.结果表明:慢火处理比淬火和空气冷却处理更能降低样品的电阻;在低于基体熔融温度下处理,可以使样品电阻降低;而在高于熔融温度下处理时,可以使电阻增大,但却缩短了样品的动作时间.在170℃加热后的样品经淬火冷却后,其动作时间缩短为28 s.
文摘Carbon fiber oxidized by KMnO4 was combined with ethylene vinyl acetate（EVA） copolymer,the obtained composite shows a fine stability of thermal cycles and nearly unchanged switching temperature under thermal（cycles）,at the same time negative temperature coefficient（NTC） phenomenon is eliminated.Solvent-extraction method is used to examine the interaction between EVA and CF and insolublity with the gel structure were found.The crosslinking network in the gel adsorb CF intensely which makes CF disperse in EVA uniformly,orientate consistently,combine with EVA tightly and shows the elimination of NTC phenomenon.The（switching） temperature of the composite in the heating process is not identical with that of the composite in the cooling process absolutely,but the temperatures in the above two processes are consistent with the outset of melting temperature and the end of crystallization temperature respectively.
