Carbon nanotubes were modified by FeSO 4 - H 2 O 2 system,iron hydroxides were adsorbed on the wall of carbon nanotubes simulta neously.These precursors were treated at723K for2h under hydrogen,nitrogen and a ir atmo ...Carbon nanotubes were modified by FeSO 4 - H 2 O 2 system,iron hydroxides were adsorbed on the wall of carbon nanotubes simulta neously.These precursors were treated at723K for2h under hydrogen,nitrogen and a ir atmo - sphere to prepare carbon nanotubes supported γ- Fe 2 O 3 catalyst,γ- Fe 2 O 3 and α- Fe 2 O 3 compound catalyst and amorphous Fe 2 O 3 catalyst,respectively.This is green method to prepare high Fe 2 O 3 loading( ≥ 50%)abstract:catalyst without adding other cation.The different structures Fe 2 O 3 catalysts can be synthesized by controlling the condi - tion of thermal treatment to content active phase requirements for different catalytic reactions.The paper presents a new method to prepare carbon nanotubes supported catalysts.展开更多
Fe3O4 catalyst supported on spherical γ-Al2O3 was prepared with and without ultrasonic treatment during the impregnation step,and the heterogeneous catalytic oxidation of dimethoate wastewater was conducted with Fent...Fe3O4 catalyst supported on spherical γ-Al2O3 was prepared with and without ultrasonic treatment during the impregnation step,and the heterogeneous catalytic oxidation of dimethoate wastewater was conducted with Fenton reagent.Then,the physical and chemical properties of the catalysts were analyzed by means of XRD,ICP-AES and SEM,especially the effect of Fe3O4 dispersity on γ-Al2O3.The results showed that the activity of the supported catalysts prepared with ultrasonic treatment for dimethoate was higher than those without ultrasonic treatment and the corresponding degradation rate doubled those of the catalyst obtained by impregnation.The probable cause was that for catalysts prepared with ultrasonic treatment,Fe3O4 was well dispersed on the catalyst surface with small particle size,or existed in non-crystalline amorphous state,and Fe content on the catalyst surface was higher than those without ultrasonic treatment.展开更多
基金The project was supported by the National Natural Science Foundation of China(21173153)Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education,China(LYY1101)~~
文摘Carbon nanotubes were modified by FeSO 4 - H 2 O 2 system,iron hydroxides were adsorbed on the wall of carbon nanotubes simulta neously.These precursors were treated at723K for2h under hydrogen,nitrogen and a ir atmo - sphere to prepare carbon nanotubes supported γ- Fe 2 O 3 catalyst,γ- Fe 2 O 3 and α- Fe 2 O 3 compound catalyst and amorphous Fe 2 O 3 catalyst,respectively.This is green method to prepare high Fe 2 O 3 loading( ≥ 50%)abstract:catalyst without adding other cation.The different structures Fe 2 O 3 catalysts can be synthesized by controlling the condi - tion of thermal treatment to content active phase requirements for different catalytic reactions.The paper presents a new method to prepare carbon nanotubes supported catalysts.
文摘Fe3O4 catalyst supported on spherical γ-Al2O3 was prepared with and without ultrasonic treatment during the impregnation step,and the heterogeneous catalytic oxidation of dimethoate wastewater was conducted with Fenton reagent.Then,the physical and chemical properties of the catalysts were analyzed by means of XRD,ICP-AES and SEM,especially the effect of Fe3O4 dispersity on γ-Al2O3.The results showed that the activity of the supported catalysts prepared with ultrasonic treatment for dimethoate was higher than those without ultrasonic treatment and the corresponding degradation rate doubled those of the catalyst obtained by impregnation.The probable cause was that for catalysts prepared with ultrasonic treatment,Fe3O4 was well dispersed on the catalyst surface with small particle size,or existed in non-crystalline amorphous state,and Fe content on the catalyst surface was higher than those without ultrasonic treatment.
