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Flatness detection method of splicing detector based on channel spectral dispersion
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作者 ZHAO Hong-chao ZHANG Xiao-qian AN Qi-chang 《中国光学(中英文)》 北大核心 2025年第4期889-898,共10页
For segmented detectors,surface flatness is critical as it directly influences both energy resolution and image clarity.Additionally,the limited adjustment range of the segmented detectors necessitates precise benchma... For segmented detectors,surface flatness is critical as it directly influences both energy resolution and image clarity.Additionally,the limited adjustment range of the segmented detectors necessitates precise benchmark construction.This paper proposes an architecture for detecting detector flatness based on channel spectral dispersion.By measuring the dispersion fringes for coplanar adjustment,the final adjustment residual is improved to better than 300 nm.This result validates the feasibility of the proposed technology and provides significant technical support for the development of next-generation large-aperture sky survey equipment. 展开更多
关键词 large aperture telescope segmented detector surface wavefront detection channel spectral dispersion
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Positive role of regulator in desulfurization of chalcopyrite in seawater based on chelation and dispersion
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作者 SONG Ning-bo YIN Wan-zhong +1 位作者 GONG Xiu-feng YAO Jin 《Journal of Central South University》 2025年第5期1791-1801,共11页
The chemical composition of seawater affects the desulfurization of chalcopyrite in flotation.In this study,desulfurization experiments of chalcopyrite were conducted in both deionized(DI)water and seawater.The result... The chemical composition of seawater affects the desulfurization of chalcopyrite in flotation.In this study,desulfurization experiments of chalcopyrite were conducted in both deionized(DI)water and seawater.The results showed that,the copper grade of the concentrate obtained from seawater flotation decreased to 24.30%,compared to 24.60%in DI water.Concurrently,the recovery of chalcopyrite decreased from 51.39%to 38.67%,while the selectivity index(SI)also had a reduction from 2.006 to 1.798.The incorporation of ethylene diamine tetraacetic acid(EDTA),sodium silicate(SS),and sodium hexametaphosphate(SHMP)yielded an enhancement in the SI value,elevating it from 1.798 to 1.897,2.250 and 2.153,separately.It is particularly noteworthy that an excess of EDTA resulted in a SI value of merely 1.831.The mechanism of action was elucidated through analysis of surface charge measurements,X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FT-IR),extended Derjaguin-Landau Verwey-Overbeek(E-DLVO)theory,and density functional theory(DFT)calculations. 展开更多
关键词 CHALCOPYRITE DESULFURIZATION CHELATION dispersion E-DLVO theory
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A cloud model target damage effectiveness assessment algorithm based on spatio-temporal sequence finite multilayer fragments dispersion
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作者 Hanshan Li Xiaoqian Zhang Junchai Gao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第10期48-64,共17页
To solve the problem of target damage assessment when fragments attack target under uncertain projectile and target intersection in an air defense intercept,this paper proposes a method for calculating target damage p... To solve the problem of target damage assessment when fragments attack target under uncertain projectile and target intersection in an air defense intercept,this paper proposes a method for calculating target damage probability leveraging spatio-temporal finite multilayer fragments distribution and the target damage assessment algorithm based on cloud model theory.Drawing on the spatial dispersion characteristics of fragments of projectile proximity explosion,we divide into a finite number of fragments distribution planes based on the time series in space,set up a fragment layer dispersion model grounded in the time series and intersection criterion for determining the effective penetration of each layer of fragments into the target.Building on the precondition that the multilayer fragments of the time series effectively assail the target,we also establish the damage criterion of the perforation and penetration damage and deduce the damage probability calculation model.Taking the damage probability of the fragment layer in the spatio-temporal sequence to the target as the input state variable,we introduce cloud model theory to research the target damage assessment method.Combining the equivalent simulation experiment,the scientific and rational nature of the proposed method were validated through quantitative calculations and comparative analysis. 展开更多
关键词 Target damage Cloud model Fragments dispersion Effectiveness assessment Spatio-temporal sequence
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Modeling and Simulation of Aerial Dispersion on Piston Dispersal Mechanism
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作者 陶如意 王浩 黄蓓 《Defence Technology(防务技术)》 SCIE EI CAS 2011年第4期197-203,共7页
For the aerial dispersing interior ballistic process and submunition exterior ballistic initial conditions of cluster munition with piston maximum travel limit, a novel model is established, and the numerical simulati... For the aerial dispersing interior ballistic process and submunition exterior ballistic initial conditions of cluster munition with piston maximum travel limit, a novel model is established, and the numerical simulation is performed. The piston maximum travel limit and the effect of reaction force on carrier body are researched using the internal ballistic model. Guide tube, cluster munition rotating and submunition assembly are analyzed using the submunition initial external ballistic model. The computational results are consistent with the practical process and the experimental data, and prove the rationality of this model. The theoretical methods are presented for the construction design and dispersion analysis of piston dispersal mechanism. 展开更多
关键词 launch and flight technology of aerocraft piston dispersion interior ballistics of aerial dispersion piston maximum travel assembly angle of submunition
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Experimental study on explosion dispersion process of a multi-layer composite charge under different initiation modes 被引量:7
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作者 Xiao-wen Hong Wei-bing Li +3 位作者 Wen-bin Li He-yang Xu Bo-liang Wang Wei Xiao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2020年第4期883-892,共10页
The influe nce of initiation modes on the explosive dispersion process of the multi-layer co mposite charge(MCC) was studied.Overpressure sensors and high-speed photography system were used to investigate the energy r... The influe nce of initiation modes on the explosive dispersion process of the multi-layer co mposite charge(MCC) was studied.Overpressure sensors and high-speed photography system were used to investigate the energy release process of an MCC with a specific structure.The shock wave pressure and explosive dispersion characteristics of the MCC under different initiation modes were compared.The forming and expanding process of the shock wave of the composite charge under different initiation modes was determined.The separation position of the shock wave and fireball interface was determined.The calculation formulas of the shock radius and overpressure of the composite charge are presented.The radius of the shock wave of the composite charge was significantly affected by the initiation mode.Moreover,the development process of the composite explosive fireball under different initiation modes was analyzed,the variation rules of the composite charge dispersion radius and fireball dispersion velocity with time were obtained under the different initiation modes,the explosion energy release rate of composite charge under simultaneous initiation modes was the highest,and the peak overpressure under the simultaneous initiation mode was 1.61 times that of central single-point initiation. 展开更多
关键词 Composite charge Initiation mode Blast wave OVERPRESSURE dispersion radius
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A novel signal feature extraction technology based on empirical wavelet transform and reverse dispersion entropy 被引量:4
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作者 Yu-xing Li Shang-bin Jiao Xiang Gao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第5期1625-1635,共11页
Feature extraction is an important part of signal processing,which is significant for signal detection,classification,and recognition.The nonlinear dynamic analysis method can extract the nonlinear characteristics of ... Feature extraction is an important part of signal processing,which is significant for signal detection,classification,and recognition.The nonlinear dynamic analysis method can extract the nonlinear characteristics of signals and is widely used in different fields.Reverse dispersion entropy(RDE)proposed by us recently,as a nonlinear dynamic analysis method,has the advantages of fast computing speed and strong anti-noise ability,which is more suitable for measuring the complexity of signal than traditional permutation entropy(PE)and dispersion entropy(DE).Empirical wavelet transform(EWT),based on the theory of wavelet analysis,can decompose a complex non-stationary signal into a number of empirical wavelet functions(EWFs)with compact support set spectrum,which has better decomposition performance than empirical mode decomposition(EMD)and its improved algorithms.Considering the advantages of RDE and EWT,on the one hand,we introduce EWT into the field of underwater acoustic signal processing and fault diagnosis to improve the signal decomposition accuracy;on the other hand,we use RDE as the features of EWFs to improve the signal separability and stability.Finally,we propose a novel signal feature extraction technology based on EWT and RDE in this paper.Experimental results show that the proposed feature extraction technology can effectively extract the complexity features of actual signals.Moreover,it also has higher distinguishing ability for different types of signals than five latest feature extraction technologies. 展开更多
关键词 Feature extraction Empirical mode decomposition Empirical wavelet transform Permutation entropy Reverse dispersion entropy
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Influence of polymer dispersants on dispersion stability of nano-TiO_2 aqueous suspension and its application in inner wall latex paint 被引量:3
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作者 彭兵 黄毅 +3 位作者 柴立元 李国良 程明明 张晓飞 《Journal of Central South University of Technology》 EI 2007年第4期490-495,共6页
The effects of SN5040 and polyethylene glycol(PEG) individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The ad... The effects of SN5040 and polyethylene glycol(PEG) individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The adsorption mechanism of these dispersants was detected by zeta potential, isothermal absorption and FTIR analysis. It is found that SN5040 is superior for stabilizing nano-TiO2 in aqueous suspension to PEG in basic region, and the optimum mass fraction of SN5040 addition is 3%. In the case of NaCl addition, the optimum value increases with .the increase of NaCl concentration in the solution. When the mixture of SN5040 and PEG is employed, the antagonism appears preponderant. When SN5040 and PEG are added sequentially, the synergistic reaction takes place. The synergistic reaction can be attributed to the mechanism that PEG adsorption decreases the electronic repulsion between SN5040 molecules, which results in the increase of SN5040 adsorption density. PEG is adsorbed by the interaction with the pre-adsorbed SN5040 layer. Furthermore, the modified inner wall latex paint with well dispersed nano-YiO2 suspension is endowed with excellent ultraviolet absorption and antibacterial properties. 展开更多
关键词 polymer dispersant dispersion stability NANO-TIO2 inner wall latex paint PEG adsorption
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Influence of nano-scaled dispersed second phase on substructure of deformed dispersion strengthened copper alloy 被引量:2
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作者 CHENG Jian-yi WANG Ming-pu CAO Jian-guo ZHAO Xue-long GUO Ming-xing 《Journal of Central South University of Technology》 2005年第z1期50-53,共4页
The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an ... The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an important influence on the dislocation substructure. The presence of fine dispersed Al2 O3 particles results in a uniform and random dislocation distribution in matrix copper and causes the difficulty in formation of dislocation cell structure and the decrease in the amount of cell structure during deformation. Deformation gives rise to much more dislocations and dislocation cells form more difficultly and the decrease in the cell size with the increase of dispersion degree. 展开更多
关键词 dispersed phase PARTICLE dispersion STRENGTHENED copper alloy DEFORMATION SUBSTRUCTURE
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Dispersion sensitivity analysis&consistency im provement of APFSDS 被引量:1
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作者 Sangeeta Sharma Panda L.K. Gite +3 位作者 A. Anandaraj R.S. Deodhar D.K. Joshi K.M. Rajan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2017年第4期316-322,共7页
The purpose of this study is to investigate and quantify some possible sources of dispersion of 120 mm APFSDS tank ammunition both experimentally and numerically.This paper aims to point out the most influential sourc... The purpose of this study is to investigate and quantify some possible sources of dispersion of 120 mm APFSDS tank ammunition both experimentally and numerically.This paper aims to point out the most influential source during In-Bore Balloting Motion phase as well as in External Ballistics phase of the ammunition and quantifies its effect on dispersion.Data obtained from flight trials is critically analysed and parameters affecting dispersion such as initial yaw/pitch rates,yaw/pitch dampening,plane start angle,launch spin,clearance,centre of gravity shift,dynamic imbalance angle,cross wind,etc.are observed and,later on,studied in detail by extensive External Ballistics Monte Carlo(EBMC)simulation and Six Degree of Freedom(6-DOF)trajectory analysis.In Bore Balloting Motion simulation shows that reduction in residual spin by about 5%results in drastic56%reduction in first maximum yaw.A correlation between first maximum yaw and residual spin is observed.Results of data analysis are used in design modification for existing ammunition.Number of designs are evaluated numerically before freezing five designs for further soundings.These designs are critically assessed in terms of their comparative performance during In-bore travel&external ballistics phase.Results are validated by free flight trials for the finalised design. 展开更多
关键词 APFSDS dispersion CONSISTENCY Accuracy Yaw rate Spin MUZZLE JUMP factor In-bore dynamics Monte Carlo simulation
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Dispersion mechanism of nano-magnetite coated with oleate in aqueous carrier 被引量:1
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作者 胡岳华 刘建平 +1 位作者 徐竸 王淀佐 《Journal of Central South University of Technology》 EI 2008年第5期663-668,共6页
To investigate dispersion mechanism of water-based ferrofluid, the effects of electrolytes on the dispersibility of ferrofluid in the dispersing system with different pH values were discussed. The ζ-potential of magn... To investigate dispersion mechanism of water-based ferrofluid, the effects of electrolytes on the dispersibility of ferrofluid in the dispersing system with different pH values were discussed. The ζ-potential of magnetic nano-particles was measured to discover the adsorbent state of oleate group on the surface of magnetite particles. The mechanism that coexisting electrolyte influences the dispersibility was studied. The results show that the electrolyte affects the stability of ferrofluid through an effect on the structure of surfactant bilayer adsorption, which was proved by ζ-potential measured. The associated mechanism of steric and electrostatic is dominant in aqueous ferrofluid. 展开更多
关键词 nano-magnetite ELECTROLYTE DISPERSIBILITY ζ-potential dispersion mechanism
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Experiences in using gas dispersion measurements to evaluate metallurgical performance of scavenger cleaner and recleaner circuit at Vale's Thompson Mill 被引量:1
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作者 刘洪均 张炜 孙春宝 《Journal of Central South University》 SCIE EI CAS 2014年第10期3955-3962,共8页
The performance of a flotation circuit is largely the result of the operator's response to visual clues. This includes manipulation of the gas input and how it is distributed to cells in a bank. A new gas dispersi... The performance of a flotation circuit is largely the result of the operator's response to visual clues. This includes manipulation of the gas input and how it is distributed to cells in a bank. A new gas dispersion technology was presented which was conducted to perform characterization tests in Outokumpu 30 m3 and 50 m3 flotation cells installed at Thompson Vale's concentrator, and subsequent data analysis. The experimental program was designed to establish "as-found" baseline conditions for each cell of the two-parallel banks in the scavenger-cleaner and recleaner circuit, to select and characterize one typical cell in the two banks with either different frother concentrations or different air flow rates, and establish what variables can be manipulated in future characterization work. A three-parameter model was developed in order to link the bubble size and frother concentration. This relationship can be used to correlate gas dispersion change to improved metallurgical performance. 展开更多
关键词 bubble size bubble size distribution bubble surface area flux gas dispersion
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Discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels 被引量:1
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作者 Akiyuki Takahashi Shota Sato 《Journal of Central South University》 SCIE EI CAS 2014年第4期1249-1255,共7页
A discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels was described. Parametric dislocation dynamics(PDD) simulation of the interaction between an edge dis... A discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels was described. Parametric dislocation dynamics(PDD) simulation of the interaction between an edge dislocation and randomly distributed spherical dispersoids(Y2O3) in bcc iron was performed for measuring the influence of the dispersoid distribution on the critical resolved shear stress(CRSS). The dispersoid distribution was made using a method mimicking the Ostwald growth mechanism. Then, an edge dislocation was introduced, and was moved under a constant shear stress condition. The CRSS was extracted from the result of dislocation velocity under constant shear stress using the mobility(linear) relationship between the shear stress and the dislocation velocity. The results suggest that the dispersoid distribution gives a significant influence to the CRSS, and the influence of dislocation dipole, which forms just before finishing up the Orowan looping mechanism, is substantial in determining the CRSS, especially for the interaction with small dispersoids. Therefore, the well-known Orowan equation for determining the CRSS cannot give an accurate estimation, because the influence of the dislocation dipole in the process of the Orowan looping mechanism is not accounted for in the equation. 展开更多
关键词 parametric dislocation dynamics oxide dispersion strengthened steel Orowan mechanism critical resolved shear stress dislocation dipole
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THE GEOTHERMAL PULSE OF HOT-SPOT AND ITS DISPERSION PROCESS OVER CHINA-INDIA-BURMA AND CHANGE OF SHORT-TERM CLIMATE
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作者 Liu Yanxiang,Tang Maocang 《地学前缘》 EI CAS CSCD 2000年第S1期376-376,共1页
The great gorge of Yarlung Zangbo river is a hot\|spot over earth has been proved by the gravity, geomagnetic, geological, geothermal heat and atmospheric data. Some substances often surge from mantle to the earth sur... The great gorge of Yarlung Zangbo river is a hot\|spot over earth has been proved by the gravity, geomagnetic, geological, geothermal heat and atmospheric data. Some substances often surge from mantle to the earth surface, which process is not constant and has obvious pulse, characterized by ground temperature over hot\|spot region where is a apparent positive relation in correlation map of the variations of Zedang’s temperature (at 3 2m) in stations over China from 1965 to 1992. It can bring more precipitation here. Out of from the hot spot, there are positive and negative axes around the hot\|spot and to arrange in circular waves with same distance. The average distant of the axes is about 820km, which prove the pulse propagation would infect the distribution of summer precipitation in China. In the hot\|spot region, the geothermal heat pulse propagation has preference direction. So, it has obvious contribution for summer precipitation in South Ch ina. 展开更多
关键词 GEOTHERMAL PULSE hot\|spot dispersion CLIMATE
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The Effect of Gum Arabic on the Dispersion of Cement Pastes
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作者 ZHAO Cuiting ZHAO Qinglin +1 位作者 ZHANG Yulin ZHOU Mingkai 《矿物学报》 CAS CSCD 北大核心 2013年第S1期141-141,共1页
Gum arabic, an inexpensive dispersant widely used in the food industry, has great potential for application in building materials. In order to find out the dispersion effect of gum arabic and the factors influencing t... Gum arabic, an inexpensive dispersant widely used in the food industry, has great potential for application in building materials. In order to find out the dispersion effect of gum arabic and the factors influencing the holding capacity of gum arabic in cement during hydration, rheological properties of cement paste with added gum arabic were assessed in this paper. The results show that 0.10wt%-0.60wt% of gum arabic positively affects dispersion, lower dosages have negligible effect. High speed mixing is required to maintain the dispersion stability of gum arabic in cement paste. The optimum dosage of gum arabic to achieve best disperse-holding capacity of cement paste was 0.3wt%, and the minimum water-cement ratio needed to obtain a dispersion effect was 0.28. 展开更多
关键词 gum ARABIC dispersion RHEOLOGICAL PROPERTY FLUIDITY STERIC hindrance
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Dispersion of SiC particles in mechanical stirring of A356-SiC_p liquid
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作者 张君 张鹏 +1 位作者 杜云慧 姚莎莎 《Journal of Central South University》 SCIE EI CAS 2012年第6期1503-1507,共5页
In order to clarify the dispersion of SiC particles in straight-blade mechanical stirring of A1-SiCp liquid, the dispersion of SiC particles in A356-3.5% SiCp (volume fraction) liquid in a cylindrical crucible was s... In order to clarify the dispersion of SiC particles in straight-blade mechanical stirring of A1-SiCp liquid, the dispersion of SiC particles in A356-3.5% SiCp (volume fraction) liquid in a cylindrical crucible was studied. The relationship between rotating speed of stirrer and radial relative deviation of SiCp content in A356 liquid between the center and the periphery of crucible was established in the conditions of 35° for the gradient angle a of blade and 10 mm/s for the speed of moving up and down of stirrer. The results show that the radial relative deviation of SiCp content increases gradually with increasing the rotating speed of stirrer. When the rotating speed of stirrer is 200 r/min, the vertical dispersion of SiC particles in A356 liquid is even, but the radial relative deviation of SiCp content is 0.24. Consequently, the northomogeneous dispersion of SiC particles in A356 liquid is mainly resulted from the nonhomogeneous radial dispersion of SiC particles. 展开更多
关键词 dispersion straight-blade mechanical stirring A356-SiCp liquid
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Dispersion of ultrafine alumina in modifier solution ——the role of polar interfacial interaction
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作者 HU Yue hua 1,QIU Guan zhou 1,J.D.Miller 2 (1.Department of Mineral Engineering, Central South University, Changsha 410083, China 2.Department of Metallurgical Engineering, University of Utah, 412 WBB, Salt Lake City, UT 84112, USA) 《Journal of Central South University of Technology》 2001年第1期18-23,共6页
Dispersion of ultrafine alumina suspension is examined by using particle size analyzer. The zeta potential and contact angle measurements were used to discuss the electrokinetic behavior and surface wettability of alu... Dispersion of ultrafine alumina suspension is examined by using particle size analyzer. The zeta potential and contact angle measurements were used to discuss the electrokinetic behavior and surface wettability of alumina in modifier solution, and to calculate the electrostatic interaction forces and interfacial interaction forces between alumina particles. The aggregation of ultrafine alumina occurs near its PZC. Addition of modifier increases the zeta potential of alumina and its surface hydrophilicity, resulting in increase of electrostatic and hydration repulsion. It makes the suspension of ultrafine alumina completely dispersed. The average particle size of the suspension is decreased from 1.73 μm in absence of modifier to 0.8 μm in the presence of tripolyphosphate. According to polar interfacial interaction approach, the hydration forces responsible for the stability of alumina suspension in the presence of modifier have also been obtained. The extended DLVO theory is successful to describe the dispersion behavior of ultrafine alumina in modifier solution. 展开更多
关键词 dispersion ALUMINA MODIFIER polar interfacial interaction extended DLVO theory
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Random walk dispersion model for missile contrail particles in cross-airspace environments
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作者 Chenshuo Li Debin Fu Tianyu Wei 《Defence Technology(防务技术)》 2025年第7期307-320,共14页
Missiles provide long-range precision strike capabilities and have become a cornerstone of modern warfare.The contrail clouds formed by missile during their active flight phase present significant chal-lenges to high-... Missiles provide long-range precision strike capabilities and have become a cornerstone of modern warfare.The contrail clouds formed by missile during their active flight phase present significant chal-lenges to high-altitude environmental observation and target detection and tracking.Existing studies primarily focus on specific airspace regions,leaving critical gaps in understanding the effects of long dispersion times,wide altitude ranges,and variable atmospheric conditions on missile contrail clouds.To address these gaps,this article develops a numerical method based on the Lagrangian random walk model,which incorporates various velocity variation terms,including particle velocity caused by the difference of wind field,by the thermal motion of local gas molecules and by random collisions between contrail cloud particles to capture the influence of environmental wind fields,atmospheric conditions,and particle concentrations on the motion of contrail cloud particles.A general coordinate system aligned with the missile's flight trajectory is employed to represent particle distribution characteristics.The proposed method is in good agreement with the conducted experiments as well as with the available numerical simulations.The results demonstrate that the proposed model effectively simulates the dispersion state of contrail clouds,accurately reflecting the impact of large-scale wind field variations and altitude changes with high computational efficiency.Additionally,simulation results indicate that the increased distance between gas molecules in rarefied environments facilitates enhanced particle dispersion,while larger particles exhibit a faster dispersion rate due to their greater mass. 展开更多
关键词 Missile contrail dispersion process Random walk model Concentration distribution Cross-airspace
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Regulating the Fe/Mo ratio of FeMoO_(x)/LaTiO_(y) to boost aerobic oxidative desulfurization of diesel
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作者 ZHANG Fengren YAN Ying +6 位作者 LIU Feng WU Yang LIANG Shuqin CHENG Huifang HAN Shanlei LIU Jixing ZHU Wenshuai 《燃料化学学报(中英文)》 北大核心 2025年第8期1255-1268,共14页
Catalytic oxidation desulfurization(CODS)technology has shown great promise for diesel desulfurization by virtue of its low cost,mild reaction conditions,and superior desulfurization performance.Herein,a series of FeM... Catalytic oxidation desulfurization(CODS)technology has shown great promise for diesel desulfurization by virtue of its low cost,mild reaction conditions,and superior desulfurization performance.Herein,a series of FeMoO_(x)/LaTiO_(y)-z samples with diverse Fe/Mo ratios were prepared via a facile citric acid-assisted method.The impact of Fe incorporation on the dispersion and surface elemental states of Mo species,as well as oxygen species content of the synthesized FeMoO_(x)/LaTiO_(y)-z catalysts were systematically characterized using TEM,BET,UV-vis DRS,XPS,XANES,and reaction kinetics,and their CODS performances were examined for 4,6-DMDBT removal.Experimental results demonstrated that Fe/Mo ratio significantly affected the Ti−O bond strength,surface dispersion and electronic structure of Mo O_(2)species on FeMoO_(x)/LaTiO_(y)-z catalysts.FeMoO_(x)/LaTiO_(y)-2 catalyst showed outstanding cycling durability and the best CODS performance with almost 100%removal of 4,6-DMDBT from model oil within 75 min due to its proper MoO3 dispersion,optimal redox property,and the most oxygen vacancy concentration.Nevertheless,further enhancing Fe content led to the increased dispersion of Mo species,while the decrease active Mo species as well as the increase of steric effect for 4,6-DMDBT accessing to the catalytic reactive sites considerably increase the apparent activation energy of FeMoO_(x)/LaTiO_(y)-z(z>2)catalysts during the CODS process,thereby seriously suppressing their CODS performances.Moreover,Radical trapping experiments reveal that the·,generated by the activation of O_(2)at the active sites,catalytic oxidized 4,6-DMDBT to the product of 4,6-DMDBTO_(2),thereby enabling both deep desulfurization and recovery of high-value 4,6-DMDBTO_(2).These findings offer an alternative strategy to achieve ultra deep desulfurization as well as separate and recover high economic value sulfone substances from diesel. 展开更多
关键词 catalytic oxidation desulfurization FeMoO_(x)/LaTiO_(y)catalyst Ti−O bond dispersion reaction kinetics
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Study on concentration distribution and detonation characteristics for non-axisymmetric fuel dispersal 被引量:2
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作者 Linghui Zeng Zhongqi Wang +1 位作者 Xing Chen Jianping Li 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期484-495,共12页
The study of non-axisymmetric fuel dispersal and detonation can provide reference for the prevention of industrial cloud explosion accidents and the design of fuel air explosive(FAE).The concentration and detonation f... The study of non-axisymmetric fuel dispersal and detonation can provide reference for the prevention of industrial cloud explosion accidents and the design of fuel air explosive(FAE).The concentration and detonation fields of 85 kg cylindrical and fan-shaped fuel are investigated by experiments and numerical simulations.A dynamic model of the whole process for fuel dispersal and detonation is built.The concentration distribution of fuel is used as the initial condition to calculate the detonation stage,thus solving the initial value problem of detonation field.The phase and component changes of fuel cloud at different locations are compared.The fuel cloud is divided into directions of 0°,90°,135°and 180°.The results show that the maximum cloud radius is 20.94 m in 135°and the minimum is 12.04 m in 0°.The diameter of the detonation fireball is 53.6 m,and the peak temperature is 3455 K.The highest peak overpressure is 3.44 MPa in 0°and the lowest is 2.97 MPa in 135°.The proportion of liquid phase in 0°is22.90%,and the fuel loss is 11.8% and 9% higher than that in 135°and cylindrical charge,respectively.The stable propagation distance of blast wave in 135°is 42.50% longer than 0°and 28.37% longer than cylindrical charge. 展开更多
关键词 Fuel dispersal Concentration distribution Detonation characteristic Fuel loss Numerical simulation
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New insights in nano-copper chromite catalyzing ultrafine AP:Evaluation of dispersity and mixing uniformity
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作者 Yong Kou Peng Luo +8 位作者 Lei Xiao Yanping Xin Guangpu Zhang Yubing Hu Junqing Yang Hongxu Gao Fengqi Zhao Wei Jiang Gazi Hao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期120-133,共14页
Improving the application of nanomaterials has always been a research hotspot in the field of energetic materials(EMs)due to their obvious catalytic effect on the EMs,especially the uniformly dispersed nanomaterials.H... Improving the application of nanomaterials has always been a research hotspot in the field of energetic materials(EMs)due to their obvious catalytic effect on the EMs,especially the uniformly dispersed nanomaterials.However,few studies have reported the dispersion of nanomaterials.In this study,the dispersity and mixing uniformity of nano-CuCr_(2)O_(4)was evaluated based on the difference of solid UV light absorption between the nano-catalytic materials and EMs.The nano-CuCr_(2)O_(4)/ultrafine AP composites with different dispersity of nano-CuCr_(2)O_(4)were prepared by manual grinding and mechanical grinding with different grinding strength and griding time.And then,the absorbance of different samples at 212 nm was obtained by solid UV testing due to the high repeatability of the absorbance at 210-214 nm for three parallel experiments,and the dispersity of different samples was calculated through the established difference equation.Furthermore,the samples were characterized by XRD,IR,SEM,EDS,DSC and TG-MS,which confirmed that different mixing methods did not change the structure of the samples(XRD and IR),and the mixing uniformity improved with the increase of grinding strength and grinding time(SEM and EDS).The scientificity and feasibility of the difference equation were further verified by DSC.The dispersity of nano-CuCr_(2)O_(4)exhibits a positive intrinsic relationship with its catalytic performance,and the uniformly dispersed nano-CuCr_(2)O_(4)significantly reduces the thermal decomposition temperature of ultrafine AP from 367.7 to 338.8℃.The TG-MS patterns show that the dispersed nano-CuCr_(2)O_(4)advanced the thermal decomposition process of ultrafine AP by about 700 s,especially in the high temperature decomposition stage,and the more concentrated energy release characteristic is beneficial to further enhance the energy performance of AP-based propellants.The above conclusions show that the evaluation method of dispersity based on solid UV curves could provide new ideas for the dispersity characterization of nano-catalytic materials in EMs,which is expected to be widely used in the field of EMs. 展开更多
关键词 Nano-CuCr_(2)O_(4) Ultrafine AP Dispersity UVeVis diffuse reflectance spectroscopy Thermal decomposition
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