Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging f...Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging from 278.15 K to 318.15 K.The solubility in each system was found to be positively correlated with temperature.Furthermore,solubility data were analyzed using four equations:the modified Apelblat equation,Van’t Hoff equation,λh equation and CNIBS/R-K equations,and they provided satisfactory results for both two systems.The average root-mean-square deviation(105RMSD)values for these models were less than 13.93.Calculations utilizing the Van’t Hoff equation and Gibbs equations facilitated the derivation of apparent thermodynamic properties of NTO dissolution in the two systems,including values for Gibbs free energy,enthalpy and entropy.The%ζ_(H)is larger than%ζ_(TS),and all the%ζ_(H)data are≥58.63%,indicating that the enthalpy make a greater contribution than entropy to theΔG_(soln)^(Θ).展开更多
The Infrared Hyperspectral Atmospheric SounderⅡ(HIRAS-Ⅱ)is the key equipment on FengYun-3E(FY-3E)satellite,which can realize vertical atmospheric detection,featuring hyper spectral,high sensitivity and high precisio...The Infrared Hyperspectral Atmospheric SounderⅡ(HIRAS-Ⅱ)is the key equipment on FengYun-3E(FY-3E)satellite,which can realize vertical atmospheric detection,featuring hyper spectral,high sensitivity and high precision.To ensure its accuracy of detection,it is necessary to correlate their thermal models to in-orbit da⁃ta.In this work,an investigation of intelligent correlation method named Intelligent Correlation Platform for Ther⁃mal Model(ICP-TM)was established,the advanced Kriging surrogate model and efficient adaptive region opti⁃mization algorithm were introduced.After the correlation with this method for FY-3E/HIRAS-Ⅱ,the results indi⁃cate that compared with the data in orbit,the error of the thermal model has decreased from 5 K to within±1 K in cold case(10℃).Then,the correlated model is validated in hot case(20℃),and the correlated model exhibits good universality.This correlation precision is also much superiors to the general ones like 3 K in other similar lit⁃erature.Furthermore,the process is finished in 8 days using ICP-TM,the efficiency is much better than 3 months based on manual.The results show that the proposed approach significantly enhances the accuracy and efficiency of thermal model,this contributes to the precise thermal control of subsequent infrared optical payloads.展开更多
Effects of ultrasonic bonding parameters on atomic diffusion, microstructure at the Al-Au interface, and shear strength of Al-Au ultrasonic bonding were investigated by the combining experiments and finite element (FE...Effects of ultrasonic bonding parameters on atomic diffusion, microstructure at the Al-Au interface, and shear strength of Al-Au ultrasonic bonding were investigated by the combining experiments and finite element (FE) simulation. The quantitative model of atomic diffusion, which is related to the ultrasonic bonding parameters, time and distance, is established to calculate the atomic diffusion of the Al-Au interface. The maximum relative error between the calculated and experimental fraction of Al atom is 7.35%, indicating high prediction accuracy of this model. During the process of ultrasonic bonding, Au8Al3 is the main intermetallic compound (IMC) at the Al-Au interface. With larger bonding forces, higher ultrasonic powers and longer bonding time, it is more difficult to remove the oxide particles from the Al-Au interface, which hinders the atomic diffusion. Therefore, the complicated stress state and the existence of oxide particles both promotes the formation of holes. The shear strength of Al-Au ultrasonic bonding increases with increasing bonding force, ultrasonic power and bonding time. However, combined with the presence of holes at especial parameters, the optimal ultrasonic bonding parameter is confirmed to be a bonding force of 23 gf, ultrasonic power of 75 mW and bonding time of 21 ms.展开更多
In view of the limitations of traditional measurement methods in the field of building information,such as complex operation,low timeliness and poor accuracy,a new way of combining three-dimensional scanning technolog...In view of the limitations of traditional measurement methods in the field of building information,such as complex operation,low timeliness and poor accuracy,a new way of combining three-dimensional scanning technology and BIM(Building Information Modeling)model was discussed.Focused on the efficient acquisition of building geometric information using the fast-developing 3D point cloud technology,an improved deep learning-based 3D point cloud recognition method was proposed.The method optimised the network structure based on RandLA-Net to adapt to the large-scale point cloud processing requirements,while the semantic and instance features of the point cloud were integrated to significantly improve the recognition accuracy and provide a precise basis for BIM model remodeling.In addition,a visual BIM model generation system was developed,which systematically transformed the point cloud recognition results into BIM component parameters,automatically constructed BIM models,and promoted the open sharing and secondary development of models.The research results not only effectively promote the automation process of converting 3D point cloud data to refined BIM models,but also provide important technical support for promoting building informatisation and accelerating the construction of smart cities,showing a wide range of application potential and practical value.展开更多
陶瓷在长时高温和高应力下工作时会发生蠕变,蠕变损伤累积将最终导致失效发生。蠕变损伤的演化与陶瓷的微结构有十分密切的关系,建立陶瓷材料的微观有限元模型有助于更深入地了解这一关系。以氮化硅陶瓷为研究对象,提出一种基于动力学...陶瓷在长时高温和高应力下工作时会发生蠕变,蠕变损伤累积将最终导致失效发生。蠕变损伤的演化与陶瓷的微结构有十分密切的关系,建立陶瓷材料的微观有限元模型有助于更深入地了解这一关系。以氮化硅陶瓷为研究对象,提出一种基于动力学的三维晶体沉积数值模型,结合Monte Carlo Potts结晶生长模型对氮化硅陶瓷的烧结过程进行模拟,力求还原氮化硅陶瓷的动态生长过程以及结晶后晶体大小、形状、取向分布以及空洞的大小、形状、分布等微观结构特征。基于该模拟生成的几何边界描述自动生成Python脚本,在有限元软件中完成建模。利用该有限元模型对氮化硅陶瓷的统计弹性常数进行验证,计算结果与试验数据对比,相对误差约为4.5%,吻合良好。展开更多
采用累积频率的统计方法和Community Climate Model 3(CCM3)模拟的10年逐日降水结果,分析了模拟的夏季极端降水事件的时空分布特征.结果表明,CCM3模拟的极端降水阈值的大值区主要在我国黄河和长江流域的上游、印度半岛及其邻近海域和孟...采用累积频率的统计方法和Community Climate Model 3(CCM3)模拟的10年逐日降水结果,分析了模拟的夏季极端降水事件的时空分布特征.结果表明,CCM3模拟的极端降水阈值的大值区主要在我国黄河和长江流域的上游、印度半岛及其邻近海域和孟加拉湾及其北部地区.CCM3能够模拟出我国长江流域极端降水量与极端降水日数显著增加的趋势.对极端降水平均强度、降水日数以及极端降水量与总降水量比值的经验正交函数(EOF)分析可知,我国大部分地区的极端降水基本呈现同相变化,且以长江和黄河中游地区较为显著.CCM3模式基本能够模拟出观测到的极端降水阈值与总降水、极端降水日数及其距平的高空间相关性.展开更多
文摘Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging from 278.15 K to 318.15 K.The solubility in each system was found to be positively correlated with temperature.Furthermore,solubility data were analyzed using four equations:the modified Apelblat equation,Van’t Hoff equation,λh equation and CNIBS/R-K equations,and they provided satisfactory results for both two systems.The average root-mean-square deviation(105RMSD)values for these models were less than 13.93.Calculations utilizing the Van’t Hoff equation and Gibbs equations facilitated the derivation of apparent thermodynamic properties of NTO dissolution in the two systems,including values for Gibbs free energy,enthalpy and entropy.The%ζ_(H)is larger than%ζ_(TS),and all the%ζ_(H)data are≥58.63%,indicating that the enthalpy make a greater contribution than entropy to theΔG_(soln)^(Θ).
基金Supported by the National Key Research and Development Program of China(2022YFB3904803)。
文摘The Infrared Hyperspectral Atmospheric SounderⅡ(HIRAS-Ⅱ)is the key equipment on FengYun-3E(FY-3E)satellite,which can realize vertical atmospheric detection,featuring hyper spectral,high sensitivity and high precision.To ensure its accuracy of detection,it is necessary to correlate their thermal models to in-orbit da⁃ta.In this work,an investigation of intelligent correlation method named Intelligent Correlation Platform for Ther⁃mal Model(ICP-TM)was established,the advanced Kriging surrogate model and efficient adaptive region opti⁃mization algorithm were introduced.After the correlation with this method for FY-3E/HIRAS-Ⅱ,the results indi⁃cate that compared with the data in orbit,the error of the thermal model has decreased from 5 K to within±1 K in cold case(10℃).Then,the correlated model is validated in hot case(20℃),and the correlated model exhibits good universality.This correlation precision is also much superiors to the general ones like 3 K in other similar lit⁃erature.Furthermore,the process is finished in 8 days using ICP-TM,the efficiency is much better than 3 months based on manual.The results show that the proposed approach significantly enhances the accuracy and efficiency of thermal model,this contributes to the precise thermal control of subsequent infrared optical payloads.
基金Project(2022YFB3707201) supported by the National Key R&D Program of ChinaProject(U2341254) supported by the Ye Qisun Science Foundation of National Natural Science Foundation of China+1 种基金Projects(0604022GH0202143,0604022SH0201143) supported by the NPU Aoxiang Distinguished Young Scholars,ChinaProject supported by the Funding of Young Top-notch Talent of the National Ten Thousand Talent Program,China。
文摘Effects of ultrasonic bonding parameters on atomic diffusion, microstructure at the Al-Au interface, and shear strength of Al-Au ultrasonic bonding were investigated by the combining experiments and finite element (FE) simulation. The quantitative model of atomic diffusion, which is related to the ultrasonic bonding parameters, time and distance, is established to calculate the atomic diffusion of the Al-Au interface. The maximum relative error between the calculated and experimental fraction of Al atom is 7.35%, indicating high prediction accuracy of this model. During the process of ultrasonic bonding, Au8Al3 is the main intermetallic compound (IMC) at the Al-Au interface. With larger bonding forces, higher ultrasonic powers and longer bonding time, it is more difficult to remove the oxide particles from the Al-Au interface, which hinders the atomic diffusion. Therefore, the complicated stress state and the existence of oxide particles both promotes the formation of holes. The shear strength of Al-Au ultrasonic bonding increases with increasing bonding force, ultrasonic power and bonding time. However, combined with the presence of holes at especial parameters, the optimal ultrasonic bonding parameter is confirmed to be a bonding force of 23 gf, ultrasonic power of 75 mW and bonding time of 21 ms.
文摘In view of the limitations of traditional measurement methods in the field of building information,such as complex operation,low timeliness and poor accuracy,a new way of combining three-dimensional scanning technology and BIM(Building Information Modeling)model was discussed.Focused on the efficient acquisition of building geometric information using the fast-developing 3D point cloud technology,an improved deep learning-based 3D point cloud recognition method was proposed.The method optimised the network structure based on RandLA-Net to adapt to the large-scale point cloud processing requirements,while the semantic and instance features of the point cloud were integrated to significantly improve the recognition accuracy and provide a precise basis for BIM model remodeling.In addition,a visual BIM model generation system was developed,which systematically transformed the point cloud recognition results into BIM component parameters,automatically constructed BIM models,and promoted the open sharing and secondary development of models.The research results not only effectively promote the automation process of converting 3D point cloud data to refined BIM models,but also provide important technical support for promoting building informatisation and accelerating the construction of smart cities,showing a wide range of application potential and practical value.
文摘陶瓷在长时高温和高应力下工作时会发生蠕变,蠕变损伤累积将最终导致失效发生。蠕变损伤的演化与陶瓷的微结构有十分密切的关系,建立陶瓷材料的微观有限元模型有助于更深入地了解这一关系。以氮化硅陶瓷为研究对象,提出一种基于动力学的三维晶体沉积数值模型,结合Monte Carlo Potts结晶生长模型对氮化硅陶瓷的烧结过程进行模拟,力求还原氮化硅陶瓷的动态生长过程以及结晶后晶体大小、形状、取向分布以及空洞的大小、形状、分布等微观结构特征。基于该模拟生成的几何边界描述自动生成Python脚本,在有限元软件中完成建模。利用该有限元模型对氮化硅陶瓷的统计弹性常数进行验证,计算结果与试验数据对比,相对误差约为4.5%,吻合良好。
文摘采用累积频率的统计方法和Community Climate Model 3(CCM3)模拟的10年逐日降水结果,分析了模拟的夏季极端降水事件的时空分布特征.结果表明,CCM3模拟的极端降水阈值的大值区主要在我国黄河和长江流域的上游、印度半岛及其邻近海域和孟加拉湾及其北部地区.CCM3能够模拟出我国长江流域极端降水量与极端降水日数显著增加的趋势.对极端降水平均强度、降水日数以及极端降水量与总降水量比值的经验正交函数(EOF)分析可知,我国大部分地区的极端降水基本呈现同相变化,且以长江和黄河中游地区较为显著.CCM3模式基本能够模拟出观测到的极端降水阈值与总降水、极端降水日数及其距平的高空间相关性.
