Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)Ni...Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)NiO_(2)suffers from inferior delithiation kinetics during the first cycle.Herein,we investigated the effects of the cost-effective copper substituted Li_(2)Ni_(1-x)Cu_(x)O_(2)(x=0,0.2,0.3,0.5,0.7)synthesized by a high-temperature solid-phase method on the structure,morphology,electrochemical performance of graphite‖LiFePO_(4)battery.The X-ray diffraction(XRD)refinement result demonstrated that Cu substitution strategy could be favorable for eliminating the NiO_(x)impurity phase and weakening Li-O bond.Analysis on density of states(DOS)indicates that Cu substitution is good for enhancing the electronic conductivity,as well as reducing the delithi-ation voltage polarization confirmed by electrochemical characterizations.Therefore,the optimal Li_(2)Ni_(0.7)Cu_(0.3)O_(2)delivered a high delithiation capacity of 437 mAh·g^(-1),around 8%above that of the pristine Li_(2)NiO_(2).Furthermore,a graphite‖LiFePO_(4)pouch cell with a nominal capacity of 3000 mAh demonstrated a notably improved reversible capacity,energy density and cycle life through introducing 2 wt%Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive,delivering a 6.2 mAh·g^(-1)higher initial discharge capacity and achieving around 5%improvement in capacity retentnion at 0.5P over 1000 cycles.Additionally,the post-mortem analyses testified that the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive could suppress solid electrolyte interphase(SEI)decomposition and homogenize the Li distribution,which benefits to stabilizing interface between graphite and electrolyte,and alleviating dendritic Li plating.In conclusion,the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive may offer advantages such as lower cost,lower delithiation voltage and higher prelithiation capacity compared with Li_(2)NiO_(2),making it a promising candidate of cathode prelithiation additive for next-generation LIBs.展开更多
Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may ...Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may exacerbate these limitations.To address these issues,this study introduced a novel cement-stabilized permeable recycled aggregate material.A total of 162 beam specimens prepared with nine different levels of cement-aggregate ratio were tested to evaluate their permeability,bending load,and bending fatigue life.The experimental results indicate that increasing the content of recycled aggregates led to a reduction in both permeability and bending load.Additionally,the inclusion of recycled aggregates diminished the energy dissipation capacity of the specimens.These findings were used to establish a robust relationship between the initial damage in cement-stabilized permeable recycled aggregate material specimens and their fatigue life,and to propose a predictive model for their fatigue performance.Further,a method for assessing fatigue damage based on the evolution of fatigue-induced strain and energy dissipation was developed.The findings of this study provide valuable insights into the mechanical behavior and fatigue performance of cement-stabilized permeable recycled aggregate materials,offering guidance for the design of low-carbon-emission,permeable,and durable roadways incorporating recycled aggregates.展开更多
The effects of nanosecond laser shock peening without coating(LSPwC)and nanosecond stacked femtosecond laser shock peening compound strengthening(LSP-CS)on the surface integrity and fretting fatigue lifetime at 500℃o...The effects of nanosecond laser shock peening without coating(LSPwC)and nanosecond stacked femtosecond laser shock peening compound strengthening(LSP-CS)on the surface integrity and fretting fatigue lifetime at 500℃of GH 4169 dovetail component were investigated.The results show that LSP treatment does not significantly lead to changes in the grain size of GH 4169 alloy,but it introduces a large number of dislocations,resulting in the formation of a plastic deformation layer and residual compressive stress layer.The surface microhardness increased by 20.5%and 28.6%after being treated by LSPwC and LSP-CS,respectively.The surface residual compressive stresses were(-306.5±42.5)MPa and(-404.3±34.7)MPa,respectively;The depth of both the hardening layer and the residual compressive stress layer is 400μm,and along the cross-section with 0-100μm region after LSP-CS treatment has higher hardness and greater residual compressive stress.The fretting fatigue lifetime of the GH 4169 dovetail component at 500℃was increased by 346.8%and 494.9%,which is the result of the combined effects of the hardening layer and the residual stress layer.The LSP-CS treatment can effectively make up for the disadvantage of the LSPwC treatment,and further enhance the fretting fatigue lifetime of the GH 4169 dovetail component at high temperature.展开更多
Using solid waste as a substitute for conventional cement has become an important way to reduce carbon emissions.This paper attempted to utilize steel slag(SS)and fly ash(FA)as supplementary cementitious material by u...Using solid waste as a substitute for conventional cement has become an important way to reduce carbon emissions.This paper attempted to utilize steel slag(SS)and fly ash(FA)as supplementary cementitious material by utilizing CO_(2)mineralization curing technology.This study examined the dominant and interactive influences of the residual water/cement ratio,CO_(2)pressure,curing time,and SS content on the mechanical properties and CO_(2)uptake rate of CO_(2)mineralization curing SS-FA-Portland cement ternary paste specimens.Additionally,microstructural development was analyzed.The findings demonstrated that each factor significantly affected compressive strength and CO_(2)uptake rate,with factor interactions becoming more pronounced at higher SS dosages(>30%),lower residual water/cement ratios(0.1-0.15),and CO_(2)pressures of 0.1-0.3 MPa.Microscopic examinations revealed that mineralization primarily yielded CaCO_(3)and silica gel.The residual w/c ratio and SS content significantly influenced the CaCO_(3)content and crystallinity of the mineralization products.Post-mineralization curing,the percentage of pores larger than 50 nm significantly decreased,the proportion of harmless pores smaller than 20 nm increased,and pore structure improved.This study also found that using CO_(2)mineralization curing SS-FA-Portland cement solid waste concrete can significantly reduce the negative impact on the environment.展开更多
根据美国Second Life Library 2.0虚拟社区的建设现状,分析图书馆虚拟社区的营销模式,认为虚拟社区改变了用户被动服务的地位,获得了主动权。对此,图书馆需采用聚众为媒的策略,为虚拟社区中的用户营造良好的使用体验,引导用户成为创建...根据美国Second Life Library 2.0虚拟社区的建设现状,分析图书馆虚拟社区的营销模式,认为虚拟社区改变了用户被动服务的地位,获得了主动权。对此,图书馆需采用聚众为媒的策略,为虚拟社区中的用户营造良好的使用体验,引导用户成为创建服务的合作者和品牌传播的中间人。展开更多
基金supported by the Significant Science and Technology Project in Xiamen(Future Industry Field)(Grant No.3502Z20231057).
文摘Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)NiO_(2)suffers from inferior delithiation kinetics during the first cycle.Herein,we investigated the effects of the cost-effective copper substituted Li_(2)Ni_(1-x)Cu_(x)O_(2)(x=0,0.2,0.3,0.5,0.7)synthesized by a high-temperature solid-phase method on the structure,morphology,electrochemical performance of graphite‖LiFePO_(4)battery.The X-ray diffraction(XRD)refinement result demonstrated that Cu substitution strategy could be favorable for eliminating the NiO_(x)impurity phase and weakening Li-O bond.Analysis on density of states(DOS)indicates that Cu substitution is good for enhancing the electronic conductivity,as well as reducing the delithi-ation voltage polarization confirmed by electrochemical characterizations.Therefore,the optimal Li_(2)Ni_(0.7)Cu_(0.3)O_(2)delivered a high delithiation capacity of 437 mAh·g^(-1),around 8%above that of the pristine Li_(2)NiO_(2).Furthermore,a graphite‖LiFePO_(4)pouch cell with a nominal capacity of 3000 mAh demonstrated a notably improved reversible capacity,energy density and cycle life through introducing 2 wt%Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive,delivering a 6.2 mAh·g^(-1)higher initial discharge capacity and achieving around 5%improvement in capacity retentnion at 0.5P over 1000 cycles.Additionally,the post-mortem analyses testified that the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive could suppress solid electrolyte interphase(SEI)decomposition and homogenize the Li distribution,which benefits to stabilizing interface between graphite and electrolyte,and alleviating dendritic Li plating.In conclusion,the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive may offer advantages such as lower cost,lower delithiation voltage and higher prelithiation capacity compared with Li_(2)NiO_(2),making it a promising candidate of cathode prelithiation additive for next-generation LIBs.
基金Project(2024JJ2073)supported by the Science Fund for Distinguished Young Scholars of Hunan Province,ChinaProjects(2023YFC3807205,2019YFC1904704)+4 种基金supported by the National Key R&D Program of ChinaProject(52178443)supported by the National Natural Science Foundation of ChinaProject(2024ZZTS0109)supported by Fundamental Research Funds for the Central Universities of Central South University,China。
文摘Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may exacerbate these limitations.To address these issues,this study introduced a novel cement-stabilized permeable recycled aggregate material.A total of 162 beam specimens prepared with nine different levels of cement-aggregate ratio were tested to evaluate their permeability,bending load,and bending fatigue life.The experimental results indicate that increasing the content of recycled aggregates led to a reduction in both permeability and bending load.Additionally,the inclusion of recycled aggregates diminished the energy dissipation capacity of the specimens.These findings were used to establish a robust relationship between the initial damage in cement-stabilized permeable recycled aggregate material specimens and their fatigue life,and to propose a predictive model for their fatigue performance.Further,a method for assessing fatigue damage based on the evolution of fatigue-induced strain and energy dissipation was developed.The findings of this study provide valuable insights into the mechanical behavior and fatigue performance of cement-stabilized permeable recycled aggregate materials,offering guidance for the design of low-carbon-emission,permeable,and durable roadways incorporating recycled aggregates.
基金Project(2022YFB3401900)supported by the the National Key R&D of ChinaProject(2025YFHZ0163)supported by the the Science and Technology Projects in Sichuan Province,ChinaProject(2682024GF004)supported by Fundamental Research Funds for the Centeral University,China。
文摘The effects of nanosecond laser shock peening without coating(LSPwC)and nanosecond stacked femtosecond laser shock peening compound strengthening(LSP-CS)on the surface integrity and fretting fatigue lifetime at 500℃of GH 4169 dovetail component were investigated.The results show that LSP treatment does not significantly lead to changes in the grain size of GH 4169 alloy,but it introduces a large number of dislocations,resulting in the formation of a plastic deformation layer and residual compressive stress layer.The surface microhardness increased by 20.5%and 28.6%after being treated by LSPwC and LSP-CS,respectively.The surface residual compressive stresses were(-306.5±42.5)MPa and(-404.3±34.7)MPa,respectively;The depth of both the hardening layer and the residual compressive stress layer is 400μm,and along the cross-section with 0-100μm region after LSP-CS treatment has higher hardness and greater residual compressive stress.The fretting fatigue lifetime of the GH 4169 dovetail component at 500℃was increased by 346.8%and 494.9%,which is the result of the combined effects of the hardening layer and the residual stress layer.The LSP-CS treatment can effectively make up for the disadvantage of the LSPwC treatment,and further enhance the fretting fatigue lifetime of the GH 4169 dovetail component at high temperature.
基金Project(52479115)supported by the National Natural Science Foundation of ChinaProject(2024SF-YBXM-615)supported by the Key Research and Development Program of Shaanxi Province,China+1 种基金Project(2022943)supported by the Youth Innovation Team of Shaanxi Universities,ChinaProject(300102283721)supported by the Fundamental Research Funds for the Central Universities,China。
文摘Using solid waste as a substitute for conventional cement has become an important way to reduce carbon emissions.This paper attempted to utilize steel slag(SS)and fly ash(FA)as supplementary cementitious material by utilizing CO_(2)mineralization curing technology.This study examined the dominant and interactive influences of the residual water/cement ratio,CO_(2)pressure,curing time,and SS content on the mechanical properties and CO_(2)uptake rate of CO_(2)mineralization curing SS-FA-Portland cement ternary paste specimens.Additionally,microstructural development was analyzed.The findings demonstrated that each factor significantly affected compressive strength and CO_(2)uptake rate,with factor interactions becoming more pronounced at higher SS dosages(>30%),lower residual water/cement ratios(0.1-0.15),and CO_(2)pressures of 0.1-0.3 MPa.Microscopic examinations revealed that mineralization primarily yielded CaCO_(3)and silica gel.The residual w/c ratio and SS content significantly influenced the CaCO_(3)content and crystallinity of the mineralization products.Post-mineralization curing,the percentage of pores larger than 50 nm significantly decreased,the proportion of harmless pores smaller than 20 nm increased,and pore structure improved.This study also found that using CO_(2)mineralization curing SS-FA-Portland cement solid waste concrete can significantly reduce the negative impact on the environment.
基金supported by the National Natural Science Foundation of China (21073120, 20773087, 21006063)Science and Technology Commission of Shanghai Municipality, China (09DZ1203603, 10DZ1202702)~~
文摘分别以四水磷酸铁(Fe PO4·4H2O)和二水草酸亚铁(FeC_2O_4·2 H_2O)为铁源,采用简单便捷的流变相法制备了碳包覆LiFe_(0.5)Co_(0.5)PO_4固溶体材料(LiFe_(0.5)Co_(0.5)PO_4/C,简称为LFCP/C)。采用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、恒流充放电等测试手段对复合材料的物相、形貌结构和电化学性能进行了表征和测试。结果表明,2种铁源得到的材料均为橄榄石晶型结构且结晶度良好,二者在颗粒尺寸分布、碳包覆效果和电化学性能方面具有显著的差别。用作锂离子电池正极材料时,以FeC_2O_4·2 H_2O为原料得到的LFCP/C具有更优异的电性能:在2.5~5.0 V电压范围内,0.1C倍率下(1C=150 m A·g^(-1)),放电比容量为137.5m Ah·g^(-1),在10C仍具有57.6 m Ah·g^(-1)的放电比容量;0.5C循环100次后容量仍保持78.1%。该样品更佳的电化学性能主要得益于其更小的平均颗粒尺寸,更高的比表面积和理想的碳包覆效果。
