We used a highly sensitive AC magnetic susceptibility technique to probe superconductivity in elemental titanium(Ti)under extreme pressures to 120 GPa in a diamond anvil cell(DAC).The measurements reveal that the crit...We used a highly sensitive AC magnetic susceptibility technique to probe superconductivity in elemental titanium(Ti)under extreme pressures to 120 GPa in a diamond anvil cell(DAC).The measurements reveal that the critical temperature(Tc)of Ti rises monotonically with increasing pressure,reaching 6.1 K at 120 GPa.Our results confirm the bulk nature of the superconductivity in Ti,as evidenced by a robust diamagnetic response in the AC magnetic susceptibility.Our work provides a routine technique to probe Meissner effect of elemental superconductors at megabar pressures.展开更多
Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan...Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.展开更多
A recent study demonstrated that solid-state photochemically induced dynamic nuclear polarization(photo-CIDNP)can achieve significant 1H NMR hyperpolarization at high magnetic fields(9.4 T and 21.1 T).This was accompl...A recent study demonstrated that solid-state photochemically induced dynamic nuclear polarization(photo-CIDNP)can achieve significant 1H NMR hyperpolarization at high magnetic fields(9.4 T and 21.1 T).This was accomplished using a specially designed donor-chromophore-acceptor(D-C-A)molecule,which exhibits an excited state electron-electron interaction that is finely tuned to match the proton Larmor frequency under high-field conditions[1].展开更多
The emerging altermagnetic RuO_(2)with both compensated magnetic moments and broken time-reversal symmetry possesses nontrivial magneto-electronic responses and nonrelativistic spin currents that are closely related t...The emerging altermagnetic RuO_(2)with both compensated magnetic moments and broken time-reversal symmetry possesses nontrivial magneto-electronic responses and nonrelativistic spin currents that are closely related to the magnetic easy axis.Ru M_(3)-edge X-ray magnetic linear dichroism(XMLD)measurements were performed to probe the Néel order in RuO_(2).For epitaxial RuO_(2) films,characteristic XMLD signals were observed for either RuO_(2)(100)or RuO_(2)(110)at normal incidence or RuO_(2)(001)at oblique incidence.The signals disappeared when the test temperature exceeded the Néel temperature.For non-epitaxial RuO_(2) films,the flat lines in the XMLD patterns of RuO_(2)(100)and RuO_(2)(110)demonstrate that there is no in-plane uniaxial alignment of the Néel order in these samples because of the counterbalanced Néel order of the twin crystals,as evidenced by X-ray diffraction phi-scan measurements.Our experimental results unambiguously demonstrate antiferromagnetism in RuO_(2) films and reveal the spatial relation of the Néel order parallel to the RuO_(2)[001]crystalline axis.These findings deepen the understanding of RuO_(2) and other attractive altermagnetic materials used in the field of spintronics.展开更多
The antiferromagnetic(AFM)semimetal NdSb is well known for the interplay between its exotic magnetism and topological properties.However,its magnetism remains poorly understood.In this study,we thoroughly investigated...The antiferromagnetic(AFM)semimetal NdSb is well known for the interplay between its exotic magnetism and topological properties.However,its magnetism remains poorly understood.In this study,we thoroughly investigated the magnetization of NdSb single crystals with a high magnetic field(H)of up to 30T applied in various directions.We found that the AFM phase is suppressed by a magnetic field of 9.41T when H‖[100]and 11.25T when H‖[110],whereas the suppression field ranges from 9.41 to 10.67T with a hysteresis of 1.26T when H‖[111].The magnetization of H‖[100],which is an easy direction with a typical magnetic transition,was studied in detail.The AFM phase with H‖[100]was suppressed at lower temperatures,disappearing at approximately 6.25 K.The critical exponents β=0.234(3),γ=0.824(6),and δ=4.90(6)were obtained for H‖[100],and aligned with a tricritical mean-field model.Analysis of the critical behavior suggests a fieldinduced tricritical phenomenon for H‖[100].An H-T phase diagram for an NdSb single crystal was constructed for H‖[100],revealing a field-induced first-order transition and a tricritical point(TCP)at T_(tr)=6.25K and H_(tr)=9.41 T.The clarification of the multiple magnetic phases and transitions in NdSb provides crucial insights into the correlation between its magnetism and topology.展开更多
Ⅰ.SAMPLE SYNTHESIS.Single erystals of NdSb were synthesized by an In-fhux method.High purity chemical elements of Nd(99.9% purity,Alfa Aesar),8b(99.999%,Aladdin),and In beads(99.99%,Aladdin)were thoroughly mixed in a...Ⅰ.SAMPLE SYNTHESIS.Single erystals of NdSb were synthesized by an In-fhux method.High purity chemical elements of Nd(99.9% purity,Alfa Aesar),8b(99.999%,Aladdin),and In beads(99.99%,Aladdin)were thoroughly mixed in a glove-box filledwith argon atmosphere,maintaining an atomie ratio of Nd:Sb:in=1:1:20.展开更多
Lanthanide-based single-molecule magnets exhibit broad magnetic hysteresis,which manifests as slow magnetic relaxation in strong magnetic fields.However,the origin of the nontrivial hysteresis behaviors remains debate...Lanthanide-based single-molecule magnets exhibit broad magnetic hysteresis,which manifests as slow magnetic relaxation in strong magnetic fields.However,the origin of the nontrivial hysteresis behaviors remains debated.Here,we propose two influential mechanisms:activation of optical-phonon-mediated direct transitions within the ground-state doublet and the resonant Raman process.These discoveries,coupled with the g-factor anisotropy,account for the observed hysteresis behaviors in the regimes of fast magnetic relaxation.Our findings complement the recognized mechanisms used to interpret the magnetic hysteresis of single-molecule magnets.展开更多
A high saturation magnetic flux density(Bs)is essential for the development of Fe-based amorphous alloys for electromagnetic devices and motors.However,achieving a high Bs often compromises the glass-forming ability(G...A high saturation magnetic flux density(Bs)is essential for the development of Fe-based amorphous alloys for electromagnetic devices and motors.However,achieving a high Bs often compromises the glass-forming ability(GFA)of Fe-based amorphous alloys.This study investigates the effects of ferromagnetic elements(Fe,Co,and Ni)on the microstructure and magnetic properties of Fe86B7C7 amorphous alloys through experiments and ab initio molecular dynamics simulations.By analyzing both the experimental and simulation results,the relationship between the atomic structures,GFA,and magnetic properties of these amorphous alloys was determined.The results indicate that the GFA of the alloys is correlated with the proportion of icosahedral and body-centered cubic clusters.The addition of Co and Ni not only improved the GFA of the alloys but also effectively increased the overall magnetic moment with an appropriate amount of Co and a small amount of Ni.This increase in the magnetic moment primarily arises from the enhancement of the magnetic moment of Fe atoms,resulting from the redistribution between the spin-up and spin-down electrons of Fe-3d orbits,as well as the strong exchange interactions between Fe and Co and Fe–Ni pairs.The results obtained offer valuable insights into the correlation between the atomic structure and magnetic properties of these amorphous alloys and suggest potential directions for the optimization of Fe-based amorphous alloys.展开更多
The construction of carbon nanocoil(CNC)-based chiral-dielectric-magnetic trinity composites is considered as a promising approach to achieve excellent low-frequency microwave absorption.However,it is still challengin...The construction of carbon nanocoil(CNC)-based chiral-dielectric-magnetic trinity composites is considered as a promising approach to achieve excellent low-frequency microwave absorption.However,it is still challenging to further enhance the low frequency microwave absorption and elucidate the related loss mechanisms.Herein,the chiral CNCs are first synthesized on a threedimensional(3D)carbon foam and then combined with the FeNi/NiFe_(2)O_(4) nanoparticles to form a novel chiral-dielectric-magnetic trinity foam.The 3D porous CNC-carbon foam network provides excellent impedance matching and strong conduction loss.The formation of the FeNi-carbon interfaces induces interfacial polarization loss,which is confirmed by the density functional theory calculations.Further permeability analysis and the micromagnetic simulation indicate that the nanoscale chiral magnetic heterostructures achieve magnetic pinning and coupling effects,which enhance the magnetic anisotropy and magnetic loss capability.Owing to the synergistic effect between dielectricity,chirality,and magnetism,the trinity composite foam exhibits excellent microwave absorption performance with an ultrabroad effective absorption bandwidth(EAB)of 14 GHz and a minimum reflection of loss less than-50 dB.More importantly,the C-band EAB of the foam is extended to 4 GHz,achieving the full C-band coverage.This study provides further guidelines for the microstructure design of the chiral-dielectric-magnetic trinity composites to achieve broadband microwave absorption.展开更多
Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration...Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.展开更多
Wireless communications in extreme environments,such as underwater and underground,is an essential technology for interconnecting various devices and enables data transmission and networking.Existing wireless technolo...Wireless communications in extreme environments,such as underwater and underground,is an essential technology for interconnecting various devices and enables data transmission and networking.Existing wireless technologies using electromagnetic(EM)waves face many known problems,such as high path loss,unpredictable multi-path fading,and large antenna size in the lossy medium.In this article,the magnetic induction(MI)based physical layer communication is introduced as a promising solution for wireless transmissions in extreme environments.Specifically,the fundamentals of the MI-based communications are reviewed.Then,with the goal of establishing reliable and low-power links between small-size devices,we review several key physical layer technologies for MI-based communications,including the MIbased signal modulations,magnetic beamforming,and relay transmissions,and summarize their state-of-theart research advances.Finally,the related open issues and challenges in each area are analyzed and presented for future investigations.展开更多
The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by...The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation method.MNMGH achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic field.The recovered silver crystals could be directly physically exfoliated,without acid/base additions.The selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective recovery.The in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional groups.Furthermore,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective reduction.Three-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery performance.This study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.展开更多
Electronics over flexible substrates offer advantages of flexibility, portability and low cost, and promising applications in the areas of energy, information, defense science and medical service. In recent years, tre...Electronics over flexible substrates offer advantages of flexibility, portability and low cost, and promising applications in the areas of energy, information, defense science and medical service. In recent years, tremendous progress has been witnessed in the development of flexible wearable devices that can be potentially massively deployed. Of particular interest are intelligent wearable devices, such as sensors and storage cells, which can be integrated by flexible magnetoelectronic devices based on magnetic thin films. To examine this further, the magnetic properties of FeNi thin films with different thicknesses grown on flexible graphene substrate are investigated at room temperature. The coercivity increases with increasing thicknesses of FeNi thin film, which can be attributed to the increase of grain size and decrease of surface roughness. Moreover, the thickness modulated magnetic property shows a magnetic anisotropy shift increase with varying thicknesses of FeNi thin film by using measurements based on ferromagnetic resonance, which further enhances the resonance frequency. In addition, the resonance peak is quite stable after bending it for ten cycles. The result is promising for the future design of flexible magnetoelectronic devices.展开更多
Based on Ginzburg-Landau theory,we investigate the electromagnetic properties of two-band superconductors with broken time-reversal symmetry.We propose an apparatus of a superconducting ring integrated with a microbri...Based on Ginzburg-Landau theory,we investigate the electromagnetic properties of two-band superconductors with broken time-reversal symmetry.We propose an apparatus of a superconducting ring integrated with a microbridge structure to probe the peculiar topological excitations in the chiral system.The phase difference of two order parameters in the superconductor satisfies the double sine-Gordon equation,and a linear relationship between the phase difference at the two ends of the junction and the total magnetic flux in the ring can be obtained.Then with the Josephson current-phase relation,we establish the dependence of the circulating current and magnetic flux on the applied external magnetic field.Our results show that this single-junction system will exhibit the irreversible behaviors and two different types of fractional flux transitions can clearly manifest the time-reversal symmetry breaking in two-component superconductors.展开更多
A large number of runaway electrons(REs)generated during disruption can cause significant damage to next-generation large-scale tokamaks.The influence of three-dimensional(3D)helical magnetic perturbations on the supp...A large number of runaway electrons(REs)generated during disruption can cause significant damage to next-generation large-scale tokamaks.The influence of three-dimensional(3D)helical magnetic perturbations on the suppression of RE generation was explored using a set of 3D helical coils in J-TEXT tokamak,which can excite m/n=-2/2 helical magnetic perturbations.Experimental evidence shows that the-2/2 magnetic perturbations caused by the opposite coil current direct plasma toward the high-field side,simultaneously enhancing the magnetic fluctuations,which would enhance the radial loss of REs and even prevent RE generation.On the other hand,-2/2 magnetic perturbations can also reduce the cooling time during the disruption phase and generate a population of high-energy REs,which can interact with high-frequency magnetic fluctuations and in turn suppress RE generation.The critical helical coil current was found to correlate with electron density,requiring higher coil currents at higher densities.According to the statistical analysis of RE generation at different electron densities,the applied-2/2 magnetic perturbations can increase the magnetic fluctuations to the same level at lower electron densities,which can decrease the threshold electron density for RE suppression.This will be beneficial for RE mitigation in future large tokamak devices.展开更多
The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electrom...The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.展开更多
The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in ...The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in modern electronic devices.Hence,a composite with three-dimensional network(Ho/U-BNNS/WPU)is developed by simultaneously incorporating magnetically modified boron nitride nanosheets(M@BNNS)and non-magnetic organo-grafted BNNS(U-BNNS)into waterborne polyurethane(WPU)to synchronous molding under a horizontal magnetic field.The results indicate that the continuous in-plane pathways formed by M@BNNS aligned along the magnetic field direction,combined with the bridging structure established by U-BNNS,enable Ho/U-BNNS/WPU to exhibit exceptional in-plane(λ//)and through-plane thermal conductivities(λ_(⊥)).In particular,with the addition of 30 wt%M@BNNS and 5 wt%U-BNNS,theλ//andλ_(⊥)of composites reach 11.47 and 2.88 W m^(-1) K^(-1),respectively,which representing a 194.2%improvement inλ_(⊥)compared to the composites with a single orientation of M@BNNS.Meanwhile,Ho/U-BNNS/WPU exhibits distinguished thermal management capabilities as thermal interface materials for LED and chips.The composites also demonstrate excellent flame retardancy,with a peak heat release and total heat release reduced by 58.9%and 36.9%,respectively,compared to WPU.Thus,this work offers new insights into the thermally conductive structural design and efficient flame-retardant systems of polymer composites,presenting broad application potential in electronic packaging fields.展开更多
Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials...Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials(PCMs).Magnetically-responsive phase change thermal storage materials are considered an emerging concept for energy storage systems,enabling PCMs to perform unprecedented functions(such as green energy utilization,magnetic thermotherapy,drug release,etc.).The combination of multifunctional magnetic nanomaterials and PCMs is a milestone in the creation of advanced multifunctional composite PCMs.However,a timely and comprehensive review of composite PCMs based on magnetic nanoparticle modification is still missing.Herein,we furnish an exhaustive exposition elucidating the cutting-edge advancements in magnetically responsive composite PCMs.We delve deeply into the multifarious roles assumed by distinct nanoparticles within composite PCMs of varying dimensions,meticulously scrutinizing the intricate interplay between their architectures and thermophysical attributes.Moreover,we prognosticate future research trajectories,delineate alternative stratagems,and illuminate prospective avenues.This review is intended to stimulate broader academic interest in interdisciplinary fields and provide valuable insights into the development of next-generation magnetically-responsive composite PCMs.展开更多
Toroidal torques,generated by the resonant magnetic perturbation(RMP)and acting on the plasma column,are numerically systematically investigated for an ITER baseline scenario.The neoclassical toroidal viscosity(NTV),i...Toroidal torques,generated by the resonant magnetic perturbation(RMP)and acting on the plasma column,are numerically systematically investigated for an ITER baseline scenario.The neoclassical toroidal viscosity(NTV),in particular the resonant portion,is found to provide the dominant contribution to the total toroidal torque under the slow plasma flow regime in ITER.While the electromagnetic torque always opposes the plasma flow,the toroidal torque associated with the Reynolds stress enhances the plasma flow independent of the flow direction.A peculiar double-peak structure for the net NTV torque is robustly computed for ITER,as the toroidal rotation frequency is scanned near the zero value.This structure is found to be ultimately due to a non-monotonic behavior of the wave-particle resonance integral(over the particle pitch angle)in the superbanana plateau NTV regime in ITER.These findings are qualitatively insensitive to variations of a range of factors including the wall resistivity,the plasma pedestal flow and the assumed frequency of the rotating RMP field.展开更多
Organophosphorus pesticides(OPPs)in foods pose a serious threat to human health,motivating the development of novel analytical methods for their rapid detection and quantification.A magnetic covalent organic framework...Organophosphorus pesticides(OPPs)in foods pose a serious threat to human health,motivating the development of novel analytical methods for their rapid detection and quantification.A magnetic covalent organic framework(M-COF)adsorbent for the magnetic solid-phase extraction(MSPE)of OPPs from foods was reported.M-COF was synthesized by the Schiff base condensation reaction of 1,3,5-tris(4-aminophenyl)benzene and 4,4-biphenyldicarboxaldehyde on the surface of amino-functionalized magnetic nanoparticles.Density functional theory(DFT)calculations showed that adsorption of OPPs onto the surface of M-COF involved hydrophobic effects,van der Waals interactions,π-πinteractions,halogen-N bonding,and hydrogen bonding.Combined with gas chromatography-mass spectrometry(GC-MS)technology,the MSPE method features low limits of detection for OPPs(0.002-0.015μg/L),good reproducibility(1.45%-6.14%),wide linear detection range(0.01-1μg/L,R≥0.9935),and satisfactory recoveries(87.3%-110.4%).The method was successfully applied for the trace analysis of OPPs in spiked fruit juices.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant No.2023YFA1406000)the National Natural Science Foundation of China(Grant No.12204514).
文摘We used a highly sensitive AC magnetic susceptibility technique to probe superconductivity in elemental titanium(Ti)under extreme pressures to 120 GPa in a diamond anvil cell(DAC).The measurements reveal that the critical temperature(Tc)of Ti rises monotonically with increasing pressure,reaching 6.1 K at 120 GPa.Our results confirm the bulk nature of the superconductivity in Ti,as evidenced by a robust diamagnetic response in the AC magnetic susceptibility.Our work provides a routine technique to probe Meissner effect of elemental superconductors at megabar pressures.
基金financially supported by the National Natural Science Foundation of China(52373271)Science,Technology and Innovation Commission of Shenzhen Municipality under Grant(KCXFZ20201221173004012)+1 种基金National Key Research and Development Program of Shaanxi Province(No.2023-YBNY-271)Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(2023T019).
文摘Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.
基金financially supported by the National Natural Science Foundation of China(Grant No.22325405,22402187 and 22432005).
文摘A recent study demonstrated that solid-state photochemically induced dynamic nuclear polarization(photo-CIDNP)can achieve significant 1H NMR hyperpolarization at high magnetic fields(9.4 T and 21.1 T).This was accomplished using a specially designed donor-chromophore-acceptor(D-C-A)molecule,which exhibits an excited state electron-electron interaction that is finely tuned to match the proton Larmor frequency under high-field conditions[1].
基金supported by the National Natural Science Foundation of China(Grant Nos.12241404,52225106,and 523B1007)Open Fund of the State Key Laboratory of Spintronics Devices and Technologies(Grant No.SPL-2401)。
文摘The emerging altermagnetic RuO_(2)with both compensated magnetic moments and broken time-reversal symmetry possesses nontrivial magneto-electronic responses and nonrelativistic spin currents that are closely related to the magnetic easy axis.Ru M_(3)-edge X-ray magnetic linear dichroism(XMLD)measurements were performed to probe the Néel order in RuO_(2).For epitaxial RuO_(2) films,characteristic XMLD signals were observed for either RuO_(2)(100)or RuO_(2)(110)at normal incidence or RuO_(2)(001)at oblique incidence.The signals disappeared when the test temperature exceeded the Néel temperature.For non-epitaxial RuO_(2) films,the flat lines in the XMLD patterns of RuO_(2)(100)and RuO_(2)(110)demonstrate that there is no in-plane uniaxial alignment of the Néel order in these samples because of the counterbalanced Néel order of the twin crystals,as evidenced by X-ray diffraction phi-scan measurements.Our experimental results unambiguously demonstrate antiferromagnetism in RuO_(2) films and reveal the spatial relation of the Néel order parallel to the RuO_(2)[001]crystalline axis.These findings deepen the understanding of RuO_(2) and other attractive altermagnetic materials used in the field of spintronics.
基金supported by the National Key R&D Program of China(Grant No.2024YFA1611103)the National Natural Science Foundation of China(Grant Nos.12374128,12374129,12074386,11974181,12204006,and 12250410238)+6 种基金the Fujian Natural Science Foundation Project(Grant No.2024J08082)the Foundation for the Introduction of High-Level Talents and the Scientific Research Launch Project of Sanming University(Grant No.113/KD23016P)Fujian Key Technology Innovation Projects(University Category)(Grant No.2022G02010)the Anhui Provincial Major S&T Project(Grant No.202305a12020005)the Alliance of International Science Organizations(Grant Nos.ANSO-VF-2022-03 and ANSO-VF-2023-03)supported by the Basic Research Program of the Chinese Academy of Sciences Based on Major Scientific Infrastructures(Grant No.JZHKYPT-2021-08)the High Magnetic Field Laboratory of Anhui Province under Contract No.AHHMFX-2020-02。
文摘The antiferromagnetic(AFM)semimetal NdSb is well known for the interplay between its exotic magnetism and topological properties.However,its magnetism remains poorly understood.In this study,we thoroughly investigated the magnetization of NdSb single crystals with a high magnetic field(H)of up to 30T applied in various directions.We found that the AFM phase is suppressed by a magnetic field of 9.41T when H‖[100]and 11.25T when H‖[110],whereas the suppression field ranges from 9.41 to 10.67T with a hysteresis of 1.26T when H‖[111].The magnetization of H‖[100],which is an easy direction with a typical magnetic transition,was studied in detail.The AFM phase with H‖[100]was suppressed at lower temperatures,disappearing at approximately 6.25 K.The critical exponents β=0.234(3),γ=0.824(6),and δ=4.90(6)were obtained for H‖[100],and aligned with a tricritical mean-field model.Analysis of the critical behavior suggests a fieldinduced tricritical phenomenon for H‖[100].An H-T phase diagram for an NdSb single crystal was constructed for H‖[100],revealing a field-induced first-order transition and a tricritical point(TCP)at T_(tr)=6.25K and H_(tr)=9.41 T.The clarification of the multiple magnetic phases and transitions in NdSb provides crucial insights into the correlation between its magnetism and topology.
文摘Ⅰ.SAMPLE SYNTHESIS.Single erystals of NdSb were synthesized by an In-fhux method.High purity chemical elements of Nd(99.9% purity,Alfa Aesar),8b(99.999%,Aladdin),and In beads(99.99%,Aladdin)were thoroughly mixed in a glove-box filledwith argon atmosphere,maintaining an atomie ratio of Nd:Sb:in=1:1:20.
基金the support from the Sichuan Normal Universitysupport from the National Natural Science Foundation of China(Grant No.22375157)+1 种基金support from the National Natural Science Foundation of China(Grant Nos.12474122,52171188,51771127,and 52111530143)the Central Government Funds of Guiding Local Scientific and Technological Development for Sichuan Province(Grant No.2021ZYD0025)。
文摘Lanthanide-based single-molecule magnets exhibit broad magnetic hysteresis,which manifests as slow magnetic relaxation in strong magnetic fields.However,the origin of the nontrivial hysteresis behaviors remains debated.Here,we propose two influential mechanisms:activation of optical-phonon-mediated direct transitions within the ground-state doublet and the resonant Raman process.These discoveries,coupled with the g-factor anisotropy,account for the observed hysteresis behaviors in the regimes of fast magnetic relaxation.Our findings complement the recognized mechanisms used to interpret the magnetic hysteresis of single-molecule magnets.
基金supported by the National Natural Science Foundation of China under Grant No.10225417the National Basic Research Program of China under Grant No.2006CB601003。
文摘A high saturation magnetic flux density(Bs)is essential for the development of Fe-based amorphous alloys for electromagnetic devices and motors.However,achieving a high Bs often compromises the glass-forming ability(GFA)of Fe-based amorphous alloys.This study investigates the effects of ferromagnetic elements(Fe,Co,and Ni)on the microstructure and magnetic properties of Fe86B7C7 amorphous alloys through experiments and ab initio molecular dynamics simulations.By analyzing both the experimental and simulation results,the relationship between the atomic structures,GFA,and magnetic properties of these amorphous alloys was determined.The results indicate that the GFA of the alloys is correlated with the proportion of icosahedral and body-centered cubic clusters.The addition of Co and Ni not only improved the GFA of the alloys but also effectively increased the overall magnetic moment with an appropriate amount of Co and a small amount of Ni.This increase in the magnetic moment primarily arises from the enhancement of the magnetic moment of Fe atoms,resulting from the redistribution between the spin-up and spin-down electrons of Fe-3d orbits,as well as the strong exchange interactions between Fe and Co and Fe–Ni pairs.The results obtained offer valuable insights into the correlation between the atomic structure and magnetic properties of these amorphous alloys and suggest potential directions for the optimization of Fe-based amorphous alloys.
基金supported by the National Natural Science Foundation of China[Grant Nos.52272288 and 51972039]the China Postdoctoral Science Foundation[No.2021M700658].
文摘The construction of carbon nanocoil(CNC)-based chiral-dielectric-magnetic trinity composites is considered as a promising approach to achieve excellent low-frequency microwave absorption.However,it is still challenging to further enhance the low frequency microwave absorption and elucidate the related loss mechanisms.Herein,the chiral CNCs are first synthesized on a threedimensional(3D)carbon foam and then combined with the FeNi/NiFe_(2)O_(4) nanoparticles to form a novel chiral-dielectric-magnetic trinity foam.The 3D porous CNC-carbon foam network provides excellent impedance matching and strong conduction loss.The formation of the FeNi-carbon interfaces induces interfacial polarization loss,which is confirmed by the density functional theory calculations.Further permeability analysis and the micromagnetic simulation indicate that the nanoscale chiral magnetic heterostructures achieve magnetic pinning and coupling effects,which enhance the magnetic anisotropy and magnetic loss capability.Owing to the synergistic effect between dielectricity,chirality,and magnetism,the trinity composite foam exhibits excellent microwave absorption performance with an ultrabroad effective absorption bandwidth(EAB)of 14 GHz and a minimum reflection of loss less than-50 dB.More importantly,the C-band EAB of the foam is extended to 4 GHz,achieving the full C-band coverage.This study provides further guidelines for the microstructure design of the chiral-dielectric-magnetic trinity composites to achieve broadband microwave absorption.
基金supported by the Instrument Developing Project of Magnetic Resonance Union of Chinese Academy of Sciences,Grant No.2022GZL002.
文摘Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.
文摘Wireless communications in extreme environments,such as underwater and underground,is an essential technology for interconnecting various devices and enables data transmission and networking.Existing wireless technologies using electromagnetic(EM)waves face many known problems,such as high path loss,unpredictable multi-path fading,and large antenna size in the lossy medium.In this article,the magnetic induction(MI)based physical layer communication is introduced as a promising solution for wireless transmissions in extreme environments.Specifically,the fundamentals of the MI-based communications are reviewed.Then,with the goal of establishing reliable and low-power links between small-size devices,we review several key physical layer technologies for MI-based communications,including the MIbased signal modulations,magnetic beamforming,and relay transmissions,and summarize their state-of-theart research advances.Finally,the related open issues and challenges in each area are analyzed and presented for future investigations.
基金supported by The National Natural Science Foundation of China(52170087,22276137).
文摘The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation method.MNMGH achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic field.The recovered silver crystals could be directly physically exfoliated,without acid/base additions.The selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective recovery.The in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional groups.Furthermore,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective reduction.Three-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery performance.This study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 51901163 and 12104171)the Fundamental Research Funds for the Central Universities (Grant No. 2021XXJS025)the Natural Science Foundation of Hubei Province (Grants No. 2024AFB888)。
文摘Electronics over flexible substrates offer advantages of flexibility, portability and low cost, and promising applications in the areas of energy, information, defense science and medical service. In recent years, tremendous progress has been witnessed in the development of flexible wearable devices that can be potentially massively deployed. Of particular interest are intelligent wearable devices, such as sensors and storage cells, which can be integrated by flexible magnetoelectronic devices based on magnetic thin films. To examine this further, the magnetic properties of FeNi thin films with different thicknesses grown on flexible graphene substrate are investigated at room temperature. The coercivity increases with increasing thicknesses of FeNi thin film, which can be attributed to the increase of grain size and decrease of surface roughness. Moreover, the thickness modulated magnetic property shows a magnetic anisotropy shift increase with varying thicknesses of FeNi thin film by using measurements based on ferromagnetic resonance, which further enhances the resonance frequency. In addition, the resonance peak is quite stable after bending it for ten cycles. The result is promising for the future design of flexible magnetoelectronic devices.
文摘Based on Ginzburg-Landau theory,we investigate the electromagnetic properties of two-band superconductors with broken time-reversal symmetry.We propose an apparatus of a superconducting ring integrated with a microbridge structure to probe the peculiar topological excitations in the chiral system.The phase difference of two order parameters in the superconductor satisfies the double sine-Gordon equation,and a linear relationship between the phase difference at the two ends of the junction and the total magnetic flux in the ring can be obtained.Then with the Josephson current-phase relation,we establish the dependence of the circulating current and magnetic flux on the applied external magnetic field.Our results show that this single-junction system will exhibit the irreversible behaviors and two different types of fractional flux transitions can clearly manifest the time-reversal symmetry breaking in two-component superconductors.
基金supported by the National Magnetic Confinement Fusion Energy R&D Program of China (Nos.2018YFE0309103 and 2019YFE03010004)National Natural Science Foundation of China (Nos.12475222,12205122,and 51821005)Hubei International Science and Technology Cooperation Projects (No.2022EHB003)。
文摘A large number of runaway electrons(REs)generated during disruption can cause significant damage to next-generation large-scale tokamaks.The influence of three-dimensional(3D)helical magnetic perturbations on the suppression of RE generation was explored using a set of 3D helical coils in J-TEXT tokamak,which can excite m/n=-2/2 helical magnetic perturbations.Experimental evidence shows that the-2/2 magnetic perturbations caused by the opposite coil current direct plasma toward the high-field side,simultaneously enhancing the magnetic fluctuations,which would enhance the radial loss of REs and even prevent RE generation.On the other hand,-2/2 magnetic perturbations can also reduce the cooling time during the disruption phase and generate a population of high-energy REs,which can interact with high-frequency magnetic fluctuations and in turn suppress RE generation.The critical helical coil current was found to correlate with electron density,requiring higher coil currents at higher densities.According to the statistical analysis of RE generation at different electron densities,the applied-2/2 magnetic perturbations can increase the magnetic fluctuations to the same level at lower electron densities,which can decrease the threshold electron density for RE suppression.This will be beneficial for RE mitigation in future large tokamak devices.
基金support for this work by Key Research and Development Project of Henan Province(Grant.No.241111232300)the National Natural Science Foundation of China(Grant.No.52273085 and 52303113)the Open Fund of Yaoshan Laboratory(Grant.No.2024003).
文摘The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.
基金support from the National Natural Science Foundation of China(22268025,52473083,and 22475176)Key Research and Development Program of Yunnan Province(202403AP140036)+2 种基金Natural Science Basic Research Program of Shaanxi(2024JC-TBZC-04)Applied Basic Research Program of Yunnan Province(202201AT070115 and 202201BE070001-031)supported by the Innovation Capability Support Program of Shaanxi(2024RS-CXTD-57).
文摘The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in modern electronic devices.Hence,a composite with three-dimensional network(Ho/U-BNNS/WPU)is developed by simultaneously incorporating magnetically modified boron nitride nanosheets(M@BNNS)and non-magnetic organo-grafted BNNS(U-BNNS)into waterborne polyurethane(WPU)to synchronous molding under a horizontal magnetic field.The results indicate that the continuous in-plane pathways formed by M@BNNS aligned along the magnetic field direction,combined with the bridging structure established by U-BNNS,enable Ho/U-BNNS/WPU to exhibit exceptional in-plane(λ//)and through-plane thermal conductivities(λ_(⊥)).In particular,with the addition of 30 wt%M@BNNS and 5 wt%U-BNNS,theλ//andλ_(⊥)of composites reach 11.47 and 2.88 W m^(-1) K^(-1),respectively,which representing a 194.2%improvement inλ_(⊥)compared to the composites with a single orientation of M@BNNS.Meanwhile,Ho/U-BNNS/WPU exhibits distinguished thermal management capabilities as thermal interface materials for LED and chips.The composites also demonstrate excellent flame retardancy,with a peak heat release and total heat release reduced by 58.9%and 36.9%,respectively,compared to WPU.Thus,this work offers new insights into the thermally conductive structural design and efficient flame-retardant systems of polymer composites,presenting broad application potential in electronic packaging fields.
基金financially supported by the National Natural Science Foundation of China(No.51902025).
文摘Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials(PCMs).Magnetically-responsive phase change thermal storage materials are considered an emerging concept for energy storage systems,enabling PCMs to perform unprecedented functions(such as green energy utilization,magnetic thermotherapy,drug release,etc.).The combination of multifunctional magnetic nanomaterials and PCMs is a milestone in the creation of advanced multifunctional composite PCMs.However,a timely and comprehensive review of composite PCMs based on magnetic nanoparticle modification is still missing.Herein,we furnish an exhaustive exposition elucidating the cutting-edge advancements in magnetically responsive composite PCMs.We delve deeply into the multifarious roles assumed by distinct nanoparticles within composite PCMs of varying dimensions,meticulously scrutinizing the intricate interplay between their architectures and thermophysical attributes.Moreover,we prognosticate future research trajectories,delineate alternative stratagems,and illuminate prospective avenues.This review is intended to stimulate broader academic interest in interdisciplinary fields and provide valuable insights into the development of next-generation magnetically-responsive composite PCMs.
基金funded by National Natural Science Foundation of China(NSFC)(Nos.12075053,11505021 and 11975068)by National Key R&D Program of China(No.2022YFE 03060002)+1 种基金by Fundamental Research Funds for the Central Universities(No.2232024G-10)supported by the U.S.DoE Office of Science(No.DE-FG02–95ER54309)。
文摘Toroidal torques,generated by the resonant magnetic perturbation(RMP)and acting on the plasma column,are numerically systematically investigated for an ITER baseline scenario.The neoclassical toroidal viscosity(NTV),in particular the resonant portion,is found to provide the dominant contribution to the total toroidal torque under the slow plasma flow regime in ITER.While the electromagnetic torque always opposes the plasma flow,the toroidal torque associated with the Reynolds stress enhances the plasma flow independent of the flow direction.A peculiar double-peak structure for the net NTV torque is robustly computed for ITER,as the toroidal rotation frequency is scanned near the zero value.This structure is found to be ultimately due to a non-monotonic behavior of the wave-particle resonance integral(over the particle pitch angle)in the superbanana plateau NTV regime in ITER.These findings are qualitatively insensitive to variations of a range of factors including the wall resistivity,the plasma pedestal flow and the assumed frequency of the rotating RMP field.
基金supported by Key Research and Development Project of Shandong Province(2021ZDSYS12)National Natural Science Foundation of China(22076086,21777089)+3 种基金Taishan Scholar Program of Shandong Province(ts20190948)Shandong Province Science and Technology Small and Medium Enterprises Innovation Ability Enhancement Project(2023TSGC0689,2023TSGC0055)Natural Science Foundation of Shandong Province(ZR2021MB086,ZR2023QB035)Jinan City University and Institute Innovation Team Project(2021GXRC061,20228045,202333027)。
文摘Organophosphorus pesticides(OPPs)in foods pose a serious threat to human health,motivating the development of novel analytical methods for their rapid detection and quantification.A magnetic covalent organic framework(M-COF)adsorbent for the magnetic solid-phase extraction(MSPE)of OPPs from foods was reported.M-COF was synthesized by the Schiff base condensation reaction of 1,3,5-tris(4-aminophenyl)benzene and 4,4-biphenyldicarboxaldehyde on the surface of amino-functionalized magnetic nanoparticles.Density functional theory(DFT)calculations showed that adsorption of OPPs onto the surface of M-COF involved hydrophobic effects,van der Waals interactions,π-πinteractions,halogen-N bonding,and hydrogen bonding.Combined with gas chromatography-mass spectrometry(GC-MS)technology,the MSPE method features low limits of detection for OPPs(0.002-0.015μg/L),good reproducibility(1.45%-6.14%),wide linear detection range(0.01-1μg/L,R≥0.9935),and satisfactory recoveries(87.3%-110.4%).The method was successfully applied for the trace analysis of OPPs in spiked fruit juices.
