The redox active species in all-vanadium redox flow batteries(VRFBs)reside in the electrolyte,while the heterogeneous reactions occur on the electrode surface;the electrode is therefore the decisive platform for dynam...The redox active species in all-vanadium redox flow batteries(VRFBs)reside in the electrolyte,while the heterogeneous reactions occur on the electrode surface;the electrode is therefore the decisive platform for dynamic adsorption,electron transfer,and ion conversion,especially for the VO^(2+)/VO_(2)^(+)and V^(2+)/V^(3+)couples.One of the major challenges for VRFBs is the slow charge transfer in VO^(2+)/VO_(2)^(+)and V^(2+)/V^(3+)reactions,mainly caused by poor catalytic performance of electrodes and weak adhesion of catalysts to electrodes.This review focuses on the key challenges and recent advancements in VRFBs.It begins with an overview of VRFBs,including their history,working principles,applications,and the advantages and limitations associated with their use.One persistent,under-addressed trade-off is that strategies that boost apparent activity(e.g.,high defect density or surface area)can degrade adhesion and cycling durability under flow shear;activity should therefore be co-reported with adhesion and durability descriptors.Addressing this trade-off is critical to improving overall efficiency and stability in VRFBs systems.A comprehensive discussion of various electrode materials is presented,categorized by their properties and preparation methods.Special emphasis is placed on the synthesis and application of carbon-based electrode materials,highlighting their potential in addressing these challenges.Finally,we map materials-level gains to stack-and system-level metrics,and outline strategies,with a focus on bifunctional and in-situ grown catalysts,for achieving high-efficiency,high-stability VRFBs.展开更多
Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of va...Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.展开更多
The muzzle blast overpressure induces disturbances in the flow field inside the crew compartment(FFICC)of a truck-mounted howitzer during the artillery firing.This overpressure is the primary factor preventing personn...The muzzle blast overpressure induces disturbances in the flow field inside the crew compartment(FFICC)of a truck-mounted howitzer during the artillery firing.This overpressure is the primary factor preventing personnel from firing artillery within the cab.To investigate the overpressure characteristics of the FFICC,a foreign trade equipment model was used as the research object,and a numerical model was established to analyze the propagation of muzzle blast from the muzzle to the interior of the crew compartment under extreme firing condition.For comparative verification,the muzzle blast experiment included overpressure data from both the flow field outside the crew compartment(FFOCC)and the FFICC,as well as the acceleration data of the crew compartment structure(Str-CC).The research findings demonstrate that the overpressure-time curves of the FFICC exhibit multi-peak characteristics,while the pressure wave shows no significant discontinuity.The enclosed nature of the cab hinders the dissipation of pressure wave energy within the FFICC,leading to sustained high-amplitude overpressure.The frameskin structure helps attenuate the impact of muzzle blast on the FFICC.Conversely,local high overpressure caused by the convex or concave features of the cab's exterior significantly amplifies the overpressure amplitude within the FFICC.展开更多
This study introduces a novel flow-through cowcatcher with integrated inlet and outlet channels as an aerodynamic noise mitigation strategy for the nose car of a high-speed train.The wall-adapting local eddy-viscosity...This study introduces a novel flow-through cowcatcher with integrated inlet and outlet channels as an aerodynamic noise mitigation strategy for the nose car of a high-speed train.The wall-adapting local eddy-viscosity large eddy simulation(WALE-LES)combined with the Ffowcs Williams-Hawkings(FW-H)acoustic analogy approach is employed to evaluate its impact on the aerodynamic and aeroacoustic characteristics of the leading bogie region.Compared with the conventional closed cowcatcher,results show that the flow-through structure suppresses the flow separation,promotes more stable vortex evolution within the bogie cavity,and reduces the spatial extent of high amplitude wall pressure fluctuations up to 40%,mitigating effectively the generation of aerodynamic noise.Semi anechoic wind tunnel experiments validate the simulation results and demonstrate that the sound pressure levels at the far field observers decrease by 0.4-0.6 dB(A)with the flow-through cowcatcher applied underneath the nose car.The dominant sound source around the leading bogie region is shrunk with intensity reduced about 1.0 dB(A).These findings confirm the effectiveness of the flow-through cowcatcher in reducing the aerodynamic noise produced from the leading bogie region,providing both theoretical insight and engineering guidance for structural optimization and low-noise design of the nose car in a high-speed train.展开更多
Redox flow batteries have gained wide attention at home and abroad as a long-duration energy storage technology with the advantages of high safety,long lifespan,mutual independence of capacity and power,and easy recyc...Redox flow batteries have gained wide attention at home and abroad as a long-duration energy storage technology with the advantages of high safety,long lifespan,mutual independence of capacity and power,and easy recycling.However,the current battery management technology faces significant challenges,and there is room for development.Digital twin(DT),as a technology that collectively senses,evaluates,predicts,and optimizes characteristics,is promising to contribute to redox flow batteries’operation,maintenance,and management.This paper begins with a brief description of redox flow batteries,followed by a short explanation of the concept and application of DTs.DTs have already made some progress in the field of batteries,and can be applied to solve the problems of redox flow batteries in terms of thermal management and system optimization.Finally,the paper analyzes the combination of redox flow battery and DT architecture,which is expected to contribute to developing DT technology for redox flow batteries.展开更多
Due to the complex high-temperature characteristics of hydrocarbon fuel,the research on the long-term working process of parallel channel structure under variable working conditions,especially under high heat-mass rat...Due to the complex high-temperature characteristics of hydrocarbon fuel,the research on the long-term working process of parallel channel structure under variable working conditions,especially under high heat-mass ratio,has not been systematically carried out.In this paper,the heat transfer and flow characteristics of related high temperature fuels are studied by using typical engine parallel channel structure.Through numeri⁃cal simulation and systematic experimental verification,the flow and heat transfer characteristics of parallel chan⁃nels under typical working conditions are obtained,and the effectiveness of high-precision calculation method is preliminarily established.It is known that the stable time required for hot start of regenerative cooling engine is about 50 s,and the flow resistance of parallel channel structure first increases and then decreases with the in⁃crease of equivalence ratio(The following equivalence ratio is expressed byΦ),and there is a flow resistance peak in the range ofΦ=0.5~0.8.This is mainly caused by the coupling effect of high temperature physical proper⁃ties,flow rate and pressure of fuel in parallel channels.At the same time,the cooling and heat transfer character⁃istics of parallel channels under some conditions of high heat-mass ratio are obtained,and the main factors affect⁃ing the heat transfer of parallel channels such as improving surface roughness and strengthening heat transfer are mastered.In the experiment,whenΦis less than 0.9,the phenomenon of local heat transfer enhancement and deterioration can be obviously observed,and the temperature rise of local structures exceeds 200℃,which is the risk of structural damage.Therefore,the reliability of long-term parallel channel structure under the condition of high heat-mass ratio should be fully considered in structural design.展开更多
A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the ph...A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.展开更多
基金National Natural Science Foundation of China(NSFC)under Grant No.22269011 and Lanzhou Science and Technology Bureau(2025-2-50)。
文摘The redox active species in all-vanadium redox flow batteries(VRFBs)reside in the electrolyte,while the heterogeneous reactions occur on the electrode surface;the electrode is therefore the decisive platform for dynamic adsorption,electron transfer,and ion conversion,especially for the VO^(2+)/VO_(2)^(+)and V^(2+)/V^(3+)couples.One of the major challenges for VRFBs is the slow charge transfer in VO^(2+)/VO_(2)^(+)and V^(2+)/V^(3+)reactions,mainly caused by poor catalytic performance of electrodes and weak adhesion of catalysts to electrodes.This review focuses on the key challenges and recent advancements in VRFBs.It begins with an overview of VRFBs,including their history,working principles,applications,and the advantages and limitations associated with their use.One persistent,under-addressed trade-off is that strategies that boost apparent activity(e.g.,high defect density or surface area)can degrade adhesion and cycling durability under flow shear;activity should therefore be co-reported with adhesion and durability descriptors.Addressing this trade-off is critical to improving overall efficiency and stability in VRFBs systems.A comprehensive discussion of various electrode materials is presented,categorized by their properties and preparation methods.Special emphasis is placed on the synthesis and application of carbon-based electrode materials,highlighting their potential in addressing these challenges.Finally,we map materials-level gains to stack-and system-level metrics,and outline strategies,with a focus on bifunctional and in-situ grown catalysts,for achieving high-efficiency,high-stability VRFBs.
基金supported by the University of Seoul’s 2025 Research Fund.
文摘Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.
基金supported by the National Natural Science Foundation of China(Grant No.U2341269)。
文摘The muzzle blast overpressure induces disturbances in the flow field inside the crew compartment(FFICC)of a truck-mounted howitzer during the artillery firing.This overpressure is the primary factor preventing personnel from firing artillery within the cab.To investigate the overpressure characteristics of the FFICC,a foreign trade equipment model was used as the research object,and a numerical model was established to analyze the propagation of muzzle blast from the muzzle to the interior of the crew compartment under extreme firing condition.For comparative verification,the muzzle blast experiment included overpressure data from both the flow field outside the crew compartment(FFOCC)and the FFICC,as well as the acceleration data of the crew compartment structure(Str-CC).The research findings demonstrate that the overpressure-time curves of the FFICC exhibit multi-peak characteristics,while the pressure wave shows no significant discontinuity.The enclosed nature of the cab hinders the dissipation of pressure wave energy within the FFICC,leading to sustained high-amplitude overpressure.The frameskin structure helps attenuate the impact of muzzle blast on the FFICC.Conversely,local high overpressure caused by the convex or concave features of the cab's exterior significantly amplifies the overpressure amplitude within the FFICC.
基金Projects(51875411,52232013)supported by the National Natural Science Foundation of ChinaProject(19DZ2290400)supported by the Shanghai Professional Technical Service Platform Program,China。
文摘This study introduces a novel flow-through cowcatcher with integrated inlet and outlet channels as an aerodynamic noise mitigation strategy for the nose car of a high-speed train.The wall-adapting local eddy-viscosity large eddy simulation(WALE-LES)combined with the Ffowcs Williams-Hawkings(FW-H)acoustic analogy approach is employed to evaluate its impact on the aerodynamic and aeroacoustic characteristics of the leading bogie region.Compared with the conventional closed cowcatcher,results show that the flow-through structure suppresses the flow separation,promotes more stable vortex evolution within the bogie cavity,and reduces the spatial extent of high amplitude wall pressure fluctuations up to 40%,mitigating effectively the generation of aerodynamic noise.Semi anechoic wind tunnel experiments validate the simulation results and demonstrate that the sound pressure levels at the far field observers decrease by 0.4-0.6 dB(A)with the flow-through cowcatcher applied underneath the nose car.The dominant sound source around the leading bogie region is shrunk with intensity reduced about 1.0 dB(A).These findings confirm the effectiveness of the flow-through cowcatcher in reducing the aerodynamic noise produced from the leading bogie region,providing both theoretical insight and engineering guidance for structural optimization and low-noise design of the nose car in a high-speed train.
基金Supported by the Special Educating Project of the Talent for Carbon Peak and Carbon Neutrality of University of Chinese Academy of Sciences(E3E56501A2)。
文摘Redox flow batteries have gained wide attention at home and abroad as a long-duration energy storage technology with the advantages of high safety,long lifespan,mutual independence of capacity and power,and easy recycling.However,the current battery management technology faces significant challenges,and there is room for development.Digital twin(DT),as a technology that collectively senses,evaluates,predicts,and optimizes characteristics,is promising to contribute to redox flow batteries’operation,maintenance,and management.This paper begins with a brief description of redox flow batteries,followed by a short explanation of the concept and application of DTs.DTs have already made some progress in the field of batteries,and can be applied to solve the problems of redox flow batteries in terms of thermal management and system optimization.Finally,the paper analyzes the combination of redox flow battery and DT architecture,which is expected to contribute to developing DT technology for redox flow batteries.
文摘Due to the complex high-temperature characteristics of hydrocarbon fuel,the research on the long-term working process of parallel channel structure under variable working conditions,especially under high heat-mass ratio,has not been systematically carried out.In this paper,the heat transfer and flow characteristics of related high temperature fuels are studied by using typical engine parallel channel structure.Through numeri⁃cal simulation and systematic experimental verification,the flow and heat transfer characteristics of parallel chan⁃nels under typical working conditions are obtained,and the effectiveness of high-precision calculation method is preliminarily established.It is known that the stable time required for hot start of regenerative cooling engine is about 50 s,and the flow resistance of parallel channel structure first increases and then decreases with the in⁃crease of equivalence ratio(The following equivalence ratio is expressed byΦ),and there is a flow resistance peak in the range ofΦ=0.5~0.8.This is mainly caused by the coupling effect of high temperature physical proper⁃ties,flow rate and pressure of fuel in parallel channels.At the same time,the cooling and heat transfer character⁃istics of parallel channels under some conditions of high heat-mass ratio are obtained,and the main factors affect⁃ing the heat transfer of parallel channels such as improving surface roughness and strengthening heat transfer are mastered.In the experiment,whenΦis less than 0.9,the phenomenon of local heat transfer enhancement and deterioration can be obviously observed,and the temperature rise of local structures exceeds 200℃,which is the risk of structural damage.Therefore,the reliability of long-term parallel channel structure under the condition of high heat-mass ratio should be fully considered in structural design.
基金supported by the National Key R&D Program of China(2021YFF0500703)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.
