Three-dimensional model of chemical vapor deposition reaction in polysilicon reduction furnace was established by considering mass, momentum and energy transfer simultaneously. Then, CFD software was used to simulate ...Three-dimensional model of chemical vapor deposition reaction in polysilicon reduction furnace was established by considering mass, momentum and energy transfer simultaneously. Then, CFD software was used to simulate the flow, heat transfer and chemical reaction process in reduction furnace and to analyze the change law of deposition characteristic along with the H_2 mole fraction, silicon rod height and silicon rod diameter. The results show that with the increase of H_2 mole fraction, silicon growth rate increases firstly and then decreases. On the contrary, SiHCl_3 conversion rate and unit energy consumption decrease firstly and then increase. Silicon production rate increases constantly. The optimal H_2 mole fraction is 0.8-0.85. With the growth of silicon rod height, Si HCl3 conversion rate, silicon production rate and silicon growth rate increase, while unit energy consumption decreases. In terms of chemical reaction, the higher the silicon rod is, the better the performance is. In the view of the top-heavy situation, the actual silicon rod height is limited to be below 3 m. With the increase of silicon rod diameter, silicon growth rate decreases firstly and then increases. Besides, SiHCl_3 conversion rate and silicon production rate increase, while unit energy consumption first decreases sharply, then becomes steady. In practice, the bigger silicon rod diameter is more suitable. The optimal silicon rod diameter must be over 120 mm.展开更多
In order to reduce the materials cost of COREX ironmaking process,sinter has been introduced into the composite burden in China.This work explored the reducing process of sinter in COREX shaft furnace to clarify its r...In order to reduce the materials cost of COREX ironmaking process,sinter has been introduced into the composite burden in China.This work explored the reducing process of sinter in COREX shaft furnace to clarify its reduction properties change and then the effect of sinter proportion on metallurgical performance of composite burden was investigated.The results show that the reducing process of sinter in COREX shaft furnace was basically same with that in blast furnace but sinter seems like breaking faster.Under reducing condition simulated COREX shaft furnace,sinter possessed the worst reduction degradation index(RDI)and undifferentiated reduction index(RI)compared with pellet and iron ore lumps.Macroscopic and microscopic mineralogy changes indicated that sinter presents integral cracking while pellet and lump ore present surface cracking,and no simple congruent relationship exists between cracks of the burden and its ultimate reduction degradation performance.The existence of partial metallurgical performance superposition between composite and single ferrous burden was confirmed.RDI_(+6.3)≥70%and RDI_(+3.15)≥80%were speculated as essential requirements for the composite burden containing sinter in COREX shaft furnace.展开更多
In this study,innovative ellipsoid pellet with craters on its surface was designed,and the direct reduction process was compared with ellipsoid(without craters)and sphere pellets.In addition,furnace temperature and un...In this study,innovative ellipsoid pellet with craters on its surface was designed,and the direct reduction process was compared with ellipsoid(without craters)and sphere pellets.In addition,furnace temperature and uneven heat flux density effects on the pellet direct reduction process were also studied.The results show that ellipsoid pellet is better than that of spherical pellet on metallization ratio.However,under the condition of non-uniform heat flow,the ellipsoid pellet final metallization rate and zinc removal rate were lower.Although the heat transfer effect of ellipsoid pellet with craters was not improved significantly,the metallization rate and zinc removal rate were found improved,which will have a cumulative effect on the pellets direct reduction process in rotary hearth furnace.Under varying furnace temperature conditions,the pellet temperature was higher than that of the constant furnace temperature.After 1200 s,pellet Fe concentration increased to 123.6%,metallization rate and zinc removal rate increased to 113.7%and 102.2%,respectively.These results can provide references for the carbon-containing pellet design used in rotary hearth furnace.展开更多
It is of great importance to elucidate reduction swelling behaviors and reaction mechanism of oxidized pellet in hydrogen-enriched atmosphere under coke oven gas injection. In this work, the effects of hydrogen concen...It is of great importance to elucidate reduction swelling behaviors and reaction mechanism of oxidized pellet in hydrogen-enriched atmosphere under coke oven gas injection. In this work, the effects of hydrogen concentration in N_2-CO-H_2 atmosphere with unchanged CO content on reduction swelling behaviors of oxidized pellet at 1173 K were studied, to clarify the mechanism of hydrogen-enriched reduction and exclude the influences of CO. Then, the reduction swelling behaviors of oxidized pellet at 1173 K in actual atmosphere under coke oven gas(COG) injection, got from the simulation results of multi-fluid blast furnace model, were investigated. The results show that with the concentration of hydrogen increasing in N_2-CO-H_2 gas from 2% to 18%, the reduction swelling index of pellet decreases from 10.12% to 5.57% while the reduction ratio of pellet increases obviously from 39.85% to 69.58%. In addition, with COG injection rate increasing from 0 to 152.34 m^3/t, the reduction swelling index of pellet decreases slightly from 10.71% to 9.54% while the reduction ratio of pellet is increased from 31.57% to 36.39%. The microstructures of pellet are transformed from the platy structure to the flocculent structure.展开更多
Clean Production is the best method for iron-steel making industry to eliminate pollution thoroughly. In order to achieve this object, smelting reduction technology should play the key role. Furthermore, process integ...Clean Production is the best method for iron-steel making industry to eliminate pollution thoroughly. In order to achieve this object, smelting reduction technology should play the key role. Furthermore, process integration method can be used to solve the problem of residual gas utilization by integrating smelting reduction process with direct reduced iron unit, gasoline, methanol or dimethyl ether synthesis unit, etc. A new smelting reduction process has been proposed which can be constructed on the present plant site. Since this process can directly treat the lump coal and iron ore fines, it reduces st6ps necessary in traditional blast furnace process and Corex smelting reduction process.展开更多
基金Project(12C0379) supported by Scientific Research Fund of Hunan Province,China
文摘Three-dimensional model of chemical vapor deposition reaction in polysilicon reduction furnace was established by considering mass, momentum and energy transfer simultaneously. Then, CFD software was used to simulate the flow, heat transfer and chemical reaction process in reduction furnace and to analyze the change law of deposition characteristic along with the H_2 mole fraction, silicon rod height and silicon rod diameter. The results show that with the increase of H_2 mole fraction, silicon growth rate increases firstly and then decreases. On the contrary, SiHCl_3 conversion rate and unit energy consumption decrease firstly and then increase. Silicon production rate increases constantly. The optimal H_2 mole fraction is 0.8-0.85. With the growth of silicon rod height, Si HCl3 conversion rate, silicon production rate and silicon growth rate increase, while unit energy consumption decreases. In terms of chemical reaction, the higher the silicon rod is, the better the performance is. In the view of the top-heavy situation, the actual silicon rod height is limited to be below 3 m. With the increase of silicon rod diameter, silicon growth rate decreases firstly and then increases. Besides, SiHCl_3 conversion rate and silicon production rate increase, while unit energy consumption first decreases sharply, then becomes steady. In practice, the bigger silicon rod diameter is more suitable. The optimal silicon rod diameter must be over 120 mm.
基金Project(2019JJ51007)supported by the Natural Science Foundation of Hunan Province,China。
文摘In order to reduce the materials cost of COREX ironmaking process,sinter has been introduced into the composite burden in China.This work explored the reducing process of sinter in COREX shaft furnace to clarify its reduction properties change and then the effect of sinter proportion on metallurgical performance of composite burden was investigated.The results show that the reducing process of sinter in COREX shaft furnace was basically same with that in blast furnace but sinter seems like breaking faster.Under reducing condition simulated COREX shaft furnace,sinter possessed the worst reduction degradation index(RDI)and undifferentiated reduction index(RI)compared with pellet and iron ore lumps.Macroscopic and microscopic mineralogy changes indicated that sinter presents integral cracking while pellet and lump ore present surface cracking,and no simple congruent relationship exists between cracks of the burden and its ultimate reduction degradation performance.The existence of partial metallurgical performance superposition between composite and single ferrous burden was confirmed.RDI_(+6.3)≥70%and RDI_(+3.15)≥80%were speculated as essential requirements for the composite burden containing sinter in COREX shaft furnace.
基金Project(cstc 2018 jszx-cyzdx 0100)supported by the Chongqing Technology Innovation and Application Demonstration Project,China。
文摘In this study,innovative ellipsoid pellet with craters on its surface was designed,and the direct reduction process was compared with ellipsoid(without craters)and sphere pellets.In addition,furnace temperature and uneven heat flux density effects on the pellet direct reduction process were also studied.The results show that ellipsoid pellet is better than that of spherical pellet on metallization ratio.However,under the condition of non-uniform heat flow,the ellipsoid pellet final metallization rate and zinc removal rate were lower.Although the heat transfer effect of ellipsoid pellet with craters was not improved significantly,the metallization rate and zinc removal rate were found improved,which will have a cumulative effect on the pellets direct reduction process in rotary hearth furnace.Under varying furnace temperature conditions,the pellet temperature was higher than that of the constant furnace temperature.After 1200 s,pellet Fe concentration increased to 123.6%,metallization rate and zinc removal rate increased to 113.7%and 102.2%,respectively.These results can provide references for the carbon-containing pellet design used in rotary hearth furnace.
基金Project(51404005)supported by the National Natural Science Foundation of China
文摘It is of great importance to elucidate reduction swelling behaviors and reaction mechanism of oxidized pellet in hydrogen-enriched atmosphere under coke oven gas injection. In this work, the effects of hydrogen concentration in N_2-CO-H_2 atmosphere with unchanged CO content on reduction swelling behaviors of oxidized pellet at 1173 K were studied, to clarify the mechanism of hydrogen-enriched reduction and exclude the influences of CO. Then, the reduction swelling behaviors of oxidized pellet at 1173 K in actual atmosphere under coke oven gas(COG) injection, got from the simulation results of multi-fluid blast furnace model, were investigated. The results show that with the concentration of hydrogen increasing in N_2-CO-H_2 gas from 2% to 18%, the reduction swelling index of pellet decreases from 10.12% to 5.57% while the reduction ratio of pellet increases obviously from 39.85% to 69.58%. In addition, with COG injection rate increasing from 0 to 152.34 m^3/t, the reduction swelling index of pellet decreases slightly from 10.71% to 9.54% while the reduction ratio of pellet is increased from 31.57% to 36.39%. The microstructures of pellet are transformed from the platy structure to the flocculent structure.
文摘Clean Production is the best method for iron-steel making industry to eliminate pollution thoroughly. In order to achieve this object, smelting reduction technology should play the key role. Furthermore, process integration method can be used to solve the problem of residual gas utilization by integrating smelting reduction process with direct reduced iron unit, gasoline, methanol or dimethyl ether synthesis unit, etc. A new smelting reduction process has been proposed which can be constructed on the present plant site. Since this process can directly treat the lump coal and iron ore fines, it reduces st6ps necessary in traditional blast furnace process and Corex smelting reduction process.
