A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_...A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)O.The structure was characterized by single-crystal X-ray diffraction,powder X-ray diffraction,elemental analysis,and infrared spectroscopy.Cd-CP belongs to the monoclinic crystal system with the P2_1/c space group and performs in a 1D double-chain structure.The adjacent double chains further form a 3D supramolecular network structure through hydrogen bonding.Thermogravimetric analysis shows that Cd-CP has good thermal stability.Fluorescence analysis showed that Cd-CP had good choosing selectively and was sensitive to metal ions(Fe^(3+)and Zn^(2+)),2,4,6-trinitrophenylhydrazine(TRI),and pyrimethanil(Pth).Interestingly,when Cd-CP was used for fluorescence detection of metal ions,it was found to have a fluorescence quenching effect on Fe^(3+)but had an obvious enhancement effect on Zn^(2+).Therefore,we designed an“on-off-on”logic gate.In addition,the mechanism of fluorescence sensing has been deeply explored.CCDC:2258625.展开更多
通过分析服务组合的故障需求,给出服务组合故障处理的框架.该框架采用Petri网来解决服务组合的错误发现及其处理问题.重点讨论了可用服务失败、组件失败及网络故障的情况,并相应地给出了服务组合故障模型.在此基础上对故障处理模型进行...通过分析服务组合的故障需求,给出服务组合故障处理的框架.该框架采用Petri网来解决服务组合的错误发现及其处理问题.重点讨论了可用服务失败、组件失败及网络故障的情况,并相应地给出了服务组合故障模型.在此基础上对故障处理模型进行分析,给出服务组合故障处理正确性准则,并证明了其正确性.最后,采用CTL(computational tree logic)描述相关性质并提出验证服务组合故障分析的实施算法.仿真结果表明,该方法在处理服务组合故障时具有一定的优越性.展开更多
文摘A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)O.The structure was characterized by single-crystal X-ray diffraction,powder X-ray diffraction,elemental analysis,and infrared spectroscopy.Cd-CP belongs to the monoclinic crystal system with the P2_1/c space group and performs in a 1D double-chain structure.The adjacent double chains further form a 3D supramolecular network structure through hydrogen bonding.Thermogravimetric analysis shows that Cd-CP has good thermal stability.Fluorescence analysis showed that Cd-CP had good choosing selectively and was sensitive to metal ions(Fe^(3+)and Zn^(2+)),2,4,6-trinitrophenylhydrazine(TRI),and pyrimethanil(Pth).Interestingly,when Cd-CP was used for fluorescence detection of metal ions,it was found to have a fluorescence quenching effect on Fe^(3+)but had an obvious enhancement effect on Zn^(2+).Therefore,we designed an“on-off-on”logic gate.In addition,the mechanism of fluorescence sensing has been deeply explored.CCDC:2258625.
文摘通过分析服务组合的故障需求,给出服务组合故障处理的框架.该框架采用Petri网来解决服务组合的错误发现及其处理问题.重点讨论了可用服务失败、组件失败及网络故障的情况,并相应地给出了服务组合故障模型.在此基础上对故障处理模型进行分析,给出服务组合故障处理正确性准则,并证明了其正确性.最后,采用CTL(computational tree logic)描述相关性质并提出验证服务组合故障分析的实施算法.仿真结果表明,该方法在处理服务组合故障时具有一定的优越性.
