LiNbO 3crystal possesses electro optic effect and nonlinear optical effect.Bec ars e it is easy to generate photo damage(photorefractive) for LiNbO 3.This limits i ts application in some fields.When doping 6mol% ZnO o...LiNbO 3crystal possesses electro optic effect and nonlinear optical effect.Bec ars e it is easy to generate photo damage(photorefractive) for LiNbO 3.This limits i ts application in some fields.When doping 6mol% ZnO or 5mol% MgO in LiNbO 3 cry stal to grow Zn∶LiNbO 3 or Mg∶LiNbO 3 crystal,the photo damage resistance ab ility fo these two crystals is two orders of magnitude higher than that of LiNbO 3.We doped 3mol% ZnO and 3mol% MgO to grow Zn∶Mg∶LiNbO 3 crystal and used Fourier spectrophotometer to measure the infrared transmission spectra.The waven umber range to measure the OH - stretched vibration transmission spectra of Zn ∶LiNbO 3,Mg∶LiNbO 3 and Zn∶Mg∶LiNbO 3 crystal is 3200 4000cm -1 .The measurement result is that the OH - stretched vibration absorption peak of Zn( 6mol%):LiNbO 3,Mg(5mol%):LiNbO 3 and Zn(3mol%):Mg(3mol%):LiNbO 3 crystal is at 3535cm -1 (2.83μm),while that of pure LiNbO 3,Zn(3mol%):LiNbO 3 and M g(3mol%):LiNbO 3 is at 3484cm -1 (2.87μm).We take the direct obseration me thod of the focula distortion in crystal to measure the photorefractive threshol d value of these crystals and gained the result that the photorefractive thresho ld value of Zn(6mol%):LiNbO 3,Mg(5mol%):LiNbO 3 and Zn(3mol%):Mg(3mol%):LiNbO 3 increase above two orders of magnitude higher than pure LiNbO 3 crystal and the photorefractive threshold value of Zn(3mol%):LiNbO 3 and Mg(3mol%):LiNbO 3 is a little higher than that of pure LiNbO 3 crystal.The congruent compositio n ratio of LiNbO 3 is Li/Nb=0.946.A part of Nb 5+ take place Li + site to form the intrinsic defect antisite Nb 4+ Li .The charge transport proc ess in LiNbO 3 is due to this kind of intrinsic defect.Especially in high light intensity,the intrinsic defect is important.The quantity that make antisite Nb 4+ Li defect structure disappear when doping ions (Mg 2+ and Zn 2+ ) substitute for all Nb 4+ Li at Li + site is called the thre shold concentration for this impurity ion.At the same time the impurity ion star t to take place Nb site.The photo damage resistance impurity ion is to drive ant i site Nb Li from Li site to normal Nb site so that the OH - absorption peak shifts to 2.83μm from 2.87μm.The fact that the OH - absorption peak of Zn(3m ol%):Mg(3mol%):LiNbO 3 crystal shifts to 2.83μm from 2.87μm and its photo dam age resistance threshold value is two orders of magnitude higher than pure LiNbO 3 crystal shows that above analyse is reasonable.展开更多
ZnO(4mol%),In 2O 3(1mol%)and Fe 2O 3(0.05mol%)were doped in LiNbO 3 and Czochralski method was used to grow Zn∶In∶Fe∶LiNbO 3 crystal.The diameter of the crystal we grew is 30mm.The technology parameter we took is t...ZnO(4mol%),In 2O 3(1mol%)and Fe 2O 3(0.05mol%)were doped in LiNbO 3 and Czochralski method was used to grow Zn∶In∶Fe∶LiNbO 3 crystal.The diameter of the crystal we grew is 30mm.The technology parameter we took is that the axial temperature gradient is 40℃/cm,the growth rate is 1mm/h, the rotation rate is 15-25r/min,the temperature of polarization is 1220℃ and the current density of polarization is 5mA/cm 2.The wafer dimension is 10mm×10mm×3mm and was covered in Li 2CO 3 powder to reduce.The reduction temperature is 500℃ and reduction time is 30 hours. OH - stretch vibration transmission spectra were measured by Fourier infrared spectrophotometer. There are two absorption peaks in OH - spectra of Zn∶In∶Fe∶LiNbO 3,in which one is at 3534cm -1 (2.83μm) and the other is at 3505cm -1 (2.85μm).The peak at 2.85μm is far lower than that at 2.83μm. Because of the threshold effect of Zn 2+ and In 3+ ,the peak at 2.83μm is generated and the peak at 2.85μm is related with Fe 3+ .In LiNbO 3 only doped with Fe,Li + site is taken place by Fe 3+ .When doping Zn 2+ and In 3+ in high concentration,these two ions take place Nb that is at Li site and Fe 3+ substitutes for Nb 5+ at the same time.The interaction between Fe 3+ and OH - make the OH - peak shift to 2.85μm.展开更多
文摘在 Fe∶Li Nb O3 中掺进 3 mol%和 6mol% Mg O,生长了 Mg∶Fe∶L i Nb O3 晶体 .测试了 Mg∶Fe∶Li Nb O3 晶体抗光致散射能力、衍射效率、响应时间和光电导 .推导响应时间与光电导之间的关系 .在 Fe∶Li Nb O3 晶体中掺进 6mol%的 Mg2 + ,它的抗光致散射能力比Fe∶L i Nb O3 晶体提高一个数量级 ,响应速度比 Fe∶Li Nb O3
文摘LiNbO 3crystal possesses electro optic effect and nonlinear optical effect.Bec ars e it is easy to generate photo damage(photorefractive) for LiNbO 3.This limits i ts application in some fields.When doping 6mol% ZnO or 5mol% MgO in LiNbO 3 cry stal to grow Zn∶LiNbO 3 or Mg∶LiNbO 3 crystal,the photo damage resistance ab ility fo these two crystals is two orders of magnitude higher than that of LiNbO 3.We doped 3mol% ZnO and 3mol% MgO to grow Zn∶Mg∶LiNbO 3 crystal and used Fourier spectrophotometer to measure the infrared transmission spectra.The waven umber range to measure the OH - stretched vibration transmission spectra of Zn ∶LiNbO 3,Mg∶LiNbO 3 and Zn∶Mg∶LiNbO 3 crystal is 3200 4000cm -1 .The measurement result is that the OH - stretched vibration absorption peak of Zn( 6mol%):LiNbO 3,Mg(5mol%):LiNbO 3 and Zn(3mol%):Mg(3mol%):LiNbO 3 crystal is at 3535cm -1 (2.83μm),while that of pure LiNbO 3,Zn(3mol%):LiNbO 3 and M g(3mol%):LiNbO 3 is at 3484cm -1 (2.87μm).We take the direct obseration me thod of the focula distortion in crystal to measure the photorefractive threshol d value of these crystals and gained the result that the photorefractive thresho ld value of Zn(6mol%):LiNbO 3,Mg(5mol%):LiNbO 3 and Zn(3mol%):Mg(3mol%):LiNbO 3 increase above two orders of magnitude higher than pure LiNbO 3 crystal and the photorefractive threshold value of Zn(3mol%):LiNbO 3 and Mg(3mol%):LiNbO 3 is a little higher than that of pure LiNbO 3 crystal.The congruent compositio n ratio of LiNbO 3 is Li/Nb=0.946.A part of Nb 5+ take place Li + site to form the intrinsic defect antisite Nb 4+ Li .The charge transport proc ess in LiNbO 3 is due to this kind of intrinsic defect.Especially in high light intensity,the intrinsic defect is important.The quantity that make antisite Nb 4+ Li defect structure disappear when doping ions (Mg 2+ and Zn 2+ ) substitute for all Nb 4+ Li at Li + site is called the thre shold concentration for this impurity ion.At the same time the impurity ion star t to take place Nb site.The photo damage resistance impurity ion is to drive ant i site Nb Li from Li site to normal Nb site so that the OH - absorption peak shifts to 2.83μm from 2.87μm.The fact that the OH - absorption peak of Zn(3m ol%):Mg(3mol%):LiNbO 3 crystal shifts to 2.83μm from 2.87μm and its photo dam age resistance threshold value is two orders of magnitude higher than pure LiNbO 3 crystal shows that above analyse is reasonable.
文摘ZnO(4mol%),In 2O 3(1mol%)and Fe 2O 3(0.05mol%)were doped in LiNbO 3 and Czochralski method was used to grow Zn∶In∶Fe∶LiNbO 3 crystal.The diameter of the crystal we grew is 30mm.The technology parameter we took is that the axial temperature gradient is 40℃/cm,the growth rate is 1mm/h, the rotation rate is 15-25r/min,the temperature of polarization is 1220℃ and the current density of polarization is 5mA/cm 2.The wafer dimension is 10mm×10mm×3mm and was covered in Li 2CO 3 powder to reduce.The reduction temperature is 500℃ and reduction time is 30 hours. OH - stretch vibration transmission spectra were measured by Fourier infrared spectrophotometer. There are two absorption peaks in OH - spectra of Zn∶In∶Fe∶LiNbO 3,in which one is at 3534cm -1 (2.83μm) and the other is at 3505cm -1 (2.85μm).The peak at 2.85μm is far lower than that at 2.83μm. Because of the threshold effect of Zn 2+ and In 3+ ,the peak at 2.83μm is generated and the peak at 2.85μm is related with Fe 3+ .In LiNbO 3 only doped with Fe,Li + site is taken place by Fe 3+ .When doping Zn 2+ and In 3+ in high concentration,these two ions take place Nb that is at Li site and Fe 3+ substitutes for Nb 5+ at the same time.The interaction between Fe 3+ and OH - make the OH - peak shift to 2.85μm.
