对以邻硝基甲苯为主要原料,经锌粉 氯化铵溶液还原、氯甲酸甲酯酰基化、硫酸二甲酯甲基化合成N 甲氧基 N 2 甲基苯基氨基甲酸甲酯的工艺路线进行了研究.重点考察了还原反应中溶剂种类、还原温度对反应的影响以及N 羟基 N 2 甲苯氨基甲...对以邻硝基甲苯为主要原料,经锌粉 氯化铵溶液还原、氯甲酸甲酯酰基化、硫酸二甲酯甲基化合成N 甲氧基 N 2 甲基苯基氨基甲酸甲酯的工艺路线进行了研究.重点考察了还原反应中溶剂种类、还原温度对反应的影响以及N 羟基 N 2 甲苯氨基甲酸甲酯的纯化方法.N 羟基 N 2 甲苯基氨基甲酸甲酯、N 甲氧基 N 2 甲苯基氨基甲酸甲酯均经MS,1HNMR确认.展开更多
Two kinds of organic-inorganic comp osite luminescent material were pre pared through sol-gel route,by dopi ng o-amino-benzoic acid(ABA)or N-phenylanthranilic acid(N-PA)into SiO 2 xerogels.Fluorescence properties and ...Two kinds of organic-inorganic comp osite luminescent material were pre pared through sol-gel route,by dopi ng o-amino-benzoic acid(ABA)or N-phenylanthranilic acid(N-PA)into SiO 2 xerogels.Fluorescence properties and thermal properties of ABA and N-PA in SiO 2 xerogels were studied.The relation ship between the fluorescence properties and the preparative cond ition was also studied.The results s howed that the ABA was easy to form dim er of non-luminescence among the molec ules.The quenching concentration o f the ABA was obviously increased owi ng to the shield of silica network.The f luorescence intensity of the composite material prepared at the acid con dition was decreased,and a red shift for the fluorescence peak appeared.With th e increasing of the pH value,the flu-orescence peak blue shifted and the i ntensity was increased.However,th e fluorescent intensity of N-PA /SiO 2 was increasing due to the concentration of N-PA was increased.The thermal stability of ABA and N-PA in the composite material was also improved.But,when the temperature continued to incre ase,the collapse of the silica netwo rk made the organic molecules escape fr om the pore of the silica network,the decomposition of escaping molecule s decreased the intensity of emission spectrum.展开更多
The halogen substituted anthranilic acid(1) was condensed with acetic anhydride to give halogen substituted 3 methyl 1H 2,4 benoxazin 1 one(2), which was further condensed with hydrazide (3) to give twelve novel halog...The halogen substituted anthranilic acid(1) was condensed with acetic anhydride to give halogen substituted 3 methyl 1H 2,4 benoxazin 1 one(2), which was further condensed with hydrazide (3) to give twelve novel halogen substituted 2 (3 methyl 5 substitued 4H 1,2,4 triazol 4 yl) benzoic acid. All compounds synthesized were identified by 1H NMR and elemental analyses.展开更多
文摘对以邻硝基甲苯为主要原料,经锌粉 氯化铵溶液还原、氯甲酸甲酯酰基化、硫酸二甲酯甲基化合成N 甲氧基 N 2 甲基苯基氨基甲酸甲酯的工艺路线进行了研究.重点考察了还原反应中溶剂种类、还原温度对反应的影响以及N 羟基 N 2 甲苯氨基甲酸甲酯的纯化方法.N 羟基 N 2 甲苯基氨基甲酸甲酯、N 甲氧基 N 2 甲苯基氨基甲酸甲酯均经MS,1HNMR确认.
文摘Two kinds of organic-inorganic comp osite luminescent material were pre pared through sol-gel route,by dopi ng o-amino-benzoic acid(ABA)or N-phenylanthranilic acid(N-PA)into SiO 2 xerogels.Fluorescence properties and thermal properties of ABA and N-PA in SiO 2 xerogels were studied.The relation ship between the fluorescence properties and the preparative cond ition was also studied.The results s howed that the ABA was easy to form dim er of non-luminescence among the molec ules.The quenching concentration o f the ABA was obviously increased owi ng to the shield of silica network.The f luorescence intensity of the composite material prepared at the acid con dition was decreased,and a red shift for the fluorescence peak appeared.With th e increasing of the pH value,the flu-orescence peak blue shifted and the i ntensity was increased.However,th e fluorescent intensity of N-PA /SiO 2 was increasing due to the concentration of N-PA was increased.The thermal stability of ABA and N-PA in the composite material was also improved.But,when the temperature continued to incre ase,the collapse of the silica netwo rk made the organic molecules escape fr om the pore of the silica network,the decomposition of escaping molecule s decreased the intensity of emission spectrum.
文摘The halogen substituted anthranilic acid(1) was condensed with acetic anhydride to give halogen substituted 3 methyl 1H 2,4 benoxazin 1 one(2), which was further condensed with hydrazide (3) to give twelve novel halogen substituted 2 (3 methyl 5 substitued 4H 1,2,4 triazol 4 yl) benzoic acid. All compounds synthesized were identified by 1H NMR and elemental analyses.
