The effects of plasticizers,antioxidants and burning rate modifiers on the aging performance of the composite solid propellant based on hydroxyl-terminated polybutadiene(HTPB)/hexamethylene diisocyanate(HMDI)were expl...The effects of plasticizers,antioxidants and burning rate modifiers on the aging performance of the composite solid propellant based on hydroxyl-terminated polybutadiene(HTPB)/hexamethylene diisocyanate(HMDI)were explored by apply-ing an accelerated aging program for 90 day at 70 ℃. The HTPB propellant matrix with the diisooctyl sebacate(DOS)as plasti-cizers and diisooctyl azelate(DOZ), antioxidants as N,N ′-Diphenyl-p-phenylenediamine(AO) and 2,2′-methylenebis(4-methyl-6-tert-butylphenol)(cyanox 2246)and burning rate modifiers as barium ferrite(BF),copper chromites(CC)and fer-ric oxide(FO)were varied. Results show that sample(S1)which based on DOS decreases the stress value and increases the strain value which considered to be an excellent start for aging program. Sample(S3)containing AO presents the higher resis-tance to oxidation showing the better performance that reflects on increasing the shelf life of the composite solid propellant mo-tor. Sample(S5)which based on BF enhances the ballistic performance among over the other tested two samples. The accelerat-ed aging program allowed us to estimate the motor in-service lifetime.展开更多
采用红外光谱、三维光学变形分析、凝胶含量及界面粘接性能测试等方法,研究了HTPB/IPDI推进剂装药界面弱粘接的增强技术。研究表明,衬层成型前,采用表面处理剂(STA-7),对绝热层表面进行预处理,可抑制近界面推进剂弱强度层的形成,显著提...采用红外光谱、三维光学变形分析、凝胶含量及界面粘接性能测试等方法,研究了HTPB/IPDI推进剂装药界面弱粘接的增强技术。研究表明,衬层成型前,采用表面处理剂(STA-7),对绝热层表面进行预处理,可抑制近界面推进剂弱强度层的形成,显著提高界面粘接强度。绝热层表面预处理后,近界面推进剂的凝胶含量可提高约90%,联合扯离强度提高400 k Pa以上,达到与推进剂本体强度相当的水平,试件破坏形式与其等效应力云图相符。展开更多
固体推进剂中AP颗粒的级配不同会导致力学性能相差巨大,为了探究AP颗粒的粒度值和质量分数对端羟基聚丁二烯(HTPB)推进剂力学性能的影响规律,采用机器学习的方法对推进剂的力学性能进行仿真预测,降低了实验成本并提高了预测效率。首先,...固体推进剂中AP颗粒的级配不同会导致力学性能相差巨大,为了探究AP颗粒的粒度值和质量分数对端羟基聚丁二烯(HTPB)推进剂力学性能的影响规律,采用机器学习的方法对推进剂的力学性能进行仿真预测,降低了实验成本并提高了预测效率。首先,对不同级配的HTPB推进剂进行拉伸试验,得到不同温度下抗拉强度和伸长率;其次,以拉伸试验结果为样本进行机器学习,分别构建了反向传播(Back Propagation,BP)神经网络、粒子群算法优化的反向传播(Particle Swarm Optimization Back Propagation,PSOBP)神经网络和遗传算法优化的反向传播(Genetic Algorithms Back Propagation,GABP)神经网络对推进剂的力学性能进行预测。结果表明,力学性能与颗粒级配的内在关系较为复杂,并非简单的线性关系。PSOBP和GABP可以用于预测不同级配下HTPB推进剂力学性能,并且GABP神经网络可以更好地预测推进剂的力学性能变化。展开更多
文摘The effects of plasticizers,antioxidants and burning rate modifiers on the aging performance of the composite solid propellant based on hydroxyl-terminated polybutadiene(HTPB)/hexamethylene diisocyanate(HMDI)were explored by apply-ing an accelerated aging program for 90 day at 70 ℃. The HTPB propellant matrix with the diisooctyl sebacate(DOS)as plasti-cizers and diisooctyl azelate(DOZ), antioxidants as N,N ′-Diphenyl-p-phenylenediamine(AO) and 2,2′-methylenebis(4-methyl-6-tert-butylphenol)(cyanox 2246)and burning rate modifiers as barium ferrite(BF),copper chromites(CC)and fer-ric oxide(FO)were varied. Results show that sample(S1)which based on DOS decreases the stress value and increases the strain value which considered to be an excellent start for aging program. Sample(S3)containing AO presents the higher resis-tance to oxidation showing the better performance that reflects on increasing the shelf life of the composite solid propellant mo-tor. Sample(S5)which based on BF enhances the ballistic performance among over the other tested two samples. The accelerat-ed aging program allowed us to estimate the motor in-service lifetime.
文摘采用红外光谱、三维光学变形分析、凝胶含量及界面粘接性能测试等方法,研究了HTPB/IPDI推进剂装药界面弱粘接的增强技术。研究表明,衬层成型前,采用表面处理剂(STA-7),对绝热层表面进行预处理,可抑制近界面推进剂弱强度层的形成,显著提高界面粘接强度。绝热层表面预处理后,近界面推进剂的凝胶含量可提高约90%,联合扯离强度提高400 k Pa以上,达到与推进剂本体强度相当的水平,试件破坏形式与其等效应力云图相符。
文摘固体推进剂中AP颗粒的级配不同会导致力学性能相差巨大,为了探究AP颗粒的粒度值和质量分数对端羟基聚丁二烯(HTPB)推进剂力学性能的影响规律,采用机器学习的方法对推进剂的力学性能进行仿真预测,降低了实验成本并提高了预测效率。首先,对不同级配的HTPB推进剂进行拉伸试验,得到不同温度下抗拉强度和伸长率;其次,以拉伸试验结果为样本进行机器学习,分别构建了反向传播(Back Propagation,BP)神经网络、粒子群算法优化的反向传播(Particle Swarm Optimization Back Propagation,PSOBP)神经网络和遗传算法优化的反向传播(Genetic Algorithms Back Propagation,GABP)神经网络对推进剂的力学性能进行预测。结果表明,力学性能与颗粒级配的内在关系较为复杂,并非简单的线性关系。PSOBP和GABP可以用于预测不同级配下HTPB推进剂力学性能,并且GABP神经网络可以更好地预测推进剂的力学性能变化。
