Two-dimensional Dion-Jacobson(DJ)perovskite has garnered significant attention due to its superior responsivity and operation stability.However,efforts are predominantly focused on discovering new organic spacer to sy...Two-dimensional Dion-Jacobson(DJ)perovskite has garnered significant attention due to its superior responsivity and operation stability.However,efforts are predominantly focused on discovering new organic spacer to synthesize novel perovskites,while material-form-associated light management,which is crucial for enhancing the photodetector’s efficiency,is largely overlooked.Herein,we introduced surface light management strategy into DJ-type perovskite system by synthesizing surface-patterned BDAPbBr4(BPB,BDA=NH_(3)(CH_(2))_(4)NH_(3))microplates(MPs)using template-assisted space-confined method,which was further elucidated by theoretical optical simulation.By leveraging surface-patterned MPs to enhance light absorption,the BPB-based photodetectors(PDs)achieved remarkable photoresponse in ultraviolet region,marked by a high on/off ratio(~5000),superior responsivity(2.24 A W^(-1)),along with large detectivity(~10^(13) Jones)and low detection limit(68.7 nW cm^(-2)).Additionally,the PDs showcased superior light communication and imaging capabilities even under weak-light illumination.Notably,the anisotropic nature of the surface-patterned MPs conferred excellent polarization sensitivity to the PD.These results represented the first demonstration of BPB perovskite in weak-light communication and imaging,as well as in polarized light detection.Our findings offer valuable insights into enhancing photodetector performance and optoelectronic applications through surface light management strategies.展开更多
Global warming and energy crisis are two major challenges in the new-century.Wearable materials that enable all-seasonal self-adapting thermal comfort without additional energy-input attract significant attention as a...Global warming and energy crisis are two major challenges in the new-century.Wearable materials that enable all-seasonal self-adapting thermal comfort without additional energy-input attract significant attention as a solution to the increasing severity of extreme climate-change.Inspired by autologous temperature-regulation and multidimensional-sensing origins of nature-skin composed of nature collagen fibers,this study engineered a nanoscale wearable natural fibers-derived thermochromic material(TMEH-skin)for robust all-season self-adapting thermal management by tactically integrating traditional immersion and spraying methods with layer-by-layer stacking-strategy.Because of the on-demand multi-functional layer-structure design,TMEH-skin achieves spontaneous~38.16%visible lightmodulation and~95.1%infrared-emission,demonstrating outstanding double-self-switching thermal management origins by simple color-changing without additional energy-input.Moreover,TMEH-skin has gratifying tensile strength of 13.18 MPa,water vapor permeability,electrical-conductivity,and hydrophobicity,further broadening the application potential and scenarios as wearable materials.In applications for military-missions or reconnaissance behind enemy-lines,TMEH-skin robustly integrates the multi-functionalities of wearing-comfort,physiological signal-response capability for accurate transmission of Morse-code,and thermal management performances under special circumstances,indicating its tremendous potential for smart military-applications.Simulation results show that TMEH-skin has prominent energy-saving efficiency in cities with different climate zones.This study provides a new reference to the booming innovation of natural-derived wearable materials for all-seasonal self-adapting thermal management.展开更多
Forest ecosystems are important for biodiversity conservation and human societies,but are under pressure due to climate change and human interventions.This applies to natural forests as well as tree plantations.The la...Forest ecosystems are important for biodiversity conservation and human societies,but are under pressure due to climate change and human interventions.This applies to natural forests as well as tree plantations.The latter are globally widespread and therefore gaining increasing importance for biodiversity conservation.However,even after dieback due to increasing disturbance frequencies,such plantations are primarily managed for economic returns,leading to growing conflicts among stakeholders.In particular,the impact of forest management on biodiversity is being discussed.This study investigates the effects of five management approaches in a landscape severely affected by spruce(Picea abies L.)dieback on beetle diversity,conservation,and community composition.We considered direct effects of management and indirect effects of environmental parameters separately in ground-dwelling and flight-active beetles.Beetle diversity was strongly affected by forest management,with nonintervention deadwood stands being most beneficial for beetles.In addition,we show indirect effects of environmental factors.In general,parameters related to salvage logging(e.g.open canopies,tree stumps)influenced beetle diversity and conservation negatively,while positive effects were found for soil nutrient availability and plant species richness.Community composition differed strongly among management categories and indicated a lack of landscape connectivity for open habitat species,as we found only low proportions of such species even on salvage-logged sites.We propose a mixture of management approaches after bark beetle outbreaks,including a substantial proportion of non-intervention deadwood stands,to increase landscape heterogeneity and connectivity.This may increase overall biodiversity while addressing the concerns of both forestry and species conservation.展开更多
Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events a...Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events and large fluctuations in ambient temperature disrupt thermal comfort and negatively impact health,driving a growing dependence on cooling and heating energy sources.Consequently,efficient thermal management has become a central focus of energy research.Traditional thermal management systems consume substantial energy,further contributing to greenhouse gas emissions.In contrast,emergent radiant thermal management technologies that rely on renewable energy have been proposed as sustainable alternatives.However,achieving year-round thermal management without additional energy input remains a formidable challenge.Recently,dynamic radiative thermal management technologies have emerged as the most promising solution,offering the potential for energy-efficient adaptation across seasonal variations.This review systematically presents recent advancements in dynamic radiative thermal management,covering fundamental principles,switching mechanisms,primary materials,and application areas.Additionally,the key challenges hindering the broader adoption of dynamic radiative thermal management technologies are discussed.By highlighting their transformative potential,this review provides insights into the design and industrial scalability of these innovations,with the ultimate aim of promoting renewable energy integration in thermal management applications.展开更多
Cardiac papillary fibroelastoma is a benign heart tumor that,despite its histologically benign nature,can have devastating clinical consequences.Advances in cardiac imaging have made papillary fibroelastoma the most c...Cardiac papillary fibroelastoma is a benign heart tumor that,despite its histologically benign nature,can have devastating clinical consequences.Advances in cardiac imaging have made papillary fibroelastoma the most common primary benign tumor,surpassing cardiac myxoma.These tumors predominantly occur on the surface of heart valves,with the aortic valve being the most frequently affected(44%),followed by the mitral valve(35%)and other locations.Aortic fibroelastomas are the second most common primary cardiac tumor,known for their risk of embolic complications.Surgical excision is recommended for symptomatic lesions,but the management of small and asymptomatic fibroelastomas remains uncertain,particularly in elderly patients with comorbidities.[1-3].展开更多
Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum...Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum-assisted filtration.Interestingly,within the polytetrafluoroethylene(PTFE)-carbon nanotube(CNT)-Fe_(3)O_(4)layer(FCFe),CNT nanofibers interweave with PTFE fibers to form a stable“silk-like”structure that effectively captures Fe_(3)O_(4)particles.By incorporating a highly conductive MXene layer,the FCFe/MXene(FCFe/M)membrane exhibits excellent electrical/thermal conductivity,mechanical properties,and flame retardancy.Impressively,benefiting from the rational regulation of component proportions and the design of a Janus structure,the FCFe/M membrane with a thickness of only 84.9μm delivers outstanding EMI shielding effectiveness of 44.56 dB in the X-band,with a normalized specific SE reaching 10,421.3 dB cm^(2)g^(-1),which is attributed to the“absorption-reflection-reabsorption”mechanism.Furthermore,the membrane demonstrates low-voltage-driven Joule heating and fast-response photothermal performance.Under the stimulation of a 3 V voltage and an optical power density of 320 mW cm^(-2),the surface temperatures of the FCFe/M membranes can reach up to 140.4 and 145.7℃,respectively.In brief,the FCFe/M membrane with anti-electromagnetic radiation and temperature regulation is an attractive candidate for the next generation of wearable electronics,EMI compatibility,visual heating,thermotherapy,and military and aerospace applications.展开更多
BACKGROUND: Targeted temperature management(TTM) is a common therapeutic intervention, yet its cost-effectiveness remains uncertain. This study aimed to evaluate the real-world cost-effectiveness of TTM compared with ...BACKGROUND: Targeted temperature management(TTM) is a common therapeutic intervention, yet its cost-effectiveness remains uncertain. This study aimed to evaluate the real-world cost-effectiveness of TTM compared with that of conventional care in adult out-of-hospital cardiac arrest(OHCA) survivors using clinical patient-level data.METHODS: We conducted a retrospective cohort study at an academic medical center in the USA to assess the cost-effectiveness of TTM in adult non-traumatic OHCA survivors between 1 January, 2019 and 30 June, 2023. The primary outcome was survival to hospital discharge. Incremental cost-effectiveness ratios(ICERs) were calculated and compared with various decision makers' willingness to pay. Cost-effectiveness acceptability curves were utilized to evaluate the economic attractiveness of TTM. Uncertainty about the incremental cost and effect was explored with a 95% confidence ellipse.RESULTS: Among 925 non-traumatic OHCA survivors, only 30(3%) received TTM. After adjusting for potential confounders, the TTM group did not demonstrate a significantly lower cost(delta cost-$5,141, 95% confidence interval [95% CI]: $-35,347 to $25,065, P=0.79) and higher survival to hospital discharge(delta effect 6%, 95% CI:-11% to 23%, P=0.41). Additionally, a 95% confidence ellipse indicated uncertainty reflected by evidence that the true value of the ICER could be in any of the quadrants of the cost-effectiveness plane.CONCLUSION: Although TTM did not demonstrate a clear survival benefit in this study, its potential cost-effectiveness warrants further investigation with larger sample sizes. These findings highlight the need for additional research to optimize TTM use in OHCA care and inform resource allocation decisions.展开更多
Climate change is the most severe ecological challenge faced by the world today.Forests,the dominant component of terrestrial ecosystems,play a critical role in mitigating climate change due to their powerful carbon s...Climate change is the most severe ecological challenge faced by the world today.Forests,the dominant component of terrestrial ecosystems,play a critical role in mitigating climate change due to their powerful carbon sequestration capabilities.Meanwhile,climate change has also become a major factor affecting the sustainable management of forest ecosystems.Climate-Smart Forestry(CSF)is an emerging concept in sustainable forest management.By utilizing advanced technologies,such as information technology and artificial intelligence,CSF aims to develop innovative and proactive forest management methods and decision-making systems to address the challenges of climate change.CSF aims to enhance forest ecosystem resilience(i.e.,maintain a condition where,even when the state of the ecosystem changes,the ecosystem functions do not deteriorate)through climate change adaptation,improve the mitigation capabilities of forest ecosystems to climate change,maintain high,stable,and sustainable forest productivity and ecosystem services,and ultimately achieve harmonious development between humans and nature.This concept paper:(1)discusses the emergence and development of CSF,which integrates Ecological Forestry,Carbon Forestry,and Smart Forestry,and proposes the concept of CSF;(2)analyzes the goals of CSF in improving forest ecosystem stability,enhancing forest ecosystem carbon sequestration capacity,and advocating the application and development of new technologies in CSF,including artificial intelligence,robotics,Light Detection and Ranging,and forest digital twin;(3)presents the latest practices of CSF based on prior research on forest structure and function using new generation information technologies at Qingyuan Forest,China.From these practices and reflections,we suggested the development direction of CSF,including the key research topics and technological advancement.展开更多
Plenter forests,also known as uneven-aged or continuous cover forests enhance forest resilience and resistance against disturbances compared to even-aged forests.They are considered as an adaptation option to mitigate...Plenter forests,also known as uneven-aged or continuous cover forests enhance forest resilience and resistance against disturbances compared to even-aged forests.They are considered as an adaptation option to mitigate climate change effects.In this study,we present a conceptual approach to determine the potentially suitable area for plenter forest management within central European mixed species forests and apply our approach to the case study area in Styria,the south-eastern Province of Austria.The concept is based on ecological and technicaleconomic constraints and considers expected future climate conditions and its impact on plenter forest management.For each 1 ha forest pixel,we assess the ecological conditions for plenter forest management according to the autecological growth conditions of silver fir,and at least one additional shade tolerant tree species.The technical-economic constraints are defined by slope(≤30%)and distance to the next forest road(≤100 m)to ensure cost-efficient harvesting.The results show that under current climate conditions 28.1%or 305,349 ha of the forests in Styria are potentially suitable for plenter forest management.For the years 2071–2100 and under the climate change scenario RCP 4.5,the potential area decreases to 286,098 ha(26.3%of the total forest area)and for the scenario RCP 8.5 to 208,421 ha(19.1%of the total forest area).The main reason for these changes is the unfavourable growing conditions for silver fir in the lowlands,while in the higher elevations silver fir is likely to expand.Our results may serve forest managers to identify areas suitable for plenter forests and assist in the transformation of even-aged pure forests to uneven-aged forests to increase resistance,resilience,and biodiversity under climate change.展开更多
5G technology has endowed mobile communication terminals with features such as ultrawideband access,low latency,and high reliability transmission,which can complete the network access and interconnection of a large nu...5G technology has endowed mobile communication terminals with features such as ultrawideband access,low latency,and high reliability transmission,which can complete the network access and interconnection of a large number of devices,thus realizing richer application scenarios and constructing 5G-enabled vehicular networks.However,due to the vulnerability of wireless communication,vehicle privacy and communication security have become the key problems to be solved in vehicular networks.Moreover,the large-scale communication in the vehicular networks also makes the higher communication efficiency an inevitable requirement.In order to achieve efficient and secure communication while protecting vehicle privacy,this paper proposes a lightweight key agreement and key update scheme for 5G vehicular networks based on blockchain.Firstly,the key agreement is accomplished using certificateless public key cryptography,and based on the aggregate signature and the cooperation between the vehicle and the trusted authority,an efficient key updating method is proposed,which reduces the overhead and protects the privacy of the vehicle while ensuring the communication security.Secondly,by introducing blockchain and using smart contracts to load the vehicle public key table for key management,this meets the requirements of vehicle traceability and can dynamically track and revoke misbehaving vehicles.Finally,the formal security proof under the eck security model and the informal security analysis is conducted,it turns out that our scheme is more secure than other authentication schemes in the vehicular networks.Performance analysis shows that our scheme has lower overhead than existing schemes in terms of communication and computation.展开更多
With the deployment of ultra-dense low earth orbit(LEO)satellite constellations,LEO satellite access network(LEO-SAN)is envisioned to achieve global Internet coverage.Meanwhile,the civil aviation communications have i...With the deployment of ultra-dense low earth orbit(LEO)satellite constellations,LEO satellite access network(LEO-SAN)is envisioned to achieve global Internet coverage.Meanwhile,the civil aviation communications have increased dramatically,especially for providing airborne Internet services.However,due to dynamic service demands and onboard LEO resources over time and space,it poses huge challenges in satellite-aircraft access and service management in ultra-dense LEO satellite networks(UDLSN).In this paper,we propose a deep reinforcement learning-based approach for ultra-dense LEO satellite-aircraft access and service management.Firstly,we develop an airborne Internet architecture based on UDLSN and design a management mechanism including medium earth orbit satellites to guarantee lightweight management.Secondly,considering latency-sensitive and latency-tolerant services,we formulate the problem of satellite-aircraft access and service management for civil aviation to ensure service continuity.Finally,we propose a proximal policy optimization-based access and service management algorithm to solve the formulated problem.Simulation results demonstrate the convergence and effectiveness of the proposed algorithm with satisfying the service continuity when applying to the UDLSN.展开更多
Thermal management system is highly desirable to guarantee the performance and thermal safety of lithium-ion batteries,but it reduces the energy density of battery modules and even is unable to provide highly effectiv...Thermal management system is highly desirable to guarantee the performance and thermal safety of lithium-ion batteries,but it reduces the energy density of battery modules and even is unable to provide highly effective protection.Here,a thermal management function integrated material is presented based on high-temperature resistant aerogel and phase change material and is applied at both charge–discharge process and thermal runaway condition.In this sandwich structure Paraffin@SiC nanowire/Aerogel sheet (denoted as PA@SAS) system,SiC nanowires endow the middle aerogel sheet (SAS) a dual nano-network structure.The enhanced mechanical properties of SAS were studied by compressive tests and dynamic mechanical analysis.Besides,the thermal conductivity of SAS at 600°C is only 0.042 W/(m K).The surface phase change material layers facilitate temperature uniformity of batteries (surface temperature difference less than 1.82°C) through latent heat.Moreover,a large-format battery module with four 58 Ah LiNi0.5Co0.2Mn0.3O2LIBs was assembled.PA@SAS successfully prevents thermal runaway propagation,yielding a temperature gap of 602°C through the 2 mm-thick cross section.PA@SAS also exhibits excellent performance in other safety issues such as temperature rise rate,flame heat flux,etc.The lightweight property and effective insulation performance achieves significant safety enhancement with mass and volume energy density reduction of only 0.79%and 5.4%,respectively.The originality of the present research stems from the micro and macro structure design of the proposed thermal management material and the combination of intrinsic advantages of every component.This work provides a reliable design of achieving the integration of thermal management functions into an aerogel composite and improves the thermal safety of lithium-ion batteries.展开更多
On October 18,2017,the 19th National Congress Report called for the implementation of the Healthy China Strategy.The development of biomedical data plays a pivotal role in advancing this strategy.Since the 18th Nation...On October 18,2017,the 19th National Congress Report called for the implementation of the Healthy China Strategy.The development of biomedical data plays a pivotal role in advancing this strategy.Since the 18th National Congress of the Communist Party of China,China has vigorously promoted the integration and implementation of the Healthy China and Digital China strategies.The National Health Commission has prioritized the development of health and medical big data,issuing policies to promote standardized applica-tions and foster innovation in"Internet+Healthcare."Biomedical data has significantly contributed to preci-sion medicine,personalized health management,drug development,disease diagnosis,public health monitor-ing,and epidemic prediction capabilities.展开更多
This paper presents a novel approach to dynamic pricing and distributed energy management in virtual power plant(VPP)networks using multi-agent reinforcement learning(MARL).As the energy landscape evolves towards grea...This paper presents a novel approach to dynamic pricing and distributed energy management in virtual power plant(VPP)networks using multi-agent reinforcement learning(MARL).As the energy landscape evolves towards greater decentralization and renewable integration,traditional optimization methods struggle to address the inherent complexities and uncertainties.Our proposed MARL framework enables adaptive,decentralized decision-making for both the distribution system operator and individual VPPs,optimizing economic efficiency while maintaining grid stability.We formulate the problem as a Markov decision process and develop a custom MARL algorithm that leverages actor-critic architectures and experience replay.Extensive simulations across diverse scenarios demonstrate that our approach consistently outperforms baseline methods,including Stackelberg game models and model predictive control,achieving an 18.73%reduction in costs and a 22.46%increase in VPP profits.The MARL framework shows particular strength in scenarios with high renewable energy penetration,where it improves system performance by 11.95%compared with traditional methods.Furthermore,our approach demonstrates superior adaptability to unexpected events and mis-predictions,highlighting its potential for real-world implementation.展开更多
Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wi...Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wide-bandgap perovskite,particularly on textured silicon surfaces.Herein,a series of halide ions(Cl^(-),Br^(-),I^(-))substituted piperazinium salts are designed and synthesized as post-treatment modifiers for perovskite surfaces.Notably,piperazinium chloride induces an asymmetric bidirectional ions distribution from the top to the bottom surface,with large piperazinium cations concentrating at the perovskite surface and small chloride anions migrating downward to accumulate at the buried interface.This results in effective dual-interface defect passivation and energy band modulation,enabling wide-bandgap(1.68 eV)perovskite solar cells to achieve a PCE of 22.3%and a record product of open-circuit voltage×fill factor(84.4%relative to the Shockley-Queisser limit).Furthermore,the device retains 91.3%of its initial efficiency after 1200 h of maximum power point tracking without encapsulation.When integrated with double-textured silicon heterojunction solar cells,a remarkable PCE of 31.5%is achieved for a 1.04 cm^(2) monolithic perovskite/silicon tandem solar cell,exhibiting excellent long-term operational stability(T_(80)=755 h)without encapsulation in ambient air.This work provides a convenient strategy on dual-interface engineering for making high-efficiency and stable perovskite platforms.展开更多
Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building hea...Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.展开更多
Chronic diabetic wounds confront a significant medical challenge because of increasing prevalence and difficult-healing circumstances.It is vital to develop multifunctional hydrogel dressings,with well-designed morpho...Chronic diabetic wounds confront a significant medical challenge because of increasing prevalence and difficult-healing circumstances.It is vital to develop multifunctional hydrogel dressings,with well-designed morphology and structure to enhance flexibility and effectiveness in wound management.To achieve these,we propose a self-healing hydrogel dressing based on structural color microspheres for wound management.The microsphere comprised a photothermal-responsive inverse opal framework,which was constructed by hyaluronic acid methacryloyl,silk fibroin methacryloyl and black phosphorus quantum dots(BPQDs),and was further re-filled with a dynamic hydrogel.The dynamic hydrogel filler was formed by Knoevenagel condensation reaction between cyanoacetate and benzaldehyde-functionalized dextran(DEX-CA and DEX-BA).Notably,the composite microspheres can be applied arbitrarily,and they can adhere together upon near-infrared irradiation by leveraging the BPQDs-mediated photothermal effect and the thermoreversible stiffness change of dynamic hydrogel.Additionally,eumenitin and vascular endothelial growth factor were co-loaded in the microspheres and their release behavior can be regulated by the same mechanism.Moreover,effective monitoring of the drug release process can be achieved through visual color variations.The microsphere system has demonstrated desired capabilities of controllable drug release and efficient wound management.These characteristics suggest broad prospects for the proposed composite microspheres in clinical applications.展开更多
In mega-constellation Communication Systems, efficient routing algorithms and data transmission technologies are employed to ensure fast and reliable data transfer. However, the limited computational resources of sate...In mega-constellation Communication Systems, efficient routing algorithms and data transmission technologies are employed to ensure fast and reliable data transfer. However, the limited computational resources of satellites necessitate the use of edge computing to enhance secure communication.While edge computing reduces the burden on cloud computing, it introduces security and reliability challenges in open satellite communication channels. To address these challenges, we propose a blockchain architecture specifically designed for edge computing in mega-constellation communication systems. This architecture narrows down the consensus scope of the blockchain to meet the requirements of edge computing while ensuring comprehensive log storage across the network. Additionally, we introduce a reputation management mechanism for nodes within the blockchain, evaluating their trustworthiness, workload, and efficiency. Nodes with higher reputation scores are selected to participate in tasks and are appropriately incentivized. Simulation results demonstrate that our approach achieves a task result reliability of 95% while improving computational speed.展开更多
Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase chan...Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.展开更多
Highly thermally conductive graphitic film(GF)materials have become a competitive solution for the thermal management of high-power electronic devices.However,their catastrophic structural failure under extreme altern...Highly thermally conductive graphitic film(GF)materials have become a competitive solution for the thermal management of high-power electronic devices.However,their catastrophic structural failure under extreme alternating thermal/cold shock poses a significant challenge to reliability and safety.Here,we present the first investigation into the structural failure mechanism of GF during cyclic liquid nitrogen shocks(LNS),which reveals a bubbling process characterized by“permeation-diffusion-deformation”phenomenon.To overcome this long-standing structural weakness,a novel metal-nanoarmor strategy is proposed to construct a Cu-modified graphitic film(GF@Cu)with seamless heterointerface.This well-designed interface ensures superior structural stability for GF@Cu after hundreds of LNS cycles from 77 to 300 K.Moreover,GF@Cu maintains high thermal conductivity up to 1088 W m^(−1)K^(−1)with degradation of less than 5%even after 150 LNS cycles,superior to that of pure GF(50%degradation).Our work not only offers an opportunity to improve the robustness of graphitic films by the rational structural design but also facilitates the applications of thermally conductive carbon-based materials for future extreme thermal management in complex aerospace electronics.展开更多
基金the Key Research and Development Program sponsored by the Ministry of Science and Technology of China(2024YFE0201800)the National Natural Science Foundation of China(Nos.12134010,12174290)the Natural Science Foundation of Hubei Province,China(Grant Nos.2023BAB102 and 2021CFB039).
文摘Two-dimensional Dion-Jacobson(DJ)perovskite has garnered significant attention due to its superior responsivity and operation stability.However,efforts are predominantly focused on discovering new organic spacer to synthesize novel perovskites,while material-form-associated light management,which is crucial for enhancing the photodetector’s efficiency,is largely overlooked.Herein,we introduced surface light management strategy into DJ-type perovskite system by synthesizing surface-patterned BDAPbBr4(BPB,BDA=NH_(3)(CH_(2))_(4)NH_(3))microplates(MPs)using template-assisted space-confined method,which was further elucidated by theoretical optical simulation.By leveraging surface-patterned MPs to enhance light absorption,the BPB-based photodetectors(PDs)achieved remarkable photoresponse in ultraviolet region,marked by a high on/off ratio(~5000),superior responsivity(2.24 A W^(-1)),along with large detectivity(~10^(13) Jones)and low detection limit(68.7 nW cm^(-2)).Additionally,the PDs showcased superior light communication and imaging capabilities even under weak-light illumination.Notably,the anisotropic nature of the surface-patterned MPs conferred excellent polarization sensitivity to the PD.These results represented the first demonstration of BPB perovskite in weak-light communication and imaging,as well as in polarized light detection.Our findings offer valuable insights into enhancing photodetector performance and optoelectronic applications through surface light management strategies.
基金the Institute of Biomass&Functional Materials of Shaanxi University of Science and Technology for funding this research workfinancially supported by the National Natural Science Foundation of China(2207081675,22278257,22308209)+1 种基金the Key R&D Program of Shaanxi Province(2024SF-YBXM-586)the Project of Innovation Capability Support Program in Shaanxi Province(2024ZC-KJXX-005)。
文摘Global warming and energy crisis are two major challenges in the new-century.Wearable materials that enable all-seasonal self-adapting thermal comfort without additional energy-input attract significant attention as a solution to the increasing severity of extreme climate-change.Inspired by autologous temperature-regulation and multidimensional-sensing origins of nature-skin composed of nature collagen fibers,this study engineered a nanoscale wearable natural fibers-derived thermochromic material(TMEH-skin)for robust all-season self-adapting thermal management by tactically integrating traditional immersion and spraying methods with layer-by-layer stacking-strategy.Because of the on-demand multi-functional layer-structure design,TMEH-skin achieves spontaneous~38.16%visible lightmodulation and~95.1%infrared-emission,demonstrating outstanding double-self-switching thermal management origins by simple color-changing without additional energy-input.Moreover,TMEH-skin has gratifying tensile strength of 13.18 MPa,water vapor permeability,electrical-conductivity,and hydrophobicity,further broadening the application potential and scenarios as wearable materials.In applications for military-missions or reconnaissance behind enemy-lines,TMEH-skin robustly integrates the multi-functionalities of wearing-comfort,physiological signal-response capability for accurate transmission of Morse-code,and thermal management performances under special circumstances,indicating its tremendous potential for smart military-applications.Simulation results show that TMEH-skin has prominent energy-saving efficiency in cities with different climate zones.This study provides a new reference to the booming innovation of natural-derived wearable materials for all-seasonal self-adapting thermal management.
基金supported by Forschungsanstalt für Waldo kologie und Forstwirtschaft(FAWF)of Landesforsten Rheinland-Pfalz(FF 5.3-01-2021)。
文摘Forest ecosystems are important for biodiversity conservation and human societies,but are under pressure due to climate change and human interventions.This applies to natural forests as well as tree plantations.The latter are globally widespread and therefore gaining increasing importance for biodiversity conservation.However,even after dieback due to increasing disturbance frequencies,such plantations are primarily managed for economic returns,leading to growing conflicts among stakeholders.In particular,the impact of forest management on biodiversity is being discussed.This study investigates the effects of five management approaches in a landscape severely affected by spruce(Picea abies L.)dieback on beetle diversity,conservation,and community composition.We considered direct effects of management and indirect effects of environmental parameters separately in ground-dwelling and flight-active beetles.Beetle diversity was strongly affected by forest management,with nonintervention deadwood stands being most beneficial for beetles.In addition,we show indirect effects of environmental factors.In general,parameters related to salvage logging(e.g.open canopies,tree stumps)influenced beetle diversity and conservation negatively,while positive effects were found for soil nutrient availability and plant species richness.Community composition differed strongly among management categories and indicated a lack of landscape connectivity for open habitat species,as we found only low proportions of such species even on salvage-logged sites.We propose a mixture of management approaches after bark beetle outbreaks,including a substantial proportion of non-intervention deadwood stands,to increase landscape heterogeneity and connectivity.This may increase overall biodiversity while addressing the concerns of both forestry and species conservation.
基金the Institute of Biomass & Functional Materials of Shaanxi University of Science and Technology for funding this research workfinancially supported by the National Natural Science Foundation of China (2207081675, 22278257, 22308209)+1 种基金the Key R&D Program of Shaanxi Province (2024SF-YBXM-586)the Project of Innovation Capability Support Program in Shaanxi Province (2024ZC-KJXX-005)
文摘Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events and large fluctuations in ambient temperature disrupt thermal comfort and negatively impact health,driving a growing dependence on cooling and heating energy sources.Consequently,efficient thermal management has become a central focus of energy research.Traditional thermal management systems consume substantial energy,further contributing to greenhouse gas emissions.In contrast,emergent radiant thermal management technologies that rely on renewable energy have been proposed as sustainable alternatives.However,achieving year-round thermal management without additional energy input remains a formidable challenge.Recently,dynamic radiative thermal management technologies have emerged as the most promising solution,offering the potential for energy-efficient adaptation across seasonal variations.This review systematically presents recent advancements in dynamic radiative thermal management,covering fundamental principles,switching mechanisms,primary materials,and application areas.Additionally,the key challenges hindering the broader adoption of dynamic radiative thermal management technologies are discussed.By highlighting their transformative potential,this review provides insights into the design and industrial scalability of these innovations,with the ultimate aim of promoting renewable energy integration in thermal management applications.
文摘Cardiac papillary fibroelastoma is a benign heart tumor that,despite its histologically benign nature,can have devastating clinical consequences.Advances in cardiac imaging have made papillary fibroelastoma the most common primary benign tumor,surpassing cardiac myxoma.These tumors predominantly occur on the surface of heart valves,with the aortic valve being the most frequently affected(44%),followed by the mitral valve(35%)and other locations.Aortic fibroelastomas are the second most common primary cardiac tumor,known for their risk of embolic complications.Surgical excision is recommended for symptomatic lesions,but the management of small and asymptomatic fibroelastomas remains uncertain,particularly in elderly patients with comorbidities.[1-3].
基金support from the National Natural Science Foundation of China(NSFC,Grant No.52175341)Shandong Provincial Natural Science Foundation(Grant No.ZR2022JQ24)Funding Project of Jinan City’s New Twenty Items for Colleges and Universities(Grant No.202333038).
文摘Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum-assisted filtration.Interestingly,within the polytetrafluoroethylene(PTFE)-carbon nanotube(CNT)-Fe_(3)O_(4)layer(FCFe),CNT nanofibers interweave with PTFE fibers to form a stable“silk-like”structure that effectively captures Fe_(3)O_(4)particles.By incorporating a highly conductive MXene layer,the FCFe/MXene(FCFe/M)membrane exhibits excellent electrical/thermal conductivity,mechanical properties,and flame retardancy.Impressively,benefiting from the rational regulation of component proportions and the design of a Janus structure,the FCFe/M membrane with a thickness of only 84.9μm delivers outstanding EMI shielding effectiveness of 44.56 dB in the X-band,with a normalized specific SE reaching 10,421.3 dB cm^(2)g^(-1),which is attributed to the“absorption-reflection-reabsorption”mechanism.Furthermore,the membrane demonstrates low-voltage-driven Joule heating and fast-response photothermal performance.Under the stimulation of a 3 V voltage and an optical power density of 320 mW cm^(-2),the surface temperatures of the FCFe/M membranes can reach up to 140.4 and 145.7℃,respectively.In brief,the FCFe/M membrane with anti-electromagnetic radiation and temperature regulation is an attractive candidate for the next generation of wearable electronics,EMI compatibility,visual heating,thermotherapy,and military and aerospace applications.
基金supported by Faculty of MedicineChiang Mai University+2 种基金supported by the National Center for Advancing Translational SciencesNational Institutes of Healththrough grant number UL1 TR001860. The content is solely the responsibility of the authors and does not necessarily represent the official views of the NIH。
文摘BACKGROUND: Targeted temperature management(TTM) is a common therapeutic intervention, yet its cost-effectiveness remains uncertain. This study aimed to evaluate the real-world cost-effectiveness of TTM compared with that of conventional care in adult out-of-hospital cardiac arrest(OHCA) survivors using clinical patient-level data.METHODS: We conducted a retrospective cohort study at an academic medical center in the USA to assess the cost-effectiveness of TTM in adult non-traumatic OHCA survivors between 1 January, 2019 and 30 June, 2023. The primary outcome was survival to hospital discharge. Incremental cost-effectiveness ratios(ICERs) were calculated and compared with various decision makers' willingness to pay. Cost-effectiveness acceptability curves were utilized to evaluate the economic attractiveness of TTM. Uncertainty about the incremental cost and effect was explored with a 95% confidence ellipse.RESULTS: Among 925 non-traumatic OHCA survivors, only 30(3%) received TTM. After adjusting for potential confounders, the TTM group did not demonstrate a significantly lower cost(delta cost-$5,141, 95% confidence interval [95% CI]: $-35,347 to $25,065, P=0.79) and higher survival to hospital discharge(delta effect 6%, 95% CI:-11% to 23%, P=0.41). Additionally, a 95% confidence ellipse indicated uncertainty reflected by evidence that the true value of the ICER could be in any of the quadrants of the cost-effectiveness plane.CONCLUSION: Although TTM did not demonstrate a clear survival benefit in this study, its potential cost-effectiveness warrants further investigation with larger sample sizes. These findings highlight the need for additional research to optimize TTM use in OHCA care and inform resource allocation decisions.
基金financially supported by the National Natural Science Foundation of China(32192435)the Application and Demonstration Project of Network Security and Informatization Technology,Chinese Academy of Sciences(CAS-WX2022SF-0101)+1 种基金the Liaoning Provincial Key Research and Development Program(2023021230-JH2/1018)the Youth Innovation Promotion Association of CAS(2023205).
文摘Climate change is the most severe ecological challenge faced by the world today.Forests,the dominant component of terrestrial ecosystems,play a critical role in mitigating climate change due to their powerful carbon sequestration capabilities.Meanwhile,climate change has also become a major factor affecting the sustainable management of forest ecosystems.Climate-Smart Forestry(CSF)is an emerging concept in sustainable forest management.By utilizing advanced technologies,such as information technology and artificial intelligence,CSF aims to develop innovative and proactive forest management methods and decision-making systems to address the challenges of climate change.CSF aims to enhance forest ecosystem resilience(i.e.,maintain a condition where,even when the state of the ecosystem changes,the ecosystem functions do not deteriorate)through climate change adaptation,improve the mitigation capabilities of forest ecosystems to climate change,maintain high,stable,and sustainable forest productivity and ecosystem services,and ultimately achieve harmonious development between humans and nature.This concept paper:(1)discusses the emergence and development of CSF,which integrates Ecological Forestry,Carbon Forestry,and Smart Forestry,and proposes the concept of CSF;(2)analyzes the goals of CSF in improving forest ecosystem stability,enhancing forest ecosystem carbon sequestration capacity,and advocating the application and development of new technologies in CSF,including artificial intelligence,robotics,Light Detection and Ranging,and forest digital twin;(3)presents the latest practices of CSF based on prior research on forest structure and function using new generation information technologies at Qingyuan Forest,China.From these practices and reflections,we suggested the development direction of CSF,including the key research topics and technological advancement.
基金part of the project“Areas of Forest Innovation Climate Smart Forestry”(project nr.101726),WP Modelling Plenter Forest vs.Even-aged Forest,funded by the Austrian Ministry of Agriculture,Forestry,Regions and Water Managementfunded by the province of Styria(Austria),the Austrian Federal Ministry of Agriculture,Forestry,Regions and Water Management and the European Union via the projects“Waldtypisierung Steiermark-FORSITE”(LE14-20)and“FORSITEⅡ-Investigation of the ecological base line information for a dynamic forest site classification in Upper Austria,Lower Austria and Burgenland”(101746)financial support came from BOKU University。
文摘Plenter forests,also known as uneven-aged or continuous cover forests enhance forest resilience and resistance against disturbances compared to even-aged forests.They are considered as an adaptation option to mitigate climate change effects.In this study,we present a conceptual approach to determine the potentially suitable area for plenter forest management within central European mixed species forests and apply our approach to the case study area in Styria,the south-eastern Province of Austria.The concept is based on ecological and technicaleconomic constraints and considers expected future climate conditions and its impact on plenter forest management.For each 1 ha forest pixel,we assess the ecological conditions for plenter forest management according to the autecological growth conditions of silver fir,and at least one additional shade tolerant tree species.The technical-economic constraints are defined by slope(≤30%)and distance to the next forest road(≤100 m)to ensure cost-efficient harvesting.The results show that under current climate conditions 28.1%or 305,349 ha of the forests in Styria are potentially suitable for plenter forest management.For the years 2071–2100 and under the climate change scenario RCP 4.5,the potential area decreases to 286,098 ha(26.3%of the total forest area)and for the scenario RCP 8.5 to 208,421 ha(19.1%of the total forest area).The main reason for these changes is the unfavourable growing conditions for silver fir in the lowlands,while in the higher elevations silver fir is likely to expand.Our results may serve forest managers to identify areas suitable for plenter forests and assist in the transformation of even-aged pure forests to uneven-aged forests to increase resistance,resilience,and biodiversity under climate change.
基金supported in part by the National Natural Science Foundation of China under Grant 61941113,Grant 61971033,and Grant 61671057by the Henan Provincial Department of Science and Technology Project(No.212102210408)by the Henan Provincial Key Scientific Research Project(No.22A520041).
文摘5G technology has endowed mobile communication terminals with features such as ultrawideband access,low latency,and high reliability transmission,which can complete the network access and interconnection of a large number of devices,thus realizing richer application scenarios and constructing 5G-enabled vehicular networks.However,due to the vulnerability of wireless communication,vehicle privacy and communication security have become the key problems to be solved in vehicular networks.Moreover,the large-scale communication in the vehicular networks also makes the higher communication efficiency an inevitable requirement.In order to achieve efficient and secure communication while protecting vehicle privacy,this paper proposes a lightweight key agreement and key update scheme for 5G vehicular networks based on blockchain.Firstly,the key agreement is accomplished using certificateless public key cryptography,and based on the aggregate signature and the cooperation between the vehicle and the trusted authority,an efficient key updating method is proposed,which reduces the overhead and protects the privacy of the vehicle while ensuring the communication security.Secondly,by introducing blockchain and using smart contracts to load the vehicle public key table for key management,this meets the requirements of vehicle traceability and can dynamically track and revoke misbehaving vehicles.Finally,the formal security proof under the eck security model and the informal security analysis is conducted,it turns out that our scheme is more secure than other authentication schemes in the vehicular networks.Performance analysis shows that our scheme has lower overhead than existing schemes in terms of communication and computation.
基金supported in part by the National Key R&D Program of China under Grant 2020YFB1806104in part by Innovation and Entrepreneurship of Jiangsu Province High-level Talent Program+1 种基金in part by Natural Sciences and Engineering Research Council of Canada (NSERC)the support from Huawei
文摘With the deployment of ultra-dense low earth orbit(LEO)satellite constellations,LEO satellite access network(LEO-SAN)is envisioned to achieve global Internet coverage.Meanwhile,the civil aviation communications have increased dramatically,especially for providing airborne Internet services.However,due to dynamic service demands and onboard LEO resources over time and space,it poses huge challenges in satellite-aircraft access and service management in ultra-dense LEO satellite networks(UDLSN).In this paper,we propose a deep reinforcement learning-based approach for ultra-dense LEO satellite-aircraft access and service management.Firstly,we develop an airborne Internet architecture based on UDLSN and design a management mechanism including medium earth orbit satellites to guarantee lightweight management.Secondly,considering latency-sensitive and latency-tolerant services,we formulate the problem of satellite-aircraft access and service management for civil aviation to ensure service continuity.Finally,we propose a proximal policy optimization-based access and service management algorithm to solve the formulated problem.Simulation results demonstrate the convergence and effectiveness of the proposed algorithm with satisfying the service continuity when applying to the UDLSN.
基金Collaborative Innovation University Project of Anhui Province (GXXT-2022-018)National Natural Science Foundation of China (52374238 and 52074253)+3 种基金Natural Science Foundation of Anhui Province (2108085J28)Taishan Industrial Leading Talent Project (2019TSCYCX-27)Major Science and Technology Projects of Anhui Province(202103a05020011)Youth Innovation Promotion Association(CX2320007001)。
文摘Thermal management system is highly desirable to guarantee the performance and thermal safety of lithium-ion batteries,but it reduces the energy density of battery modules and even is unable to provide highly effective protection.Here,a thermal management function integrated material is presented based on high-temperature resistant aerogel and phase change material and is applied at both charge–discharge process and thermal runaway condition.In this sandwich structure Paraffin@SiC nanowire/Aerogel sheet (denoted as PA@SAS) system,SiC nanowires endow the middle aerogel sheet (SAS) a dual nano-network structure.The enhanced mechanical properties of SAS were studied by compressive tests and dynamic mechanical analysis.Besides,the thermal conductivity of SAS at 600°C is only 0.042 W/(m K).The surface phase change material layers facilitate temperature uniformity of batteries (surface temperature difference less than 1.82°C) through latent heat.Moreover,a large-format battery module with four 58 Ah LiNi0.5Co0.2Mn0.3O2LIBs was assembled.PA@SAS successfully prevents thermal runaway propagation,yielding a temperature gap of 602°C through the 2 mm-thick cross section.PA@SAS also exhibits excellent performance in other safety issues such as temperature rise rate,flame heat flux,etc.The lightweight property and effective insulation performance achieves significant safety enhancement with mass and volume energy density reduction of only 0.79%and 5.4%,respectively.The originality of the present research stems from the micro and macro structure design of the proposed thermal management material and the combination of intrinsic advantages of every component.This work provides a reliable design of achieving the integration of thermal management functions into an aerogel composite and improves the thermal safety of lithium-ion batteries.
文摘On October 18,2017,the 19th National Congress Report called for the implementation of the Healthy China Strategy.The development of biomedical data plays a pivotal role in advancing this strategy.Since the 18th National Congress of the Communist Party of China,China has vigorously promoted the integration and implementation of the Healthy China and Digital China strategies.The National Health Commission has prioritized the development of health and medical big data,issuing policies to promote standardized applica-tions and foster innovation in"Internet+Healthcare."Biomedical data has significantly contributed to preci-sion medicine,personalized health management,drug development,disease diagnosis,public health monitor-ing,and epidemic prediction capabilities.
基金supported by the Science and Technology Project of State Grid Sichuan Electric Power Company Chengdu Power Supply Company under Grant No.521904240005.
文摘This paper presents a novel approach to dynamic pricing and distributed energy management in virtual power plant(VPP)networks using multi-agent reinforcement learning(MARL).As the energy landscape evolves towards greater decentralization and renewable integration,traditional optimization methods struggle to address the inherent complexities and uncertainties.Our proposed MARL framework enables adaptive,decentralized decision-making for both the distribution system operator and individual VPPs,optimizing economic efficiency while maintaining grid stability.We formulate the problem as a Markov decision process and develop a custom MARL algorithm that leverages actor-critic architectures and experience replay.Extensive simulations across diverse scenarios demonstrate that our approach consistently outperforms baseline methods,including Stackelberg game models and model predictive control,achieving an 18.73%reduction in costs and a 22.46%increase in VPP profits.The MARL framework shows particular strength in scenarios with high renewable energy penetration,where it improves system performance by 11.95%compared with traditional methods.Furthermore,our approach demonstrates superior adaptability to unexpected events and mis-predictions,highlighting its potential for real-world implementation.
基金supported by the National Natural Science Foundation of China(Grant No.62204245,U23A200098)Baima Lake Laboratory Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(Grant No.LBMHD24E020002)+4 种基金Key Research and Development Program of Zhejiang Province(Grant No.2022C01215,2024C01092)China Postdoctoral Science Foundation(Grant No.2023M743620,2024T170960)Key Research and Development Program of Ningbo(Grant No.2023Z151)National Key Research and Development Program of China(Grant No.2024YFB3817304)Zhejiang Provincial Natural Science Foundation of China(Grant No.LY24F040003).
文摘Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wide-bandgap perovskite,particularly on textured silicon surfaces.Herein,a series of halide ions(Cl^(-),Br^(-),I^(-))substituted piperazinium salts are designed and synthesized as post-treatment modifiers for perovskite surfaces.Notably,piperazinium chloride induces an asymmetric bidirectional ions distribution from the top to the bottom surface,with large piperazinium cations concentrating at the perovskite surface and small chloride anions migrating downward to accumulate at the buried interface.This results in effective dual-interface defect passivation and energy band modulation,enabling wide-bandgap(1.68 eV)perovskite solar cells to achieve a PCE of 22.3%and a record product of open-circuit voltage×fill factor(84.4%relative to the Shockley-Queisser limit).Furthermore,the device retains 91.3%of its initial efficiency after 1200 h of maximum power point tracking without encapsulation.When integrated with double-textured silicon heterojunction solar cells,a remarkable PCE of 31.5%is achieved for a 1.04 cm^(2) monolithic perovskite/silicon tandem solar cell,exhibiting excellent long-term operational stability(T_(80)=755 h)without encapsulation in ambient air.This work provides a convenient strategy on dual-interface engineering for making high-efficiency and stable perovskite platforms.
基金support from the Research Grants Council of the Hong Kong Special Administrative Region,China(PolyU152052/21E)Green Tech Fund of Hong Kong(Project No.:GTF202220106)+1 种基金Innovation and Technology Fund of the Hong Kong Special Administrative Region,China(ITP/018/21TP)PolyU Endowed Young Scholars Scheme(Project No.:84CC).
文摘Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.
基金supported by the Ruijin Hospital Guangci Introducing Talent Projectfinancial support from National Natural Science Foundation of China(82372145)+4 种基金the Research Fellow(Grant No.353146)Research Project(347897)Solutions for Health Profile(336355)InFLAMES Flagship(337531)grants from Academy of Finlandthe Finland China Food and Health International Pilot Project funded by the Finnish Ministry of Education and Culture.
文摘Chronic diabetic wounds confront a significant medical challenge because of increasing prevalence and difficult-healing circumstances.It is vital to develop multifunctional hydrogel dressings,with well-designed morphology and structure to enhance flexibility and effectiveness in wound management.To achieve these,we propose a self-healing hydrogel dressing based on structural color microspheres for wound management.The microsphere comprised a photothermal-responsive inverse opal framework,which was constructed by hyaluronic acid methacryloyl,silk fibroin methacryloyl and black phosphorus quantum dots(BPQDs),and was further re-filled with a dynamic hydrogel.The dynamic hydrogel filler was formed by Knoevenagel condensation reaction between cyanoacetate and benzaldehyde-functionalized dextran(DEX-CA and DEX-BA).Notably,the composite microspheres can be applied arbitrarily,and they can adhere together upon near-infrared irradiation by leveraging the BPQDs-mediated photothermal effect and the thermoreversible stiffness change of dynamic hydrogel.Additionally,eumenitin and vascular endothelial growth factor were co-loaded in the microspheres and their release behavior can be regulated by the same mechanism.Moreover,effective monitoring of the drug release process can be achieved through visual color variations.The microsphere system has demonstrated desired capabilities of controllable drug release and efficient wound management.These characteristics suggest broad prospects for the proposed composite microspheres in clinical applications.
基金supported in part by the National Natural Science Foundation of China under Grant No.U2268204,62172061 and 61871422National Key R&D Program of China under Grant No.2020YFB1711800 and 2020YFB1707900+2 种基金the Science and Technology Project of Sichuan Province under Grant No.2023ZHCG0014,2023ZHCG0011,2022YFG0155,2022YFG0157,2021GFW019,2021YFG0152,2021YFG0025,2020YFG0322Central Universities of Southwest Minzu University under Grant No.ZYN2022032,2023NYXXS034the State Scholarship Fund of the China Scholarship Council under Grant No.202008510081。
文摘In mega-constellation Communication Systems, efficient routing algorithms and data transmission technologies are employed to ensure fast and reliable data transfer. However, the limited computational resources of satellites necessitate the use of edge computing to enhance secure communication.While edge computing reduces the burden on cloud computing, it introduces security and reliability challenges in open satellite communication channels. To address these challenges, we propose a blockchain architecture specifically designed for edge computing in mega-constellation communication systems. This architecture narrows down the consensus scope of the blockchain to meet the requirements of edge computing while ensuring comprehensive log storage across the network. Additionally, we introduce a reputation management mechanism for nodes within the blockchain, evaluating their trustworthiness, workload, and efficiency. Nodes with higher reputation scores are selected to participate in tasks and are appropriately incentivized. Simulation results demonstrate that our approach achieves a task result reliability of 95% while improving computational speed.
基金financially supported by the National Key Research and Development Program(Grant No.2022YFE0207400)the National Natural Science Foundation of China(Grant No.U22A20168 and 52174225)。
文摘Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.
基金the National Natural Science Foundation of China(Nos.52272046,52090030,52090031,52122301,51973191)the Natural Science Foundation of Zhejiang Province(LR23E020003)+4 种基金Shanxi-Zheda Institute of New Materials and Chemical Engineering(2021SZ-FR004,2022SZ-TD011,2022SZ-TD012,2022SZ-TD014)Hundred Talents Program of Zhejiang University(188020*194231701/113,112300+1944223R3/003,112300+1944223R3/004)the Fundamental Research Funds for the Central Universities(Nos.226-2023-00023,226-2023-00082,2021FZZX001-17,K20200060)National Key R&D Program of China(NO.2022YFA1205300,NO.2022YFA1205301,NO.2020YFF0204400,NO.2022YFF0609801)“Pioneer”and“Leading Goose”R&D Program of Zhejiang 2023C01190.
文摘Highly thermally conductive graphitic film(GF)materials have become a competitive solution for the thermal management of high-power electronic devices.However,their catastrophic structural failure under extreme alternating thermal/cold shock poses a significant challenge to reliability and safety.Here,we present the first investigation into the structural failure mechanism of GF during cyclic liquid nitrogen shocks(LNS),which reveals a bubbling process characterized by“permeation-diffusion-deformation”phenomenon.To overcome this long-standing structural weakness,a novel metal-nanoarmor strategy is proposed to construct a Cu-modified graphitic film(GF@Cu)with seamless heterointerface.This well-designed interface ensures superior structural stability for GF@Cu after hundreds of LNS cycles from 77 to 300 K.Moreover,GF@Cu maintains high thermal conductivity up to 1088 W m^(−1)K^(−1)with degradation of less than 5%even after 150 LNS cycles,superior to that of pure GF(50%degradation).Our work not only offers an opportunity to improve the robustness of graphitic films by the rational structural design but also facilitates the applications of thermally conductive carbon-based materials for future extreme thermal management in complex aerospace electronics.
