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“Zero‑Strain” NiNb_(2)O_(6) Fibers for All‑Climate Lithium Storage
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作者 Yan Zhao Qiang Yuan +5 位作者 Liting Yang Guisheng Liang Yifeng Cheng Limin Wu Chunfu Lin Renchao Che 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期348-360,共13页
Niobates are promising all-climate Li^(+)-storage anode material due to their fast charge transport,large specific capacities,and resistance to electrolyte reaction.However,their moderate unit-cellvolume expansion(gen... Niobates are promising all-climate Li^(+)-storage anode material due to their fast charge transport,large specific capacities,and resistance to electrolyte reaction.However,their moderate unit-cellvolume expansion(generally 5%–10%)during Li^(+)storage causes unsatisfactory long-term cyclability.Here,“zero-strain”NiNb_(2)O_(6) fibers are explored as a new anode material with comprehensively good electrochemical properties.During Li^(+)storage,the expansion of electrochemical inactive NiO_(6) octahedra almost fully offsets the shrinkage of active NbO_(6) octahedra through reversible O movement.Such superior volume-accommodation capability of the NiO_(6) layers guarantees the“zero-strain”behavior of NiNb_(2)O_(6) in a broad temperature range(0.53%//0.51%//0.74%at 25//−10//60℃),leading to the excellent cyclability of the NiNb_(2)O_(6) fibers(92.8%//99.2%//91.1%capacity retention after 1000//2000//1000 cycles at 10C and 25//−10//60℃).This NiNb_(2)O_(6) material further exhibits a large reversible capacity(300//184//318 mAh g−1 at 0.1C and 25//−10//60℃)and outstanding rate performance(10 to 0.5C capacity percentage of 64.3%//50.0%//65.4%at 25//−10//60℃).Therefore,the NiNb_(2)O_(6) fibers are especially suitable for large-capacity,fast-charging,long-life,and all-climate lithium-ion batteries. 展开更多
关键词 NiNb_(2)O_(6)porous fiber “Zero-strain”mechanism Electrochemical property Harsh-temperature operation Operando characterization
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Coaxial Wet Spinning of Boron Nitride Nanosheet‑Based Composite Fibers with Enhanced Thermal Conductivity and Mechanical Strength 被引量:1
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作者 Wenjiang Lu Qixuan Deng +3 位作者 Minsu Liu Baofu Ding Zhiyuan Xiong Ling Qiu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期126-138,共13页
Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric properties.However,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron ni... Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric properties.However,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron nitride,thereby limiting their performance in applications such as thermal management.In this study,we present a coaxial wet spinning approach for the fabrication of BNNSs/polymer composite fibers with high nanosheet orientation.The composite fibers were prepared using a superacid-based solvent system and showed a layered structure comprising an aramid core and an aramid/BNNSs sheath.Notably,the coaxial fibers exhibited significantly higher BNNSs alignment compared to uniaxial aramid/BNNSs fibers,primarily due to the additional compressive forces exerted at the core-sheath interface during the hot drawing process.With a BNNSs loading of 60 wt%,the resulting coaxial fibers showed exceptional properties,including an ultrahigh Herman orientation parameter of 0.81,thermal conductivity of 17.2 W m^(-1)K^(-1),and tensile strength of 192.5 MPa.These results surpassed those of uniaxial fibers and previously reported BNNSs composite fibers,making them highly suitable for applications such as wearable thermal management textiles.Our findings present a promising strategy for fabricating high-performance composite fibers based on BNNSs. 展开更多
关键词 Boron nitride nanosheets Coaxial fiber Interfacial compression Nanosheet aligning Wearable thermal management
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Controllable large-scale processing of temperature regulating sheath-core fibers with high-enthalpy for thermal management
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作者 Ziye Chen Zexu Hu +4 位作者 Shining Chen Senlong Yu Liping Zhu Hengxue Xiang Meifang Zhu 《Nano Materials Science》 EI CAS CSCD 2024年第3期337-344,共8页
Temperature regulating fibers(TRF_(s)) with high enthalpy and high form stability are the key factors for thermal management. However, the enthalpies of most TRFsare not high, and the preparation methods are still at ... Temperature regulating fibers(TRF_(s)) with high enthalpy and high form stability are the key factors for thermal management. However, the enthalpies of most TRFsare not high, and the preparation methods are still at the laboratory scale. It remains a great challenge to use industrial spinning equipment to achieve continuous processing of TRF_(s) with excellent thermal and mechanical properties. Here, polyamide 6(PA6) based TRF_(s) with a sheath-core structure were prepared by bicomponent melt-spinning. The sheath-core TRF(TRF_(sc)) are composed of PA6 as sheath and functional PA6 as core, which are filled with the shape stable phase change materials(ssPCM),dendritic silica@polyethylene glycol(SiO_(2)@PEG). With the aid of the sheath structure, the filling content of SiO_(2)@PEG can reach 30 %, so that the enthalpy of the TRF_(s) can be as high as 21.3 J/g. The ultra-high enthalpy guarantees the temperature regulation ability during the alternating process of cooling and heating. In hot environment, the temperature regulation time is 6.59 min, and the temperature difference is 12.93℃. In addition, the mechanical strength of the prepared TRF_(sc) reaches 2.26 cN/dtex, which can fully meet its application in the field of thermal management textiles and devices to manage the temperature regulation of the human body or precision equipment, etc. 展开更多
关键词 Thermal management Hybrid fibers Polyamides Bicomponent melt spinning Temperature regulating fibers
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Seeing at a distance with multicore fibers
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作者 Haogong Feng Xi Chen +4 位作者 Runze Zhu Yifeng Xiong Ye Chen Yanqing Lu Fei Xu 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第7期39-49,共11页
Images and videos provide a wealth of information for people in production and life.Although most digital information is transmitted via optical fiber,the image acquisition and transmission processes still rely heavil... Images and videos provide a wealth of information for people in production and life.Although most digital information is transmitted via optical fiber,the image acquisition and transmission processes still rely heavily on electronic circuits.The development of all-optical transmission networks and optical computing frameworks has pointed to the direction for the next generation of data transmission and information processing.Here,we propose a high-speed,low-cost,multiplexed parallel and one-piece all-fiber architecture for image acquisition,encoding,and transmission,called the Multicore Fiber Acquisition and Transmission Image System(MFAT).Based on different spatial and modal channels of the multicore fiber,fiber-coupled self-encoding,and digital aperture decoding technology,scenes can be observed directly from up to 1 km away.The expansion of capacity provides the possibility of parallel coded transmission of multimodal high-quality data.MFAT requires no additional signal transmitting and receiving equipment.The all-fiber processing saves the time traditionally spent on signal conversion and image pre-processing(compression,encoding,and modulation).Additionally,it provides an effective solution for 2D information acquisition and transmission tasks in extreme environments such as high temperatures and electromagnetic interference. 展开更多
关键词 long-distance fiber imaging image transmission parallel transmission all-optical encoding multicore fiber
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Piezoelectric fibers based on silk fibroin with excellent output performance
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作者 甄文强 陈杰 +1 位作者 范苏娜 张耀鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期128-135,共8页
The self-powered tissue engineering scaffold with good biocompatibility is of great significance for stimulating nerve cell growth.In this study,silk fibroin(SF)-based fibers with regulatable structure and piezoelectr... The self-powered tissue engineering scaffold with good biocompatibility is of great significance for stimulating nerve cell growth.In this study,silk fibroin(SF)-based fibers with regulatable structure and piezoelectric performance are fabricated by dry-spinning and post-treatment.The concentration of SF and calcium ion in spinning dope and the post-treatment affect the conformation transition and crystallinity of SF.As a result,the SF fibers exhibit high piezoelectric coefficient d_(33)(3.24 pm/V)and output voltage(~27 V).Furthermore,these piezoelectric fibers promote the growth of PC-12 cells,demonstrating the promising potential for nerve repair and other energy harvester. 展开更多
关键词 silk fibroin piezoelectric fiber DRY-SPINNING conformation transition
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Flexible coal-derived carbon fibers via electrospinning for self-standing lithium-ion battery anodes
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作者 Baolin Xing Weibo Meng +7 位作者 Hao Liang Weiwei Kang Huihui Zeng Chuanxiang Zhang Ishioma Laurene Egun Peng Li Yijun Cao Zhengfei Chen 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第12期1753-1763,共11页
A series of flexible and self-standing coal-derived carbon fibers(CCFs)were fabricated through electro-spinning coupled with carbonization using bituminous coal and polyacrylonitrile(PAN)as the carbon precursors.These... A series of flexible and self-standing coal-derived carbon fibers(CCFs)were fabricated through electro-spinning coupled with carbonization using bituminous coal and polyacrylonitrile(PAN)as the carbon precursors.These CCFs were utilized as free-standing lithium-ion battery(LIB)anodes.Optimizing car-bonization temperature reveals that the CCFs exhibit a one-dimensional solid linear structure with a uni-form distribution of graphite-like microcrystals.These fibers possess a dense structure and smooth surface,with averaging diameter from approximately 125.0 to 210.0 nm at carbonization temperatures ranging from 600 to 900℃.During electrospinning and carbonization,the aromatic rings enriched in bituminous coal crosslink with PAN chains,forming a robust three-dimensional(3D)framework.This 3D microstructure significantly enhances the flexibility and tensile strength of CCFs,while increasing the graphite-like sp^(2)microcrystalline carbon content,thus improving electrical conductivity.The CCFs carbonized at 700℃demonstrate an optimal balance of sp^(3)amorphous and sp^(2)graphite-like carbons.The average diameter of CCFs-700 is 177 nm and the specific surface area(SSA)is 7.2 m^(2)g^(-1).Additionally,the fibers contain oxygen-containing functional groups,as well as nitrogen-containing func-tional groups,including pyridinic nitrogen and pyrrolic nitrogen.Owing to its characteristics,the CCFs-700 showcases remarkable electrochemical performance,delivering a high reversible capacity of 631.4 mAh g^(-1).CCFs-700 also exhibit outstanding cycle stability,which retains approximately all of their first capacity(400.1 mAh g^(-1))after 120 cycles.This research offers an economical yet scalable approach for producing flexible and self-supporting anodes for LIBs that do not require current collectors,binders and conductive additives,thereby simplifying the electrode fabrication process. 展开更多
关键词 Lithium-ion batteries Coal-derived carbon fibers ELECTROSPINNING Flexible anode Electrochemical performance
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Paving continuous heat dissipation pathways for quantum dots in polymer with orangeinspired radially aligned UHMWPE fibers
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作者 Xuan Yang Xinfeng Zhang +3 位作者 Tianxu Zhang Linyi Xiang Bin Xie Xiaobing Luo 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第7期27-38,共12页
Thermal management of nanoscale quantum dots(QDs)in light-emitting devices is a long-lasting challenge.The existing heat transfer reinforcement solutions for QDs-polymer composite mainly rely on thermal-conductive fil... Thermal management of nanoscale quantum dots(QDs)in light-emitting devices is a long-lasting challenge.The existing heat transfer reinforcement solutions for QDs-polymer composite mainly rely on thermal-conductive fillers.However,this strategy failed to deliver the QDs’heat generation across a long distance,and the accumulated heat still causes considerable temperature rise of QDs-polymer composite,which eventually menaces the performance and reliability of lightemitting devices.Inspired by the radially aligned fruit fibers in oranges,we proposed to eliminate this heat dissipation challenge by establishing long-range ordered heat transfer pathways within the QDs-polymer composite.Ultrahigh molecular weight polyethylene fibers(UPEF)were radially aligned throughout the polymer matrix,thus facilitating massive efficient heat dissipation of the QDs.Under a UPEF filling fraction of 24.46 vol%,the in-plane thermal conductivity of QDs-radially aligned UPEF composite(QDs-RAPE)could reach 10.45 W m^(−1) K^(−1),which is the highest value of QDs-polymer composite reported so far.As a proof of concept,the QDs’working temperature can be reduced by 342.5℃ when illuminated by a highly concentrated laser diode(LD)under driving current of 1000 mA,thus improving their optical performance.This work may pave a new way for next generation high-power QDs lighting applications. 展开更多
关键词 quantum dots UHMWPE fibers radial alignment heat dissipation light-emitting devices
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Progress in the application of polymer fibers in solid electrolytes for lithium metal batteries
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作者 Junbao Kang Nanping Deng +1 位作者 Bowen Cheng Weimin Kang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期26-42,共17页
Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed... Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed solid-state electrolytes(SSEs)are still difficult to meet the practical application requirements of SSLMBs.In this review,based on the analysis of main problems and challenges faced by the development of SSEs,the ingenious application and latest progresses including specific suggestions of various polymer fibers and their membrane products in solving these issues are emphatically reviewed.Firstly,the inherent defects of inorganic and organic electrolytes are pointed out.Then,the application strategies of polymer fibers/fiber membranes in strengthening strength,reducing thickness,enhancing thermal stability,increasing the film formability,improving ion conductivity and optimizing interface stability are discussed in detail from two aspects of improving physical structure properties and electrochemical performances.Finally,the researches and development trends of the intelligent applications of high-performance polymer fibers in SSEs is prospected.This review intends to provide timely and important guidance for the design and development of polymer fiber composite SSEs for SSLMBs. 展开更多
关键词 Composite solide lectrolytes Polymer fibers Solid-state lithium metal batteries Solid-stateel ectrolytes Nanofiber membranes
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Thermal stress simulation analysis of aerospace optical fibers and connectors and related extensions to high-speed railway area
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作者 Feng Zhou Siyuan Yu +3 位作者 Zeren Gao Jie Kan Hao Xu Mengjie Liu 《High-Speed Railway》 2024年第2期122-132,共11页
Aerospace optical cables and fiber-optic connectors have numerous advantages(e.g.,low loss,wide transmission frequency band,large capacity,light weight,and excellent resistance to electromagnetic interference).They ca... Aerospace optical cables and fiber-optic connectors have numerous advantages(e.g.,low loss,wide transmission frequency band,large capacity,light weight,and excellent resistance to electromagnetic interference).They can achieve optical communication interconnections and high-speed bidirectional data transmission between optical terminals and photodetectors in space,ensuring the stability and reliability of data transmission during spacecraft operations in orbit.They have become essential components in high-speed networking and optically interconnected communications for spacecrafts.Thermal stress simulation analysis is important for evaluating the temperature stress concentration phenomenon resulting from temperature fluctuations,temperature gradients,and other factors in aerospace optical cables and connectors under the combined effects of extreme temperatures and vacuum environments.Considering this,advanced optical communication technology has been widely used in high-speed railway communication networks to transmit safe,stable and reliable signals,as high-speed railway optical communication in special areas with extreme climates,such as cold and high-temperature regions,requires high-reliability optical cables and connectors.Therefore,based on the finite element method,comprehensive comparisons were made between the thermal distributions of aerospace optical cables and J599III fiber optic connectors under different conditions,providing a theoretical basis for evaluating the performance of aerospace optical cables and connectors in space environments and meanwhile building a technical foundation for potential optical communication applications in the field of high-speed railways. 展开更多
关键词 Aerospace optical fiber Aerospace optic connector Simulation analysis
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Revolutionize fashion with waterless technology for wood-based cellulosic fibers
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《China Textile》 2024年第3期50-51,共2页
From producing fibers made from wood to becoming a global technology leader:take an inspiring journey in time through 80 years of innovation history.The journey began in 1890,when Emil Hamburger,a paper industrialist ... From producing fibers made from wood to becoming a global technology leader:take an inspiring journey in time through 80 years of innovation history.The journey began in 1890,when Emil Hamburger,a paper industrialist from Lower Austria,acquired the"Starlingermühle"in Lenzing(Austria).Today,the Lenzing Group is an internationally established company with nine production sites and nine sales and planning offices in more than 10 countries. 展开更多
关键词 fibers BECOMING TECHNOLOGY
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Preserving glacier mass:Cellulosic LENZING^(TM) fibers provide snow and ice protection solution
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《China Textile》 2024年第1期10-11,共2页
In field trials on Austrian glaciers,nonwovens made of ce u osic LENZING^(TM) fibers are being used to cover glacier mass.They are showing promising results and offer a sustainable solution for glacier protection.Nonw... In field trials on Austrian glaciers,nonwovens made of ce u osic LENZING^(TM) fibers are being used to cover glacier mass.They are showing promising results and offer a sustainable solution for glacier protection.Nonwovens containing fossilbased synthetic fibers might cause negative environmental consequences such as microplastics on glaciers.Geotextiles with ce u osic LENZINGTMfibers won the prestigious Swiss BIO TOP,an award for wood and material innovations.Geotextiles are already widely used to protect snow and ice on glaciers frommelting. 展开更多
关键词 fibers GLACIER NONWOVEN
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CONSTITUTIVE EQUATIONS OF METAL-CORE PIEZOELECTRIC FIBERS 被引量:3
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作者 边义祥 裘进浩 王鑫伟 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2008年第3期169-175,共7页
Metal-core piezoelectric fibers (MPFs) are one of the new type piezoelectric devices. To investigate the piezoelectricity and the mechanical properties of the piezoelectric fibers, the constitutive equations are est... Metal-core piezoelectric fibers (MPFs) are one of the new type piezoelectric devices. To investigate the piezoelectricity and the mechanical properties of the piezoelectric fibers, the constitutive equations are established. It can describe the response of piezoelectric fibers subject to an axial force and an external voltage. A cantilever bar subject to a tip axial force and an external voltage on the electrodes is considered. The internal energy density in thermodynamic equilibrium is obtained. The total internal energy is calculated by integrating over the entire volume of the bar. The generalized displacement of the tip axial force is the tip elongation δ, and the generalized displacement of the voltage is the electrical charge Q on the electrodes. In the established constitutive equations, the excitation (input) parameters are the axial force and the external voltage, the response (output) parameters are the tip elongation and the electric charge. And the response parameters are related to the excitation parameters by a 2× 2 piezoelectric matrix. Finally, two experiments using MPF as a sensor or an actuator are performed to verify the constitutive equations. And experimental results are compared with analytical ones. 展开更多
关键词 piezoelectric ceramics fibers constitutive equations metal core
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Fabrication and study of supercapacitor electrodes based on oxygen plasma functionalized carbon nanotube fibers 被引量:6
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作者 Paa Kwasi Adusei Seyram Gbordzoe +6 位作者 Sathya Narayan Kanakaraj Yu-Yun Hsieh Noe T.Alvarez Yanbo Fang Kevin Johnson Colin McConnell Vesselin Shanov 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第1期120-131,I0005,共13页
Dry-spun Carbon Nanotube(CNT)fibers were surface-modified by atmospheric pressure oxygen plasma functionalization using a well controlled and continuous process.The fibers were characterized by scanning electron micro... Dry-spun Carbon Nanotube(CNT)fibers were surface-modified by atmospheric pressure oxygen plasma functionalization using a well controlled and continuous process.The fibers were characterized by scanning electron microscopy(SEM),Raman spectroscopy,and X-ray Photoelectron Spectroscopy(XPS).It was found from the conducted electrochemical measurements that the functionalized fibers showed a 132.8% increase in specific capacitance compared to non-functionalized fibers.Dye-adsorption test and the obtained Randles-Sevcik plot demonstrated that the oxygen plasma functionalized fibers exhibited increased surface area.It was further established by Brunauer-Emmett-Teller(BET)measurements that the surface area of the CNT fibers was increased from 168.22 m^2/g to 208.01 m^2/g after plasma functionalization.The pore size distribution of the fibers was also altered by this processing.The improved electrochemical data was attributed to enhanced wettability,increased surface area,and the presence of oxygen functional groups,which promoted the capacitance of the fibers.Fiber supercapacitors were fabricated from the oxygen plasma functionalized CNT fiber electrodes using different electrolyte systems.The devices with functionalized electrodes exhibited excellent cyclic stability(93.2% after 4000 cycles),flexibility,bendability,and good energy densities.At 0.5 m A/cm^2,the EMIMBF4 device revealed a specific capacitance,which is 27% and 65%greater than the specific capacitances of devices using EMIMTFSI and H2SO4 electrolytes,respectively.The practiced in this work plasma surface processing can be employed in other applications where fibers,yarns,ribbons,and sheets need to be chemically modified. 展开更多
关键词 Oxygen plasma functionalization fiber supercapacitors CNT fiber electrodes Ionic liquid
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Activated carbon fibers with manganese dioxide coating for flexible fiber supercapacitors with high capacitive performance 被引量:3
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作者 Huifang Li Jiachen Liang +4 位作者 Huan Li Xiaoyu Zheng Ying Tao Zheng-Hong Huang Quan-Hong Yang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第4期95-100,共6页
Fiber supercapacitor(FSC)is a promising power source for wearable/stretchable electronics and high capacitive performance of FSCs is highly desirable for practice flexible applications.Here,we report a composite of ma... Fiber supercapacitor(FSC)is a promising power source for wearable/stretchable electronics and high capacitive performance of FSCs is highly desirable for practice flexible applications.Here,we report a composite of manganese dioxide(Mn O_2)and activated carbon fibers(ACFs)with high MnO_2mass loading and microporous structure(abbreviated as Mn O_2@ACF),which is used as a fiber electrode to produce a FSC with a high capacitive performance and a good flexibility.The MnO_2@ACF composite electrode in FSCs delivers an ultrahigh specific capacitance of 410 mF/cm^2at 0.1 mA/cm^2,corresponding to a high energy density of 36μWh/cm^2and high power density of 726μW/cm^2.Such high capacitive performance and simple fabrication method indicates that the Mn O_2@ACF composite is a very promising electrode material for flexible fiber supercapacitors. 展开更多
关键词 fiber SUPERCAPACITORS ACTIVATED carbon fibers MASS LOADING FLEXIBILITY
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Statistical Tensile Strength for High Strain Rate of Aramid and UHMWPE Fibers 被引量:4
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作者 YANG Bin XIONG Tao XIONG Jie 《材料工程》 EI CAS CSCD 北大核心 2006年第5期46-50,共5页
Dynamic tensile impact properties of aramid (Technora) and UHMWPE (DC851) fiber bundles were studied at two high strain rates by means of reflecting type Split Hopkinson Bar, and stress-strain curves of fiber yarns ... Dynamic tensile impact properties of aramid (Technora) and UHMWPE (DC851) fiber bundles were studied at two high strain rates by means of reflecting type Split Hopkinson Bar, and stress-strain curves of fiber yarns at different strain rates were obtained. Experimental results show that the initial elastic modulus, failure strength and unstable strain of aramid fiber yarns are strain rate insensitive, whereas the initial elastic modulus and unstable strain of UHMWPE fiber yarns are strain rate sensitive. A fiber-bundle statistical constitutive equation was used to describe the tensile behavior of aramid and UHMWPE fiber bundles at high strain rates. The good consistency between the simulated results and experimental data indicates that the modified double Weibull function can represent the tensile strength distribution of aramid and UHMWPE fibers and the method of extracting Weibull parameters from fiber bundles stress-strain data is valid. 展开更多
关键词 aramid fiber UHMWPE fiber impact behaviour statistical properties statistical constitutive equation
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Wet-spun poly(ionic liquid)-graphene hybrid fibers for high performance all-solid-state flexible supercapacitors 被引量:6
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作者 Karthikeyan Gopalsamy Qiuyan Yang +3 位作者 Shengying Cai Tieqi Huang Zhengguo Gao Chao Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第7期104-110,共7页
It is crucial to develop flexible and wearable electronic devices that have attracted tremendous interest due to their merits on compactness,flexibility and high capacitive properties.Herein we report the continuously... It is crucial to develop flexible and wearable electronic devices that have attracted tremendous interest due to their merits on compactness,flexibility and high capacitive properties.Herein we report the continuously ordered macroscopic poly(ionic liquid)-graphene fibers by wet spinning method via liquid crystal assembly for supercapacitor application.The fabricated all-solid-state supercapacitors exhibited a high areal capacitance(268.2 mF cm 2)and volumetric capacitance(204.6 F cm 3)with an outstanding areal energy density(9.31μWh cm-2)and volumetric energy density(8.28 mWh cm-3).The fiber supercapacitors demonstrated exceptional cycle life for straight electrodes of about 10,000 cycles(94.2%capacitance retention)and flexibility at different angles(0°,45°,90°,180°)along with a good flexible cycling stability after 6000 cycles(92.7%capacitance retention).To date,such a novel poly(ionic liquid)-graphene fiber supercapacitors would be a new platform in real-time flexible electronics. 展开更多
关键词 GRAPHENE fiber Poly(ionic liquid) WET spinning SUPERCAPACITORS Flexibility
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Preparation of amidoxime-based PE/PP fibers for extraction of uranium from aqueous solution 被引量:6
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作者 Xiao Xu Xiao-Jun Ding +7 位作者 Jun-Xuan Ao Rong Li Zhe Xing Xi-Yan Liu Xiao-Jing Guo Guo-Zhong Wu Hong-Juan Ma Xiao-Yan Zhao 《Nuclear Science and Techniques》 SCIE CAS CSCD 2019年第2期39-51,共13页
A novel amidoxime-based fibrous adsorbent,denoted as PE/PP-g-(PAAc-co-PAO), was prepared by preirradiation grafting of acrylic acid and acrylonitrile onto polyethylene-coated polypropylene skin-core(PE/PP)fibers using... A novel amidoxime-based fibrous adsorbent,denoted as PE/PP-g-(PAAc-co-PAO), was prepared by preirradiation grafting of acrylic acid and acrylonitrile onto polyethylene-coated polypropylene skin-core(PE/PP)fibers using 60 Co γ-ray irradiation, followed by amidoximation. The original and modified PE/PP fibers were characterized by a series of characterization methods to demonstrate the attachment of amidoxime groups onto the PE/PP fibers. Breaking strength tests confirmed that the fibrous adsorbent could maintain good mechanical properties. The adsorption capacity of the PE/PP-g-(PAAc-coPAO) fibers was investigated in simulated seawater with an initial uranium concentration of 330 μg/L. The uranium adsorption capacity was 2.27 mg/g-adsorbent after 24 h in simulated seawater, and the equilibrium data were well described by the Freundlich isotherm model. The PE/PP-g-(PAAc-co-PAO) adsorbent exhibited good regeneration and recyclability during five adsorption-desorption cycles.The adsorption test was also performed in simulated radioactive effluents with uranium concentrations of 10 and100 μg/L. The effect of the pH value on the adsorption capacity was also studied. At a very low initial concentration 10 μg/L solution, the PE/PP-g-(PAAc-co-PAO)fiber could remove as much as 93.0% of the uranium, and up to 71.2% of the uranium in the simulated radioactive effluent. These results indicated that the PE/PP-g-(PAAcco-PAO) adsorbent could be used in radioactive effluents over a wide range of pH values. Therefore, the PE/PP-g-(PAAc-co-PAO) fibers, with their high uranium selectivity,good regeneration and recyclability,good mechanical properties, and low cost, are promising adsorbents for extracting uranium from aqueous solutions. 展开更多
关键词 AMIDOXIME GROUPS PRE-IRRADIATION PEcoated PP skin-core fiber Adsorption URANIUM
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Effect of radiation-induced mean wavelength shift in optical fibers on the scale factor of an interferometric fiber optic gyroscope at a wavelength of 1300 nm 被引量:7
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作者 金靖 王学勤 +1 位作者 林松 宋凝芳 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第9期366-372,共7页
In order to analyze the effect of wavelength-dependent radiation-induced attenuation (RIA) on the mean trans- mission wavelength in optical fiber and the scale factor of interferometric fiber optic gyroscopes (IFOG... In order to analyze the effect of wavelength-dependent radiation-induced attenuation (RIA) on the mean trans- mission wavelength in optical fiber and the scale factor of interferometric fiber optic gyroscopes (IFOGs), three types of polarization-maintaining (PM) fibers are tested by using a 60Co γ-radiation source. The observed different mean wave- length shift (MWS) behaviors for different fibers are interpreted by color-center theory involving dose rate-dependent absorption bands in ultraviolet and visible ranges and total dose-dependent near-infrared absorption bands. To evaluate the mean wavelength variation in a fiber coil and the induced scale factor change for space-borne IFOGs under low radiation doses in a space environment, the influence of dose rate on the mean wavelength is investigated by testing four germanium (Ge) doped fibers and two germanium-phosphorus (Ge-P) codoped fibers irradiated at different dose rates. Experimental results indicate that the Ge-doped fibers show the least mean wavelength shift during irradiation and their mean wavelength of optical signal transmission in fibers will shift to a shorter wavelength in a low-dose-rate radiation environment. Finally, the change in the scale factor of IFOG resulting from the mean wavelength shift is estimated and tested, and it is found that the significant radiation-induced scale factor variation must be considered during the design of space-borne IFOGs. 展开更多
关键词 space radiation fiber optic gyroscope scale factor mean wavelength
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In-situ growth of vertically aligned nickel cobalt sulfide nanowires on carbon nanotube fibers for high capacitance all-solid-state asymmetric fiber-supercapacitors 被引量:5
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作者 Na Liu Zhenghui Pan +6 位作者 Xiaoyu Ding Jie Yang Guoguang Xu Linge Li Qi Wang Meinan Liu Yuegang Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第2期209-215,共7页
Fiber-supercapacitors(FSCs)are promising power sources for miniature portable and wearable electronic devices.However,the development and practical application of these FSCs have been severely hindered by their low vo... Fiber-supercapacitors(FSCs)are promising power sources for miniature portable and wearable electronic devices.However,the development and practical application of these FSCs have been severely hindered by their low volumetric capacitance and narrow operating voltage.In this work,vertically aligned nickel cobalt sulfide(Ni Co2S4)nanowires grown on carbon nanotube(CNT)fibers were achieved through an in-situ two-step hydrothermal reaction method.The as-prepared Ni Co2S4@CNT fiber electrode exhibits a high volumetric capacitance of 2332 F cm-3,benefiting from its superior electric conductivity,large surface area,and rich Faradic redox reaction sites.Furthermore,a Ni Co2S4@CNT//VN@CNT(vanadium nitride nanosheets grown on CNT fibers)asymmetric fiber-supercapacitor(AFSC)was successfully fabricated.The device exhibits an operating voltage up to 1.6 V and a high volumetric energy density of 30.64m Wh cm-3.The device also possesses outstanding flexibility as evidenced by no obvious performance degradation under various bending angles and maintaining high capacitance after 5000 bending cycles.This work promotes the practical application of flexible wearable energy-storage devices. 展开更多
关键词 fiber-supercapacitors Volumetric energy density NICKEL COBALT SULFIDE NANOWIRES Carbon nanotube fiber Wearable energy storage devices
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Stabilizing and reinforcing effects of different fibers on asphalt mortar performance 被引量:3
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作者 Meng-Meng Wu Rui Li +3 位作者 Yu-Zhen Zhang Liang Fan Yu-Chao Lv Jian-Ming Wei 《Petroleum Science》 SCIE CAS CSCD 2015年第1期189-196,共8页
Physical properties of different fibers (mineral, cellulose, or carbon fiber) and their stabilizing and reinforcing effects on asphalt mortar performance were studied. Scanning electron microscopy was used to study ... Physical properties of different fibers (mineral, cellulose, or carbon fiber) and their stabilizing and reinforcing effects on asphalt mortar performance were studied. Scanning electron microscopy was used to study the effect of fiber's microstructure on asphalt mortar's performance. Laboratory tests of mesh-basket draindown and oven heating were designed and performed to evaluate the fibers' asphalt absorption and thermostability. A cone penetration test was used to study the flow resistance of fiber-modified asphalt mortar. Results showed that fiber can form a three-dimensional network structure in asphalt, and this network can be retained at high temperature. This network of fibers favors the formation of a thick coating of mastic without asphalt draining down. Cellulose fiber possessed a greater effect on asphalt absorption and sta- bilization than did the other fibers (mineral and carbon fiber). A dynamic shear rheometer was used to evaluate their rheological properties and rut resistance. Results indicated that fiber can effectively improve the rut and flow resistance of asphalt mortar. However, the bending beam rheometer results demonstrated that the addition of fiber had negative effects on the creep stiffness and creep rate of asphalt mortar. 展开更多
关键词 fiber Asphalt mortar SEM RHEOLOGY Mechanical properties
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