Lithium-oxygen batteries attract considerable attention due to exceptionally high theoretical energy density,while the development remains in its early stage.As is widely suggested,the solution mechanism induces great...Lithium-oxygen batteries attract considerable attention due to exceptionally high theoretical energy density,while the development remains in its early stage.As is widely suggested,the solution mechanism induces greater discharge capacity,while the surface mechanism induces greater cycle stability.Therefore,battery performance can be improved by adjusting the reaction mechanism.Previous studies predominantly focus on extremely thin or flat electrodes.In contrast,this work utilizes thick electrodes,emphasizing the importance of mass transport.Given that the electrolyte solvent is the main site of mass transport,the effects of two typical solvents on mass transport and battery performance are investigated:dimethyl sulfoxide with low viscosity and a high O_(2) diffusion rate and tetraethylene glycol dimethyl ether with high O_(2) solubility and high Li+transport capability.The results reveal a novel pathway for reaction mechanism induction where the mechanism varies with the spatial position of the electrode.As the spatial distribution of the electrode progresses,a layered appearance of solution mechanism products,transition state products,and surface mechanism products emerges,which is attributed to the increase in the mass transfer resistance.This work presents a distinct perspective on the way solvents influence reaction pathways and offers a new approach to regulating reaction pathways.展开更多
To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechani...To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.展开更多
A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the movi...A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the moving platform along the guideway,the levitation subsystem uses six pairs of electromagnets to steadily suspend the moving platform over the guideway.The model of the levitation system,which is a typical nonlinear multi-input multi-output coupling system and has many inner nonlinear coupling characteristics,was deduced.For testifying the model,the levitation mechanism was firstly controlled by proportional-integral-differential(PID) control,and then a lot of input-output data were collected for model parameter identification.The least-square parameter identification method was used.The identification results prove that the model is feasible and suitable for the real system.展开更多
Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics...Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics within NC-based propellants was reported,and its effect on the evolution of mechanical properties was not interpreted yet.This study is conducted to gain a comprehensive understanding of hot-air drying for NC-based propellants and clarify the effect of temperature on solvent transport behavior and further the change of mechanical properties during drying.The drying kinetic curves show the drying time required is decreased but the steady solvent content is increased and the drying rate is obviously increased with the increase of hot-air temperatures,indicating hot-air temperatures have a significant effect on drying kinetics.A modified drying model was established,and results show it is more appropriate to describe solvent transport behavior within NC-based propellants.Moreover,two linear equations were established to exhibit the relationship between solvent content and its effect on the change of tensile properties,and the decrease of residual solvent content causes an obvious increase of tensile strength and tensile modulus of propellant products,indicating its mechanical properties can be partly improved by adjustment of residual solvent content.The outcomes can be used to clarify solvent transport mechanisms and optimize drying process parameters of double-based gun propellants.展开更多
针对红外船舶图像目标特征模糊、背景复杂以及小目标漏检等问题,基于YOLOv8提出一种面向海上交通中船舶目标的检测算法YOLO-IST(YOLO for infrared ship target)。在基线模型的骨干网络中引入C2f_DBB模块和CPCA注意力机制,通过增加特征...针对红外船舶图像目标特征模糊、背景复杂以及小目标漏检等问题,基于YOLOv8提出一种面向海上交通中船舶目标的检测算法YOLO-IST(YOLO for infrared ship target)。在基线模型的骨干网络中引入C2f_DBB模块和CPCA注意力机制,通过增加特征提取层来提升模型对目标的识别能力;利用C2f_Faster_EMA模块替换颈部网络中的C2f模块,以提升模型检测精度和速度;采用多重注意力的动态检测头Dynamic Head优化模型框架,增强模型对小船舶目标的检测效果。研究结果表明:YOLO-IST的召回率R_(ecall)、精确率P_(recision)、平均精度M_(ap@50)、平均精度M_(ap@50-95)和F_(1score)分别达到89.7%、90.5%、94.7%、66.6%、90.1%,较基线模型YOLOv8分别提升了4.5%、3.8%、4.4%、4.7%、4.2%。该模型的提出在海上智能交通中具有较广泛的应用前景。展开更多
基金supported by the National Natural Science Foundation of China(52376080 and 52306122)the Anhui Provincial Natural Science Foundation(2308085QE174)+3 种基金the China Postdoctoral Science Foundation(2023TQ0346)the Postdoctoral Fellowship Program of CPSF(GZC20232522)the Fundamental Research Funds for the Central Universities(WK2090000057)the Students’Innovation and Entrepreneurship Foundation of USTC(CY2023C008).
文摘Lithium-oxygen batteries attract considerable attention due to exceptionally high theoretical energy density,while the development remains in its early stage.As is widely suggested,the solution mechanism induces greater discharge capacity,while the surface mechanism induces greater cycle stability.Therefore,battery performance can be improved by adjusting the reaction mechanism.Previous studies predominantly focus on extremely thin or flat electrodes.In contrast,this work utilizes thick electrodes,emphasizing the importance of mass transport.Given that the electrolyte solvent is the main site of mass transport,the effects of two typical solvents on mass transport and battery performance are investigated:dimethyl sulfoxide with low viscosity and a high O_(2) diffusion rate and tetraethylene glycol dimethyl ether with high O_(2) solubility and high Li+transport capability.The results reveal a novel pathway for reaction mechanism induction where the mechanism varies with the spatial position of the electrode.As the spatial distribution of the electrode progresses,a layered appearance of solution mechanism products,transition state products,and surface mechanism products emerges,which is attributed to the increase in the mass transfer resistance.This work presents a distinct perspective on the way solvents influence reaction pathways and offers a new approach to regulating reaction pathways.
基金Foundation item： Project（PLN1129）supported by Opening Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation （Southwest Petroleum University）, China
文摘To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.
基金Projects(50735007,51005253) supported by the National Natural Science Foundation of ChinaProject(2007AA04Z344) supported by the National High-Tech Research and Development Program of China
文摘A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the moving platform along the guideway,the levitation subsystem uses six pairs of electromagnets to steadily suspend the moving platform over the guideway.The model of the levitation system,which is a typical nonlinear multi-input multi-output coupling system and has many inner nonlinear coupling characteristics,was deduced.For testifying the model,the levitation mechanism was firstly controlled by proportional-integral-differential(PID) control,and then a lot of input-output data were collected for model parameter identification.The least-square parameter identification method was used.The identification results prove that the model is feasible and suitable for the real system.
基金the National Natural Science Foundation of China(Grant No.22075146).
文摘Appropriate drying process with optimized controlling of drying parameters plays a vital role in the improvement of the quality and performance of propellant products.However,few research on solvent transport dynamics within NC-based propellants was reported,and its effect on the evolution of mechanical properties was not interpreted yet.This study is conducted to gain a comprehensive understanding of hot-air drying for NC-based propellants and clarify the effect of temperature on solvent transport behavior and further the change of mechanical properties during drying.The drying kinetic curves show the drying time required is decreased but the steady solvent content is increased and the drying rate is obviously increased with the increase of hot-air temperatures,indicating hot-air temperatures have a significant effect on drying kinetics.A modified drying model was established,and results show it is more appropriate to describe solvent transport behavior within NC-based propellants.Moreover,two linear equations were established to exhibit the relationship between solvent content and its effect on the change of tensile properties,and the decrease of residual solvent content causes an obvious increase of tensile strength and tensile modulus of propellant products,indicating its mechanical properties can be partly improved by adjustment of residual solvent content.The outcomes can be used to clarify solvent transport mechanisms and optimize drying process parameters of double-based gun propellants.
