Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are...Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are a few marble producing quarries in the area, it is long been known that the marbles of this area are generally highly fractured and don’t yield large blocks or suitable slabs meeting the industrial demands. Thus, most of the production is currently carried out mainly as building stone, crushed stone and micronized calcite. Due mainly to high demand, micronized calcite has been becoming very significant export product to the state’s economy. Because the Nigde marbles are coarse grained with high CaCO3 content, high purity and whiteness, they are considered to be the highest quality micronized calcite quarries in the country. Consequently, the area drew many national and international investors resulting in significant increase in the number and extent of micronized calcite plants in the area. In early 1980’s, the city of Nigde had only one or two plants, it is now well over 5 including foreign investors and joint ventures. Annual production is also considerably increased from 20,000-30,000 tones to almost half a million tones and it is still in increasing trend.展开更多
The analysis of gunshot residue(GSR) has played an integral role within the legal system in relation to shooting cases. With a characteristic elemental composition of lead, antimony, barium, and a typically discrimina...The analysis of gunshot residue(GSR) has played an integral role within the legal system in relation to shooting cases. With a characteristic elemental composition of lead, antimony, barium, and a typically discriminative spheroidal morphology, the presence and distribution of GSR can aid in firearm investigations. In this experiment, three shots of low velocity rim-fire ammunition were fired over polished silicon collection substrates placed at six intervals over a 100 cm range. The samples were analysed using a Field Emission Gun Scanning Electron Microscope(FEG-SEM) in conjunction with an X-flash Energy Dispersive X-ray(EDX) detector, allowing for GSR particle analyses of composition and structure at the sub-micron level. The results of this experiment indicate that although classic spheroidal particles are present consistently throughout the entire range of samples their sizes vary significantly, and at certain distances from the firearm particles with an irregular morphology were discerned, forming "impactdisrupted" GSR particles, henceforth colloquially referred to as "splats". Upon further analysis, trends with regards to the formation of these splat particles were distinguished. An increase in splat frequency was observed starting at 10 cm from the firearm, with 147 mm^(-2) splat density, reaching a maximal flux at 40 cm(451 mm^(-2)), followed by a gradual decrease to the maximum range sampled. Moreover, the structural morphology of the splats changes throughout the sampling range. At the distances closest to the firearm, molten-looking particles were formed, demonstrating the metallic residues were in a liquid state when their flight path was disrupted. However, at increased distances-primarily where the discharge plume was at maximum dispersion and moving away from the firearm, the residues have had time to cool in-fight resulting in semi-congealed and solid particles that subsequently disrupted upon impact, forming more structured as well as disaggregated splats. The relative compositions of the characteristic elements that are present in GSR also change in the different splat morphologies sampled,which may contribute to the particles' physical structures. Two distinct populations of splats were also observed: circular and elongated, which suggest the residues hit the substrate at different angles. The difference in the splat impact angle can be ascribed to the position of the residues within the firearm discharge plume; particles get caught up in the vortex that is created by the discharge gases behind the projectile as it leaves the barrel, thereby affecting their directionality and flight time. This reasoning could also justify the existence of both spheroidal and splat particles at certain distances. The novel sampling and analytical techniques used in this experiment have provided previously unknown information in relation to GSR structure and formation which could have greater implications to its current analysis amongst laboratories and law enforcement agencies worldwide.展开更多
文摘Marble that exploited for micronized calcite production in Nigde area (South Central Turkey) occur in the Upper Cretaceous Gümü ler, A gedi i, and Kaleboynu Formations of the Nigde Massif. Although there are a few marble producing quarries in the area, it is long been known that the marbles of this area are generally highly fractured and don’t yield large blocks or suitable slabs meeting the industrial demands. Thus, most of the production is currently carried out mainly as building stone, crushed stone and micronized calcite. Due mainly to high demand, micronized calcite has been becoming very significant export product to the state’s economy. Because the Nigde marbles are coarse grained with high CaCO3 content, high purity and whiteness, they are considered to be the highest quality micronized calcite quarries in the country. Consequently, the area drew many national and international investors resulting in significant increase in the number and extent of micronized calcite plants in the area. In early 1980’s, the city of Nigde had only one or two plants, it is now well over 5 including foreign investors and joint ventures. Annual production is also considerably increased from 20,000-30,000 tones to almost half a million tones and it is still in increasing trend.
文摘The analysis of gunshot residue(GSR) has played an integral role within the legal system in relation to shooting cases. With a characteristic elemental composition of lead, antimony, barium, and a typically discriminative spheroidal morphology, the presence and distribution of GSR can aid in firearm investigations. In this experiment, three shots of low velocity rim-fire ammunition were fired over polished silicon collection substrates placed at six intervals over a 100 cm range. The samples were analysed using a Field Emission Gun Scanning Electron Microscope(FEG-SEM) in conjunction with an X-flash Energy Dispersive X-ray(EDX) detector, allowing for GSR particle analyses of composition and structure at the sub-micron level. The results of this experiment indicate that although classic spheroidal particles are present consistently throughout the entire range of samples their sizes vary significantly, and at certain distances from the firearm particles with an irregular morphology were discerned, forming "impactdisrupted" GSR particles, henceforth colloquially referred to as "splats". Upon further analysis, trends with regards to the formation of these splat particles were distinguished. An increase in splat frequency was observed starting at 10 cm from the firearm, with 147 mm^(-2) splat density, reaching a maximal flux at 40 cm(451 mm^(-2)), followed by a gradual decrease to the maximum range sampled. Moreover, the structural morphology of the splats changes throughout the sampling range. At the distances closest to the firearm, molten-looking particles were formed, demonstrating the metallic residues were in a liquid state when their flight path was disrupted. However, at increased distances-primarily where the discharge plume was at maximum dispersion and moving away from the firearm, the residues have had time to cool in-fight resulting in semi-congealed and solid particles that subsequently disrupted upon impact, forming more structured as well as disaggregated splats. The relative compositions of the characteristic elements that are present in GSR also change in the different splat morphologies sampled,which may contribute to the particles' physical structures. Two distinct populations of splats were also observed: circular and elongated, which suggest the residues hit the substrate at different angles. The difference in the splat impact angle can be ascribed to the position of the residues within the firearm discharge plume; particles get caught up in the vortex that is created by the discharge gases behind the projectile as it leaves the barrel, thereby affecting their directionality and flight time. This reasoning could also justify the existence of both spheroidal and splat particles at certain distances. The novel sampling and analytical techniques used in this experiment have provided previously unknown information in relation to GSR structure and formation which could have greater implications to its current analysis amongst laboratories and law enforcement agencies worldwide.
