The activities and stabilities of the polymer-bound palladium complexes fordecarbonyl-arylation were investigated in this paper.It was found that the activities ofpolymer-bound complexes are comparable to those of the...The activities and stabilities of the polymer-bound palladium complexes fordecarbonyl-arylation were investigated in this paper.It was found that the activities ofpolymer-bound complexes are comparable to those of their homogeneous counterparts.Among the catalysts examined,the sulfur-containing polymer-bound palladium complexeshave high activity and better stability than the phosphine-,amine-and nitrile-containingpolymerie palladium catalysts.Experimental work was undertaken to evaluate the possibleside reactions.The factors which caused the catalyst deactivation were discussed and the in-flucnce of experimental parameters on the reaction was studied as well.展开更多
基金This work was supported by the Science Foundation of Chinese Academy of sciences.
文摘The activities and stabilities of the polymer-bound palladium complexes fordecarbonyl-arylation were investigated in this paper.It was found that the activities ofpolymer-bound complexes are comparable to those of their homogeneous counterparts.Among the catalysts examined,the sulfur-containing polymer-bound palladium complexeshave high activity and better stability than the phosphine-,amine-and nitrile-containingpolymerie palladium catalysts.Experimental work was undertaken to evaluate the possibleside reactions.The factors which caused the catalyst deactivation were discussed and the in-flucnce of experimental parameters on the reaction was studied as well.
