A n-type small molecule DC-IDT2E with 4,4,9,9-tetrakis（4-hexylphenyl）-indaceno[1,2-b：5,6-bt]dithiophene as a central building block, furan as rr-bridges, and 1,1 -dicyanomethylene-3-indanone as end acceptor groups,...A n-type small molecule DC-IDT2E with 4,4,9,9-tetrakis（4-hexylphenyl）-indaceno[1,2-b：5,6-bt]dithiophene as a central building block, furan as rr-bridges, and 1,1 -dicyanomethylene-3-indanone as end acceptor groups, was synthesized and used as an electron acceptor in solution-processed organic solar cells （OSCs）. DC-IDT2F exhibited good thermal stability, broad and strong absorption in 500-850 rim, a narrow bandgap of 1.54 eV, LUMO of-3.88 eV, HOMO of-5.44 eV and an electron mobility of 6.5 × 10-4 cm2/（V.s）. DC-IDT2F-based OSCs with conventional and inverted structures exhibited power conversion efficiencies of 2.26 and 3.08% respec- tively. The effect of vertical phase separation and morphology of the active layer on the device performance in the two structures was studied.展开更多
A high-performance terahertz Schottky barrier diode(SBD)with an inverted trapezoidal epitaxial cross-sectional structure featuring high varactor characteristics and reverse breakdown characteristics is reported in thi...A high-performance terahertz Schottky barrier diode(SBD)with an inverted trapezoidal epitaxial cross-sectional structure featuring high varactor characteristics and reverse breakdown characteristics is reported in this paper.Inductively coupled plasma dry etching and dissolution wet etching are used to define the profile of the epitaxial layer,by which the voltage-dependent variation trend of the thickness of the metal-semiconductor contact depletion layer is modified.The simulation of the inverted trapezoidal epitaxial cross-section SBD is also conducted to explain the physical mechanism of the electric field and space charge region area.Compared with the normal structure,the grading coefficient M increases from 0.47 to 0.52,and the capacitance modulation ratio(C^(max)/C_(min))increases from 6.70 to 7.61.The inverted trapezoidal epitaxial cross-section structure is a promising approach to improve the variable-capacity ratio by eliminating the accumulation of charge at the Schottky electrode edge.A 190 GHz frequency doubler based on the inverted trapezoidal epitaxial cross-section SBD also shows a doubling efficiency of 35%compared to that 30%of a normal SBD.展开更多
Due to their excellent photoelectron chemical properties and suitable energy level alignment with perovskite,perylene diimide(PDI)derivatives are competitive non-fullerene electron transport material(ETM)candidates fo...Due to their excellent photoelectron chemical properties and suitable energy level alignment with perovskite,perylene diimide(PDI)derivatives are competitive non-fullerene electron transport material(ETM)candidates for perovskite solar cells(PSCs).However,the conjugated rigid plane structure of PDI units result in PDI-based ETMs tending to form large aggregates,limiting their application and photovoltaic performance.In this study,to restrict aggregation and further enhance the photovoltaic performance of PDI-type ETMs,two PDI-based ETMs,termed PDO-PDI2(dimer)and PDO-PDI3(trimer),were constructed by introducing a phenothiazine 5,5-dioxide(PDO)core building block.The research manifests that the optoelectronic properties and film formation property of PDO-PDI2 and PDO-PDI3 were deeply affected by the molecular spatial configuration.Applied in PSCs,PDO-PDI3 with threedimensional spiral molecular structure,exhibits superior electron extraction and transport properties,further achieving the best PCE of 18.72%and maintaining 93%of its initial efficiency after a 720-h aging test under ambient conditions.展开更多
Several international oil companies had conducted petroleum exploration, but failed to make any commercially viable discoveries in the Doseo Basin for over 30 years. In this article, an integrated analysis, based on t...Several international oil companies had conducted petroleum exploration, but failed to make any commercially viable discoveries in the Doseo Basin for over 30 years. In this article, an integrated analysis, based on the latest seismic and drilling data combined with exploration practice and tectonic, sedimentary as well as petroleum-geological characteristics of the basin, has been conducted with the aim to disclose the key factors of hydrocarbon accumulation and enrichment and then to find the potential petroleum plays. The Doseo Basin in Chad is a Meso-Cenozoic lacustrine rift basin developed on the Precambrian crystalline basement in the Central African Shear Zone. It is a half graben rift controlled by the strike-slip fault at the northern boundary, and can be divided into two sub-basins, an uplift and a slope. The basin experienced two rifting periods in the Cretaceous and was strongly inverted with the erosion thickness of 800–1000 m during the Eocene, and then entered the depression and extinction period. Structurally, a large number of normal faults and strike-slip faults are identified in the basin, and the boundary faults are inverted faults with normal at first. The main structural styles include inverted anticlines, fault noses, complex fault-blocks and flower structures. The Lower Cretaceous is the main sedimentary strata, which are divided into the Mangara Group, Kedeni, Doba and Koumra Formations from bottom to up. Two transgressive-regressive cycles developed in the Lower Cretaceous indicates with mainly lacustrine, fluvial, delta, braided-delta, fan-delta sandstone and mudstone. The effective source rock in the basin is the deep-lacustrine mudstone of the Lower Cretaceous containing the type Ⅰ and type Ⅱ;organic matters. Furthermore, Inverted anticlines and fault-complicated blocks comprise the main trap types and the Kedeni Uplift is the most favorable play, followed by the Northern Steep Slope and Southern Gentle Slope. Lateral sealing capacity of faults controls the hydrocarbon abundance.展开更多
We report an MoO3/Ag/Al/ZnO intermediate layer connecting two identical bulk heterojunction subcells with a poly（3-hexylthiophene） and [6,6]-phenyl-C61-butyric acid methyl ester （P3HT and PCBM） active layer for in...We report an MoO3/Ag/Al/ZnO intermediate layer connecting two identical bulk heterojunction subcells with a poly（3-hexylthiophene） and [6,6]-phenyl-C61-butyric acid methyl ester （P3HT and PCBM） active layer for inverted tan- dem polymer solar cells. The highly transparent intermediate layer with an optimized thickness realizes an Ohmic contact between the two subcells for effective charge extraction and recombination. A maximum power conversion efficiency of 3.76% is obtained for the tandem cell under 100 mW/cm2 illumination, which is larger than that of a single cell （3.15%）. The open-circuit voltage of the tandem cell （1.18 V） approaches double that of the single cell （0.61 V）.展开更多
基金supported by the National Natural Science Foundation of China(91433114,51261130582,21025418)the 973 Program(2011CB808401)the Chinese Academy of Sciences
文摘A n-type small molecule DC-IDT2E with 4,4,9,9-tetrakis（4-hexylphenyl）-indaceno[1,2-b：5,6-bt]dithiophene as a central building block, furan as rr-bridges, and 1,1 -dicyanomethylene-3-indanone as end acceptor groups, was synthesized and used as an electron acceptor in solution-processed organic solar cells （OSCs）. DC-IDT2F exhibited good thermal stability, broad and strong absorption in 500-850 rim, a narrow bandgap of 1.54 eV, LUMO of-3.88 eV, HOMO of-5.44 eV and an electron mobility of 6.5 × 10-4 cm2/（V.s）. DC-IDT2F-based OSCs with conventional and inverted structures exhibited power conversion efficiencies of 2.26 and 3.08% respec- tively. The effect of vertical phase separation and morphology of the active layer on the device performance in the two structures was studied.
基金Project supported by the National Natural Science Foundation of China (Grant No.61871072)。
文摘A high-performance terahertz Schottky barrier diode(SBD)with an inverted trapezoidal epitaxial cross-sectional structure featuring high varactor characteristics and reverse breakdown characteristics is reported in this paper.Inductively coupled plasma dry etching and dissolution wet etching are used to define the profile of the epitaxial layer,by which the voltage-dependent variation trend of the thickness of the metal-semiconductor contact depletion layer is modified.The simulation of the inverted trapezoidal epitaxial cross-section SBD is also conducted to explain the physical mechanism of the electric field and space charge region area.Compared with the normal structure,the grading coefficient M increases from 0.47 to 0.52,and the capacitance modulation ratio(C^(max)/C_(min))increases from 6.70 to 7.61.The inverted trapezoidal epitaxial cross-section structure is a promising approach to improve the variable-capacity ratio by eliminating the accumulation of charge at the Schottky electrode edge.A 190 GHz frequency doubler based on the inverted trapezoidal epitaxial cross-section SBD also shows a doubling efficiency of 35%compared to that 30%of a normal SBD.
基金financially supported by the National Natural Science Foundation of China(Grants 21805114,21905119)Key Research and Development program of Jiangsu Province(BE2019009-2)+4 种基金Natural Science Foundation of Jiangsu province(BK20180869,BK20180867)China Postdoctoral Science Foundation(2019M651741),Top talents in Jiangsu province(XNY066)the Jiangsu University Foundation(17JDG032,17JDG031)Hightech Research Key laboratory of Zhenjiang(SS2018002)the State Key Laboratory of Fine Chemicals(KF1902)。
文摘Due to their excellent photoelectron chemical properties and suitable energy level alignment with perovskite,perylene diimide(PDI)derivatives are competitive non-fullerene electron transport material(ETM)candidates for perovskite solar cells(PSCs).However,the conjugated rigid plane structure of PDI units result in PDI-based ETMs tending to form large aggregates,limiting their application and photovoltaic performance.In this study,to restrict aggregation and further enhance the photovoltaic performance of PDI-type ETMs,two PDI-based ETMs,termed PDO-PDI2(dimer)and PDO-PDI3(trimer),were constructed by introducing a phenothiazine 5,5-dioxide(PDO)core building block.The research manifests that the optoelectronic properties and film formation property of PDO-PDI2 and PDO-PDI3 were deeply affected by the molecular spatial configuration.Applied in PSCs,PDO-PDI3 with threedimensional spiral molecular structure,exhibits superior electron extraction and transport properties,further achieving the best PCE of 18.72%and maintaining 93%of its initial efficiency after a 720-h aging test under ambient conditions.
基金Supported by the China National Science and Technology Major Project (2016ZX05029005)CNPC Scientific Research and Technology Development Project (2021DJ31)。
文摘Several international oil companies had conducted petroleum exploration, but failed to make any commercially viable discoveries in the Doseo Basin for over 30 years. In this article, an integrated analysis, based on the latest seismic and drilling data combined with exploration practice and tectonic, sedimentary as well as petroleum-geological characteristics of the basin, has been conducted with the aim to disclose the key factors of hydrocarbon accumulation and enrichment and then to find the potential petroleum plays. The Doseo Basin in Chad is a Meso-Cenozoic lacustrine rift basin developed on the Precambrian crystalline basement in the Central African Shear Zone. It is a half graben rift controlled by the strike-slip fault at the northern boundary, and can be divided into two sub-basins, an uplift and a slope. The basin experienced two rifting periods in the Cretaceous and was strongly inverted with the erosion thickness of 800–1000 m during the Eocene, and then entered the depression and extinction period. Structurally, a large number of normal faults and strike-slip faults are identified in the basin, and the boundary faults are inverted faults with normal at first. The main structural styles include inverted anticlines, fault noses, complex fault-blocks and flower structures. The Lower Cretaceous is the main sedimentary strata, which are divided into the Mangara Group, Kedeni, Doba and Koumra Formations from bottom to up. Two transgressive-regressive cycles developed in the Lower Cretaceous indicates with mainly lacustrine, fluvial, delta, braided-delta, fan-delta sandstone and mudstone. The effective source rock in the basin is the deep-lacustrine mudstone of the Lower Cretaceous containing the type Ⅰ and type Ⅱ;organic matters. Furthermore, Inverted anticlines and fault-complicated blocks comprise the main trap types and the Kedeni Uplift is the most favorable play, followed by the Northern Steep Slope and Southern Gentle Slope. Lateral sealing capacity of faults controls the hydrocarbon abundance.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB933704)the Doctoral Foundation of the Ministry of Education of China(Grant No.20100171110025)the State Key Laboratory of Optoelectronic Materials and Technologies,Sun Yat-Sen University,China(GrantNo.2010-RC-3-1)
文摘We report an MoO3/Ag/Al/ZnO intermediate layer connecting two identical bulk heterojunction subcells with a poly（3-hexylthiophene） and [6,6]-phenyl-C61-butyric acid methyl ester （P3HT and PCBM） active layer for inverted tan- dem polymer solar cells. The highly transparent intermediate layer with an optimized thickness realizes an Ohmic contact between the two subcells for effective charge extraction and recombination. A maximum power conversion efficiency of 3.76% is obtained for the tandem cell under 100 mW/cm2 illumination, which is larger than that of a single cell （3.15%）. The open-circuit voltage of the tandem cell （1.18 V） approaches double that of the single cell （0.61 V）.
