Hexagonal boron nitride(h-BN)is found to have widespread application,owing to its outstanding properties,including gate dielectrics,passivation layers,and tunneling layers.The current studies on the funda⁃mental physi...Hexagonal boron nitride(h-BN)is found to have widespread application,owing to its outstanding properties,including gate dielectrics,passivation layers,and tunneling layers.The current studies on the funda⁃mental physical properties of these ultrathin h-BN films and the electron tunneling effect among them are inade⁃quate.In this work,the effective mass in h-BN was successfully determined through a combined approach of ex⁃perimental and theoretical research methods by fitting the current-voltage curves of metal/insulator/metal struc⁃tures.It was observed that within a range of 4-22 layers,the effective mass of h-BN exhibits a monotonic de⁃crease with an increase in the number of layers.The physical parameters of the Fowler-Nordheim tunneling model in the context of electron tunneling in h-BN are precisely ascertained by utilizing the extracted effective mass.Ad⁃ditionally,the impact of fixed charges at the metal/h-BN interface and various metal electrode types on FowlerNordheim tunneling within this structure is investigated utilizing this physical parameter in Sentaurus TCAD soft⁃ware.This work is informative and instructive in promoting applications in the fields of h-BN related infrared physics and technology.展开更多
The nitrogen (N) metabolic experiments were made to estimate separately amino acid requirements of 4348 weeks old layers for maintenance, for protein accretion to estabolish models to estimate digestible amino acid re...The nitrogen (N) metabolic experiments were made to estimate separately amino acid requirements of 4348 weeks old layers for maintenance, for protein accretion to estabolish models to estimate digestible amino acid requirements. The regression relationship of nitrogen retention vs amino acid intake was estimated for each amino acid by giving, at rate of N intake of 091, 052, 015 and 0007gkg-1 body-weight (W075) per d, the semi-synthetic diets was made specially deficient in one amino acid. From the regression coefficients, it was calculated that, for the accretion of 1 g protein, the dietary digestible amino acid requirements were (mg) Thr 631, Val 1004, Met 399, Ile 886, Leu 1143, Phe 632, Lys 870, His 205, Arg 879, Trp 214, Met+Cys 776, and Phe+Tyr 1143. Daily amino acid requirements for N equilibrium were estimated to be (mgkg-1W075 per day) Thr 506, Val 747, Met 303, ILe 667 Leu 814, Phe 448, Lys 605 His 147, Arg 739 ,Trp 173, Met+Cys 586, and Phe+Tyr 839 The dietary degestible amino acid patterns for protein accretion and N equilibrium were also proposed. The models of estimating digestible amino acid requirements for the different productions were developed.展开更多
An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the...An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.展开更多
As the proton transport channel and binder within the catalytic layer(CL),the physicochemical properties of the ionomer can affect the CL microstructure and performance of the membrane electrode assembly.In this paper...As the proton transport channel and binder within the catalytic layer(CL),the physicochemical properties of the ionomer can affect the CL microstructure and performance of the membrane electrode assembly.In this paper,we select ionomers with different side-chain lengths and investigate the effects of the side-chain structure and content of the ionomers on the performance of membrane electrode assembly(MEA).Electrochemical tests show that at a mass ratio of 10 wt.%of ionomer/Ir(I/Ir),long-side-chain(LSC)ionomer exhibits the best performance(2.141 V@2.00 A/cm^(2),while short-side-chain(SSC)ionomer is 2.208 V@2.00 A/cm^(2)).The MEA containing LSC ionomer shows better electrochemical performance than the SSC at the same I/Ir mass ratio,especially at high current density.The MEA containing LSC ionomer has a larger average pore size and porosity,which indicates that it may have better mass-transfer properties.From the analysis of voltage loss,it can be seen that LSC ionomers have a smaller ohmic impedance and mass transfer resistance than SSC ionomers.In conclusion,LSC ionomers are more conducive to water-gas transport,which can provide excellent water electrolysis performance.This article focuses on the optimization of ionomer side chains and content,which can enhance PEM water electrolysis performance at lower cost.展开更多
Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technologic...Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technological Research Council of Turkey(TÜB˙ITAK)for receiving financial support for this work through the 2221 Fellowship Program for Visiting Scientists and Scientists on Sabbatical Leave(Grant ID:E 21514107-115.02-228864).Sasan YAZDANI also expresses his gratitude to Sahand University of Technology for granting him sabbatical leave to facilitate the completion of this research.展开更多
A 31 week feeding trial was conducted to investigated the effects of dietary supplementation of microbial phytase and cellulase on performance,nutrients utilization and tibia quality of laying hens fed maize and soyb...A 31 week feeding trial was conducted to investigated the effects of dietary supplementation of microbial phytase and cellulase on performance,nutrients utilization and tibia quality of laying hens fed maize and soybean meal diets.192 18 week old Hisex layers were used in the trial A 2×2×2 factorial design was used in the experiment with three factors of two levels each:0 38% and 0 16% of dietary non phytate P(nP).0 and 300 U·kg -1 of phytase (Ph),and 0 and 0 10% of cellulase (Ce).The results showed that supplementation of 300 U·kg -1 phytase significantly improved utilization of dietary crude ash,CP,Ca,total P and copper (P<0 05),and improved tibia breaking strength (P<0 05).No effect of phytase on performance was observed.Addition of 0 10% cellulase decreased feed intake (P<0 05),increased utilization of CF (P<0 05) and Ca(P<0 01),and decreased total tibia ash weight (P<0 05).300 U·kg -1 phytase and 0 10% cellulase exhibited obvious positive interactions to enhance utilization of dietary phytic P and copper (P<0 05).0 16% nP did not reduce performance of the layers,but improved egg shell quality at 20 wks,increased utilization of dietary total P,phytic P and Copper (P<0 01),decreased utilization of dietary CP,increased tibia breaking strength and Ca,Mn contents of tibia(P<0 01)展开更多
A numerical analysis of the log-law behavior for the turbulent boundary layer of a wall-bounded flow is performed over a flat plate immersed in three nanofluids(Zn O-water,SiO_(2)-water,TiO_(2)-water).Numerical simula...A numerical analysis of the log-law behavior for the turbulent boundary layer of a wall-bounded flow is performed over a flat plate immersed in three nanofluids(Zn O-water,SiO_(2)-water,TiO_(2)-water).Numerical simulations using CFD code are employed to investigate the boundary layer and the hydrodynamic flow.To validate the current numerical model,measurement points from published works were used,and the compared results were in good compliance.Simulations were carried out for the velocity series of 0.04,0.4 and 4 m/s and nanoparticle concentrations0.1% and 5%.The influence of nanoparticles’ concentration on velocity,temperature profiles,wall shear stress,and turbulent intensity was investigated.The obtained results showed that the viscous sub-layer,the buffer layer,and the loglaw layer along the potential-flow layer could be analyzed based on their curving quality in the regions which have just a single wall distance.It was seen that the viscous sub-layer is the biggest area in comparison with other areas.Alternatively,the section where the temperature changes considerably correspond to the thermal boundary layer’s thickness goes a downward trend when the velocity decreases.The thermal boundary layer gets deep away from the leading edge.However,a rise in the volume fraction of nanoparticles indicated a minor impact on the shear stress developed in the wall.In all cases,the thickness of the boundary layer undergoes a downward trend as the velocity increases,whereas increasing the nanoparticle concentrations would enhance the thickness.More precisely,the log layer is closed with log law,and it is minimal between Y^(+)=50 and Y^(+)=95.The temperature for nanoparticle concentration φ=5%is higher than that for φ=0.1%,in boundary layers,for all studied nanofluids.However,it is established that the behavior is inverted from the value of Y^(+)=1 and the temperature for φ =0.1% is more important than the case of φ =5%.For turbulence intensity peak,this peak exists at Y^(+)=100 for v=4 m/s,Y^(+)=10 for v=0.4 m/s and Y^(+)=8 for v=0.04 m/s.展开更多
We have systematically investigated the feature, genetic model and distribution of calcareous insulating layers in marine strata of the Ⅰ oil group in member 2 of Zhujiang formation(ZJ2I oil formation), western Pearl...We have systematically investigated the feature, genetic model and distribution of calcareous insulating layers in marine strata of the Ⅰ oil group in member 2 of Zhujiang formation(ZJ2I oil formation), western Pearl River Mouth basin(PRMB) in the north of the South China Sea by using data such as cores, thin sections, X-ray diffraction of whole-rock, and calcite cement carbon and oxygen isotopes. The lithology of the calcareous insulating layers in the study area is mainly composed of the terrigenous clastic bioclastic limestone and a small amount of fine-grained calcareous sandstone. On this basis, two genetic models of calcareous insulating layers are established, including the evaporation seawater genetic model and shallow burial meteoric water genetic model. The calcareous insulating layers of the evaporation seawater genetic model developed in the foreshore subfacies, mainly at the top of the 1-1 strata and 1-3 strata. The calcareous insulating layers of the shallow burial meteoric water genetic model developed in the backshore subfacies, primarily in the 1-2 strata.展开更多
Comparative studies of four common-used anode gas diffusion layers(A-GDLs),namely carbon cloth,carbon paper,carbon paper based on XC-72(in short XC-72)and GDL made of carbon nanotubes(CNT)for direct methanol fuel cell...Comparative studies of four common-used anode gas diffusion layers(A-GDLs),namely carbon cloth,carbon paper,carbon paper based on XC-72(in short XC-72)and GDL made of carbon nanotubes(CNT)for direct methanol fuel cells(DMFCs)were carried out and discussed.The results of scanning electron microscope(SEM),mercury intrusion porosimeter(MIP)and electrochemical test show that CNT has large pore size distribution in pore size of 1000-3000nm and the largest total porosity compared with those of the other three.Carbon paper and XC-72show disadvantageous influences on cell performances at high current density,because carbon paper has many large pores which are unsuited for water transport,while XC-72has many small pores which are unsuited for gas transport.Though cell with carbon cloth has the highest methanol diffusion coefficient,it shows a little lower performance than that with CNT due to its thickness.Anode polarization(AP)results also display that the cell with CNT has the least methanol mass transfer resistance.As a result,the cell with CNT shows the best performance with the highest limiting current density and peak power density of 460 mA·cm^(-2)and 110mW·cm^(-2),respectively.展开更多
Infrared transmission and photoconductivity spectra of mercury cadmium telluride (MCT) epitaxial layers, grown by liquid phase epitaxy (LPE) on CdTe and CdZnTe wide band gap substrates, were investigated both theoreti...Infrared transmission and photoconductivity spectra of mercury cadmium telluride (MCT) epitaxial layers, grown by liquid phase epitaxy (LPE) on CdTe and CdZnTe wide band gap substrates, were investigated both theoretically and experimentally at temperatures T =82 K and T =300 K in the infrared (IR) wavelength region 3 15 μm. The photoresponse position of the diodes was determined at cryogenic temperatures from the transmission spectra of room temperature. Theoretical calculations of optical density D(h-ω), needed for analysis of experimental optical transmission data, were performed in the framework of WKB approximation.展开更多
Kinematic models compute the temperature distribution by prescribing a constant convergent velocity for the subducting slab,resulting in an artificial velocity discontinuity,which may accelerate the heating of subduct...Kinematic models compute the temperature distribution by prescribing a constant convergent velocity for the subducting slab,resulting in an artificial velocity discontinuity,which may accelerate the heating of subducting slabs.For the purpose to moderate the influence of such artificial discontinuity, we construct a 2D thermal model for subduction zones with a velocity boundary layer,within which the velocities decrease linearly with the distance from the interfaces of slabs.Temperatures are calculated展开更多
Daidzein is always added into poultry feed to make the production performance and immunity of poultry better. In this study, a total of 600 40-week-old Hy-Line variety brown layers were randomized into five groups and...Daidzein is always added into poultry feed to make the production performance and immunity of poultry better. In this study, a total of 600 40-week-old Hy-Line variety brown layers were randomized into five groups and fed with a corn-soybean-mixed basal diet supplement with 0, 10, 50, 100, and 500 mg · kg^-1 daidzein, respectively. Then, two PCR-based typing methods（RAPD-PCR and ERIC-PCR） were combined to analyze the ileum content and explore the changes of ileum microflora biodiversity. The results of RAPD-PCR and ERIC-PCR showed that bands under 10 mg · kg^-1 and 50 mg · kg^-1 were the most, and their similarity was the largest. Bands under 500 mg · kg^-1 were the least and similarity with other groups was the minimum. Ileum microflora biodiversity under 10 mg · kg^-1 or 50 mg · kg^-1 was richer than that under 500 mg · kg^-1. A corn-soybean-mixed basal diet supplement with 10 mg · kg^-1 to 50 mg · kg^-1 of daidzein might be beneficial to Hy-Line variety brown layers intestinal bacteria.展开更多
Polycrystalline diamond films have been synthesized on various substrates by hot filament CVD from the mixture gases of methane and hydrogen. The interface layers between CVD diamond films and substrates have been inv...Polycrystalline diamond films have been synthesized on various substrates by hot filament CVD from the mixture gases of methane and hydrogen. The interface layers between CVD diamond films and substrates have been investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, visible luminescence between 2.0～3.5eV of undoped and boron-doped CVD diamond films has also been studied by cathodoluminescence.展开更多
The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,w...The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,we have designed LiNi_(0.8)Co_(0.1)Mn 0.1 O_(2)cathodes modified by Nb/Al co-doping and LiNbO_(3)/LiAlO_(2)composite coating.Detailed characterization reveals that Nb/Al co-doping can stabilize the crystal structure of the cathodes and expand the layer spacing of the layered lattice,thereby increasing the diffusion rate and reversibility of Li^(+).And the composite coatings can improve the electrochemical kinetic and inhibit the erosion of acidic substances by hindering direct contact between the cathodes and electrolyte.As a result,the Ni-rich cathodes with dual modification can still exhibit a higher capacity of 184.02 mA·h/g after 100 cycles with a capacity retention of up to 98.1%,and can still release a capacity of 161.6 mA·h/g at a high rate of 7 C,meanwhile,it shows excellent thermal stability compared to bare NCM.This work provides a new perspective for enhancing electrochemical properties of cathodes through integrated strategies.展开更多
基金Supported by the National Natural Science Foundation of China(62074085,62104118)。
文摘Hexagonal boron nitride(h-BN)is found to have widespread application,owing to its outstanding properties,including gate dielectrics,passivation layers,and tunneling layers.The current studies on the funda⁃mental physical properties of these ultrathin h-BN films and the electron tunneling effect among them are inade⁃quate.In this work,the effective mass in h-BN was successfully determined through a combined approach of ex⁃perimental and theoretical research methods by fitting the current-voltage curves of metal/insulator/metal struc⁃tures.It was observed that within a range of 4-22 layers,the effective mass of h-BN exhibits a monotonic de⁃crease with an increase in the number of layers.The physical parameters of the Fowler-Nordheim tunneling model in the context of electron tunneling in h-BN are precisely ascertained by utilizing the extracted effective mass.Ad⁃ditionally,the impact of fixed charges at the metal/h-BN interface and various metal electrode types on FowlerNordheim tunneling within this structure is investigated utilizing this physical parameter in Sentaurus TCAD soft⁃ware.This work is informative and instructive in promoting applications in the fields of h-BN related infrared physics and technology.
文摘The nitrogen (N) metabolic experiments were made to estimate separately amino acid requirements of 4348 weeks old layers for maintenance, for protein accretion to estabolish models to estimate digestible amino acid requirements. The regression relationship of nitrogen retention vs amino acid intake was estimated for each amino acid by giving, at rate of N intake of 091, 052, 015 and 0007gkg-1 body-weight (W075) per d, the semi-synthetic diets was made specially deficient in one amino acid. From the regression coefficients, it was calculated that, for the accretion of 1 g protein, the dietary digestible amino acid requirements were (mg) Thr 631, Val 1004, Met 399, Ile 886, Leu 1143, Phe 632, Lys 870, His 205, Arg 879, Trp 214, Met+Cys 776, and Phe+Tyr 1143. Daily amino acid requirements for N equilibrium were estimated to be (mgkg-1W075 per day) Thr 506, Val 747, Met 303, ILe 667 Leu 814, Phe 448, Lys 605 His 147, Arg 739 ,Trp 173, Met+Cys 586, and Phe+Tyr 839 The dietary degestible amino acid patterns for protein accretion and N equilibrium were also proposed. The models of estimating digestible amino acid requirements for the different productions were developed.
文摘An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.
基金Project(52271013)supported by the National Natural Science Foundation of ChinaProject(23DZ1200600)supported by the Science and Technology Innovation Action Plan of Shanghai,China。
文摘As the proton transport channel and binder within the catalytic layer(CL),the physicochemical properties of the ionomer can affect the CL microstructure and performance of the membrane electrode assembly.In this paper,we select ionomers with different side-chain lengths and investigate the effects of the side-chain structure and content of the ionomers on the performance of membrane electrode assembly(MEA).Electrochemical tests show that at a mass ratio of 10 wt.%of ionomer/Ir(I/Ir),long-side-chain(LSC)ionomer exhibits the best performance(2.141 V@2.00 A/cm^(2),while short-side-chain(SSC)ionomer is 2.208 V@2.00 A/cm^(2)).The MEA containing LSC ionomer shows better electrochemical performance than the SSC at the same I/Ir mass ratio,especially at high current density.The MEA containing LSC ionomer has a larger average pore size and porosity,which indicates that it may have better mass-transfer properties.From the analysis of voltage loss,it can be seen that LSC ionomers have a smaller ohmic impedance and mass transfer resistance than SSC ionomers.In conclusion,LSC ionomers are more conducive to water-gas transport,which can provide excellent water electrolysis performance.This article focuses on the optimization of ionomer side chains and content,which can enhance PEM water electrolysis performance at lower cost.
文摘Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technological Research Council of Turkey(TÜB˙ITAK)for receiving financial support for this work through the 2221 Fellowship Program for Visiting Scientists and Scientists on Sabbatical Leave(Grant ID:E 21514107-115.02-228864).Sasan YAZDANI also expresses his gratitude to Sahand University of Technology for granting him sabbatical leave to facilitate the completion of this research.
文摘A 31 week feeding trial was conducted to investigated the effects of dietary supplementation of microbial phytase and cellulase on performance,nutrients utilization and tibia quality of laying hens fed maize and soybean meal diets.192 18 week old Hisex layers were used in the trial A 2×2×2 factorial design was used in the experiment with three factors of two levels each:0 38% and 0 16% of dietary non phytate P(nP).0 and 300 U·kg -1 of phytase (Ph),and 0 and 0 10% of cellulase (Ce).The results showed that supplementation of 300 U·kg -1 phytase significantly improved utilization of dietary crude ash,CP,Ca,total P and copper (P<0 05),and improved tibia breaking strength (P<0 05).No effect of phytase on performance was observed.Addition of 0 10% cellulase decreased feed intake (P<0 05),increased utilization of CF (P<0 05) and Ca(P<0 01),and decreased total tibia ash weight (P<0 05).300 U·kg -1 phytase and 0 10% cellulase exhibited obvious positive interactions to enhance utilization of dietary phytic P and copper (P<0 05).0 16% nP did not reduce performance of the layers,but improved egg shell quality at 20 wks,increased utilization of dietary total P,phytic P and Copper (P<0 01),decreased utilization of dietary CP,increased tibia breaking strength and Ca,Mn contents of tibia(P<0 01)
基金support he received through General Research Project under the grant number (R.G.P.2/138/42)。
文摘A numerical analysis of the log-law behavior for the turbulent boundary layer of a wall-bounded flow is performed over a flat plate immersed in three nanofluids(Zn O-water,SiO_(2)-water,TiO_(2)-water).Numerical simulations using CFD code are employed to investigate the boundary layer and the hydrodynamic flow.To validate the current numerical model,measurement points from published works were used,and the compared results were in good compliance.Simulations were carried out for the velocity series of 0.04,0.4 and 4 m/s and nanoparticle concentrations0.1% and 5%.The influence of nanoparticles’ concentration on velocity,temperature profiles,wall shear stress,and turbulent intensity was investigated.The obtained results showed that the viscous sub-layer,the buffer layer,and the loglaw layer along the potential-flow layer could be analyzed based on their curving quality in the regions which have just a single wall distance.It was seen that the viscous sub-layer is the biggest area in comparison with other areas.Alternatively,the section where the temperature changes considerably correspond to the thermal boundary layer’s thickness goes a downward trend when the velocity decreases.The thermal boundary layer gets deep away from the leading edge.However,a rise in the volume fraction of nanoparticles indicated a minor impact on the shear stress developed in the wall.In all cases,the thickness of the boundary layer undergoes a downward trend as the velocity increases,whereas increasing the nanoparticle concentrations would enhance the thickness.More precisely,the log layer is closed with log law,and it is minimal between Y^(+)=50 and Y^(+)=95.The temperature for nanoparticle concentration φ=5%is higher than that for φ=0.1%,in boundary layers,for all studied nanofluids.However,it is established that the behavior is inverted from the value of Y^(+)=1 and the temperature for φ =0.1% is more important than the case of φ =5%.For turbulence intensity peak,this peak exists at Y^(+)=100 for v=4 m/s,Y^(+)=10 for v=0.4 m/s and Y^(+)=8 for v=0.04 m/s.
基金Project(51534006)supported by the Key Program of National Natural Science Foundation of ChinaProject(2014CB239005)supported by the National Key Basic Research and Development,ChinaProjects(41772150,51674211)supported by the National Natural Science Foundation of China。
文摘We have systematically investigated the feature, genetic model and distribution of calcareous insulating layers in marine strata of the Ⅰ oil group in member 2 of Zhujiang formation(ZJ2I oil formation), western Pearl River Mouth basin(PRMB) in the north of the South China Sea by using data such as cores, thin sections, X-ray diffraction of whole-rock, and calcite cement carbon and oxygen isotopes. The lithology of the calcareous insulating layers in the study area is mainly composed of the terrigenous clastic bioclastic limestone and a small amount of fine-grained calcareous sandstone. On this basis, two genetic models of calcareous insulating layers are established, including the evaporation seawater genetic model and shallow burial meteoric water genetic model. The calcareous insulating layers of the evaporation seawater genetic model developed in the foreshore subfacies, mainly at the top of the 1-1 strata and 1-3 strata. The calcareous insulating layers of the shallow burial meteoric water genetic model developed in the backshore subfacies, primarily in the 1-2 strata.
文摘Comparative studies of four common-used anode gas diffusion layers(A-GDLs),namely carbon cloth,carbon paper,carbon paper based on XC-72(in short XC-72)and GDL made of carbon nanotubes(CNT)for direct methanol fuel cells(DMFCs)were carried out and discussed.The results of scanning electron microscope(SEM),mercury intrusion porosimeter(MIP)and electrochemical test show that CNT has large pore size distribution in pore size of 1000-3000nm and the largest total porosity compared with those of the other three.Carbon paper and XC-72show disadvantageous influences on cell performances at high current density,because carbon paper has many large pores which are unsuited for water transport,while XC-72has many small pores which are unsuited for gas transport.Though cell with carbon cloth has the highest methanol diffusion coefficient,it shows a little lower performance than that with CNT due to its thickness.Anode polarization(AP)results also display that the cell with CNT has the least methanol mass transfer resistance.As a result,the cell with CNT shows the best performance with the highest limiting current density and peak power density of 460 mA·cm^(-2)and 110mW·cm^(-2),respectively.
文摘Infrared transmission and photoconductivity spectra of mercury cadmium telluride (MCT) epitaxial layers, grown by liquid phase epitaxy (LPE) on CdTe and CdZnTe wide band gap substrates, were investigated both theoretically and experimentally at temperatures T =82 K and T =300 K in the infrared (IR) wavelength region 3 15 μm. The photoresponse position of the diodes was determined at cryogenic temperatures from the transmission spectra of room temperature. Theoretical calculations of optical density D(h-ω), needed for analysis of experimental optical transmission data, were performed in the framework of WKB approximation.
文摘Kinematic models compute the temperature distribution by prescribing a constant convergent velocity for the subducting slab,resulting in an artificial velocity discontinuity,which may accelerate the heating of subducting slabs.For the purpose to moderate the influence of such artificial discontinuity, we construct a 2D thermal model for subduction zones with a velocity boundary layer,within which the velocities decrease linearly with the distance from the interfaces of slabs.Temperatures are calculated
基金Supported by the Science&Technology Department of Sichuan Province(2013FZ0014)the Construction Project of Postgraduate Academic Degree in Southwest University for Nationalities(2014XWD-S071007)the National Training Plan of Excellent Agricultural and Forestal Talents(2014)
文摘Daidzein is always added into poultry feed to make the production performance and immunity of poultry better. In this study, a total of 600 40-week-old Hy-Line variety brown layers were randomized into five groups and fed with a corn-soybean-mixed basal diet supplement with 0, 10, 50, 100, and 500 mg · kg^-1 daidzein, respectively. Then, two PCR-based typing methods（RAPD-PCR and ERIC-PCR） were combined to analyze the ileum content and explore the changes of ileum microflora biodiversity. The results of RAPD-PCR and ERIC-PCR showed that bands under 10 mg · kg^-1 and 50 mg · kg^-1 were the most, and their similarity was the largest. Bands under 500 mg · kg^-1 were the least and similarity with other groups was the minimum. Ileum microflora biodiversity under 10 mg · kg^-1 or 50 mg · kg^-1 was richer than that under 500 mg · kg^-1. A corn-soybean-mixed basal diet supplement with 10 mg · kg^-1 to 50 mg · kg^-1 of daidzein might be beneficial to Hy-Line variety brown layers intestinal bacteria.
基金This work is supported by the National Natural Science Foundation of China.
文摘Polycrystalline diamond films have been synthesized on various substrates by hot filament CVD from the mixture gases of methane and hydrogen. The interface layers between CVD diamond films and substrates have been investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, visible luminescence between 2.0～3.5eV of undoped and boron-doped CVD diamond films has also been studied by cathodoluminescence.
基金Project(2023JJ40759)supported by the Natural Science Foundation of Hunan Province,China。
文摘The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,we have designed LiNi_(0.8)Co_(0.1)Mn 0.1 O_(2)cathodes modified by Nb/Al co-doping and LiNbO_(3)/LiAlO_(2)composite coating.Detailed characterization reveals that Nb/Al co-doping can stabilize the crystal structure of the cathodes and expand the layer spacing of the layered lattice,thereby increasing the diffusion rate and reversibility of Li^(+).And the composite coatings can improve the electrochemical kinetic and inhibit the erosion of acidic substances by hindering direct contact between the cathodes and electrolyte.As a result,the Ni-rich cathodes with dual modification can still exhibit a higher capacity of 184.02 mA·h/g after 100 cycles with a capacity retention of up to 98.1%,and can still release a capacity of 161.6 mA·h/g at a high rate of 7 C,meanwhile,it shows excellent thermal stability compared to bare NCM.This work provides a new perspective for enhancing electrochemical properties of cathodes through integrated strategies.
