Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge c...Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge could seriously damage the ecological environment.In this study,an innovative method for cooperative removal Mn^(2+),NH_(4)^(+)-N,PO_(4)^(3-)-P,F^(-)from PG and POFT was studied.The result showed that Mn^(2+),PO_(4)^(3-)-P and F^(-)were mainly removed in forms of Mg_(3)Si_(4)O_(10)(OH)_(2),Mn_(3)O_(4),Mn_(3)(PO_(4))_(2),Mg_(3)(PO_(4))_(2),CaSO_(4)·2H_(2)O,MnF_(2),MnOOH and Ca_(2)P_(2)O_(7)·2H_(2)O,when LG-MgO was used to adjust the pH value of the system to 9.5,and the volume ratio of EMRL and PGL was 1:4,as well as reaction for 1 h at 25℃.NH_(4)^(+)-N was mainly removed by struvite precipitate,when the molar ratio of N:Mg:P was 1:3:2.4.The concentrations of Mn^(2+),NH_(4)^(+)-N and F^(-)were lower than the integrated wastewater discharge standard.The concentration of PO_(4)^(3-)-P decreased from 254.20 mg/L to 3.21 mg/L.This study provided a new method for EMRL and PGL cooperative harmless treatment.展开更多
Large amounts of ammonium and a low content of biodegradable chemical oxygen demand（COD） are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen aft...Large amounts of ammonium and a low content of biodegradable chemical oxygen demand（COD） are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen after biochemical treatment. Treatment effect of anaerobic ammonium oxidation （anammox） process on the mixture of the leachate and its biochemical effluent was investigated. The results show that the average removal efficiencies of ammonium, nitric nitrogen and total nitrogen are 87.51%, 74.95% and 79.59%, respectively, corresponding to the average ratio of removed nitric nitrogen to ammonium, i.e. 1.14 during the steady phase of anammox activity. The mean removal efficiency of COD is only 24.01% during the experimental period. Thc,dcmand of total phosphorous for the anammox process is unobvious. Especially, the alkalinity and pH value of the effluent are close to those of the inftuent during the steady phase of anammox activity. In addition, it is demonstrated that the status of the anammox bioreactor can be indicated by the alkalinity and pH value during the course of the experiment. The anammox bioreactor has shown potential for nitrogen removal in the leachate mixture. However, COD and total phosphorous in the leachate mixture need further treatment for removal efficiencies of COD and total phosphorous are not good in the anammox bioreactor.展开更多
The experiment was conducted to treat the leachate from two simulating columns by recycling to the columns themselves without being discharged into the enviroment. The columns were employed to simulate anaerobic and s...The experiment was conducted to treat the leachate from two simulating columns by recycling to the columns themselves without being discharged into the enviroment. The columns were employed to simulate anaerobic and semi-aerobic landfills separately. The influence of landfill structure on stabilization of fully recycled leachate was studied. The results show that semi-aerobic landfill structure accelerates the stabilization of leachate recycled. The full recycle of leachate in semi-aerobic landfill is a very feasible and effective technology for leachate treatment with low cost and energy saving especially in arid and rare rainfall regions. Meanwhile, the environmental impact of landfill can be greatly minimized.展开更多
Due to rainwater and surface water infiltration, leachate generated by buried landfill can result in the secondary pollution of groundwater.In this study, combination technologies of chemical coagulation and electroch...Due to rainwater and surface water infiltration, leachate generated by buried landfill can result in the secondary pollution of groundwater.In this study, combination technologies of chemical coagulation and electrochemistry were used to treat landfill leachate.First,experiments were carried out with Ca（OH）<sub>2</sub> and FeCl<sub>3</sub> as the flocculant to pre-treat landfill leachate.The optimum treatment conditions are as follows:the dosages of Ca（OH）<sub>2</sub> and FeCl<sub>3</sub> are 17 g/L and 17 mL/L,respectively;mixing time is 5min,and the 86.8%of COD<sub>Cr</sub>,38.6%of NH<sub>3</sub>-N and 93.2%of phosphorus were removed(COD<sub>Cr</sub>,NH<sub>3</sub>展开更多
The main components of the hydrochloric acid leachate of the asbestos tailings were MgCl<sub>2</sub>,FeCl<sub>3</sub>, FeCl<sub>2</sub>,AlCl<sub>3</sub> and surplus acid...The main components of the hydrochloric acid leachate of the asbestos tailings were MgCl<sub>2</sub>,FeCl<sub>3</sub>, FeCl<sub>2</sub>,AlCl<sub>3</sub> and surplus acid.An experimental study on optimization of purification process of acid leachate focusing on preparing magnesium hydroxide solution was carried on.The main approach used in the experiment was to oxidize Fe<sup>2+</sup>to Fe<sup>3+</sup>,and then purified it by the precipitation reaction with alkali.展开更多
The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibr...The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibrium isotherms and a kinetic model.Additionally,the removal of Pb(Ⅱ) in leachate of litchi pericarps was also evaluated.The results show that litchi pericarps exhibit a high adsorption capacity to Pb(Ⅱ),with the maximum removal efficiency occurring at a temperature of 25 ℃,a pH of 6.0-7.0 and an adsorbent dosage of 10 g/L.Langmuir and Freundlich isotherms and the pseudo-second-order kinetic model can all fit the equilibrium adsorption satisfactorily,with correlation coefficients(R^2) of 0.9935,0.9918 and 1.0,respectively.An average removal efficiency of 66.65% is found for Pb(Ⅱ) in leachate of litchi pericarps.展开更多
Pb2+ and Cd2+ in leachate were adsorbed on clay-solidified grouting curtain for waste landfills with equilibrium experiment. The cation exchange capacity was determined with ammonium acetate. And the concentration of ...Pb2+ and Cd2+ in leachate were adsorbed on clay-solidified grouting curtain for waste landfills with equilibrium experiment. The cation exchange capacity was determined with ammonium acetate. And the concentration of heavy metal cations in leachate was determined with atomic absorption spectrophotometer. Their equilibrium isotherms were measured, and the experimental isotherm data were analyzed by using Freundlich and Langmuir models. The results show that the adsorption capacities of the heavy metal cations are closely related to the compositions of clay-solidified grouting curtain, and the maximum adsorption appears at the ratio of cement to clay of 2∶4 in the experimental conditions. At their maximum adsorption and pH 5.0, the adsorption capacities of Pb 2+ and Cd 2+ are 16.19mg/g and 1.21mg/g. The competitive adsorption coefficients indicate that the adsorption of clay-solidified grouting curtain for Pb2+ is stronger than that for Cd 2+ . The adsorption process conforms to Freundlich’s model with related coefficient higher than 0.996.展开更多
The effects of components and their ratio of grouts on anti-seepage capability of clay-solidified grouting curtain and its permeability of heavy metal cations were investigated by permeating experiments, using reactiv...The effects of components and their ratio of grouts on anti-seepage capability of clay-solidified grouting curtain and its permeability of heavy metal cations were investigated by permeating experiments, using reactive solute transport model to study the permeation of heavy metals (Cd2+, Pb2+ and Hg2+). The study of permeating for different mixture ratios of cement and clay indicates that hydraulic conductivity of clay-solidified grouting curtain with different ratios of solid to liquid or with the same ratio of solid to liquid but with different ratios of cement to clay is changed. The laboratory simulation test results also show that precipitates produced in heavy metal cation migration process in curtain block up water flowing passage which makes the hydraulic conductivity of the solution-permeated curtain decrease with the leakage time. The permeation velocities for different heavy metal cations vary with ionic concentration, exchange capacity and ion radius etc. The test results indicate that the permeation rapidity order of heavy metals cations in clay-solidified grouting curtain is Hg2+>Pb2+ in the same experimental circumstance. In addition, permeability for different mixture ratios and antisepsis capabilities of clay-solidified grouting curtain were studied in tests.展开更多
Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of...Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of similar WWTP. When the proposed measures,such as using 0.1% (volume fraction of wastewater) landfill leachate,shortening HRT by 2/3 in the primary sedimentation tank and controlling DO at 0.5 mg/L in the 3rd section of aerobic zone,are applied,15% of the carbon source can be complemented,the favorable property of activated sludge is achieved,and the nitrogen removal effect is significantly improved. The effluent NH3-N is 2 mg/L and the removal rate is 90%. The effluent TN is 17 mg/L and the removal rate is 54%. The up-to-standard discharge of the effluent is achieved. And after the optimization,the unit electricity consumption also reaches 0.21 kW/h and saves 20%.展开更多
Nowadays,a certain amount of landfills in China were constructed without horizontal liner system.The research conducted focuses mainly on the contaminants from landfill leachate migrating in the aquifer of a fractured...Nowadays,a certain amount of landfills in China were constructed without horizontal liner system.The research conducted focuses mainly on the contaminants from landfill leachate migrating in the aquifer of a fractured granite area,and pollution predictions for groundwater were made by establishing numerical model with Visual Modflow combining field investigation like geological surveys,drilling,geophysical explorations,hydrogeological experiments,water quality analysis.The transportation of the chloride ion from landfill in the aquifer was simulated in the model with time frames of 2 555,3 650,5 475 and7 300 d.The model shows that from 2 555 d to 7 300 d starting from 2003,the chloride ion migrated from 900 m to 1 300 m,respectively,along the groundwater flow.The results indicate that as leachate plume migrated in the aquifer,the concentration of the pollutants can be up to 19.74 to 251.76 times that of background value.The research proves that the leachate poses a threat to the local water body and offers a reference towards groundwater pollution prevention for fractured granite landfill sites.展开更多
Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor l...Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor landfill(IASBRL)was put forward on the basis of leachate self-recirculation.By monitoring MSW composition,leachate characteristics variation and landfill gas(LFG)generation,the effect of IASBRL was comparatively studied by simulation landfill.Based on the adjusting,scouring and carrying effects of leachate self-recirculation,IASBRL can rapidly decrease Eh value to about-500mV and form a suitable biochemical environment for methanogens,which provides a precondition for stable cooperation between non-methanogens and methanogens.IASBRL can avoid the accumulation of organic acids,make VFA(volatile fatty acid)concentration and CODCr decrease along with the small range fluctuations,and form a stable decomposition-consumption synergy during MSW degradation,therefore,the hydrolysis rate of easy hydrolyze material reaches 71.2% in IASBRL.From the viewpoint of LFG resources in IASBRL,the cumulative LFG production increases to 2327.0L,CH4 mass fraction stabilizes at about 50%,and these provide a favorable precondition for LFG development.展开更多
基金Project(2018YFC1903500)supported by the National Key Research and Development Program of ChinaProject(52174386)supported by the National Natural Science Foundation of ChinaProject(2021YFH0058)supported by the Science and Technology Plan Project of Sichuan Province,China。
文摘Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge could seriously damage the ecological environment.In this study,an innovative method for cooperative removal Mn^(2+),NH_(4)^(+)-N,PO_(4)^(3-)-P,F^(-)from PG and POFT was studied.The result showed that Mn^(2+),PO_(4)^(3-)-P and F^(-)were mainly removed in forms of Mg_(3)Si_(4)O_(10)(OH)_(2),Mn_(3)O_(4),Mn_(3)(PO_(4))_(2),Mg_(3)(PO_(4))_(2),CaSO_(4)·2H_(2)O,MnF_(2),MnOOH and Ca_(2)P_(2)O_(7)·2H_(2)O,when LG-MgO was used to adjust the pH value of the system to 9.5,and the volume ratio of EMRL and PGL was 1:4,as well as reaction for 1 h at 25℃.NH_(4)^(+)-N was mainly removed by struvite precipitate,when the molar ratio of N:Mg:P was 1:3:2.4.The concentrations of Mn^(2+),NH_(4)^(+)-N and F^(-)were lower than the integrated wastewater discharge standard.The concentration of PO_(4)^(3-)-P decreased from 254.20 mg/L to 3.21 mg/L.This study provided a new method for EMRL and PGL cooperative harmless treatment.
基金Project (20377013) supported by the National Natural Science Foundation of China project (020959) supported by Department of Science and Technology of Guangdong Province
文摘Large amounts of ammonium and a low content of biodegradable chemical oxygen demand（COD） are contained in leachate from aged landfills, together with the effluent containing high concentration of nitric nitrogen after biochemical treatment. Treatment effect of anaerobic ammonium oxidation （anammox） process on the mixture of the leachate and its biochemical effluent was investigated. The results show that the average removal efficiencies of ammonium, nitric nitrogen and total nitrogen are 87.51%, 74.95% and 79.59%, respectively, corresponding to the average ratio of removed nitric nitrogen to ammonium, i.e. 1.14 during the steady phase of anammox activity. The mean removal efficiency of COD is only 24.01% during the experimental period. Thc,dcmand of total phosphorous for the anammox process is unobvious. Especially, the alkalinity and pH value of the effluent are close to those of the inftuent during the steady phase of anammox activity. In addition, it is demonstrated that the status of the anammox bioreactor can be indicated by the alkalinity and pH value during the course of the experiment. The anammox bioreactor has shown potential for nitrogen removal in the leachate mixture. However, COD and total phosphorous in the leachate mixture need further treatment for removal efficiencies of COD and total phosphorous are not good in the anammox bioreactor.
基金Project(2003-MOC-NGGP-03) supported by the Netherlands Government Grant Project
文摘The experiment was conducted to treat the leachate from two simulating columns by recycling to the columns themselves without being discharged into the enviroment. The columns were employed to simulate anaerobic and semi-aerobic landfills separately. The influence of landfill structure on stabilization of fully recycled leachate was studied. The results show that semi-aerobic landfill structure accelerates the stabilization of leachate recycled. The full recycle of leachate in semi-aerobic landfill is a very feasible and effective technology for leachate treatment with low cost and energy saving especially in arid and rare rainfall regions. Meanwhile, the environmental impact of landfill can be greatly minimized.
文摘Due to rainwater and surface water infiltration, leachate generated by buried landfill can result in the secondary pollution of groundwater.In this study, combination technologies of chemical coagulation and electrochemistry were used to treat landfill leachate.First,experiments were carried out with Ca（OH）<sub>2</sub> and FeCl<sub>3</sub> as the flocculant to pre-treat landfill leachate.The optimum treatment conditions are as follows:the dosages of Ca（OH）<sub>2</sub> and FeCl<sub>3</sub> are 17 g/L and 17 mL/L,respectively;mixing time is 5min,and the 86.8%of COD<sub>Cr</sub>,38.6%of NH<sub>3</sub>-N and 93.2%of phosphorus were removed(COD<sub>Cr</sub>,NH<sub>3</sub>
文摘The main components of the hydrochloric acid leachate of the asbestos tailings were MgCl<sub>2</sub>,FeCl<sub>3</sub>, FeCl<sub>2</sub>,AlCl<sub>3</sub> and surplus acid.An experimental study on optimization of purification process of acid leachate focusing on preparing magnesium hydroxide solution was carried on.The main approach used in the experiment was to oxidize Fe<sup>2+</sup>to Fe<sup>3+</sup>,and then purified it by the precipitation reaction with alkali.
基金Project(51208173)supported by the National Natural Science Foundation of ChinaProject(ZR2014EEM005)supported by the Natural Science Foundation of Shandong Province,China
文摘The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibrium isotherms and a kinetic model.Additionally,the removal of Pb(Ⅱ) in leachate of litchi pericarps was also evaluated.The results show that litchi pericarps exhibit a high adsorption capacity to Pb(Ⅱ),with the maximum removal efficiency occurring at a temperature of 25 ℃,a pH of 6.0-7.0 and an adsorbent dosage of 10 g/L.Langmuir and Freundlich isotherms and the pseudo-second-order kinetic model can all fit the equilibrium adsorption satisfactorily,with correlation coefficients(R^2) of 0.9935,0.9918 and 1.0,respectively.An average removal efficiency of 66.65% is found for Pb(Ⅱ) in leachate of litchi pericarps.
基金Project (200065) supported by University Key Teacher Foundation of the Ministry of Education of China
文摘Pb2+ and Cd2+ in leachate were adsorbed on clay-solidified grouting curtain for waste landfills with equilibrium experiment. The cation exchange capacity was determined with ammonium acetate. And the concentration of heavy metal cations in leachate was determined with atomic absorption spectrophotometer. Their equilibrium isotherms were measured, and the experimental isotherm data were analyzed by using Freundlich and Langmuir models. The results show that the adsorption capacities of the heavy metal cations are closely related to the compositions of clay-solidified grouting curtain, and the maximum adsorption appears at the ratio of cement to clay of 2∶4 in the experimental conditions. At their maximum adsorption and pH 5.0, the adsorption capacities of Pb 2+ and Cd 2+ are 16.19mg/g and 1.21mg/g. The competitive adsorption coefficients indicate that the adsorption of clay-solidified grouting curtain for Pb2+ is stronger than that for Cd 2+ . The adsorption process conforms to Freundlich’s model with related coefficient higher than 0.996.
文摘The effects of components and their ratio of grouts on anti-seepage capability of clay-solidified grouting curtain and its permeability of heavy metal cations were investigated by permeating experiments, using reactive solute transport model to study the permeation of heavy metals (Cd2+, Pb2+ and Hg2+). The study of permeating for different mixture ratios of cement and clay indicates that hydraulic conductivity of clay-solidified grouting curtain with different ratios of solid to liquid or with the same ratio of solid to liquid but with different ratios of cement to clay is changed. The laboratory simulation test results also show that precipitates produced in heavy metal cation migration process in curtain block up water flowing passage which makes the hydraulic conductivity of the solution-permeated curtain decrease with the leakage time. The permeation velocities for different heavy metal cations vary with ionic concentration, exchange capacity and ion radius etc. The test results indicate that the permeation rapidity order of heavy metals cations in clay-solidified grouting curtain is Hg2+>Pb2+ in the same experimental circumstance. In addition, permeability for different mixture ratios and antisepsis capabilities of clay-solidified grouting curtain were studied in tests.
基金Project (2009ZX07315-002-01) supported by Water Pollution Control and Management of Major Special Science and Technology
文摘Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of similar WWTP. When the proposed measures,such as using 0.1% (volume fraction of wastewater) landfill leachate,shortening HRT by 2/3 in the primary sedimentation tank and controlling DO at 0.5 mg/L in the 3rd section of aerobic zone,are applied,15% of the carbon source can be complemented,the favorable property of activated sludge is achieved,and the nitrogen removal effect is significantly improved. The effluent NH3-N is 2 mg/L and the removal rate is 90%. The effluent TN is 17 mg/L and the removal rate is 54%. The up-to-standard discharge of the effluent is achieved. And after the optimization,the unit electricity consumption also reaches 0.21 kW/h and saves 20%.
基金Project(12JJ305)supported by the Education Department of Hunan Province,China
文摘Nowadays,a certain amount of landfills in China were constructed without horizontal liner system.The research conducted focuses mainly on the contaminants from landfill leachate migrating in the aquifer of a fractured granite area,and pollution predictions for groundwater were made by establishing numerical model with Visual Modflow combining field investigation like geological surveys,drilling,geophysical explorations,hydrogeological experiments,water quality analysis.The transportation of the chloride ion from landfill in the aquifer was simulated in the model with time frames of 2 555,3 650,5 475 and7 300 d.The model shows that from 2 555 d to 7 300 d starting from 2003,the chloride ion migrated from 900 m to 1 300 m,respectively,along the groundwater flow.The results indicate that as leachate plume migrated in the aquifer,the concentration of the pollutants can be up to 19.74 to 251.76 times that of background value.The research proves that the leachate poses a threat to the local water body and offers a reference towards groundwater pollution prevention for fractured granite landfill sites.
基金Project(41072236)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,ChinaProject(2009A027)supported by Youth Research Foundation of China University of Mining and Technology
文摘Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor landfill(IASBRL)was put forward on the basis of leachate self-recirculation.By monitoring MSW composition,leachate characteristics variation and landfill gas(LFG)generation,the effect of IASBRL was comparatively studied by simulation landfill.Based on the adjusting,scouring and carrying effects of leachate self-recirculation,IASBRL can rapidly decrease Eh value to about-500mV and form a suitable biochemical environment for methanogens,which provides a precondition for stable cooperation between non-methanogens and methanogens.IASBRL can avoid the accumulation of organic acids,make VFA(volatile fatty acid)concentration and CODCr decrease along with the small range fluctuations,and form a stable decomposition-consumption synergy during MSW degradation,therefore,the hydrolysis rate of easy hydrolyze material reaches 71.2% in IASBRL.From the viewpoint of LFG resources in IASBRL,the cumulative LFG production increases to 2327.0L,CH4 mass fraction stabilizes at about 50%,and these provide a favorable precondition for LFG development.
