A comprehensive and precise analysis of shale gas production performance is crucial for evaluating resource potential,designing a field development plan,and making investment decisions.However,quantitative analysis ca...A comprehensive and precise analysis of shale gas production performance is crucial for evaluating resource potential,designing a field development plan,and making investment decisions.However,quantitative analysis can be challenging because production performance is dominated by the complex interaction among a series of geological and engineering factors.In fact,each factor can be viewed as a player who makes cooperative contributions to the production payoff within the constraints of physical laws and models.Inspired by the idea,we propose a hybrid data-driven analysis framework in this study,where the contributions of dominant factors are quantitatively evaluated,the productions are precisely forecasted,and the development optimization suggestions are comprehensively generated.More specifically,game theory and machine learning models are coupled to determine the dominating geological and engineering factors.The Shapley value with definite physical meaning is employed to quantitatively measure the effects of individual factors.A multi-model-fused stacked model is trained for production forecast,which provides the basis for derivative-free optimization algorithms to optimize the development plan.The complete workflow is validated with actual production data collected from the Fuling shale gas field,Sichuan Basin,China.The validation results show that the proposed procedure can draw rigorous conclusions with quantified evidence and thereby provide specific and reliable suggestions for development plan optimization.Comparing with traditional and experience-based approaches,the hybrid data-driven procedure is advanced in terms of both efficiency and accuracy.展开更多
Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer ...Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.展开更多
It is known that there is a discrepancy between field data and the results predicted from the previous equations derived by simplifying three-dimensional（3-D） flow into two-dimensions（2-D）.This paper presents a ne...It is known that there is a discrepancy between field data and the results predicted from the previous equations derived by simplifying three-dimensional（3-D） flow into two-dimensions（2-D）.This paper presents a new steady-state productivity equation for horizontal wells in bottom water drive gas reservoirs.Firstly,the fundamental solution to the 3-D steady-state Laplace equation is derived with the philosophy of source and the Green function for a horizontal well located at the center of the laterally infinite gas reservoir.Then,using the fundamental solution and the Simpson integral formula,the average pseudo-pressure equation and the steady-state productivity equation are achieved for the horizontal section.Two case-studies are given in the paper,the results calculated from the newly-derived formula are very close to the numerical simulation performed with the Canadian software CMG and the real production data,indicating that the new formula can be used to predict the steady-state productivity of such horizontal gas wells.展开更多
Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakth...Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.展开更多
As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect a...As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect and the theory of multiphase flow. With this model, the transient flow of gas well can be simulated by segmenting the curved part of tubing and calculating numerical solution with the method of characteristic curve. The results show that the higher the opening coefficient of the valve when closed, the larger the peak value of the wellhead pressure, the more gentle the pressure fluctuation, and the less obvious the pressure mutation area will be. On the premise of not exceeding the maximum shut-in pressure of the tubing, adopting large opening coefficient can reduce the impact of the pressure wave. The higher the cross-section liquid holdup, the greater the pressure wave speed, and the shorter the propagation period will be. The larger the liquid holdup, the larger the variation range of pressure, and the greater the pressure will be. In actual production, the production parameters can be adjusted to get the appropriate liquid holdup, control the magnitude and range of fluctuation pressure, and reduce the impact of water hammer effect. When the valve closing time increases, the maximum fluctuating pressure value of the wellhead decreases, the time of pressure peak delays, and the pressure mutation area gradually disappears. The shorter the valve closing time, the faster the pressure wave propagates. Case simulation proves that the transient flow model of gas well can optimize the reasonable valve opening coefficient and valve closing time, reduce the harm of water hammer impact on the wellhead device and tubing, and ensure the integrity of the wellbore.展开更多
A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing metho...A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing methods for transient flow analysis and the characteristics of the injection-production operation of strongly heterogeneous gas reservoirs, and the corresponding theoretical charts were drawn. In addition, an injection-production dynamic transient flow analysis model named "three points and two stages" suitable for an underground gas storage(UGS) well with alternate working conditions was proposed. The "three points" refer to three time points during cyclic injection and production, namely, the starting point of gas injection for UGS construction, the beginning and ending points of the injection-production analysis stage;and the "two stages" refer to historical flow stage and injection-production analysis stage. The study shows that the dimensionless pseudo-pressure and dimensionless pseudo-pressure integral curves of UGS well flex downward in the early stage of the injection and production process, and the dimensionless pseudo-pressure integral derivative curve is convex during the gas production period and concave during the gas injection period, and the curves under different flow histories have atypical features. The new method present in this paper can analyze transient flow of UGS accurately. The application of this method to typical wells in Hutubi gas storage shows that the new method can fit the pressure history accurately, and obtain reliable parameters and results.展开更多
The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to amm...The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to ammonia synthesis and other reactions. Advanced catalysts have been developed for both high and low-temperature reactions and are widely used in industry. In recent years, supported metal nanoparticle catalysts have been researched due to their high metal utilization. Low-temperature catalysts have shown promising results, including high selectivity, high shift rates, and higher activity potential. Additionally, significant progress has been made in removing trace CO through the redox reaction in electrolytic cell. This paper reviews the development of WGS reaction catalysts, including the reaction mechanism, catalyst design, and innovative research methods. The catalyst plays a crucial role in the WGS reaction, and this paper provides an instant of catalyst design under different conditions. The progress of catalysts is closely related to the development of advanced characterization techniques.Furthermore, modifying the catalyst surface to enhance activity and significantly increase reaction kinetics is a current research direction. This review goals to stimulate a better understanding of catalyst design, performance optimization, and driving mechanisms, leading to further progress in this field.展开更多
基于固相萃取结合超高效液相色谱-串联质谱技术建立同时测定水源水中176种药品和个人护理用品(pharmaceutical and personal care products,PPCPs)含量的方法。将水源水调节至pH 7后,经Cleanert PEP固相萃取柱富集净化,洗脱液采用二甲...基于固相萃取结合超高效液相色谱-串联质谱技术建立同时测定水源水中176种药品和个人护理用品(pharmaceutical and personal care products,PPCPs)含量的方法。将水源水调节至pH 7后,经Cleanert PEP固相萃取柱富集净化,洗脱液采用二甲基亚砜辅助浓缩后,以甲醇-0.1%甲酸水(含0.2 mmol乙酸铵)为流动相,在HSS T3色谱柱(2.1 mm×150 mm,1.8μm)中进行分离,用电喷雾离子源(正负离子切换模式)、多反应监测模式进行测定。方法学验证结果表明,176种PPCPs在5~200 ng/mL范围内线性关系较好,相关系数均高于0.99。176种PPCPs的方法的定量限为0.1 ng/mL。在空白水样中进行3种加标水平(0.1、0.4、1.0 ng/mL)的加标回收实验(n=6),176种化合物的平均回收率在68.0%~126.7%之间,相对标准偏差在1.1%~10.3%之间。综上,本研究所建立的方法简单快速、重现性好、灵敏度高,能够满足水源水中176种PPCPs含量的高通量检测要求。展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant No.42050104)the Science Foundation of SINOPEC Group(Grant No.P20030).
文摘A comprehensive and precise analysis of shale gas production performance is crucial for evaluating resource potential,designing a field development plan,and making investment decisions.However,quantitative analysis can be challenging because production performance is dominated by the complex interaction among a series of geological and engineering factors.In fact,each factor can be viewed as a player who makes cooperative contributions to the production payoff within the constraints of physical laws and models.Inspired by the idea,we propose a hybrid data-driven analysis framework in this study,where the contributions of dominant factors are quantitatively evaluated,the productions are precisely forecasted,and the development optimization suggestions are comprehensively generated.More specifically,game theory and machine learning models are coupled to determine the dominating geological and engineering factors.The Shapley value with definite physical meaning is employed to quantitatively measure the effects of individual factors.A multi-model-fused stacked model is trained for production forecast,which provides the basis for derivative-free optimization algorithms to optimize the development plan.The complete workflow is validated with actual production data collected from the Fuling shale gas field,Sichuan Basin,China.The validation results show that the proposed procedure can draw rigorous conclusions with quantified evidence and thereby provide specific and reliable suggestions for development plan optimization.Comparing with traditional and experience-based approaches,the hybrid data-driven procedure is advanced in terms of both efficiency and accuracy.
基金supported by the National Natural Science Foundation of China(Grant Nos.52304044,52222402,52234003,52174036)Sichuan Science and Technology Program(Nos.2022JDJQ0009,2023NSFSC0934)+2 种基金Key Technology R&D Program of Shaanxi Province(2023-YBGY-30)the Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX030202)the China Postdoctoral Science Foundation(Grant No.2022M722638)。
文摘Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.
基金financial support from the Open Fund(PLN1003) of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Southwest Petroleum University)the National Science and Technology Major Project in the l lth Five-Year Plan(Grant No.2008ZX05054)
文摘It is known that there is a discrepancy between field data and the results predicted from the previous equations derived by simplifying three-dimensional（3-D） flow into two-dimensions（2-D）.This paper presents a new steady-state productivity equation for horizontal wells in bottom water drive gas reservoirs.Firstly,the fundamental solution to the 3-D steady-state Laplace equation is derived with the philosophy of source and the Green function for a horizontal well located at the center of the laterally infinite gas reservoir.Then,using the fundamental solution and the Simpson integral formula,the average pseudo-pressure equation and the steady-state productivity equation are achieved for the horizontal section.Two case-studies are given in the paper,the results calculated from the newly-derived formula are very close to the numerical simulation performed with the Canadian software CMG and the real production data,indicating that the new formula can be used to predict the steady-state productivity of such horizontal gas wells.
基金Supported by the China National Science and Technology Major Project(2016ZX05062)the PetroChina Science and Technology Major Project(2016E-0611)
文摘Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.
基金Supported by National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05026-002,2016ZX05028-001,2016ZX05024-005)
文摘As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect and the theory of multiphase flow. With this model, the transient flow of gas well can be simulated by segmenting the curved part of tubing and calculating numerical solution with the method of characteristic curve. The results show that the higher the opening coefficient of the valve when closed, the larger the peak value of the wellhead pressure, the more gentle the pressure fluctuation, and the less obvious the pressure mutation area will be. On the premise of not exceeding the maximum shut-in pressure of the tubing, adopting large opening coefficient can reduce the impact of the pressure wave. The higher the cross-section liquid holdup, the greater the pressure wave speed, and the shorter the propagation period will be. The larger the liquid holdup, the larger the variation range of pressure, and the greater the pressure will be. In actual production, the production parameters can be adjusted to get the appropriate liquid holdup, control the magnitude and range of fluctuation pressure, and reduce the impact of water hammer effect. When the valve closing time increases, the maximum fluctuating pressure value of the wellhead decreases, the time of pressure peak delays, and the pressure mutation area gradually disappears. The shorter the valve closing time, the faster the pressure wave propagates. Case simulation proves that the transient flow model of gas well can optimize the reasonable valve opening coefficient and valve closing time, reduce the harm of water hammer impact on the wellhead device and tubing, and ensure the integrity of the wellbore.
基金Supported by the CNPC Major Scientific and Technological Project(2019B-3204)PetroChina Major Scientific and Technological Project(kt2020-16-01)。
文摘A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing methods for transient flow analysis and the characteristics of the injection-production operation of strongly heterogeneous gas reservoirs, and the corresponding theoretical charts were drawn. In addition, an injection-production dynamic transient flow analysis model named "three points and two stages" suitable for an underground gas storage(UGS) well with alternate working conditions was proposed. The "three points" refer to three time points during cyclic injection and production, namely, the starting point of gas injection for UGS construction, the beginning and ending points of the injection-production analysis stage;and the "two stages" refer to historical flow stage and injection-production analysis stage. The study shows that the dimensionless pseudo-pressure and dimensionless pseudo-pressure integral curves of UGS well flex downward in the early stage of the injection and production process, and the dimensionless pseudo-pressure integral derivative curve is convex during the gas production period and concave during the gas injection period, and the curves under different flow histories have atypical features. The new method present in this paper can analyze transient flow of UGS accurately. The application of this method to typical wells in Hutubi gas storage shows that the new method can fit the pressure history accurately, and obtain reliable parameters and results.
基金financially supported by the National Natural Science Foundation of China (22279118, 22279117, 22075254,31901272)the Top-Notch Talent Program of Henan Agricultural University (30501034)。
文摘The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to ammonia synthesis and other reactions. Advanced catalysts have been developed for both high and low-temperature reactions and are widely used in industry. In recent years, supported metal nanoparticle catalysts have been researched due to their high metal utilization. Low-temperature catalysts have shown promising results, including high selectivity, high shift rates, and higher activity potential. Additionally, significant progress has been made in removing trace CO through the redox reaction in electrolytic cell. This paper reviews the development of WGS reaction catalysts, including the reaction mechanism, catalyst design, and innovative research methods. The catalyst plays a crucial role in the WGS reaction, and this paper provides an instant of catalyst design under different conditions. The progress of catalysts is closely related to the development of advanced characterization techniques.Furthermore, modifying the catalyst surface to enhance activity and significantly increase reaction kinetics is a current research direction. This review goals to stimulate a better understanding of catalyst design, performance optimization, and driving mechanisms, leading to further progress in this field.
文摘基于固相萃取结合超高效液相色谱-串联质谱技术建立同时测定水源水中176种药品和个人护理用品(pharmaceutical and personal care products,PPCPs)含量的方法。将水源水调节至pH 7后,经Cleanert PEP固相萃取柱富集净化,洗脱液采用二甲基亚砜辅助浓缩后,以甲醇-0.1%甲酸水(含0.2 mmol乙酸铵)为流动相,在HSS T3色谱柱(2.1 mm×150 mm,1.8μm)中进行分离,用电喷雾离子源(正负离子切换模式)、多反应监测模式进行测定。方法学验证结果表明,176种PPCPs在5~200 ng/mL范围内线性关系较好,相关系数均高于0.99。176种PPCPs的方法的定量限为0.1 ng/mL。在空白水样中进行3种加标水平(0.1、0.4、1.0 ng/mL)的加标回收实验(n=6),176种化合物的平均回收率在68.0%~126.7%之间,相对标准偏差在1.1%~10.3%之间。综上,本研究所建立的方法简单快速、重现性好、灵敏度高,能够满足水源水中176种PPCPs含量的高通量检测要求。
