Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres befor...Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres before and after high temperature treatment(HTT) were characterized by X-ray diffractometry(XRD) ,scanning electronic microscopy(SEM) ,energy diffraction spectroscopy(EDS) ,and transmission electron microscopy(TEM) .The formation mechanism of carbon spheres was discussed.The results indicate that the carbon spheres convert to hollow polyhedron through HTT.Carbon spheres are composed of entangled and curve graphitic layers with short range order similar to cotton structure,and carbon polyhedron with dimension of 50-250 nm and shell thickness of 15-30 nm.The change of solid spheres to hollow polyhedron with branches gives a new evidence for formation mechanism of hollow carbon spheres.展开更多
Heat-treated wood has good dimensional stability,corrosion resistance and visual quality,but it is prone to mold,which limits its application.Based on the pH value of heat-treated wood,this study examines the factors ...Heat-treated wood has good dimensional stability,corrosion resistance and visual quality,but it is prone to mold,which limits its application.Based on the pH value of heat-treated wood,this study examines the factors affecting the pathogenesis causing heat-treated wood mold.Normally,the pH value of the heat-treated wood is between 4.38 and 5.10,which is suitable for the growth of mold.However,the pH of the heat-treated copper-containing material is between 6.63 and 7.12,which deviates the treated wood from the comfortable growth conditions for the mold,thereby reducing the occurrence of mold.展开更多
基金Project(2006CB600901) supported by the National Basic Research Program of ChinaProject(0991015) supported by Guangxi Natural Science Foundation,ChinaProject(200808MS083) supported by Guangxi Education Department Foundation,China
文摘Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres before and after high temperature treatment(HTT) were characterized by X-ray diffractometry(XRD) ,scanning electronic microscopy(SEM) ,energy diffraction spectroscopy(EDS) ,and transmission electron microscopy(TEM) .The formation mechanism of carbon spheres was discussed.The results indicate that the carbon spheres convert to hollow polyhedron through HTT.Carbon spheres are composed of entangled and curve graphitic layers with short range order similar to cotton structure,and carbon polyhedron with dimension of 50-250 nm and shell thickness of 15-30 nm.The change of solid spheres to hollow polyhedron with branches gives a new evidence for formation mechanism of hollow carbon spheres.
基金Provincial Science and Technology Research Project of Guangdong(2014A040401043)
文摘Heat-treated wood has good dimensional stability,corrosion resistance and visual quality,but it is prone to mold,which limits its application.Based on the pH value of heat-treated wood,this study examines the factors affecting the pathogenesis causing heat-treated wood mold.Normally,the pH value of the heat-treated wood is between 4.38 and 5.10,which is suitable for the growth of mold.However,the pH of the heat-treated copper-containing material is between 6.63 and 7.12,which deviates the treated wood from the comfortable growth conditions for the mold,thereby reducing the occurrence of mold.
