The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modifie...The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modified silicon gel as the substrate, a kind of novel inorganic-organic hybrid material with the polymer metal complex was synthesized. The result of ESR indicates that the inorganic/organic hybrid material with the polymer metal complex based on silicon gel possesses well paramagnetis.展开更多
Mono-hydroxyl terminated polycaprolactone(PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization(ROP) of ε-caprolactone(ε-CL) initiated by methanol,and subsequently converted to bromine ended PCL by...Mono-hydroxyl terminated polycaprolactone(PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization(ROP) of ε-caprolactone(ε-CL) initiated by methanol,and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide.The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization(ATRP) of glycidyl methacrylate(GMA) with CuCl/2,2-bipyridine(bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.展开更多
A new approach to the synthesis of dendrimer-like star polymer,[(PMMA)2PSt]4,was presented via the combination of atom transfer radical polymerization(ATRP) and ckick chemistry.Firstly four-arm bromine-terminated poly...A new approach to the synthesis of dendrimer-like star polymer,[(PMMA)2PSt]4,was presented via the combination of atom transfer radical polymerization(ATRP) and ckick chemistry.Firstly four-arm bromine-terminated polystyrene(PSt-Br)4 was obtained from ATRP of styrene using pentaerythritol tetra(2-bromoisobutyrate) as an initiator,and the(PSt-Br)4 was efficiently converted to the azido-terminated polymers[(PSt-N3)4] through the bromine substitution reaction with sodium azide.Furthermore,the(PSt-N3)4 reacted with propargyl 2,2-bis[2-(bromomethyl)propionato]propionyrate via a click reaction,1,3-dipolar cycloaddition reaction,and the polymer[(PSt-Br2)4] containing eight end-bromine was obtained.The(PSt-Br2)4 could further serve as a macroinitiator for the ATRP of methyl methacrylate(MMA).Accordingly,the dendrimer-like star polymer,[(PMMA)2PSt]4 was successfully prepared.The structure of [(PMMA)2PSt]4 was characterized via IR,1H NMR,GPC and DSC.展开更多
文摘The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modified silicon gel as the substrate, a kind of novel inorganic-organic hybrid material with the polymer metal complex was synthesized. The result of ESR indicates that the inorganic/organic hybrid material with the polymer metal complex based on silicon gel possesses well paramagnetis.
文摘Mono-hydroxyl terminated polycaprolactone(PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization(ROP) of ε-caprolactone(ε-CL) initiated by methanol,and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide.The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization(ATRP) of glycidyl methacrylate(GMA) with CuCl/2,2-bipyridine(bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.
文摘A new approach to the synthesis of dendrimer-like star polymer,[(PMMA)2PSt]4,was presented via the combination of atom transfer radical polymerization(ATRP) and ckick chemistry.Firstly four-arm bromine-terminated polystyrene(PSt-Br)4 was obtained from ATRP of styrene using pentaerythritol tetra(2-bromoisobutyrate) as an initiator,and the(PSt-Br)4 was efficiently converted to the azido-terminated polymers[(PSt-N3)4] through the bromine substitution reaction with sodium azide.Furthermore,the(PSt-N3)4 reacted with propargyl 2,2-bis[2-(bromomethyl)propionato]propionyrate via a click reaction,1,3-dipolar cycloaddition reaction,and the polymer[(PSt-Br2)4] containing eight end-bromine was obtained.The(PSt-Br2)4 could further serve as a macroinitiator for the ATRP of methyl methacrylate(MMA).Accordingly,the dendrimer-like star polymer,[(PMMA)2PSt]4 was successfully prepared.The structure of [(PMMA)2PSt]4 was characterized via IR,1H NMR,GPC and DSC.
基金Foundation item：Supported by the National Natural Science Foundation of China（20134020）,Science Research Fund of the Chinese Ministry of Education（104005）,Science Research Fund of Shandong Provincial Education Department of China（J05D11）Science Research Fund of Shandong Jiaotong University（Z200617）
