The title compound N,N′ ditosyl 3 methoxyimino 1,5 diaza cyclooctane(4) has been prepared by two methods,the reactions of all steps are carried out under very moderate conditions and the overall yield is high.The str...The title compound N,N′ ditosyl 3 methoxyimino 1,5 diaza cyclooctane(4) has been prepared by two methods,the reactions of all steps are carried out under very moderate conditions and the overall yield is high.The structures of the new compounds 2,3,4 are characterized by elemental analysis,IR, 1H NMR and MS spectroscopy.展开更多
The complex UO2(DDPEZ)(NO3)2 has been prepared and characterized by IR spectroscopy and XPS spectra. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belongs to Triclinic syst...The complex UO2(DDPEZ)(NO3)2 has been prepared and characterized by IR spectroscopy and XPS spectra. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belongs to Triclinic system and space group P1, with cell parameters: a=0.664 2(3) nm, b=0.805 0(2) nm, c=1.515 6(5) nm, α=104.39(2)°, β=91.13(3)°, γ=94.84(3)°, and V=0.781 4(5) nm3, Z=2, Dc=1 676 kg·m-3, μ(Mo Kα)=0.071 073 nm, F(000)=390, final R=0.037 9 and wR=0.091 7 for observed reflections[I>2σ(I)]. The results indicated that uranyl ion is coordinated with six oxygen atoms, four of them from two nitrate groups and two from carbonyl groups of different organic ligands. CCDC: 284452.展开更多
The α-acetyl ketene dithioacetals 2, which bear various alkylthio groups, are a kind of important intermediates in organic synthesis. In this paper, dithioacetals 2 were prepared in very high yields (90%—100%) via t...The α-acetyl ketene dithioacetals 2, which bear various alkylthio groups, are a kind of important intermediates in organic synthesis. In this paper, dithioacetals 2 were prepared in very high yields (90%—100%) via the deacetylation reaction of the corresponding α,α-diacetyl ketene dithioacetals 1 in the presence of concentrated sulfuric acid. This reaction involves an %in-situ% electrophilic addition-deacetylation mechanism and shows the nucleophilicity of the α-carbon atom in α-oxo ketenedithioacetals. Meanwhile, when the reaction time was prolonged to 22—25 h, the β-keto thiolesters 3a and 3c were produced in good yields.展开更多
Nine N,N diacyl adipic dihydrazides were synthesized. The compounds all exhibited remarkable inhibiting effects on the aging of polypropylene(PP) contacted with copper and their metal deactivation activity was incr...Nine N,N diacyl adipic dihydrazides were synthesized. The compounds all exhibited remarkable inhibiting effects on the aging of polypropylene(PP) contacted with copper and their metal deactivation activity was increased with increase in their molecular weight. They didnt reduce the mechanical property of PP. The most effective were N,N dihexanoyl adipic dihydrazide and N,N dioctanoyl adipic dihydrazide. At 150 ℃ their aging periods for PP film were over 510 hours.展开更多
文摘The title compound N,N′ ditosyl 3 methoxyimino 1,5 diaza cyclooctane(4) has been prepared by two methods,the reactions of all steps are carried out under very moderate conditions and the overall yield is high.The structures of the new compounds 2,3,4 are characterized by elemental analysis,IR, 1H NMR and MS spectroscopy.
文摘The complex UO2(DDPEZ)(NO3)2 has been prepared and characterized by IR spectroscopy and XPS spectra. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belongs to Triclinic system and space group P1, with cell parameters: a=0.664 2(3) nm, b=0.805 0(2) nm, c=1.515 6(5) nm, α=104.39(2)°, β=91.13(3)°, γ=94.84(3)°, and V=0.781 4(5) nm3, Z=2, Dc=1 676 kg·m-3, μ(Mo Kα)=0.071 073 nm, F(000)=390, final R=0.037 9 and wR=0.091 7 for observed reflections[I>2σ(I)]. The results indicated that uranyl ion is coordinated with six oxygen atoms, four of them from two nitrate groups and two from carbonyl groups of different organic ligands. CCDC: 284452.
文摘The α-acetyl ketene dithioacetals 2, which bear various alkylthio groups, are a kind of important intermediates in organic synthesis. In this paper, dithioacetals 2 were prepared in very high yields (90%—100%) via the deacetylation reaction of the corresponding α,α-diacetyl ketene dithioacetals 1 in the presence of concentrated sulfuric acid. This reaction involves an %in-situ% electrophilic addition-deacetylation mechanism and shows the nucleophilicity of the α-carbon atom in α-oxo ketenedithioacetals. Meanwhile, when the reaction time was prolonged to 22—25 h, the β-keto thiolesters 3a and 3c were produced in good yields.
文摘Nine N,N diacyl adipic dihydrazides were synthesized. The compounds all exhibited remarkable inhibiting effects on the aging of polypropylene(PP) contacted with copper and their metal deactivation activity was increased with increase in their molecular weight. They didnt reduce the mechanical property of PP. The most effective were N,N dihexanoyl adipic dihydrazide and N,N dioctanoyl adipic dihydrazide. At 150 ℃ their aging periods for PP film were over 510 hours.
