Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,viole...Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.展开更多
To investigate the performance of organic and inorganic phosphorous on growth of Roselle (Hibiscus sabdariffa L.), an experiment was carried out at Newly Developmental Farm (NDF), Horticulture Section, the univers...To investigate the performance of organic and inorganic phosphorous on growth of Roselle (Hibiscus sabdariffa L.), an experiment was carried out at Newly Developmental Farm (NDF), Horticulture Section, the university of Agriculture Peshawar, Pakistan, during 2012. The experiment was laid out in a Randomized Complete Block Design (RCBD) with split plot arrangement and replicated three times. The chemical fertilizer Single Super Phosphate (SSP) was used as inorganic source of phosphorus, while Organic Phosphate (OP) from organic product produced by Niha corporation containing 20% organic mineralized P205, was used as the source of organic phosphorous. Both the sources of fertilizer were applied at the rate of 10, 20, 30 40 and 50 kg. hm2 and control. The statistical analysis of data revealed that both the sources and levels of phosphorus significantly affected most of the growth parameters of Roselle except germination percentage and survival percentage. Plant height (112.09 era), numbers of leave plant1 (177.87), numbers of branch plant1 (4.08), leaf areas (126.60 cm2), days to flowering (142.83), fresh flower weight (2.56 g), fresh calyx weight (1.70 g), dry calyx weight (0.43 g), numbers of calyces (94.10), numbers of root plant-1 (11.03), root length (22.67 cm) and root weight (27.50 g) were observed in plants fertilized with organic source of phosphorous. Phosphorous levels significantly affected all of the parameters except germination percentage and survival percentage. The maximum plant height (124.39 cm), numbers of branches (5.32), numbers of leave plantl (204.89), leaf areas (148.14 cm2), fresh flower weight (3.32 g), fresh calyx weight (2.04 g), dry calyx weight (0.51 g), numbers of calyces (105.30), numbers of root plant-1 (12.78), root length (24.50 cm) and root weight (29.94 g) were observed in plants fertilized with 40 kg. hm-2 phosphorous and the maximum numbers of days to flowering (148.17) were observed in the control plants. It was concluded from the experimental results that organic phosphorous at the rate 40 kg. hm2 would be used for better production of Roselle under agro-climatic condition of Peshawar.展开更多
Activated carbon was prepared from bamboo by mechanochemical process with phosphoric acid as activating agent.The effects of milling time on the adsorption property and porous structure of the obtained activated car-b...Activated carbon was prepared from bamboo by mechanochemical process with phosphoric acid as activating agent.The effects of milling time on the adsorption property and porous structure of the obtained activated car-bon were discussed.The results showed that phosphoric acid activation assisted by mechanochemical process can slightly improve the adsorption performance of the prepared activated carbon.The iodine,methylene blue adsorption value and the specific surface area of the prepared activated carbons increased from 840.16 mg/g,168 mg/g and 1229.246 m/g to 947.51 mg/g,195 mg/g,and 1265.373 m2/g,respectively.Compared with conventional phosphoric acid activation,the activated carbon produced by mechanochemical process has greater adsorption capacity.展开更多
基金National Key Research and Development Program of China(2021YFB3500501)。
文摘Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.
文摘To investigate the performance of organic and inorganic phosphorous on growth of Roselle (Hibiscus sabdariffa L.), an experiment was carried out at Newly Developmental Farm (NDF), Horticulture Section, the university of Agriculture Peshawar, Pakistan, during 2012. The experiment was laid out in a Randomized Complete Block Design (RCBD) with split plot arrangement and replicated three times. The chemical fertilizer Single Super Phosphate (SSP) was used as inorganic source of phosphorus, while Organic Phosphate (OP) from organic product produced by Niha corporation containing 20% organic mineralized P205, was used as the source of organic phosphorous. Both the sources of fertilizer were applied at the rate of 10, 20, 30 40 and 50 kg. hm2 and control. The statistical analysis of data revealed that both the sources and levels of phosphorus significantly affected most of the growth parameters of Roselle except germination percentage and survival percentage. Plant height (112.09 era), numbers of leave plant1 (177.87), numbers of branch plant1 (4.08), leaf areas (126.60 cm2), days to flowering (142.83), fresh flower weight (2.56 g), fresh calyx weight (1.70 g), dry calyx weight (0.43 g), numbers of calyces (94.10), numbers of root plant-1 (11.03), root length (22.67 cm) and root weight (27.50 g) were observed in plants fertilized with organic source of phosphorous. Phosphorous levels significantly affected all of the parameters except germination percentage and survival percentage. The maximum plant height (124.39 cm), numbers of branches (5.32), numbers of leave plantl (204.89), leaf areas (148.14 cm2), fresh flower weight (3.32 g), fresh calyx weight (2.04 g), dry calyx weight (0.51 g), numbers of calyces (105.30), numbers of root plant-1 (12.78), root length (24.50 cm) and root weight (29.94 g) were observed in plants fertilized with 40 kg. hm-2 phosphorous and the maximum numbers of days to flowering (148.17) were observed in the control plants. It was concluded from the experimental results that organic phosphorous at the rate 40 kg. hm2 would be used for better production of Roselle under agro-climatic condition of Peshawar.
文摘Activated carbon was prepared from bamboo by mechanochemical process with phosphoric acid as activating agent.The effects of milling time on the adsorption property and porous structure of the obtained activated car-bon were discussed.The results showed that phosphoric acid activation assisted by mechanochemical process can slightly improve the adsorption performance of the prepared activated carbon.The iodine,methylene blue adsorption value and the specific surface area of the prepared activated carbons increased from 840.16 mg/g,168 mg/g and 1229.246 m/g to 947.51 mg/g,195 mg/g,and 1265.373 m2/g,respectively.Compared with conventional phosphoric acid activation,the activated carbon produced by mechanochemical process has greater adsorption capacity.